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69 views10 pages

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Shashwat Pandey
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Test - 02 11th JEE Main

DURATION : 180 Minutes DATE : 27/10/2024 M.MARKS : 300

Topics Covered
Physics: Motion in a Plane, Newton law of Motion
Chemistry: Chemical Bonding and Molecular Structure, Classification of Elements and Periodicity in Properties
Mathematics: Quadratic Equations, Complex Number-I, Sequence and Series

General Instructions:
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 75 questions. The maximum marks are 300.
4. There are three Sections in the question paper, Section I, II & III consisting of Section-I (Physics), Section-II
(Chemistry), Section-III (Mathematics) and having 25 questions in each part in which first 20 questions are of
Objective Type and Last 5 questions are integers type and all 25 questions are compulsory.
5. There is only one correct response among 4 alternate choices provided for each objective type question.
6. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
9. Do not fold or make any stray mark on the Answer Sheet (OMR).
OMR Instructions:
1. Use blue/black dark ballpoint pens.
2. Darken the bubbles completely. Don't put a tick mark or a cross mark where it is specified that you fill the bubbles
completely. Half-filled or over-filled bubbles will not be read by the software.
3. Never use pencils to mark your answers.
4. Never use whiteners to rectify filling errors as they may disrupt the scanning and evaluation process.
5. Writing on the OMR Sheet is permitted on the specified area only and even small marks other than the specified area
may create problems during the evaluation.
6. Multiple markings will be treated as invalid responses.
7. Do not fold or make any stray mark on the Answer Sheet (OMR).

Name of the Student (In CAPITALS) : _______________________________________________________________

Roll Number : _____________________________________________________________________________________________

OMR Bar Code Number : ________________________________________________________________________________

Candidate’s Signature : _______________________________ Invigilator’s Signature _____________________

[1]
IMPORTANT CONSTANTS

Speed of light in free space, : 3.00 × 108 ms–1


Permeability of free space, : 4 × 10–7 Hm–1
Permittivity of free space, : 8.85 × 10–12 Fm–1
The Planck constant, : 6.63 × 10–34 Js
Rest mass of electron, : 9.1 × 10–31 kg
Rest mass of proton, : 1.67 × 10–27 kg
Molar gas constant, : 8.31 JK–1 mol–1
The Avogadro constant, : 6.02 × 1023 mol–1
The Boltzmann constant, : 1.38 × 10–23 JK–1
Gravitational constant, : 6.67 × 10–11 N m2kg–2
Acceleration of free fall : 9.8 ms–2
Rydberg Constant : 1.097 × 107 m–1
Atomic mass unit : 1.67 × 10–27 kg
Charge on proton : 1.6 × 10–19 C

IMPORTANT VALUES

2 = 1.414 ln 10 = 2.303
3 = 1.732 log102 = 0.3010
5 = 2.236 log103= 0.4770
 = 3.142 log107 = 0.845
e (Euler’s constant) = 2.718

* Use above values unless otherwise specified in a question.


❑❑❑

[2]
SECTION-I (PHYSICS)
Single Correct Type Questions 2
(2) If   friction, on bead is kinetic
1. At a moment a car is travelling with linear 
velocity v on a circular road of radius r. If the
2
speed is increasing at the rate of ‘a’ metre/sec2, (3) If   friction, is static

then the resultant acceleration of car at that
(4) If bead does not slide relative to rod, then
moment, will be-
friction will not exist between bead and rod
 v2 2
 2 − a  m/sec
2
(1)
 r  4. A block of mass 5.0 kg slides down from the top
of an inclined plane of length 3 m. The first 1 m
 v4 2
 2 + a  m/sec
2
(2) of the plane is smooth and the next 2 m is rough.
 r  The block is released from rest and again comes
 v4 2
to rest at the bottom of the plane. If the plane is
 2 − a  m/sec
2
(3) inclined at 30 with the horizontal, find the
 r 
coefficient of friction on the rough portion
 v2 2
 2 + a  m/sec
2
(4)
 r 

2. A body A is dropped from a height h above the


ground. At the same time another body B at a
horizontal distance d from the line of motion of A, 2 3
(1) (2)
is fired from the ground at an angle  to the 3 2
horizontal. If the two collide at the highest point
3 3
of the trajectory of B, the angle of projection is (3) (4)
4 5
given by

5. A particle starts from the origin at t = 0 and moves


in the xy plane with constant acceleration a in the
y-direction and with uniform velocity in x-
direction. Its equation of motion is y = bx2 where
d  b is constant. The x-component of its velocity is
(1)  = tan −1  
 
h  2a 
(1) Variable (2)  
h  b 
(2)  = sin −1  
 
d
a  a 
−1 
h (3) (4)  
(3)  = tan   2b  2b 
d 
h
(4)  = cos −1   6. A projectile is projected from the base of a hill
 
d
whose shape is that of right circular cone, whose
axis is vertical. The projectile grazes the vertex
3. A bead of mass m is constrained to move on rod
and strikes the hill again at a point on the base. If
in gravity free space as shown in figure. Initially
 be the semi-vertex angle of the cone and  is
the rod and the bead are stationary. Now the rod is
the angle of projection from horizontal, then value
rotated with constant angular acceleration α about
of  will be
its end A. μ is coefficient of friction. Rod rotates
(1) tan–1 (2tan)
in the plane of paper. If at an instant the angular
(2) tan–1 (2cot)
velocity of rod is ω then for that instant
 cot  
(3) tan −1  
 2 
 tan  
2 (4) tan −1  
(1) If   friction, on bead is static in nature  2 

[3]
7. A heavy uniform chain lies on a horizontal table. The river flows towards east. Which of the
If the co-efficient of friction between the chain following is true?
and table surface is 0.25, then the maximum
fraction of length of the chain, that can hang over
one edge of the table is
(1) 0.20
(2) 0.25
(3) 0.35
(4) 0.15
(1) Swimmers A and B cannot collide
(2) Swimmers A and B will definitely collide
8. With forces F1 and F2 applied on a system as somewhere on line connecting points A & B
shown in figure, match the following : (g = 10 (3) Swimmers A and B will definitely collide
m/s2) somewhere to the east of line connecting
points A & B
(4) Swimmers A and B will definitely collide
somewhere to the west of line connecting
points A & B

11. On a table, three blocks (including the first block)


are placed as shown in the figure. Mass of each
block is m and coefficient of friction for each
Column-I Column-II block is μ. A force F is applied on the first block
so as to move the system. The minimum value of
A Acceleration of 2 kg block (in P 5 F should be
m/s2)
B Acceleration of 3 kg block (in Q 50
m/s2)
C Normal reaction between 2 kg R 45 (1) 8μmg (2) 9μmg
(3) 7μmg (4) 5μmg
and 3 kg (in N)
D Normal reaction between 3 kg S 60 12. A man in a motorboat wants to reach the point B
and 5 kg (in N) from point A. Point B is on opposite bank of a
T zero river of width a as shown in figure. The river flow
A B C D speed is v0 . At what minimum speed w.r.t. water
(1) P P S S should the boat travel to reach the point B?
(2) P T R Q
(3) P P T T
(4) T P R R

9. A projectile is projected with initial velocity b a


( 6iˆ + 8 ˆj ) m/s. Minimum time after which its (1) v0
a 2 + b2
(2) v0
a 2 + b2
velocity becomes parallel to the line b a
(3) v0   (4) v0  
(
4y – 3x + 2 = 0, is g = − 10 ˆj m / s 2
) a b

7 7 13. Figure shows a block of mass m placed on a


(1) s (2) s
12 40 bracket of mass M. Bracket-block system is
7 7 moved downward with constant velocity on an
(3) s (4) s incline. What is magnitude of total force of
20 10
bracket on block?
10. Figure shows two swimmers starting from point A
and B on opposite banks. They started at same
instant with constant velocities with respect to the
river. Both of them are swimming with respect to
the river in a direction parallel to line AB always. (1) Zero (2) mg sin θ
(3) mg cos θ (4) mg

[4]
14. A smooth ring P of mass m can slide on a fixed
horizontal rod. A string tied to the ring passes
over a fixed pulley and carries a block Q of mass
(m/2) as shown in the figure. At an instant the
system is released when, the string between the
ring and the pulley makes an angle 60° with the (1) 12 (2) 15
rod. The acceleration of the ring at that instant is (3) 10 (4) 20

18. A particle is moving with velocity v = K ( y iˆ + x ˆj ) ,


where K is a constant. The general equation for its
path is:
(1) y = x2 + constant
(2) y2 = x + constant
(3) xy = constant
2g 2g (4) y2 = x2 + constant
(1) (2)
3 5
2g g 19. In the given figure, what is the reading of the
(3) (4)
9 3 spring balance? (g = 10m/s2)

15. A block of mass m = 2kg is resting on a horizontal


surface. Coefficient of friction is µ = 0.5. A force
F = 15N is applied on the block in horizontal
direction. The speed of the block after it has
(1) 10 N (2) 20 N
travelled through a distance of 4 m, is (g =10
(3) 5 N (4) Zero
m/s2)
(1) 2 5 ms–1 (2) 5 2 ms–1 20. A cart is sliding on a smooth incline. An observer
–1
(3) 4 3 ms (4) None of these (O1) fixed to cart and another observer (O2) fixed
on ground observe, a loose bolt that is released
16. STATEMENT-1 : Two stones are simultaneously from ceiling. At the instant of release cart has
projected from level ground from same point with velocity v0 as seen by O2. Mark the correct option.
same speeds but different angles with horizontal. (1) Trajectory of bolt for O1 is parabola
Both stones move in same vertical plane. Then the
(2) Trajectory of bolt for O2 is straight line
two stones may collide in mid air.
inclined at an angle θ with vertical
STATEMENT-2 : For two stones projected
(3) Trajectory of bolt for O2 is a straight line
simultaneously from same point with same speed
at different angles with horizontal, their perpendicular to ceiling of cart
trajectories may cross at some point. (4) Trajectory of bolt for O1 is straight line
(1) STATEMENT-1 is true, STATEMENT-2 is
true and STATEMENT-2 is correct Integer Type Questions
explanation for STATEMENT-1 21. Two particles p1 and p2 are projected
(2) STATEMENT-1 is true, STATEMENT-2 is simultaneously on an inclined plane with same
true and STATEMENT-2 is not correct speeds at equal angles α = 30° with the inclined
explanation for STATEMENT-1 plane as shown in the figure, if the angle of the
(3) STATEMENT-1 is true, STATEMENT-2 is inclined plane with the horizontal is θ = 30°, then
false the value of ratio of time of flights of p1 to that of
(4) STATEMENT-1 is false, STATEMENT-2 is p2 is _____
true

17. If the projectile, projected from A with initial


speed u as shown, strike the plane OB at point B
normally. If OA = OB = 20 m, find u (in m/s)

[5]
22. A particle is projected obliquely from origin with 24. Block B is moving towards right with constant
1 velocity v0. Magnitude of velocity of block A with
speed 12 5 m/s at an angle tan −1   with X
2 v
respect to block B is 0 . Value of x is______.
axis in a vertical X-Y plane in a region of space x
where acceleration due to gravity makes an angle
53° with the negative Y-axis as shown in figure.
The maximum possible X-coordinate of the (Assume all pulleys and strings are ideal)
particle till the time it crosses the X-axis is p
metre. Find the value of p. (g = 10 m/s2) 25. Reading shown in two spring balances S1 and S2 is
90 kg and 30 kg respectively when lift; is
accelerating upwards with acceleration 10 m/s2.
The mass is stationary with respect to lift. Then
the mass of the block will be______kg. (g = 10
m/s2)

23. If block A shown is moving with speed 4 3m/s as


observed by a person on ground then the
magnitude of velocity of A with respect to the
block B is (the wedge is fixed)______ m/s

SECTION-II (CHEMISTRY)
Single Correct Type Questions 29. The ion that has sp3d2 hybridization of the central
26. Consider the following statements. atom, is
(I) Element with atomic number 43 belongs to (1) [ICl2]– (2) [IF6]–
d-block.
(II) 64Gd is present in group 3. (3) [BrF2]– (4) [ICl4]–
(III) Se has two unpaired electrons in p-subshell.
The correct statement(s) is(are) 30. Following transformations are carried out.
(1) Only (III) (2) Only (I) & (II) NO ⎯→ NO+ + e– ...(I)
(3) Only (I) & (III) (4) (I), (II) & (III) CN + e ⎯→ CN
– –
...(II)
27. The alkaline earth metal halide (X = Cl, Br, I) Which of the following statement is correct?
having maximum covalent character is (1) Bond order is increased in (I) but decreased in
(1) BeX2 (2) SrX2 (II)
(3) CaX2 (4) MgX2 (2) Bond order is decreased in (I) but increased in
(II)
28. Among the following, choose the incorrect (3) Bond order is increased in both cases
statement. (4) Bond order is decreased in both cases
(1) SiF4 is non-polar whereas SF4 is polar
(2) I3− is linear 31. In which one of the following changes, bond
Cl
order and magnetic moment both increases?
(1) O2 → O2+ (2) N2 → N2–
(3) has more magnitude of dipole
(3) B2 → B2+ (4) C2 → C2–
Cl
Cl
32. Bond distance in HF is 9.17 × 10–11 m. Dipole
moment of HF is 6.104 × 10–30 C m. The
moment than that of percentage ionic character in HF will be
(1) 61.0% (2) 38.0%
(4) ClF3 is polar (3) 35.5% (4) 41.6%

[6]
33. The correct order of increasing s-character (in 39. In which one of the following groups all the
percentage) in the hybrid orbitals of central atom members have linear shape?
in following molecules/ions is (consider (1) NO 2 , N3− , ICl+2
s-character is equally distributed between bond-
(2) N3− , I3− , NO +2
pairs and lone-pairs)
(3) XeF2 ,C2 H 2 ,SO 2
(I) CO32− (II) XeF4
(4) CO 2 , BeCl2 ,SnCl2
(III) I3− (IV) NH3
(V) NO +2 40. Given below are two statements, one is labelled
as Assertion(A) and the other is labelled as
(1) II < III < IV < I < V
Reason (R)
(2) II < IV < III < V < I
Assertion(A): Bond energy of Cl − Cl bond is
(3) III < II < I < V < IV
more than F − F bond.
(4) II < IV < III < I < V
Reason(R): Shorter the bond length, more is the
bond energy.
34. In which one of the following pairs, the dipole
In the light of above statements choose the
moment of first species is greater than second?
correct option
(1) NH3, NF3
(1) A is correct, R is correct & R is the correct
(2) BF3, BCl3
explanation of A.
(3) trans-But-2-ene, cis-But-2-ene
(2) A is correct, R is correct but R is not the
correct explanation of A.
(3) A is correct and R is incorrect.
(4) (4) A is incorrect and R is correct.

41. With respect to periodic properties, the correct


statement from the following is
35. In which one of the following molecules, the (1) 1st Electron affinity order is F > O > Cl
O – O bond length is shortest? (2) First ionisation energy order is Al > Mg > K
(1) O3 (3) Atomic radii order is N > P > As
(2) O2 (4) Ionic radii order is K+ > Ca2+ > Mg2+
(3) H2O2
42. Match the atomic number given in Column-I with
(4) KO2
the IUPAC names given in Column-II
Column-I Column-II
36. In which one of the following options, bond
angles are correctly matched? A 101 P Ununoctium
Bond angle: 120° 107.5° 110.9°
B 106 Q Ununpentium
(1) N(SiH3)3 N(CH3)3 NH3
(2) N(CH3)3 NH3 N (SiH3)3 C 115 R Unnilhexium
(3) N(SiH3)3 NH3 N(CH3)3
D 118 S Unnilunium
(4) N(CH3)3 N(SiH3)3 NH3
Choose the correct answer form the codes given
37. Regarding the structure of compound, below.
PBr2Cl(CH3)2, which one of the following A B C D
statements is correct? (1) Q S P R
(1) Both CH3 occupy axial position. (2) P R Q S
(2) Both Br occupy axial position. (3) S R Q P
(3) One Cl and one Br occupy axial position. (4) R S P Q
(4) One CH3 and one Br occupy axial position.
43. The correct order of 3rd ionisation enthalpy for
38. The increasing order of bond angles in OF2,
Mg, Al, Si and P is
OCl2, ClO2 and H2O is
(1) OF2 < H2O < OCl2 < ClO2 (1) Mg  Al  P  Si
(2) H2O < OF2 < ClO2 < OCl2 (2) Mg  Si  P  Al
(3) OF2 < OCl2 < H2O < ClO2 (3) P  Si  Al  Mg
(4) OCl2 < OF2 < ClO2 < H2O
(4) P  Al  Si  Mg

[7]
44. Correct order of ionic size is 47. A third period element has successive ionisation
(1) Be2+ ~~ Li +  Na +  Mg 2+ enthalpies as 1000, 2000, 3000, 5000, 6200,
21200 kJ mol–1. Maximum covalency is x and
(2) Be2+  Mg 2+ ~~ Li +  Na + maximum oxidation state is y. Then, the value of
(3) Mg 2+  Na +  Be 2+  Li + x · y is_______.
(4) Li +  Be2+  Mg 2+  Na +
48. Among NO,CN − , H 2 , He 2+ , Li 2 , B2 ,C 2 , N 2 ,

45. From the following, identify the incorrect O −2 , NO + ,O 22− and F2, the number of diamagnetic
statement. species is_______.
(1) Van der waal’s radius of iodine is more than
its covalent radius 49. How many of the following species contain one
(2) IE1 of nitrogen is greater than that of or more lone pair(s) on central atom, that is
oxygen while IE 2 of oxygen is higher than present in an orbital having contribution from
d-orbital?
that of nitrogen
(3) 1st Electron affinity of oxygen is less than
SOF4 SeOCl2 SeF3+ ICl−4
sulphur XeF5+ XeOF4 TeF5−
(4) Na has a positive 1st electron gain enthalpy

50. An element has electronic configuration


Integer Type Questions
46. Three elements X, Y and Z follow Dobereiner’s [Kr]4d75s2. On the basis of this electronic
Triad rule in the given sequence. If the atomic configuration, the group number of element
weights of X and Y are 10 and 26 (g/mol) according to modern periodic table is______.
respectively, then atomic weight of Z will be (in
g/mol)________.

SECTION-III (MATHEMATICS)
Single Correct Type Questions  7 + 33 
(3)  ,  
1 1 1 4 2
51. It is given that 4 + 4 + 4 + .... to  = .  
1 2 3 90
 7 − 33 
1 1 1 (4)  −, 
Then 4 + 4 + 4 + .... to  is equal to
 2 
1 3 5
4 4
(1) (2) 54. If a, b, c are in G.P. and a – b, c – a, b – c are in
96 45
H.P., then the value of a + 4b + c is equal to
894 4 (1) 1 (2) 0
(3) (4)
90 180 (3) 2abc (4) b2 + ac

52. If a, b, c, d are in G.P., then (a2 + b2 + c2) (b2 + c2 55. Let , ,  be roots of the cubic x3 + ax + a = 0
+ d2) equals to where a  R – {0}, then the value of ( + ) –1 +
(1) ab + bc + cd (2) (ab + bc + cd)2 ( + ) –1 + ( + ) –1 is equal to
(3) (ab + bc + cd) (4) (ab + bc + cd)1/2
4
(1) 0 (2) –1
(3) 1 (4) a2
53. The value of p for which both roots of the
quadratic equation 2x2 – 2(1 + 2p)x + p(1 + p) = 56. If a2 + b2 = 23ab (a, b > 0), then A.M. of lna and
0 (p  R) are smaller than 2 is lnb is equal to
 7 − 33   7 + 33  1 a+b
(1)  −,   ,   (1) ln(a + b) (2) ln  
 2   2  2  25 
 7 − 33 7 + 33  a+b 1 a+b
(2)  ,  (3) ln   (4) ln  
 2 2   5  2  5 

[8]
57. The sum to 50 terms of the series 64. If z1 = –3 + 5i ; z2 = –5 – 3i and z is a complex
1 3 7 15 number lying on the line segment joining z1 and
+ + + + ...., is
2 4 8 16 z2, then arg(z) can be :
(1) 250 – 51 (2) 1 – 2–50 3 
(1) − (2) −
(3) 2–50 + 49 (4) 250 – 1 4 4
 5
58. The number of imaginary roots of the equation (3) (4)
6 6
(x – 1) (x – 2) (3x – 2) (3x + 1) = 32 is
(1) Zero (2) 1 65. The sum to 10 terms of the series whose nth term
(3) 2 (4) 4
is n2 – 5, is
(1) 230 (2) 335
59. If 2(y – a) is H.M. of y – x and y – z, then x – a, y
(3) 125 (4) 151
– a and z – a are in
(1) A.P. (2) G.P.
(3) H.P. (4) A.G.P. 66. If T1 , T2 , T3 , T4 , .... are in G.P. Such that T1 = 1
and 4T2 + 5T3 is minimum, then common ratio, is
60. Let  be a root of quadratic equation ax + bx + 2
5 2
c = 0 and  be a root of quadratic equation –ax2 + (1) (2)
2 5
bx + c = 0, where a, b, c are real numbers and 0 <
−2 −5
a (3) (4)
 < , a > 0. If the equation x 2 + bx + c = 0 has 5 2
2
a positive root  then which of the following
67. The roots of ax2 + bx + c = 0 are greater than the
must be true?
roots of 2x2 + 3x + 1 = 0 by unity, then
(1)  < min. {, } (2)  > min. {, }
(1) 2b2 = a2 (1 + 4ac)
(3)  <  <  (4)  < –  < 
(2) 2b2 = a2 (1 + 8ac)
(3) 8b2 = a2 (1 + 4ac)
61. Let α, β be real and z be a non-real complex
(4) 4b2 = a2 (1 + 16ac)
number. If z2 + αz + β = 0 has two distinct roots
on line Re(z) = 1, then it is necessary that
(1) β  (–1, 0) (2) |β| = 1 (−1 + i 3)12 (−1 − i 3)12
68. + is equal to
(3) β  (1, ) (4) β  (0, 1) (1 − i )20 (1 + i)20
(1) –8 (2) 8

62. The principal argument of


( )3 + i i5
is
(3) –6 (4) 6

(1 + i 3 ) 69. If the roots of the equation x2 – ax + 2b = 0 are


(where i = −1 ) prime numbers, where a, b are integers, then (b –
  a) is equal to
(1) (2)
3 6 (1) –2 (2) 2
−  (3) –1 (4) 1
(3) (4)
6 2
2
 4i 3 − i 
63. Given a non-constant geometric progression a1, 70. If   = x + iy then (x + y) is equal to
a2, a3 … where S = a1 + a2 + a3 + ⋯ + a10 = 3(a1  2i + 1 
+ a3 + a5 + a7 + a9), then (where, i2 = –1)
S (1) –3
(1) [250,300]
a1 (2) 5
(3) 7
S
(2) [500,550] (4) –5
a1
S Integer Type Questions
(3) [1000,1050]
a1 71. If α, β be the roots of 4x2 – 16x + λ = 0, where λ
S  R, such that 1 < α < 2 and 2 < β < 3, then the
(4) [2000, 2050] number of integral values of λ is
a1

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72. The AM of 2 positive numbers is 9 times their the A.P. and common ratio of the G.P. are equal
HM. The GM of those numbers will be k times to n each, n  N. Number of such terms in this
their HM. The value of k is series which are perfect squares of a natural
number for all n, is
73. If a, b, c and d are four positive real numbers
such that abcd = 1, the minimum value of (1 + a) a b
1 − i 2  i −1 3
 =1= 
(1 + b) (1 + c) (1 + d) is If 
75.  (where a, b are natural
 1+ i   1+ i 
74. rth term of a series is the sum of rth term of an numbers), then minimum value of (a + b) is
A.P. and rth term of a G.P., whose first terms are
equal to one each and the common difference of


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