SAFETY DATA SHEET

OGS 49WC Oil Soluble Gas Sweetener

Section 1. Identification
GHS product identifier : OGS 49WC Oil Soluble Gas Sweetener

Other means of : Not available.

identification

Product use : Oil Soluble Gas Sweetener

Proprietary Organic Mixture

Product type : Liquid.

Manufacturer : Jacam Catalyst, LLC

11999 E Hwy 158
Gardendale, TX 79758

Validation date : 8/24/2017

For Chemical Emergency : Call CHEMTREC Day or Night

Spill, Leak Fire, Exposure or Within USA and Canada 800-424-9300
Accident: Or +1 703-527-3887 (Collect calls accepted)

Direct all other calls to:

Jacam Catalyst, LLC 432-563-0727
Mon – Fri 8 a.m. to 5 p.m. (Closed on major holidays)

Supplier's details : Jacam Catalyst, LLC

11999 E Hwy 158
Gardendale, TX 79758

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 3

substance or mixture ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (optic nerve) -
Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic
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Section 2. Hazards identification

effects) - Category 3

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H302 + H312 - Harmful if swallowed or in contact with skin.
H319 - Causes serious eye irritation.
H317 - H317 - May cause an allergic skin reaction.
H370 - Causes damage to organs. (optic nerve)
H336 - May cause drowsiness or dizziness.
Precautionary statements
General : P103 - Read label before use.
P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P280 - Wear protective gloves. Wear eye or face protection. Wear protective
clothing.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P241 - Use explosion-proof electrical, ventilating, lighting and all material-
handling equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P233 - Keep container tightly closed.
P271 - Use only outdoors or in a well-ventilated area.
P260 - Do not breathe vapor.
P270 - Do not eat, drink or smoke when using this product.
P264 - Wash hands thoroughly after handling.
P272 (OSHA) - Contaminated work clothing must not be allowed out of the
workplace.
Response : P307 + P311 - IF exposed: Call a POISON CENTER or physician.
P304 + P340 + P310 - IF INHALED: Remove person to fresh air and keep
comfortable for breathing. Immediately call a POISON CENTER or physician.
P301 + P310 + P330 + P331 - IF SWALLOWED: Immediately call a POISON
CENTER or physician. Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 + P363 + P310 - IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. Wash
contaminated clothing before reuse. Immediately call a POISON CENTER or
physician.
P302 + P361+P364 + P352 + P312 + P363 - IF ON SKIN: Take off immediately
all contaminated clothing and wash it before reuse. Wash with plenty of soap
and water. Call a POISON CENTER or physician if you feel unwell. Wash
contaminated clothing before reuse.
P333 + P313 - If skin irritation or rash occurs: Obtain medical attention.
P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.
P370 - In Case of Fire: Use dry chemical, CO₂, water spray (fog) or foam.

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Section 2. Hazards identification

Storage : P405 - Store locked up.
P403 - Store in a well-ventilated place.
P235 - Keep cool.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Hazards not otherwise : None known.
classified

Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.

INGESTION: Although not a normal route of entry, ingestion is expected to be
harmful. DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY.
Target organs : Contains material which causes damage to the following organs: upper
respiratory tract, skin.
Contains material which may cause damage to the following organs: blood,
kidneys, liver, spleen, lymphatic system, gastrointestinal tract, bone marrow,
central nervous system (CNS), eye, lens or cornea.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.

Ingredient name % CAS number

Proprietary 10 - 30 Proprietary
Proprietary 10 - 30 Proprietary
Methanol 10 - 30 67-56-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least
15 minutes. If irritation persists, obtain medical attention. If necessary, call a
poison center or physician.

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Section 4. First aid measures

Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an
appropriate mask or self-contained breathing apparatus. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. If irritation persists, obtain medical attention. If
necessary, call a poison center or physician. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 15 minutes. If irritation persists, obtain
medical attention. If necessary, call a poison center or physician. In the event of
any complaints or symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. If irritation
persists, obtain medical attention. If necessary, call a poison center or physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Harmful in contact with skin. H317 - May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
stomach pains
blindness

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Section 4. First aid measures

Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Methanol Category 1 Oral optic nerve
Category 3 Not applicable. Narcotic effects

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard
Name Result
Not available.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. The vapor/
gas is heavier than air and will spread along the ground. Vapors may accumulate
in low or confined areas or travel a considerable distance to a source of ignition
and flash back. Runoff to sewer may create fire or explosion hazard.
Additional Vapor Statement : Not available.
Not available.

Hazardous thermal : Decomposition products may include the following materials:

decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident
for fire-fighters if there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.

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Section 5. Fire-fighting measures

Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not
breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.

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Section 7. Handling and storage

Precautions for safe handling : Eating, drinking and smoking should be prohibited in areas where this material is
Advice on general
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and
incompatibilities well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Proprietary OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin.
TWA: 25 ppm 8 hours.
TWA: 120 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 2/2013).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.
Methanol ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 200 ppm 8 hours.
TWA: 262 mg/m³ 8 hours.
STEL: 250 ppm 15 minutes.
STEL: 328 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin.
TWA: 200 ppm 8 hours.
TWA: 260 mg/m³ 8 hours.
STEL: 250 ppm 15 minutes.
STEL: 325 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 200 ppm 10 hours.
TWA: 260 mg/m³ 10 hours.
STEL: 250 ppm 15 minutes.
STEL: 325 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 260 mg/m³ 8 hours.
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Section 8. Exposure controls/personal protection

Control parameters

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Personal protective :
equipment (Pictograms)

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Section 9. Physical and chemical properties

Appearance
Physical state : Liquid. [Clear.]
Color : Colorless.
Odor : Aromatic.
Odor threshold : Not available.
pH : 10 to 11
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: 28.889°C (84°F) [Pensky-Martens.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : >1 [Air = 1]
Relative density : 0.98 to 1.02
Density : 8.17 to 8.51 (lbs/gal)
Solubility : Easily soluble in the following materials: cold water.
Partition coefficient: n-octanol/ : Not available.
water

Auto-ignition temperature : Not available.

Decomposition temperature : Not available.
Viscosity : Not available.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Proprietary LD50 Dermal Rabbit 435 mg/kg -
LD50 Oral Rat 250 mg/kg -
Proprietary LD50 Oral Rat 763 mg/kg -
Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours
LC50 Inhalation Gas. Rat 64000 ppm 4 hours
LC50 Inhalation Vapor Rat 10 mg/l 4 hours
LD50 Dermal Rabbit 1000 mg/kg -
LD50 Oral Rat 300 mg/kg -

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Proprietary Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams

Sensitization
Product/ingredient name Route of Species Result
exposure
Proprietary skin Rabbit Sensitizing

Mutagenicity
Product/ingredient name Test Experiment Result
Not available.

Carcinogenicity
Product/ingredient name Result Species Dose Exposure
Not available.

Classification
Product/ingredient name OSHA IARC NTP
Proprietary - 3 -
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
Not available.
Teratogenicity
Product/ingredient name Result Species Dose Exposure
Not available.

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Section 11. Toxicological information

Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Methanol Category 1 Oral optic nerve
Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Name Result
Not available.

Information on the likely : Routes of entry anticipated: Oral, Dermal, Inhalation.

ToxKinetics - routes of
exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Harmful in contact with skin. H317 - May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
stomach pains
blindness

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
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Section 11. Toxicological information

Potential chronic health effects

Not available.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 443.4 mg/kg
Dermal 1450 mg/kg
Inhalation (vapors) 50 mg/l

Section 12. Ecological information

Toxicity

Product/ingredient name Result Species Exposure

Proprietary Acute EC50 1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 800000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours
Proprietary Acute EC50 26.1 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 39 ppm Fresh water Fish - Lepomis macrochirus 96 hours
Methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
- Adult
Acute LC50 3289 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours
Conclusion/Summary : Not available.

Persistence and degradability

Not available.

Product/ingredient name
Not available.
Product/ingredient name

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Section 12. Ecological information

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential

Proprietary 0.81 - low

Proprietary -2 - low
Methanol -0.77 <10 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
United States - RCRA Toxic hazardous waste "U" List
Ingredient CAS # Status Reference
number
Methanol (I); Methyl alcohol (I) 67-56-1 Listed U154

Section 14. Transport information

Regulatory UN/NA Proper shipping name Hazard PG*

information Number Class(es)

DOT Classification PG* : Packing group

UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) RQ (methanol) 3 III

Additional information

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Section 14. Transport information

Emergency Response Guide (ERG): 128

Reportable quantity
25000 lbs / 11350 kg [2998.4 gal / 11350 L]
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.

Label

TDG
Classification
UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 III

Additional information

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.
18-2.19 (Class 3).
Label

IMDG Class
UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 III

Marine pollutant notes: : Not available.

Additional information

Label

IATA-DGR Class
UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 III

Additional information

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Section 14. Transport information

Label

Section 15. Regulatory information

U.S. Federal regulations : TSCA 4(a) final test rules: Proprietary
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
All components are listed or exempted.

Clean Air Act Section 112 : Listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients

No products were found.

SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) health (chronic)
pressure hazard health hazard

Proprietary 10 - 30 Yes. No. No. Yes. Yes.

Proprietary 10 - 30 No. No. No. Yes. No.
Methanol 10 - 30 Yes. No. No. Yes. No.

SARA 313
Product name CAS number %
Form R - Reporting Proprietary Proprietary 10 - 30
requirements Methanol 67-56-1 10 - 30
Supplier notification Proprietary Proprietary 10 - 30
Methanol 67-56-1 10 - 30

Date of issue/Date of revision 8/24/2017 Version : 1.02

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Section 15. Regulatory information

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: METHANOL; Proprietary
New York : The following components are listed: Methanol
New Jersey : The following components are listed: METHYL ALCOHOL; METHANOL; Proprietary
Pennsylvania : The following components are listed: METHANOL; Proprietary
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk level Maximum acceptable
dosage level

methanol No. Yes. No. 23000 µg/day

(ingestion)
47000 µg/day
(inhalation)
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Canadian lists
Canadian NPRI : The following components are listed: Methanol; 2-Butoxyethanol
(Pollution Release)
CEPA Toxic substances : The following components are listed: 2-butoxyethanol
Canada inventory-DSL / NDSL : All components are listed or exempted.
International lists
National inventory
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): Not determined.
Malaysia : Not determined.
New Zealand : All components are listed or exempted.
Philippines : Not determined.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
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Section 16. Other information

National Fire Protection Association (U.S.A.)

Flammability
3
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997,
National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National
Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied
only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited
number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the
chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Normal Package Size(s): Ball: 2" Ball 50/Cooler; 4" Ball 12/Cooler
Dry Product: 50 Lbs/Box
Liquid: 5 Gallon/55 Gallon/Bulk
Pellets: 30 Lbs/Cooler; 24 Lbs/Pail
Stix: 1 1/4": 50 Each/Cooler

History
Date of issue/Date of revision : 8/24/2017
Version : 1.02
Date of previous issue : 1/3/2017
Previous Validation Date : 1/3/2017

Prepared by : Jacam Regulatory Department

SDS Requests: : [email protected]

Key to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader

Date of issue/Date of revision 8/24/2017 Version : 1.02

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Section 16. Other information

This Safety Data Sheet (“SDS”) is a mandatory disclosure pursuant to 29 CFR § 1910.1200 and related rules
and regulations. Therefore, it is not intended, nor shall it serve to create, any rights, obligations, liabilities,
and remedies, of any kind whatsoever, between Jacam Catalyst, LLC and any users of this SDS (“Users”).

To the extent that a court of competent jurisdiction determines that this SDS creates any rights, obligations,
liabilities, and remedies, of any kind whatsoever, notwithstanding the foregoing paragraph, Users accept the
product AS IS and WITH ALL FAULTS. Further, Jacam Catalyst DISCLAIMS ANY EXPRESS OR IMPLIED
WARRANTY OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Users’ sole and
exclusive remedies shall be (if any), in Jacam Catalyst's sole and absolute discretion, either: (1) return of the
product and repayment of the purchase price; or (2) repair/replacement of the product. In no event shall
Jacam Catalyst be liable for any damages of any kind whatsoever, including but not limited to, actual,
compensatory, reliance, expectancy, foreseeable, future, statutory, incidental, consequential, and exemplary
damages. Users assume any and all risks of any kind whatsoever that in any way relate to the product.

*** END OF SDS ***

Date of issue/Date of revision 8/24/2017 Version : 1.02