DATE ® P11-20

30-08-2020

ADVANCED PATTERN CUMULATIVE TEST-2 (ACT-2)

PAPER
TARGET : JEE (MAIN + ADVANCED) 2022

1 COURSE : VIKAAS (JA) | BATCH : 01JA

Time : 3 Hours Maximum Marks : 180

CODE

1 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS TO CANDIDATES
 Question Paper-1 has three (03) parts: Mathematics, Physics and Chemistry.

 Each part has a total twenty (20) questions divided into two (02) sections (Section-1 and Section-2).

 Total number of questions in Question Paper-1 are Sixty(60) and Maximum Marks are One Hundred Eighty (180)

TYPE OF QUESTIONS AND MARKING SCHEMES

SECTION-1 (Maximum Marks : 30)

 This section contains TEN (10) questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

 Marking scheme :

 Full Marks : +3 If ONLY the correct option is chosen.

 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).

 Negative Marks : –1 In all other cases.

SECTION-2 : (Maximum Marks : 30)

 This section contains TEN (10) questions

 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is correct

 Marking scheme :

 Full Marks : +3 If ONLY the correct option is chosen.

 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).

 Negative Marks : –1 In all other cases

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

Resonance Eduventures Limited

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 INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
 Darken the appropriate bubbles on the original by applying sufficient pressure.
 The original is machine-gradable and will be collected by the invigilator at the end of the examination.
 Do not tamper with or mutilate the ORS.
 Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :

 Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
 Darken the bubble COMPLETELY.
 Darken the bubble ONLY if you are sure of the answer.
 The correct way of darkening a bubble is as shown here :
 There is NO way to erase or "un-darkened bubble.
 The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles
are evaluated.
 Zero marks ‘0’ If none of the options is chosen (i.e. the question is unanswered).

FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :

 For example, if answer ‘SINGLE DIGIT’ integer type below :
0 1 2 3 4 5 6 7 8 9
 For example, if answer ‘SINGLE DIGIT’ integer with positive / negative type below :
0
– 1
2
3
4
5
6
7
8
9
 For example, if answer ‘DOUBLEDIGIT’ integer type below :
0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9

FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE :

COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in 3rd or 4th column.
 If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column and 7 in 4th column.
 If answer is, 23 then fill 2 & 3 in 1st and 2nd column respectively, while you can either leave column 3 & 4 or fill ‘0’ in either
of them.

Resonance Eduventures Limited

REGISTERED & CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : 0744-2777777, 0744-2777700 | Toll Free : 1800 258 5555 | FAX No. : +91-022-39167222 | 73400 10333
Website : www.resonance.ac.in | E-mail : [email protected] | CIN: U80302RJ2007PLC024029
 PART :I MATHEMATICS

SYLLALBUS : FOM-I, Quadratic Equation Sequence and Series,

Trigonometry, FOM-II (Except graphical transformation)

SECTION – 1 : (Maximum Marks : 30)

 This section contains TEN (10) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 1 : (vf/kdre vad : 30)
 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u dk mÙkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kk±d gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

| p1 – p 4001 |
4000

 pp
1
1. If p1, p2, p3, ....., p4001 are in A.P. such that  10 and p1 + p4001 = 50, then is
i1 i i1 6

| p1 – p 4001 |
4000

 pp
1
;fn p1, p2, p3, ....., p4001 lekUrj Js.kh esa gS tcfd  10 rFkk p1 + p4001 = 50, rc
i1 i i1 6
gS&
Ans. 5
1  1 1   1 1   1 1 
4000

 pp
1
Sol.        .....       10
i1 i i1 d  p1 p2   p2 p3   p4000 p4001  
p4001  p1 4000d
 10   10  p1 p4001  400 and vkSj p1  p4001  50
d  p1  p4001  d  p1  p 4001 

p1  p4001  30


2. Simplified value of 4
17  12 2  tan  is:
8


4
17  12 2  tan  dk ljyre eku gS -
8

Ans. 2

Sol. 17  12 2 = 32  (2 2 )2  2.3.(2 2 )

= (3  2 2 )

4
17  12 2 = 32 2 = 2 1 …(i)


and we know that tan  = 2 1 …(ii)
8
from equation (i) and (ii)
=2
Hindi 17  12 2 = 32  (2 2 )2  2.3.(2 2 )

= (3  2 2 )

4
17  12 2 = 32 2 = 2 1 …(i)


rFkk ge tkurs gS fd tan  = 2  1 …(ii)
8

lehdj.k (i) vkSj (ii) ls

=2

3. If we add 1, 1, 7 respectively to first three terms of an increasing A.P. whose common difference is
an integer, then the resulting three terms are in an increasing G.P. whose common ratio is also an
integer, then the number of possible values of d are
;fn ge o/kZeku lekUrj Js.kh ftldk lkoZvUrj ,d iw.kk±d gS] ds izFke rhu inksa esa 1, 1, 7 dks tksMrs gS rc
ifj.kkeh rhuksa in o/kZeku xq.kksÙkj Js.kh esa gS ftldk lkoZvuqikr Hkh ,d iw.kk±d gS] rc d ds laHkkfor ekuksa dh
la[;k gS&
Ans. 4
Sol. Let the first three terms of an A.P. be a, a + d, a + 2d then (a + d + 1)2 = (a + 1)(a + 2d + 7)
ekuk lekUrj Js.kh ds izFke rhu in a, a + d, a + 2d gS] rc (a + d + 1)2 = (a + 1)(a + 2d + 7)
d2
 d2  6a  6   a 1
6
d2
d
a  d  1  a  1  d d6
Common ratio is   6 2  for common ratio to be an integer d is
a 1 a 1 d d
6
equal to 1, 2, 3, 6
d2
d
a  d  1  a  1  d d6
lkoZvuqikr   6 2  , iw.kk±d d ds fy, lkoZvuqikr 1, 2, 3, 6 gSA
a 1 a 1 d d
6
x y
4. If (x, y) satisfies the equation x2  xy  y2  4  x  y  4  , then value of  is (x, y  R)
y x
x y
;fn (x, y) lehdj.k x2  xy  y2  4  x  y  4  dks larq"V djrk gS] rc  dk eku gS& (x, y  R)
y x
Ans. 2
Sol. x2  x  y  4   y 2  4y  16  0

D  0   y  4  0  y  4
2

5. If 1, 2, 3, 4 are the roots of x4 + 2x3 + bx2 + cx + d = 0 such that 1 – 3 = 4 – 2, then b – c is
equal to
;fn lehdj.k x4 + 2x3 + bx2 + cx + d = 0 ds ewy 1, 2, 3, 4 gS tcfd 1 – 3 = 4 – 2, rc b – c dk
eku cjkcj gS&
Ans. 1
Sol. x 4
  
 2x3  bx 2  cx  d   x  1  x  2  x  3  x  4   x2  px  q x 2  px  r 
 x 4  2px3  q  r  p  x
2 2
 pr  pq x  qr

p = 1, b = q + r + p2
 c = pr + pq
b – c = q + r + p2 – pr – pq
=q+r+1–r–q=1
1  2  3  4
6. If 1  1  2 2  4  3 3  9  4  4  16  where 1, 2 , 3 , 4 are all real.
2
Then 3 – 2 – 1 is equal to
1  2  3  4
;fn 1  1  2 2  4  3 3  9  4 4  16  tgk¡ 1, 2 , 3 , 4 lHkh
2
okLrfod gS rc 3 – 2 – 1 dk eku gS &
Ans. 8
Sol. 2 1 – 1  4 2 – 4  6 3 – 9  8  4 – 16
= (1 – 1) + 1 + (2 – 4) + 4 + (3 – 9) + 9 + (4 – 16) + 16
       
2 2 2 2
 1 – 1 – 1  2 – 4 – 2 3 – 9 – 3  4 – 16 – 4 0

 1 – 1  1 , 2 – 4  2 , 3 – 9  3 ,  4 – 16  4
 1  2, 2  8, 3  18, 4  32

7. Let log3M = a1 + b1 and log5M = a2 + b2 where a1 , a2  N (a1 > a2) and b1, b2 [0, 1). If a1a2 = 6
and number of possible integer values of M can take are 9k, then k equal to
ekuk log3M = a1 + b1 vkSj log5M = a2 + b2 tgk¡ a1 , a2  N (a1 > a2) vkSj b1, b2 [0, 1). ;fn a1a2 = 6
vkSj M ds laHkkfor iw.kk±d ekuksa dh la[;k 9k gks ldrh gS] rc k dk eku cjkcj gS&
Ans. 6
Sol. M = 3a1b1 and M = 5a2  b2
3a1  M < 3a11 and 5a2  M < 5a2 1
a1a2 = 6 = 6 × 1 then 36  M < 37 & 51  M < 52
No common value of M
so only 3 × 2 satisfy  a1 = 3 , a2 = 2
33  M < 34 and 52  M < 53  so number of common integral value equal to 80 – 26 = 54
gy. M = 3a1b1 vkSj M = 5a2  b2
3a1  M < 3a11 vkSj 5a2  M < 5a2 1
a1a2 = 6 = 6 × 1 rc 36  M < 37 & 51  M < 52
M dk dksbZ mHk;fu"B ewy ughA
dsoy 3 × 2 larq"B djrk gS  a1 = 3 , a2 = 2
33  M < 34 vkSj 52  M < 53  blfy, mHk;fu"B iw.kkZad ekuksa dh la[;k 80 – 26 = 54 gSA 

               
8. Let F(k) =  1  sin     1  sin  (k  1)    1  sin  (2k  1)    1  sin  (3k  1)  
   
2k  2k    2k    2k 

a
The value of F(1) + F(2) + F(3) = then value of (b – a) is equal to (Where a, b are co-prime)
b
Ans. 9

           
Sol. Here F(k) =  1  sin   1  cos 2k   1  sin 2k   1  cos 2k 
 2k       

   2   1 
=  1  sin 2   1  cos 2k  = sin
2
 2k   4 k

5x  13
9. If logx2 6x 8 log2x2  2x 3 (x2 – 2x) = 0 then value of is
x3
5x  13
;fn logx2 6x 8 log2x2  2x3 (x2 – 2x) = 0 rc dk eku gS &
x3
Ans. 4
Sol. log2x2  2x 3 (x2 – 2x) = 1
x2 – 2x = 2x2 + 2x + 3
 x = –1, –3
but x = –3 is not satisfied
Hence x = –1 only solution
Hindi. log2x2  2x 3 (x2 – 2x) = 1
x2 – 2x = 2x2 + 2x + 3  x = –1, – 3
ijUrq x = –3 larq"V ugha gksrk gSA
vr% x = –1 dsoy gy

10. For the equation x2  x2  11  x2 – x2  11  4 , the number of irrational solutions is

Ans. 2
Sol. x2 + 11 = t2  x2  x2  11  x2 – x2  11  4
 t 2  t – 11  t 2 – t – 11  4 ...........(i)
 (t2 – t + 11) – (t2 – t – 11) = 2t
  t 2  t – 11  t 2 – t – 11  
t 2  t – 11 – t 2 – t – 11  2t
t
 t 2  t – 11 – t 2 – t – 11  ...........(ii)
2
t t2
(i) + (ii)  t 2  t – 11  2 
 t2 + t – 11 = +4+t
4 16
 15t2 = 15(16)  t2 = 16  x2 = 5  x = ± 5
some solution if
(i) + (ii)  t2 = 16  x = ± 5

SECTION – 2 : (Maximum Marks : 30)

 This section contains TEN (10) questions.
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is correct
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 2 : (vf/kdre vad : 30)
 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

11. The maximum value of the function f(x) = (7cosx + 24sinx)(7sinx – 24cosx), for every x  R.

625 625
(A) 25 (B) 625 (C*) (D) (E) 10
2 4
Sol. y = (7cosx + 24sinx)(7sinx – 24cosx)
rcos = 7, rsin = 24
 24
r2 = 625, tan =
7
y = rcos(x – ). rsin( – x)

r2 r2
= .2sin(x – )cos(x– ) = .(sin2(x – ))
2 2

25 2 625
ymax = =
2 2

12. If  and  are the roots of the equation x2 + qx + p = 0 (p  0, p, q  R) then the equation
x(x + q³) + (p³ – 3pqx) = 0 has roots
3 3 1 1 1 5
(A*)  2 and  2 (B)  2 and  2  (C)  and  (D)    4 and    4
1 1
(E)  3 and  3

;fn  vkSj  lehdj.k x2 + qx + p = 0 (p  0, p, q  R) ds ewy gS] rc x(x + q³) + (p³ – 3pqx) = 0 ds

ewy gS&
3 3 1 1 1 5
(A*)  2 vkSj  2 (B)  2 vkSj  2  (C)  vkSj  (D)    4 vkSj    4
1 1
(E)  3 vkSj  3
1 1
    p
Sol.

    q


x2  x 3pq  q3  p3  0 
Let the roots be 1 , 1
ekuk ewy 1 , 1 gSA
11  p3   
3/2

3 3

   
3
1  1  3pq  q3  3        2  2

3 3
 1   2 and vkSj 1   2

13. Set of all values of x satisfying the inequality x – 3 < x2  4x  5

vlfedk x – 3 < x2  4x  5 dks larq"B djus okys x ds lHkh ekuksa dk leqPp; gS -
(1*) (–  , –5]  [1,  ) (2) (–5, 3]
(3) [3, 5) (4) (–5, 3) (E) (–  , –5)  (1,  )
Sol. Case fLFkfr – 1
x–3<0
x 2 + 4x – 5  0
x 2 + 5x – x – 5  0
(x – 1) (x + 5)  0
x  (–  , –5]  [1,  )
x  (–, –5]  [1, 3) ……..(i) 
Case fLFkfr – II
If ;fn x – 3  0
(x – 3)2 < (x2 + 4x – 5)
 7
x>
5
x  [3,  ) ……..(ii)
(i) (ii) x  (–  , –5]  [1,  )

14. If equation x2 – 4 |x| + k = 0 has 4 distinct real roots, then values of k can be
;fn x2 – 4 |x| + k = 0 ds 4 fHkUu fHkUu okLrfod ewy gS rc k dk eku gks ldrk gS -
(A) – 2, 2 (B*) 1, 2 (C) 2, 7 (D) 4, 5 (E) 3, 5
Sol. k = 4|x| – |x|2
4

y=k
0
-2 2
y=4|x|–|x|
2

15. Let 1, abc, a2b2c2 are in A.P. (a, b, c > 0), then minimum value of 27a 8b 125c is
ekuk 1, abc, a2b2c2 lekUrj Js.kh esa gS] (a, b, c > 0) rc 27a 8b 125c dk U;wure eku gS&
(A) 30 (B) 60 (C*) 90 (D) 120
(E) 100
Sol. s1, abc, a²b²c² also in A.P. lekUrj Js.kh esa gSA
 2abc = 1 + a²b²c²  (abc – 1)² = 0
Now vc A.M.  G.M., we get ;gk¡ 27a + 8b + 125c  90


16. If 1  cot   cot for 0 <  <  , then  is equal to
2

;fn 1  cot   cot , 0 <  <  ds fy, rc  dk eku gS&
2
   
(A) (B) (C*) (D)
6 4 2 8

(E)
3
2
  
  cot  1

1  cot   cot    0
2
Sol.
2 
2cot
2
 
 cot  1  
2 2

(2009)a
17. If 2b = |b – 1| + |b + 1| and = (2009) log a2010 a, b  R such that logba = logbp1 + logbp2 + logbp3 +
2010
logp b logp b logp b
logbp4, where p1 < p2 < p3 < p4 are prime numbers, then the value of 4 1
+ 25 3
+ 9 2
+
logp b
67 4
is

(2009)a
;fn 2b = |b – 1| + |b + 1| vkSj = (2009) log a2010 a, b  R bl izdkj gS fd logba = logbp1 + logbp2 +
2010
logp b logp b logp b logp b
logbp3 + logbp4, tgk¡ p1 < p2 < p3 < p4 vHkkT; la[;k,a gS] rc 4 1
+ 25 3
+ 9 2
+ 67 4
dk
eku gS&
 (A) 12 (B) 71 (C*) 14 (D) 38
(E) 21
Sol. 2b = |b – 1| + |b + 1|  b = 1, 2
(2009)a
= (2009)loga 2010  a = 2010 = 2 × 5 × 3 × 67
2010
logp b
4 1
= 4log2 2 = 4
logp b
25 3
= 25log5 2 = 4
9log5 b = 9log3 2 = 4
log b
67 p4 = 67log7 2 = 2
sum = 4 + 4 + 4 + 2 = 14

(e x – 1)(2x – 3)( x 2  x  2)
18. The set of all solution of inequality  0 is
(sinx – 5 )( x  1)x
(e x – 1)(2x – 3)( x 2  x  2)
vlfedk  0 ds lHkh gyksa dk leqPp; gS -
(sinx – 5 )( x  1)x
3  3 
(1)  ,   (2*) (–, –1)   ,  
2  2 
3  3 
(3) (–1, 0)   ,   (4) R – {0, –1} (E) (–, –1]   ,  
2   2 
+ – – +
Sol.
–1 0 3/2
sinx – 5 is negative
x2 + x + 2 is
always positive
3 
x (– , –1)   ,  
2 
+ – – +
Hindi
–1 0 3/2
sinx – 5 _.kkRed gS
x2 + x + 2
lnSo /kukRed gSA
3 
x (– , –1)   ,  
 2 
  
19. If ,  and  are non zero rational numbers, and S is the set of all possible values of   ,
  
then S is
(A) {3, 1} (B) {–3, 1, –1} (C) {3, –3, 0, 1, –1} (D*) {3, –3, 1, –1}
(E) None of these
  
;fn ,  vkSj  v'kwU; ifjes; la[;k,a gS rFkk S,   ds lHkh laHko ekuksa dk leqPp; gS] rc S gS&
  
(A) {3, 1} (B) {–3, 1, –1} (C) {3, –3, 0, 1, –1} (D*) {3, –3, 1, –1}
(E) buesa ls dksbZ ugha
Sol. If exactly one negative then the value of expression is 1
If exactly two negative then value of expression is –1
If all three negative then value of expression is –3
If all three positive then value of expression is 3
Hindi. ;fn Bhd ,d _.kkRed gS] rc O;atd dk eku 1 gSA
;fn Bhd ,d _.kkRed gS] rc O;atd dk eku –1 gSA
;fn lHkh rhu _.kkRed gS] rc O;atd dk eku –3 gSA
;fn lHkh rhu /kukRed gS] rc O;atd dk eku 3 gSA
 61
20. Let cos2  + p and sin2  + p are the roots of the equation x 2  4x   0 . The equation whose
16
roots are tan2  and cot2  is
61
ekuk cos2  + p vkSj sin2  + p lehdj.k x2  4x   0 ds ewy gS] rc lehdj.k gksxh ftlds ewy tan2
16
 vkSj cot2  ds ewy gS&
(A) x2 – 4x + 1 = 0 (B) x2 – 10x + 1 = 0 (C) x2 + 10x + 1 = 0 (D*) x2 – 14x + 1 = 0
(E) x2 + 14x + 1 = 0
Sol. cos2   p  sin2   p  4
5
p
2

cos 2

  p sin2   p  61
16
1
sin2  cos2  
16
 
x2  tan2   cot 2  x  tan2  cot 2   0

Required equation vHkh"V lehdj.k x2  14x  1  0

 PART : 000 MATHEMATICS

30-08-20
TEST SYLLABUS : Rectilinear motion, Projectile motion , Relative
motion , Newton's law of motion , Friction ,Work energy & power,
Circular motion (till centripetal acceleration)

Submit & Final : 28-08-20 (YA sir)

ACT-2 | PAPER-1 | PATTERN NO. 11-20

S.No. Subject Nature of Questions No. of Questions Marks Partial Marks Negative Total
1 to 10 Integer (Single digit) 10 3 - –1 30
Maths
11 to 20 SCQ (5 option) 10 3 - –1 30
21 to 30 Integer (Single digit) 10 3 - –1 30
Physics
31 to 40 SCQ (5 option) 10 3 - –1 30
41 to 50 Integer (Single digit) 10 3 - –1 30
Chemistry
51 to 60 SCQ (5 option) 10 3 - –1 30
Total 60 Total 180

PAPER-1
SECTION – 1 : (Maximum Marks : 30)
 This section contains TEN (10) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 1 : (vf/kdre vad : 30)
 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u dk mÙkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kk±d gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

Integer_(10)_(Single Digit)
21. The work done by a force F  5 kˆ as its point of application moves from the point (1, 1, 1) to
the origin is equal to ______ .
cy F  5 kˆ }kjk blds fØ;k fcUnq dks fcUnq (1, 1, 1) ls ewy fcUnq rd ys tkus esa fd;k x;k dk;Z ______
ds cjkcj gSA
Ans. 5
Sol. ˆ ˆi  ˆj  k]
W = 5k.[ ˆ  5J

22. Block A of mass 1 kg is placed on the rough surface of block B of mass 3 kg. Block B is placed on
smooth horizontal surface. Blocks are given the velocities as shown. Find the net work done by the
frictional force [in (-) ve J] (assume block B is sufficiently long)
1 kg nzO;eku dk CykWd A 3 kg nzO;eku ds CykWd B dh [kqjnjh lrg ij j[kk gSA CykWdks dks fp=kkuqlkj osx
fn;k tkrk gS rks ?k"kZ.k cy }kjk fd;k x;k dqy dk;Z Kkr djksA (ekuk CykWd B cgqr yEck gSA)
A 8 m/s
B 4 m/s
Ans. 6
Sol. (1 + 3)v = (1)(8) + (3)(4) = 20
V = 5 m/s
1 39
For block A CykWd (1)(52  82 )   J
ds fy,, W f =
2 2
1 27
W f  (3)(52  42 )   J
For block B CykWd ds fy,, 2 2

Net work done by friction = -6 J

?k"kZ.k }kjk fd;k x;k dqy dk;Z = -6 J

23. A block A of mass M rests on a wedge B of mass 2M of inclination θ . There is sufficient friction
between A and B so that A does not slip on B .If there is no friction between B and ground, the
N
compression in spring is ? (Given data M= 10 kg,  = 30º, k = 100 )
m
,d CykWd A, 2M nzO;eku ds θ dks.k ds urry B ij fojkekoLFkk esa j[kk gSaA A rFkk B ds e/; ?k"kZ.k bl
izdkj gS fd A B ij ugh fQlyrkA ;fn CykWd B rFkk lrg ds e/; ?k"kZ.k ugh gS rks fLiazx eas laihMu Kkr
N
djksA (Given data M= 10 kg,  = 30º, k = 100 )
m
M B

A K
2M

Ans. 0
Sol. Net force on wedge by block is in downward direction.
urry ij dqycy uhps fd vksj gS
No displacement of center of mass as well as block 2M.
nzO;eku dsUnz rFkk 2M CykWad dk foLFkkiu 'kqU; gS

24. Two particles are projected in opposite direction horizontally from same position at sufficient height
above the ground with velocities v1 = 3 m/s and v2 = 4 m/s. The time (in seconds) at which their
3
velocity vectors become mutually perpendicular is then the value of p is. (g = 10 m/s2)
p
nks d.k tehu ls Ik;kZIr ÅpkbZ ij leku fLFkfr ls {kSfrt fn'kk esa nqljs ds foifjr osx v1 = 3 m/s rFkk
3
v2 = 4 m/s ls iz{kSfir fd, tkrs gSA le; t = ij muds osx ,d nqljs ds yEcor~ gks tkrs gSA rks p dk
p
eku gS (g = 10 m/s2)
Ans. 5
Sol. (5)For particle 1 d.k 1 ds fy,
3 m/s 2 1 4 m/s

V1 = 4 î – 10t ĵ
For particle 2 d.k 2 ds fy,
V 2 = –3 î – 10t ĵ
V1  V 2 = –12 + 100t2 = 0
3
t= , P = 5 [Ans.: 5]
5

25. A stone is dropped from a certain height of 5x meter (height from the surface of lake) into a lake
100m deep. The stone reaches the bed of the lake 7 seconds after it was dropped. Assume that
both the velocity and the acceleration of the stone are halved on entering the water. Then value of
x is. (g = 10 m/s2)
 ,d iRFkj dks >hy dh lrg ls 5x ehVj ÅWpkbZ ls 100m xgjh >hy esa NksM+k tkrk gSA iRFkj dks NksM+us ds
Ik'pkr~ >hy ds ry ij igqWprk gSA ekuk tc iRFkj >hy ds vanj izos'k djrk gS rc osx rFkk Roj.k nksuks dk
eku vk/kk gks tkrk gSA rks x dk eku gS (g = 10 m/s2)
Ans. 9
Sol. In air time taken is t1
gok esa fy;k x;k le; t1 gS
1 2
5x = g t1
2
t1 = x
u=0
g
5x

g Lake
2 100 m

In water time taken is t2 ikuh esa fy;k x;k le; t2 gS

V = u + gt1 = 10t1
on entering water velocity becomes half ikuh esa izos'k djus ij osx vk/kk gks tkrk gS
V 1 g 2
100 = t2 + t2
2 2 2
5 2
100 = 5t1t2 + t2
2
40 = 2t1t2 + t 22
40 = t2[t1+7]
40 = (7 – t1) (7 + t1)
40 = (72 – t12 )
t1 = 3 sec
x=9

26. A block of mass m is attached with a massless spring of spring constant k. The block is placed
3
over a fixed rough inclined surface for which the coefficient of friction is µ = . The block of mass
4
m is initially at rest. The block of mass M is released from rest with spring in unstretched state. If
a
minimum value of M required to move the block up the plane is m . Then find the minimum value
b
2a
of  b . a, b are integers. (neglect mass of string and pulley and friction in pulley.)
3
3
,d m nzO;eku dk CykWad k fLizax fu;rkad dh nzO;ekughu fLizax ls tqM+k gSA fudk; dks µ = ?k"kZ.k ds ,d
4
fLFkj urry ij j[kk tkrk gSA CykWad M izkjaHk esa fojkekoLFkk esa gS tc fLiazx izkd`frd yEckbZ ij gS rc CykWad
a
M dks NksM+k tkrk gSA ;fn CykWad m dks Åij fd vksj xfr djkus ds fy, M dk U;qure eku m gS rc
b
2a
 b dk U;qure eku Kkr djks tgkWa a, b iw.kkZad gSA (f?kjuh ?k"kZ.kghu rFkk jLlh nzO;ekughu gS)
3

Ans. 7
Sol. As long as the block of mass m remains stationary, the block of mass M released from rest comes
2Mg
down by (before coming it rest momentanly again).
K
2Mg
tc m nzO;eku dk CykWad fojkekoLFkk esa gS M nzO;eku dk CykWad NksM+k tkrk gS tks uhps vkrk gSA
K
 Thus the maximum extension in spring is blizdkj fLizax esa vf/kdre [khpko
2Mg
x= ................. (1)
K
for block of mass m to just move up the incline
m nzO;eku ds CykWd dks urry ij Åij fd vksj xfr djus ds fy,
kx = mg sin  +  mg cos  ................. (2)
3 3 4 3
2Mg = mg × + mg × or M = m
5 4 5 5

27. A particle is projected from ground with an initial speed u = 4 2 m/sec at an angle  = tan–1 2
with horizontal. Find the magnitude of average velocity of particle between its point of projection
and the highest point. (g = 10 m/s2)
,d d.k {kSfrt ls = tan–1 2 dks.k ij izkjfEHkd pky u = 4 2 m/sec ls iz{ksfir fd;k tkrk gSA d.k ds
iz{ksi.k fcUnq ls vf/kdre ÅWpkbZ ds e/; vkSlr osx dk ifjek.k Kkr djksA (g = 10 m/s2)
Ans. 4
Sol. (4)
S
(1) vav =
T/2

2
R
 2  H
2
 
=
T
2
u2 sin2
(2) Putting R j[kus ij =
g
u2 sin2 
H=
2g
2usin 
T=
g
u
vav = 1  3cos2  = 4 m/sec
2

28. Initially spring is in its natural length and blocks A & B are at rest. Find maximum value of constant force F
that can be applied on B such that block A remains at rest. (g = 10 m/s2) (give answer in Newton)

izkjEHk esa fLiazx izkd`frd yEckbZ ij rFkk CykWd A rFkk B fojkekoLFkk esa gSA B ij yxk, fu;r cy dk U;wure
eku Kkr djks ftlls CykWd A fojkekoLFkk ij jgsA (g = 10 m/s2) (mÙkj U;wVu esa nsaA)

Ans. 3
Sol. Values of mg for A and B are 2N & 2N
A rFkk B ds fy, mg dk eku 2N rFkk 2N gSA
Work energy theorm on B gives
B ij dk;Z ÅtkZ izes; ls
Fx – 2x – (K/2) x2 = 0
F = 2 + kx/2 .......(i)
For equilibrium of A, kx = mg = 2
 A ds lkE;oLFkk ds fy,, kx = mg = 2
So vr% F = 2 + 1 = 3N

29. A small block of mass m is taken slowly up a fixed hemisphere from P to Q and then slowly down
along its surface from Q to S by force F, which at each point of the surface, is tangential to the
surface. If the coefficient of friction is , then the work performed by the force F in taking the block
xmgR
from P to S along the hemispherical surface of radius R is equal to then find x.
3
,d NksVk CykWd F cy yxkdj P ls Q rd /khjs&/khjs v)Zxksys ij ys tk;k tkrk gS rFkk Q ls S rd /khjs&/khjs
yk;k tkrk gSA cy F ges'kk CykWd ij xksys ds Li'kZ js[kh; yxrk gSA ;fn ?k"kZ.k xq.kkad gS rks CykWd dks P ls
xmgR
S rd ys tkus esa cy F dk dk dk;Z gS rFkk xksys dh f=kT;k R gS rks x dk eku gSA
3

Ans. 6
Sol. W=  mgcos  ds
2R
W=  mgdx
0

W = 2mg R
Work done against gravity is zero.
xq:Ro ds fo:) dk;Z 'kwU; gSA

30. Wind entering in a wind mill with a velocity of 20 m/sec facing area of the windmill is 10m 2 and
density of air is 1.2 kg/m 3. If wind energy is converted into electrical energy with 33.3% efficiency,
if the electrical power produced by the wind mill is 8n (in kw ) then n is.
iou pDdh esa gok 20 m/sec ds osx ls izos'k djrh gSA iou pDdh dk {ks=kQy 10m2 rFkk gok dk ?kuro
1.2 kg/m3 gSA ;fn iou ÅtkZ 33.3% n{krk ds lkFk fo|qr ÅtkZ esa cnyrh gSA iou pDdh }kjk mRiUu fo|qr
ÅtkZ 8n (kw esa) rks n dk eku gSA
Ans. 2
Sol. Energy entering in the windmill
iou pDdh eas izos'k djus okyh ÅtkZ
1
= mv2
2
dE  1 2   dm 
Pin = =  v  
dt  2   dt 
 1 2 1
Pin =  v  (AV) = AV3
2  2
Electrical power output
fuxZr fo|qr 'kfDr
1 1 
AV 3 
3  2
Pout fuxZr=

 1 1
Pout fuxZr = AV 3 =  1.2  10  (20)3
6 6
Pout fuxZr = 16 kW.

SECTION – 2 : (Maximum Marks : 30)

 This section contains TEN (10) questions.
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is correct
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
[kaM 2 : (vf/kdre vad : 30)
 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

SCQ._(10_(5 options)
31. Two forces P and Q acting at a point are such that if P is reversed, the direction of the resultant is
turned through 900. Then
,d fcUnq ij nks cy P rFkk Q bl izdkj yx jgs gS fd ;fn P dh fn'kk foijhr dh tk, rks ifj.kkeh lfn'k
dh fn'kk 90º dks.k ls ?kwe tkrh gS rc
(A) P  2 Q
(B) P=2Q
(C) P=Q/2
(D) no relation between P and Q
P rFkk Q ds e/; dksbZ laca/k ugh gSA
(E*) P = Q

32. The components of a vector along x and y directions are (n+1) and 1 respectively. If the co-
ordinate system is rotated by an angle  = 60º, then the components change to n and 3. The value
of n is
,d lfn'k ds x rFkk y rFkk ?kVd (n + 1) vkSj 1 gS ;fn v{kh; fudk;  = 60º dks.k ls ?kqek fn;k tk, rks
?kVd n rFkk 3 gks tkrs gks rks n dk eku gSA
0 0
(A) 2 (B) cos60 (C) sin 60 (D*) 3.5
(E) 3.2
Sol. The length of the vector is not changed by the rotation of the co-ordinate axes
v{kh; fudk; ds cnyus ls lfn'k dh yEckbZ ifjofrZr ugh gksrhA
  n  1  12  n 2  32
or n 2  2n  2  n 2  9
7
Or ;k 2n  7 or n   3.5
2

33. A car starts moving from rest with an acceleration whose value linearly increases with time from
zero to 6 m/s2 in 6 sec after which it moves with constant velocity. Find the time taken by the car to
travel first 72 m from starting point
,d dkj fojkekoLFkk ls Rofjr gksrh gS ftlds Roj.k dk eku 6 sec esa 'kwU; ls 6 m/s2 le; ds lkFk js[kh; :Ik
ls c<+rk gSA blds i'pkr ;g fu;r osx ls pyrh gSA izkjfEHkd fcUnq ls izFke 72 m pyus esa dkj }kjk fy;k
x;k le; gSA
(A) 12s (B) 15s (C) 9s (D) 10s
 (E*) 8s
dv
Sol. a=t=
dt
v t
0
dv   dt
0
6
t2 
v0  
 2 0
v  18m/s .
8
S   Vdt
0
6 t2
 dt
0 2
6
t3  36
    36m Total time 6  8sec.
 6 0 18
34. The maximum height attained by a projectile is increased by 5%, keeping the angle of projection
constant, what is the percentage increase in horizontal range?
;fn ,d iz{ksI; dh vf/kdre ÅWpkbZ 5% c<+k nh tk,, rFkk iz{ksI; dks.k fu;r j[kk tkrk gS rks ijkl esa izfr'kr
ifjorZu Kkr djks ?
(A*) 5% (B) 10% (C) 20% (D) 40%
(E) 2.5%
U 2 sin 2 
Sol. H
2g
  const. fu;r
U 2 increasing by 5%
U 2 5% ls c<+k nh tkrh gSA
So range increases by 5%.
bl izdkj ijkl 5% ls c<+ tkrh gSA

35. In the track shown in figure section AB is a quadrant of a circle of 1 metre radius. A block is
released at A and slides without friction until it reaches B. After B it moves on a rough horizontal
floor and comes to rest at distance 3 metres from B. What is the coefficient of friction between floor
and body ?

fp=k esa n'kkZ;s x;s iFk esa [k.M AB, 1 ehVj f=kT;k ds o`Ùk dk ,d prqFkkZa'k gSA A ij ,d CykWd NksM+k tkrk gS
tks fcuk ?k"kZ.k ds rc rd fQlyrk gS tc rd fd ;g B ij ugha igq¡p tkrk gSA B ij igq¡pus ds ckn ;g ,d
[kqjnjs {kSfrt ry ij xfr djrk gS vkSj B ls 3 ehVj dh nwjh ij tkdj :d tkrk gSA CykWd o ry ds chp
?k"kZ.k xq.kkad D;k gS ?

(A*) 1/3 (B) 2/3 (C) 1/4 (D) 3/8

(E ) None of these
1
Sol. mg1 = mu2  u2 = 2g ............... (1)
2
v2 = u2 + 2as  0 = 2g – 2a(3)
g g 1
a=  µk g = a  µk g =  uK =
3 3 3
36. A particle is projected from point P with velocity 53 ms-1 perpendicular to the surface of a hollow
right angled cone as shown in figure. It collides at Q normally. The velocity with which it collides at
Q will be
,d d.k P fcUnq ls fp=kkuqlkj [kks[kys 90º dks.k okys 'kadq dh lrg ds yEcor 53 ms-1 ds osx ls iz{ksfir
fd;k tkrk gSA ;g Q ij yEcor Vdjkrk gSaA fcUnq Q ij d.k fdrus osx ls Vdjk;sxkA

0 Q
30
(A) 25 ms-1 (B*) 15 ms-1 (C) 5 3 ms-1 (D) 103 ms-1
(E) 106 m/s
Sol. Parallel to the plane ry ds lekUrj 0  u parallel  g cos 600t
Perpendicular to plane ry ds yEcor v  u   g sin 60 0 t

37. A block is kept on a smooth inclined plane of angle of inclination  that moves with a constant

horizontal acceleration so that the block does not slide relative to the inclined plane. If the inclined

plane stops, the normal contact force offered by the plane on the block changes by the factor

 dks.k ds ,d urry ij ,d CykWd j[kk gSA urry fu;r {kSfrt Roj.k ls bl izdkj ls xfreku gS fd ml

ij j[kk CykWd urry ds lkis{k ugh fQlyrkA ;fn urry fojkekoLFkk esa vk tkrk gS rks CykWd ij yxus okyk

vfHkyEc izfrfØ;k cy ds ifjorZu dk xq.kkad gSA

(A) cos  (B) sec2  (C) cos2  (D) sin 

(E*) sin 2 

Sol. The block will be be at rest

CykWd fojkekoLFkk ij gSA

If ;fn mg sin   ma cos 

a = g tan 

mg
Ni = mg tan sin + mg cos =
cos

N f  mg cos 
Ni  N f mg  sec   cos  
  1  cos 2 
Ni mg
cos 
38. A particle is projected at t = 0 from a point on the ground with certain velocity at an angle with the
horizontal. The instantaneous power due to gravitational force is plotted against time. Which of the
following is the best representation?
,d d.k t = 0 fdlh fcUnq ls {kSfrt ls fdlh dks.k ij ,d fuf'pr osx ls iz{ksfir fd;k tkrk gSA xq:Rokd"kZ.k
cy ds dkj.k rkR{kf.kd 'kfDr rFkk le; ds e/; xzkQ cuk;k tkrk gSA fuEu ls dkSulk xzkQ lgh gS ?

(A) (B)

(C*) (D)

(E)

Sol.  
P  mg  j . u cos  i   u sin   gt  j 
39. A particle of mass m is moving in a circular path of constant radius r such that its centripetal
acceleration ac is varying with time as ac  k rt , where k is constant. The power delivered to
2 2

the particle by the forces acting on it is

,d m nzO;eku dk d.k r fu;r f=kT;k ds o`fÙk; iFk esa bl izdkj xfr djrk gS fd bldk vfHkdsfUnz; Roj.k
le; ds lkFk ac  k 2 rt 2 , ds vuqlkj ifjofrZr gksrk gSA tgkW k fu;r gSA d.k ij yxus okys cy ds }kjk nh
xbZ 'kfDr gSA
1
(A) 2 mk r t
2 2 2 2 4 2 5
(B*) mk r t (C) mk r t (D) 0
3
1 4 25
(E) 0, mk r t
3
Sol. ac  k 2 rt 2  v 2 / r or v  krt.
dv
The tangential acceleration is at   kr.
dt
dv
Li'kZ js[kh; Roj.k at   kr.
dt
the net tangential force on the particle  mat  mkr  Ft .
d.k ij dqy Li'kZ js[kh; cy  mat  mkr  Ft .
Work is done on the particle only by tangential forces, as the radial forces are perpendicular to v.

d.k ij Li'kZjs[kh; cy dk;Z djrk gSA Li'kZ js[kh; Roj.k v ds yEcor gksA

t   mkr  krt   mk r t.
the power delivered to the particle  Fv 2 2

t   mkr  krt   mk r t.
d.k dks nh xbZ 'kfDr  Fv 2 2
40. Acceleration – time graph of a particle is shown in Figure. Work done by all the forces acting on
the particle of mass m in time interval t1 and t2 while a1 is the acceleration at time t1 is given by
(assume at t = 0 particle was at rest)
Roj.k le; vkjs[k fp=k esa n'kkZ;k x;k gS rks m nzO;eku ij cy }kjk le;kUrjky t1 ls t2 esa fd;k x;k dk;Z gS
tcfd le; t1 ij Roj.k a1 gS (ekuk t = 0 ij d.k fojkekoLFkk esa Fkk)

Acceleration
a2
a1

t1 t2 Time

ma12 3 3 ma  t  t
2 4 4
 ma12 4 4
(A)
4t1
 t2  t1  (B*)
1

8t
2
2
1
(C)
4t12
 t2  t1  (D)
2t1
 t2  t1 
ma1 2 2
1

(E)
2t1
 t2  t1 
3ma1 2 2

Sol. W = Kf - Ki
1  1  
2 2
 1
= m  v f  vi   m  a2t2    a1t1  
1 2 2

2 2  2  2  
ma12 4 4
=
8t12
 t2  t1 
 PAPER-1
SECTION – 1 : (Maximum Marks : 30)
 This section contains TEN (10) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases

[kaM 1 : (vf/kdre vad : 30)

 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u dk mÙkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kk±d gSA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA

41. In a closed container NO2 was taken which dimerises to give N2O4. After some time mole fraction
of N2O4 was found to be 2/3 in the container then calculate % dimerisation of NO 2. (Give your
answer dividing 10).
,d cUn ik=k esa NO2 fy;k x;k tks f}ydhd`r gksdj N2O4 nsrk gSA dqN le; i'pkr~ N2O4 dk eksy fHkUu
2/3 izkIr gqvk rks ml le; NO2 dk % f}ydhdj.k fdruk gqvk gksxk \ (vius mÙkj dks 10 dk Hkkx ns dj
fy[ksaA)
Ans. 8
Sol. 2 NO2  N2O4
100 – x x/2 mol
x
2 2
mole fraction of N2O4 = =
x 3
(100  x) 
2
3x
200 – 2x + x =
2
200 = 1.5 x + x
200
x= = 80 = 8 Ans.
2.5

42. The slope of 'P' v/s ''T" plot at constant volume for a fixed amount of an ideal gas is 0.01 atm/ K.
Then what will be the value of pressure of gas (in atm) at 300 K temperature ? .

vkn'kZ xSl dh ,d fuf'pr ek=kk ds fy, fu;r vk;ru ij 'P' v/s ''T" dk <ky 0.01 atm/ K gS] rc 300 K
rki ij xSl ds nkc dk eku (atm esa) D;k gksxk\
Ans. 3
Sol. slope =0.01 atm/ K if T= 300 then P = 3 atm
gy% <ky =0.01 atm/ K ;fn T= 300 rc P = 3 atm

43. Calculate the molecular weight of a gas which diffuses four times as fast as another gas Y, which
in turn diffuses twice as fast as another gas Z [All under identical conditions]. Molecular weight of Z
is 128.

xSl dk v.kqHkkj Kkr dhft, tks fdlh vU; xSl Y dh vis{kk pkj xquk rsth ls folfjr gksrh gS tks (Y) fdlh
vU; xSl Z dh vis{kk nks xquk rsth ls folfjr gksrh gS [lHkh leku ifjfLFkfr;ksa esa gSa]A Z dk v.kqHkkj 128 gSA
Ans. 2

44. Total number of electrons having n + l = 4 in V (23) atom in its ground state is :

V (23) ijek.kq dh vk| voLFkk esa n + l = 4 j[kus okys dqy bysDVǻkWuks dh la[;k gS&
Ans. 8

45. Consider the reaction of oxide of a hypothetical element X :

X2O5 + CO  X2O3 + CO2 (unbalanced)
If the percentage yield of this reaction is 20%, what mass of Carbon monoxide (in kg) is required to
produce 10 moles of X2O3?
Report your answer, rounding it off to the nearest whole number .
,d dkYifud rRo X ds vkWDlkbM dh vfHkfØ;k dk voyksdu dhft;s :
X2O5 + CO  X2O3 + CO2 (vlarqfyr)
;fn bl vfHkfØ;k dh izfr'kr yfC/k 20% gks] rks 10 eksy X2O3 mRikfnr djus ds fy, dkcZu eksuksvkWDlkbM
dk D;k nzO;eku (kg esa) vko';d gS?
vkidk mÙkj fudVre iw.kkZad esa nhft;sA
Ans. 3
Sol. X2O5 + 2CO   X2O3 + 2CO2
nactual = 10
100
   nexpected = 10  = 50
20
50  2
 nCO required = 100 moles.
=
1
 mCO required = 100 × 28 = 2800 g
= 2.8 kg  3 kg
gy X2O5 + 2CO   X2O3 + 2CO2
nokLrfod = 10
100
   nvk'kkfUor = 10  = 50
20
50  2
 nCO vko';d = = 100 moles.
1
 mCO vko';d = 100 × 28 = 2800 g
= 2.8 kg  3 kg

46. How many structural isomers of formula C5H12O can give positive iodoform test.
v.kqlw=k C5H12O ds fdrus lajpukRed leko;oh /kukRed vk;ksMksQkWeZ ijh{k.k ns ldrs gS\
Ans. 2
OH OH
Sol.

47. In how many of the following compounds ring is considered as parent (principle) chain.
fuEu esa ls fdrus ;kSfxd esa tud ¼eq[;½ J`a[kyk ds :i esa oy; dk iz;ksx gksrk gS\

, , , , ,
O COOH
Cl

, SO3H
OH
Cl
Ans. 2
Sol. ,
O

48. Consider all possible isomeric amines of molecular weight = 87. How many of them are secondary
amines.
v.kqHkkj 87 ds lHkh lEHko leko;oh ,ehu ij fopkj dhft,A buesa ls fdrus f}rh;d ,ehu gS \
Ans. 6
C
Sol. C–C–C–C–NH–C, C–C–C–NH–C, C–C–C–NH–C , C–C–NH–C , C–C–C–NH–C–C, C–C–NH–C–C
C C C C

49. How many structural isomers of ester having molecular formula C5H10O2 are possible with parent
name as methanoate?
v.kqlw=k C5H10O2 j[kus okys ,LVj ds fdrus lajpukRed leko;oh tud uke ¼Parent name½ esFksuks,V ds
lkFk lEHko gSaA
Ans. 4
Sol. (1) H–C–O–CH2–CH2–CH2–CH3 (2) H–C–O–CH–CH2–CH3
O O CH3
CH3
(3) H–C–O–CH2–CH–CH3 (4) H–C–O–C–CH3
O CH3 O CH3

50. Number of products obtained on ozonolysis of 1, 2-dimethyl benzene is:

1, 2-MkbZesfFky csUthu ds vkstksuhvi?kVu ls izkIr mRiknksa dh dqy la[;k gS &
Ans. 3
H H CH CH3 Cl3
C —C 3
C —CHO C —C
Sol. O , , O
O O O

SECTION – 2 : (Maximum Marks : 30)

 This section contains TEN (10) questions.
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is correct
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases

[kaM 2 : (vf/kdre vad : 30)

 bl [kaM esa nl (10) iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 vadu ;kstuk :
 iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
51. Consider the following vessel. Compartment A is dipping in melting ice while B in boiling water. As
the valve connecting compartments A and B is opened, pressure in compartment A finally is :

(A) More than that of final pressure of compartment B

(B*) Equal to that of final pressure of compartment B
(C) Less than that of final pressure of compartment B
 (D) Unpredictable
(E) None of these
fuEu ik=k dk voyksdu fdft;sA d{k (Compartment) A dks xfyr cQZ esa Mqcks;k tkrk gS] tcfd B dks
mcyrs gq, ty esa Mqcks;k tkrk gSA tc d{k A o B dks tksM+us okyk okWYo [kksyk tkrk gS] rc vUrr% d{k
(compartment) A esa nkc %
(A) d{k (compartment) B ds vfUre nkc ls vf/kd gksxkA
(B*) d{k (compartment) B ds vfUre nkc ds cjkcj gksxkA
(C) d{k (compartment) B ds vfUre nkc ls de gksxkA
(D) dqN dgk ugha tk ldrkA
(E) bues ls dksbZ ugha

52. Density of CO2 gas at 27C and 5 atm pressure (R = 0.082 atmL/mol K) is:
CO2 xSl dk ?kuRo 27C vkSj 5 atm nkc ij (R = 0.082 atmL/mol K) gS&
(A) 4.5 gL–1 (B) 6.6 gL–1 (C*) 8.9 gL–1 (D) 10.2 gL–1
(E) 3 gL–1
PM 5  44
Sol. d= = = 8.9 g/L
RT 0.082  300

53. If 2 litre of 9.8 % w/w H2SO4 (d = 1.5 g/mL) solution is mixed with 3 litre of 1 M KOH solution then
the concentration of H+ if solution is acidic or concentration of OH – if solution is basic in the final
solution is:
;fn 9.8 % w/w H2SO4 (d = 1.5 g/mL) foy;u ds 2 yhVj dks 1 M KOH foy;u ds 3 yhVj ds lkFk fefJr
djrs gS] rc vfUre foy;u esa H+ dh lkUnzrk ;fn foy;u vEyh; gS vFkok OH – dh lkUnzrk ;fn foy;u
{kkjh; gS] crkb;s&
3 3 2
(A) 0 (B) M (C*) M (D) M
10 5 5
5
(E) M
2
Sol. moles of KOH added are = 3 × 1
= 3 mol
2 KOH + H2SO4  K2SO4 + 2HOH
initial moles 3 3 0 0
moles after reaction 3 – 3 3 – 1.5 1.5 3
= 0 = 1.5
2  1.5 3
 [ H+ ] = = M
23 5
Sol. feyk;s x;s KOH ds eksy = 3 × 1
= 3 eksy
2 KOH + H2SO4  K2SO4 + 2HOH
izkjfEHkd eksy 3 3 0 0
vfHkfØ;k ds i'pkr~ eksy 3–3 3 – 1.5 1.5 3
= 0 = 1.5
2  1.5 3
 [ H+ ] = = M
23 5

54. Given : Na2CO3.xH2O + H2SO4   Na2SO4 + CO2 + (x + 1)H2O

10 mL of 0.1 M H2SO4 is needed for complete reaction with 25 mL of 11.44g litre–1 Na2CO3.xH2O
solution. The value of x is :
fn;k x;k gS % Na2CO3.xH2O + H2SO4  Na2SO4 + CO2 + (x + 1)H2O
10 mL, 0.1 M H2SO4 dh iw.kZ vfHkfØ;k ds fy, 25 mL, 11.44g litre–1 Na2CO3.xH2O dh vko';drk gksrh gSA
x dk eku gksxk&
(A) 2 (B) 3 (C) 6 (D*) 10 (E) 5
11.44
Sol. Molarity of Na2CO3xH2O = M
106 18x
 11.44
Na2CO3xH2O dh eksyjrk = M
106 18x
 Moles of Na2CO3.xH2O = Moles of H2SO4
  Na2CO3.xH2O ds eksYk = H2SO4 ds eksYk
 11.44   25   10 
 106  18x   1000  =  1000  (0.1)
     
x = 10

55. At 27ºC the ratio of rms velocities of ozone to oxygen is

27ºC ij vkstksu rFkk vkWDlhtu dh rms osxksa dk vuqikr gksxkA
(A) 5/5 (B) 4/3 (C*) 2/3 (D) 0.25 (E) 3/4

VO3 ,r m s MO2
32 2
Sol. VO2 ,r m s = MO3 = =
48 3

56. What is the structure of 4-Methylhex-5-en-3-ol.

fuEu esa ls dkSulh 4-esfFkygsDl-5-bZu-3-vkWy dh lajpuk gS %

(A) (B*)

(C) (D) (E)

OH

Sol.

57. Which of the following statement is incorrect.

(A) Methyl cyclopropane and cyclobutane are chain isomers.
(B) Cyclohexane and hexene have same general formula.
(C*) Ethyl methanoate and methyl ethanoate are chain isomers of each other.
(D) Ethoxybenzene and 1-Methoxy-2-methylbenzene are metamers.
(E) p- methyl phenol and benzyl alcohol are functional isomers.
fuEu esa ls dkSulk dFku xyr gS &
(A) esfFky lkbDyksizksisu vkSj lkbDyksC;wVsu Ja`[kyk leko;oh gksrs gSaA
(B) lkbDyksgsDlsu vkSj gsDlhu dk lkekU; lw=k leku gksrk gSA
(C*) ,fFky esFksuks,V vkSj esfFky ,sFksuks,V ,d nwljs ds Ja`[kyk leko;oh gksrs gSaA
(D) ,FkksDlhcsUthu o 1-esFkksDlh-2-esfFkycsUthu e/;ko;oh gksrs gSaA
(E) p-esfFky fQukWy o csfUty ,YdksgkWy fØ;kRed leko;oh gksrs gSA
Sol. Ethyl methanoate and methyl ethanoate are metamers.
,fFky esFksuks,V vkSj esfFky ,sFksuks,V e/;ko;oh gksrs gSaA

58. Which is correct IUPAC name ?

(A) 3-Methylenebutanamide (B) Ethenylcyclohexane
(C) 3-(1-Methylethyl) butanoic acid (D*) Tricyclopropyl methane
(E) 1,2,5-tribromo-3,4,6-trichlorocyclohexane
fUkEu esa ls dkSulk IUPAC uke lgh gS \
(A) 3-esfFkyhuC;wVsukekbM (B) ,fFkuhylkbDyksgsDlsu
(C) 3-(1-esfFky,fFky) C;wVsukWbd vEy (D*) VªkbZlkbDyksizksfiyesFksu
(E) 1,2,5-VªkbZczkseks-3,4,6-VªkbZDyksjkslkbDyksgsDlsu
 O
3 2
Sol. (A) CH3—CH—CH2—C—NH2
1
CH2
4
3-Methyl but-3-enamide
3-esfFkyC;wV-3-bukekbM

(B)
Cyclohexyl ethene
lkbDyksgsfDly ,Fkhu

3 2 1
(C) CH3 — CH — CH2 — COOH
|4
CH3 — CH
|
CH3
5
3, 4– Dimethyl pentanoic acid
3,4-MkbesfFkyisUVsukWbd vEy
Br
2
Cl Br
3 1

(E) Br 4 6
Cl
5
Cl
1,2,4-Tribromo-3,5,6-trichlorocyclohexane
1,2,4-VªkbZczkseks-3,5,6-VªkbZDyksjkslkbDyksgsDlsu

59. IUPAC name of the compound is

(A*) 3-(2-bromo cyclopentyl)-6-methylcyclohex-1-ene

(B) 3-methyl-6-(2-bromo cyclopentyl) cyclohex-1-ene
(C) 1-methyl-4-(2-bromo cyclopentyl) cyclohex-2-ene
(D) 4-methyl-1-(2-bromo cyclopentyl) cyclohex-2-ene
(E) 2-methyl-1-(4-bromo cyclopentyl) cyclohex-1-ene
;kSfxd dk IUPAC uke gS &

(A*) 3-(2-czksekslkbDyksisfUVy)-6-esfFkylkbDyksgsDl-1-bZu
(B) 3-esfFky-6-(2-czksekslkbDyksisfUVy) lkbDyksgsDl-1-bZu
(C) 1-esfFky-4-(2-czksekslkbDyksisfUVy) lkbDyksgsDl-2-bZu
(D) 4-esfFky-1-(2-czksekslkbDyksisfUVy) lkbDyksgsDl-2-bZu
 (E) 2-esfFky-1-(4-czksekslkbDyksisfUVy) lkbDyksgsDl-1-bZu

Sol.

60. Which of the following alkane can be produced by the hydrogenation of four structural alkene ?

(A) Pentane (B) Butane (C) Isobutane (D*) Isohexane

(E) None of these
fuEu esa ls fdl ,Ydsu dks pkj lajpukRed ,Ydhu ds gkbMªkstuhdj.k }kjk izkIr fd;k tk ldrk gS \
(A) isUVsu (B) C;wVsu (C) vkblksC;wVsu (D*) vkblksgsDlsu
(E) bues ls dksbZ ugha
Sol.