Chemistry For NEET By Prince Sir

INORGANIC CHEMISTRY

CHEMICAL BONDING

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Chemistry For NEET By Prince Sir
LEVEL - I 10. The maximum valency of an element
with atomic number 7 is
1. 2 2.5 3.4 4.3
INTRODUCTION
11. Electrovalency of non-metal atom is not
equal to, that of the metal atom in
1. Chemical bond implies
1) repulsion 2) attraction 1. Sodium bromide
3) attraction and repulsion balanced at a 2. Magnesium oxide
particular distance 3. Aluminium nitride
4) attraction and repulsion 4. Potassium sulphide
2. During bond formation potential energy 12. E le ct ro va le n c y o f me t a l at om i s
of the system maximum in
1. Increases 2. decreases 1. Sodium hydride 2. Calcium carbide
3. remains the same4.cannot be predicted
3. Magnesium oxide 4. Aluminium fluoride
3. Cl  Cl  Cl2 , this is an example for
1. Endothermic reaction IONIC BOND
2. Exothermic reaction
3. Either exothermic or endothermic
4. Neither exothermic nor endothermic 13. The electronegativities of two elements
4. Most energitic species among the are 0.7 an d 3.0. The b ond formed
following is between them would be
1. Ionic 2. Covalent
1) H 2 2) Ne 3) F 4) F2
3. Co-ordinate covalent 4. Metallic
5. Duplet configuration is not found in
14. Highly ionic compound is formed by the
1.hydride ion 2. hydrogen molecule
combination of elements belonging to
3. Lithium cation 4. Be 3+
6. Valency of an element indicates 1. I A group and VII A gruop
1) combining power with hydrogen 2. II A group VI A group
2) acidity 3. III A group and V A group
3) electrons in the outmost orbit 4. ‘O’ group and VII A group
4) none of these 15. Most ionic compound is formed by the
7. In a short period, as the atomic number combination of
increases, the valency of elements with 1. P and S 2. K and F2
respect to oxygen
3. H 2 and O 2 4. Na and I 2
1. decreases 2. remains constant
3. first increases and then decreases 16. Cation is isoelectronic with anion in
4. increases 1. Sodium chloride
8. The element having highest valency with 2. Potassium Bromide
respect to oxygen is 3. Lithium fluoride
1. Sodium 2. Aluminium 4. Rubedium bromide
3. Chlorine 4. Sulphur 17. Which of the following is a favourable
9. The number of valency electrons and the factor for cation formation?
valency with respect to hydrogen are
1. Low ionisation potential
equal for
2. High electron affinity
1. Sulphur 2. Silicon
3. Phosphorus 4. Chlorine 3. High electronegativity
4.Small atomic size
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Chemistry For NEET By Prince Sir
18. (A) : Among Ca 2  and Zn 2 ions, Ca 2  is 24. For two i onic solid s, CaO and K l.
Identify the wrong statement among the
more stable than Zn 2  following
(R) : Both Ca 2  and Zn 2 ions are 1) Lattice energy of CaO is much larger
diamagnetic than that of Kl
1) Both (A) and (R) are true and (R) is the 2) KI is soluble in benzene
correct explanation of (A) 3) CaO has higher melting point
2) Both (A) and (R) are true and (R) is not 4) KI has lower melting point
the correct explanation of (A) 25. What is the crystal structure of Cesium
3) (A) is true but (R) is false Chloride? (2000 E)
4) (A) is false but (R) is true 1. Body centered cubic
19. Which of the following has pseudo inert 2. face centered cubic
gas configuration
3. tetrahedral
1. Na + 2. Cu + 3. K+ 4. S 2
4. octahedral
20. M o st i on i c c om p o u n d am on g t h e
26. Number of ion pairs in CsCl unit cell is
following is
1. 1 2. 2 3. 4 4. 8
1. Sodium fluoride 2. Sodium Chloride
3. Sodium bromide 4. Sodium iodide 27. The co-ordination number of the cation
21. Least i on i c comp ou n d amon g t h e in the face centred cubic lattice is
following is 1. 4 2. 8 3. 3 4. 6
1. NaCl 2. KCl 3. CsI 4. LiI 28. The number of op positely charged
nearest neighbours to a Caesium ion in
22. Most favourable conditions for
Caesium Chloride lattice are
electrovalency are
1. Low charge on ions, large cation and 1. 8 2. 6 3. 4 4. 2
small anion 29. The positions of Cl- ions in NaCl structure
2. High charge on ions, small cation and are
large anion 1. Corners of the cube
3. High charge on ions, large cation and 2. Centres of faces of the cube
small anion 3. Corners as well as centres of the faces
4. Low charge on ions, small cation and of the cube
large anion 4. Edge centres of the cube
23. From the data given below for NaCl, the 30. The position of Cs+ ion in CsCl structure
electron affinity of chlorine [- E a] is is
H f = - 98.2 K.Cal / mole 1. At the corners of the cube and body
S Na = 36 K.Cal / mole centre of the cube.
I Na = 118.5 K.Cal / mole 2. At the centre of each face of the cube
3. At the body centre of the cube
1 = 29 K.Cal / mole
DCl 4. At the edge centre of the cube
2 2
U Nacl = - 184.2 K.Cal / mole 31. Co-ordination number of cation is
minimum in
1. -97.5 K.Cal / mole 2. -108 K.Cal / mole
3. -75 K.Cal / mole 4. -128 K.Cal 1. NaCl 2. CsCl 3. ZnO 4. KCI

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Chemistry For NEET By Prince Sir
32. (A) : Ionic compounds tend to be non -
volatile COVALENT BOND
(R) : Inter ionic forces in ionic com-
pounds are weak 39. Maximum number of covalent bonds
1) Both (A) and (R) are true and (R) is by which two atoms can be bonded to
the correct explanation of (A) each other
2) Both (A) and (R) are true and (R) is 1) Four 2) Two
not the correct explanation of (A) 3) Three 4) No fixed number
3) (A) is true but (R) is false 40. Bond present in iodinemonochloride is
4) (A) is false but (R) is true 1) Coordinate 2) Electrovalent
33. (A) : NaCl is bad conductor in the 3) Covalent 4) Metalic
solid state 41. Only triple bond is present in

(R) : Na and Cl ions are not free in
 1. N 2O 2. CO 2 3. HCN 4. N 2
the solid state 42. Assertion (A) : CCl4 is non polar mol-
1) Both (A) and (R) are true and (R) is ecule
the correct explanation of (A) Reason ( R) : CCl4 has polar bonds.
2) Both (A) and (R) are true and (R) is 1. Both ‘A’ and ‘R’ are true and ‘R’ is the
not the correct explanation of (A) correct explanation to ‘A’.
3) (A) is true but (R) is false 2. Both ‘A’ and ‘R’ are true but ‘R’ is not
4) (A) is false but (R) is true the correct explanation to ‘A’.
34. Wh i c h of t h e f ol lo wi n g i s n o t an 3. ‘A’ is true but ‘R’ is false.
electrolyte in molten state 4. ‘A’ is false but ‘R’ is true.
1. Cryolite 2. Sylvine
43. The compound having least covalent
3. Urea 4. Rock salt
nature is
35. Ionic compounds do not exhibit space
1. AlCl3 2. MgCl2 3. NaCl 4. KCl
isomerism because
1. they are solids 44. Which of the following has a tendency
2. the ionic bond is non-directional to form covalent compounds
3. they are electrolytes 1. Ba 2. Be 3. Na 4. Ca
4. they contain ions 45. Covalency of nitrogen in Ammonium ion
36. Number of ion pairs in NaCl unit cell is is
1. 2 2. 4 3. 6 4. 8 1. 2 2. 3 3. 4 4. 5
37. W h i ch o f t h e fo l lo wi n g c on d u ct s 46. Maximum covalency of nitrogen is
electricity 1. 4 2. 5 3. 3 4. 6
1. Crystalline NaCl 2. Fused NaCl 47. Number of bonded electrons in ethane
3. Molten sulphur 4. Diamond molecule are
38. Which of the following is not a correct 1. 7 2. 12 3. 10 4. 14
statement about an ionic compound
48. The number of electron pairs involved
1. The higher the temperature, the more the
in the formation of hydrogen cyanide
solubility
molecule are
2. The higher the dielectric constant of the
1. two 2. eight 3. three 4. four
solvent, the more the solubility
3. The higher the dipole moment of the 49. The number of electron pairs present in
solvent, the more the solubility the valency shell of central atom in SF6
4. The higher the lattice energy, the more molecule are
the solubility 1. 4 2. 6 3. 8 4. 7

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Chemistry For NEET By Prince Sir
50 . Among LiCl, BeCl2, BCl3 and CCl4, the 59. W h i ch o f t h e fo l lo wi n g c ov al en t
covalent bond character follows the molecule is an exception to octet rule?
order: (1999 E)
1) LiCl  BeCl2  BCl3  CCl4 1. BeCl2 2. CO 2 3. H 2O 4. CH 4

2) LiCl  BeCl2  BCl3  CCl4 V.B. Theroy

3) LiCl  BeCl2  CCl4  BCl3
60. Which of the following is not correct
4) LiCl  BeCl2  BCl3  CCl4
1. A sigma bond is weaker than pi bond
51. The electronegativities of F,Cl,Br and 2. A sigma bond is stronger than pi bond
1 are 4.0,3.0,2.8,2.5 respectively. The 3. A double bond is stronger than a single
hydrogen halide with a high percentage bond
of ionic character is
4. A double bond between two atoms is
1) HF 2) HCl 3) HBr 4) HI shorter than a single bond between the same
52. Molecule having maximum number of atoms.
covalent bonds is 61. pi bond is formed by the overlapping of
1. NH 4OH 2. NH 4Cl
1. p - p orbitals along their axis
3. CO(NH 2) 2 4. CH 3OH
2. s - p orbitals along the axis of p - orbital
53. The mol.wt of an Oxide of Hydrogen is 3. p - p orbitals perpendicular to their axis
34. Therefore the number of covalent 4. s - s orbitals
bonds in its molecule are
62. Wh i ch on e of t h e f ollo wi n g i s an
1.4 2. 5 3. 2 4. 3 incorrect statement
54. T h e c orre ct d ec re as i n g o rd er o f 1. A pi bond is formed when a sigma
polarisability of ions is already exists
1) Cl - , Br- , I - , F - 2) F - , I - , Br - , Cl - 2. A pi bond may be formed by t he
overlapping of ‘p’ or ‘d’ orbitals
3) F - , Cl - , Br - , I - 4) I - , Br - , Cl - , F -
3. A pi bond is formed by the overlapping
55. W h i ch o f t h e fo l lo wi n g c on t a i n s of hybrid orbitals
unpaired electron (1993 M) 4. A pi bond is formed by the lat eral
1. NO 2 2. CO 2 3. NO2 4. CN
 overlapping of atomic orbitals
56. Which of the following has least polarity 63. Molecule which contains only sigma
in bond? bonds in it is
1) H - F 2) H - Cl 3) H - O 4) H - S 1. Pentene 2. Pentane
57. Which contains both polar and non-polar 3. Pentadiene 4. Pentyne
bonds ? 64. Strongest bond is formed by the, head
on overlapping of :
1) NH 4Cl 2) HCN
1) 2s and 2p-orbitals
3) H 2O2 4) CH 4 2) 2p- and 2p-orbitals
58. The molecule that deviates from octet 3) 2s and 2s-orbitals
rule is (1995 M) 4) All of these
1. NaCl 2. BeCl2 65. s - p overlapping is present in
3. MgO 4. NH 3] 1. Br 2 2. H 2 3. O 2 4. HF
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Chemistry For NEET By Prince Sir
66. The type of overlap present in the 77. The geometry of ClO3- ion according to
bonds of hydrogen sulphide molecule
Valence Shell Electron Pair Repulsion
is
(VSEPR) theory will be
1)  s-p 2)  s-s
1) Planar triangular 2) Pyramidal
3)  p-p 4)  sp 3  s 3) Tetrahedral 4) Square planar
67. According to V.B. theory, the bonds in 78. In OF2 , number of bond pairs and alone
me t h an e are fo rm ed d u e t o t h e pairs of electrons are respectively
overlapping 1) 2, 6 2) 2, 8 3) 2, 10 4) 2, 9
1) 1 s  s,3 s  p 2) 1 s  p,3 s  s 79. In NO3- ion, number of bond pairs and
3) 2 s  s, 2 s  p 4) 4 sp3  s lone pairs of electrons on nitrogen atom
are
68. Which of the following has
1) 2,2 2) 3,1 3) 1,3 4) 3,0
homoatomic overlap ?
80. The orientation of electron pairs and
1) H - Cl 2) Li-Cl 3) C- Cl 4) Cl-Cl the shape of molecule are different in
69. The orbital overlapping is maximum in 1) BeCl2 2) H 2 O 3) BCl3 4) CCl4
1. Cl2 2. HI 3. HCl 4. HBr 81. Maximum number of planar atoms in
70. The number of sigma and Pi bonds in a SF6 molecule
molecule of cyanogen are
1) 5 2) 4 3) 6 4) 7
1. 4,3 2. 3,4 3. 5,2 4. 3,5 82 A molecu le whi ch can not exist
71. Which of the following molecule does theoretically is
not have a linear arrangement of atoms
1) SF4 2) OF2 3) OF4 4) O2 F2
1. H 2S 2. C 2H 2 3. BeH 2 4. CO 2
HYBRIDISATION
VSEPR Theory
83 Hybridisation involves
72. CO 2 is not iso-structural with 1. Addition of an electron pair
1. HgCl2 2. SnCl2 3. C 2H 2 4. ZnCl2 2. Combination and redistribution of atomic
orbitals
73. Shape of phosphorus pentachloride
molecule is 3. Removal of an electron pair
4. Separation of orbitals
1. Octahedron 2. Square pyramid
84. The s - character in the hybrid orbital
3.Trigonal bipyramid 4. Pyramid
of t h e cen t ral at om , p resen t i n a
74. Which of the following has distorted m ol ec u l e h a vi n g t h e sh ap e of a n
tetrahedron shape octahedron is
1. SiH 4 2. CCl4 3. H 2O 4. CHCl3 1. 25 % 2. 75 % 3. 40 % 4. 16.66 %
75. W h i ch o f t h e fo l lo wi n g i s n o t a 85. The hybridisation of Nitrogen in Nitrate
pyramidal species ion is
1. NH 3 2.H 3+O 3. PH 3 4. NH +4 1. sp 2. sp 2 3. sp 3 4. sp 3d
76. Of the following species, the one having 86 Hybridisation of iodine in iodine hepta
planar structure is fluoride molecule is
1. NH 4+ 2. BF4- 3. XeF4 4.CCl4 1. sp 3d 3 2. sp 3d 3. sp 3d 2 4. dsp 2

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Chemistry For NEET By Prince Sir
87 The molecule which contains sp 3d 2 and 99. Molecule which contains 4 bonded pairs
p orbitals overlapping in it is and 2 lone pairs of electrons on the central
1. PCl5 2. BrF5 3. ClF3 4. IF7 atom is
88. In which of the following molecule, the 1. XeF2 2. CO 2 3. XeF4 4. SF6
central atom is not sp 3d hybridised 100. In which of the following molecule, the
1. PCl5 2. ClF3 3.SeF 6 4.XeF2 central atom has three lone pairs of
89. Linear combination of two hybridised electrons
orbitals belonging to two atoms and each 1. Ammonia
having one electron leads to a 2. Xenon difluoride
1. Sigma bond 2. Double bond 3. Chlorine trifluoride
3. Co-ordinate covalent bond 4. Hydrogen sulphide
4. Pi-bond 101. Molecule having maximum number of
90. Decreasing order of size of various lone pairs of electrons on central atom
hybrid orbitals is : is
1) sp > sp 2 > sp 3 2) sp 3 > sp 2 > sp 1. PH 3 2. H 2S 3. CH 4 4. BrF5
102. Number of bonded pairs and lone pairs
3) sp 2 > sp > sp 3
4) sp > sp3 > sp 2 of electrons present in the central atom
of ammonia molecule are
91. The molecule which contains  sp  sp and 3 3

1. 3,1 2. 2,2 3. 1,3 4. 4,0

 sp 3  p bonds in it is 103 Number of hybrid orbitals present in a
1. CH 3CH 3 2. CH 3CHO molecule of propene are
3. CH 3CH 2Cl 4. CHCl3 1. 12 2. 10 3. 9 4. 8
92 The type of hybrid orbitals used by the 104. The number of hybrid orbitals in a
oxygen atom in Cl2O molecule is molecule of decane are
1. sp 3 2. sp 2 3. sp 4. None 1. 36 2. 40 3. 38 4. 8
93. Bond angle between two hybrid orbitals 105. The hybridisation of carbon in diamond,
is 107 o, s - orbital character of hybrid graphite and acetylene are
orbital is nearly 1. sp 3,sp,sp 2 2. sp,sp 2,sp 3
1. 50 % 2.33.33% 3. 16.6 % 4. 25 % 3. sp 3,sp 2,sp 4. sp 2,sp 3,sp
94 Hybridisation of oxygen in hydronium 106 The structural formula of a compound
ion is is CH 3 - CH = C= CH 2 . The type of
hybridisation at the four carbons from
1. sp 2.sp 2 3.sp 3 4. dsp 2
left to right are
95. The hybridisation of carbon in carbon 1. sp 3,sp,sp 2,sp 3 2. sp 2,sp 3,sp 2,sp
dioxide molecule is 3. sp 3,sp 2,sp,sp 2 4. sp 3,sp 2,sp 2,sp 2
1. sp 2 2. sp 3. sp 3 4. None 107 As the s - character in a hybrid orbital
96. The hybridisation of central atom is not increases, the bond angle
sp3d in 1. Increases 2. Decreases
1. PCl5 2.BrF3 3. XeF2 4. BrF5 3. Does not change 4. Becomes zero
97 N-H Bond in Ammonia molecule is
108. A molecule XY2 contains two sigma bonds
1.  s-s
2.  p-s
3.  sp3  s 4.  sp 3  p , two Pi bonds and one lone pair of
elecrons in the valence shell of X. The
98  sp 2  s bond is present in shape of molecule is
1. CH 4 2. NH 3 1)Linear 2)Angular
3. SiCl4 4. CH 2 = CHCl 3)Tetrahedral 4)Pyramidal

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Chemistry For NEET By Prince Sir
DATIVEBOND 2. H - O ....... H - O
3. H - Cl ..... H - Cl
109. Molecule having maximum number of 4. H - N ....... H - N
dative bonds is 117. Bond energy of covalent O - H bond in
1. H 2O 2 2. NH 4+ 3. Al2Cl6 4. B 3N 3H6 water is
110. In potassium ferrocyanide, the nature 1. Greater than bond energy of hydrogen
of bond between iron and cyanide ions bond
is 2. Equal to bond energy of hydrogen bond
1. Ionic Bond 2. Covalent Bond
3. Less than bond energy of hydrogen bond
3. Dative Bond 4. Polar Bond 4. Half of the bond energy of hydrogen bond
111. Indicate the nature of bonding in CCl4
118. St ren gt h of h yd ro ge n b o n d i s
and CaH2
intermediate between
1. Covalent in CCl4 and electrovalent in
1. Vander Waal forces and covalent bond
CaH 2
2. Electrtovalent in both CCl4 and CaH 2 2. Ionic bond and covalent bond
3. Covalent in both CCl4 and CaH 2 3. Ionic bond and metallic bonding
4. Electrovalent in CCl4 and covalent in 4. Resonance
CaH 2 119. Strongest hydrogen bond is present in
112. When a cation gets hydrated, normally 1. Ammonia 2. Water
the bond formed between cation and 3. Hydrogen fluoride 4. Ethyl alcohol
water molecule is 120. Which of the following exists as a liquid
1. Dative bond 2. Ionic bond at roo m t e mp erat u re d u e t o t h e
3. Covalent bond 4. Hydrogen bond formation of associated molecules only
113. CuSO4 .5H 2O is represented as : 1. Benzene 2. Ammonia
1) [Cu(SO4)].5H 2O 3. Bromine 4. Carbon disulphide
2) [Cu(H 2O) 3SO 4].2H 2O 121. Wat e r i s a li q u i d wh i l e h yd rogen
3) [Cu(H 2O) 4SO 4].H 2O sulphide is a gas because
4) [Cu(H 2O) 5]SO 4 1. Water has higher molecular weight
2. Hydrogen sulphide is a weak acid
HYDROGEN BONDING 3. Sulphur has high electronegativity than
oxygen
114. Inter molecular hydrogen bond is not 4. Wat er molecules associate t hrough
present in hydrogen bonding
1. Ammonia 2. Water 122. The high boiling point of ethanol [78.2oc]
3. Hydrofluoric acid 4. Salicylaldehyde compared to dimethyl ether [-23.6 oc],
115. Intra molecular hydrogen bond is not though they have ther same molecular
present in formula [C 2H6O], is due to
1. O - Fluoro phenol 1. Hydrogen bonding
2. Salicylaldehyde 2. Ionic bonding
3. O- Nitro phenol
3. Co-ordinate covalent bonding
4. P - Nitro phenol
4. Resonance
116 The strongest hydrogen bond is present
123. Among the following, the boiling point
in
is high for
1. H - F ....... H - F
1. Ethyl alcohol 2. Dimethyl ether
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Chemistry For NEET By Prince Sir
3. Acetone 4. Chloroform 1. Electrovalent and covalent
124. Of the following hydrides the boiling 2. Electrovalent and co-ordinate covalent
point is very low for 3. Electrovalent, covalent, co-ordinate
1. NH 3 2. PH 3 3. SbH 3 4. AsH 3 covalent and hydrogen bond
125. NH3 has a much higher boiling point than 4. Covalent and co-ordinate covalent
PH 3 because
1. NH 3 has a larger molecular weight MOLECULAR ORBITAL THEORY
2. NH3 undergoes umbrella inversion
3. NH 3 contains hydrogen bonds 134. Molecular orbital theory was proposed
4. NH 3 contains ionic bonds where as PH 3 by
contains covalent bonds 1) Lewis 2) Muliken
3) Slater 4) Pauling
126. Which of the following is a normal liquid
135. The para magnetic nature of oxygen is
1. NH 3 2. H 2O 3. HF 4. Br 2
best explained by
127. The maximum number of molecules that 1) V.B theory 2) Hybridisation
one water molecule can hold through 3) M.O theory 4) VSEPR theory
hydrogen bonding is 136. Molecular orbitals are
1) 2 2) 4 3) 6 4) 8 1) Monocentric 2) Bicentric
128. The high density of water compared to 3) polycentric 4) None
ice is due to 137. When two atomic orbitals combine they
1) H-bonding interactions from
2) dipole-dipole interactions 1) One molecular orbital
3) dipole-induced dipole interactions 2) Two molecular orbitals
4 ) indu ce d dipo le - ind uc ed d ip o le 3) Three molecular orbitals
interactions 4) Four molecular orbitals
129. Which of the following compounds would 138. Anti- bon ding molecular orbital is
show evidence of the strongest hydrogen formed by
bonding ? 1) Addition of wave functions of atomic
1) Propan-l-ol 2) Propan-2-ol orbitals
3) Propan-l,2-diol 4) Propan-l,2,3-triol 2) Substraction of wave functions of atomic
130. Which of the following is steam volatile orbitals
1. Phenol 2. o - Nitrophenol 3) Multiplication of wave functions of
3. m - Nitrophenol 4. p - Nitrophenol atomic orbitals
131. Which of the following is miscible with 4) Finding the arthemitic mean
water 139. Nu mber of p ai red elect rons i n O2
1. CS 2 2. C 2H 5OH 3. CCl4 4.CHCl3 molecule is:
132 The coupling between base units of DNA 1) 7 2) 8 3) 16 4) 14
is through
140. Among the following degenerate orbit-
1. Hydrogen bonding als are
2. Electrostatic bonding
1)  1s ,  1s * 2)  2 px,  2 px*
3. Covalent bonding
4. Vander Waal’s forces 3)  2 px ,  2 p y 4)  2 p y ,  2 pz *
133. The types of bonds present in CuSO 4.
5H 2O are 141. While filling electrons in  2 px and

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Chemistry For NEET By Prince Sir
 2 py the eletronic configuration rules
that one to be followed is a) O  2 , O2 b) N 2 , N 2 
1) Pauli’s exclusion principle c) NO  , NO 
2) Aufbau principle
1) a only 2) b only
3) Both Pauli’s and Hund’s rule
4) All the above 3) a and c only 4) b and c only
142. The number of antibonding electron 151. Match List I (Molecules) with List II
(Bond order) and select the correct
pairs in O22  molecular ion on the basis answer using the codes.
of molecular orbital theory is List - I List - II
1) 2 2) 3 3) 4 4) 5
I. Li2 A. 3
143. The molecular electronic configuration
of H 2 ion is II. N 2 B. 1.5
2 2 III. Be2 C. 1.0
2)  1s   *1s 
2
1)  1s 
1
IV. O2 D. 0
2
3)  1s   *1s 
3
4)  1s  E. 2
144. Which of the following has fractional 1) I - B, II - C, III - A, IV - E
bond order 2) I - C, II - A, III - D, IV - E
1) O22  2) O22  3) F22 4) H 2 3) I - D, II - A, III - E, IV - C
4) I - C, II - B, III - E, IV - A
145. In O2 , O2 and O22 molecular species,
t h e t ot al n u m b e r o f an t i b o n d i n g 152. The bond order of He  2 molecule ion is
electrons respectively are 1 1
1) 7, 6, 8 2) 1, 0, 23) 6, 6, 6 4) 8, 6, 8 1) 1 2) 2 3)
4)
2 4
146. Whi ch of th e following pairs have
153. What is correct sequence of bond order
idential bond order?
1) O2  O2  O2 2) O2  O2  O2
1) N 2 , O22 2) N 2 , O21
3) O2  O2  O2 4) O2  O2  O2
3) N 2 , O2 4) O 2  , N 2
147. Wh ich of t h e followin g can n ot b e 154. The bond order of O2 is
formed? 1) 1 2) 1.5 3) 2.5 4) 3
1) He 2) He 3) He
2 4) He2
 155 Wh i ch of t h e followi n g sp eci e s i s
148. Which of the following molecular paramagnetic?
orbitals has the lowest energy for O2 1) CO 2) NO 3) O22- 4) CN -
molecule? 156 Which statement is correct about O2+ ?
1)  2 pz 2)  2 py 3)  *2 px 4)  *2 py
1) Paramagnetic and bond order < O2
149. Which of the following molecule species
has unpaired electron(s)? 2) Paramagnetic and bod order > O 2
3) Diamagnetic and bond order < O 2
1) N 2 2) F2 3) O2 4) O22 
4) Diamagnetic and bond order > O 2
150. In which pair, the stronger bond is 157. The species having bond order different
found in the first species ? from that in CO is

10
Chemistry For NEET By Prince Sir
1) NO- 2) NO + 3) CN - 4) N 2 LEVEL - II
158. Among the flowing , the paramagnetic
compound is : IONIC BOND
1) Na2O2 2) O3 3) N 2O 4) KO2
1. Valency of sulphur in sulphuric acid is
159. Ground state electronic configuration of
valence sh ell electrons i n ni trogen
mo lec u le ( N2 ) i s wri t t e n as 1.2 2.4 3.6 4.8

(s 2 s )2 (s *2 s ) 2 (p 2 p ) 4 (s 2 p ) 2 . Hence the bond

2. Variable valency is a property of
order of nitrogen molecule is 1. Alkali metals
1) 2 2) 3 3) 0 4) 1 2. Transition metals
160. Which of the following orbitals of a 3. Alkaline earth metals
diatomic molecule AB will not have 4. Inert gases
positive overlap?
3. Number of electrons transferred from
1) 2s(A) and 2s(B) 2)2s(A) and 2P x(A)
on e at om t o an ot h er d u ri n g bon d
3) 2p x(A) and 2p x(B) 4) 2s(A) and 2p z(B) formation in SrS (Strontium Sulphide)
1. 1 2. 2 3. 3 4. 4.
DIPOLE MOMENT
4. Metal ‘M’ forms a peroxide of the type
161. S.I. unit for dipole moment is MO 2. Valency of the metal with respect
1) e.s.u-cm 2) coulomb-cm to oxygen
3) coulomb-metre 4) e.s.u - metre 1. 0 2. 1 3. 2 4. 4
162. Dipolemoment is least in 5. The Atomic numbers of three elements
1) para - dichlorobenzene A,B and C are a,a+1 and a+2. C is an
2) meta - dichlorobenzene alkali metal. In a compound of A and C,
3) ortho - dichlorobenzene the nature of bonding is
4) monochloro benzene 1. Coordinate 2. Covalent
163. The geometry of H 2 S and its dipole moment 3. Ionic 4. Metallic
are : 6. Two elements X and Y the have following
1) Angular and non zero electron configurations, X= 1s22s2 2p6 3s2
2) Angular and zero 3p 6 4s 2 and Y= 1s 22s 2 2p 6 3s 2 3p 5 . The
3) Linear and non zero formula of the compound formed by the
4) Linear and zero combination of X and Y is
164. Which of the following has the highest 1. X Y 2 2. X 5 Y 2 3. X 2 Y 5 4. X Y 5
dipolemoment? 7. The relation between the magnitudes of
1) AsH 3 2) SbH 3 3) PH 3 4) NH 3 la t t i c e en ergy o f crys t a l an d i t s
formation energy is
165. Which of the following has zero dipole
moment? 1. Lattice energy > Formation energy
2. Lattice energy = Formation energy
1) CIF 2) PCl3 3) SiF4 4) CFCl3
3. Lattice energy < Formation energy
4. None

11
Chemistry For NEET By Prince Sir
8. (A) : Na2 SO4 is more soluble in water 15. An electrovalent compound does not
exhibit space isomerism due to
while BaSO4 is less soluble
1. Presence of ions
(R) : Lattice energy of Na2 SO4 is 2. High melting point
greater than that of BaSO4 3. Strong electrostatic forces between the
constituent ions
1) Both (A) and (R) are true and (R) is 4. Non directional nature of electrovalent
the correct explanation of (A) bond.
2) Both (A) and (R) are true and (R) is 16. ——HCl is bad conductor of electricity
not the correct explanation of (A) but ——HCl is good conductor
3) (A) is true but (R) is false 1. Solid, aqueous
4) (A) is false but (R) is true 2. Aqueous, Solid
9. Lattice energy of NaCl is ‘X’. If the 3. Anhydrous, Solid
ionic size of A2 is equal to that of 4. Anhydrous, aqueous
Na  and B 2 is equal to Cl  , then
lattice enegry associated with crystal COVALENT BOND
AB is
1) X 2) 2X 3) 4X 4) 8X 17. The bond between two identical non-
10. The mass of one unit cell of NaCl is metal atoms has a pair of electrons
1) 234 amu 2) 234 gm 1. Unequally shared between them
3) 58.5 amu 4) 58.5 gm 2. Transfered fully from one atom to the
11. Which of the following reaction in- other atom
volves the liberation of energy? 3. With identical spins
 4. Equally shared between them
1) Na s   Na  g  2) Cl2 g   2Cl g 
18. Which of the following bond has the
 
3) Na g  Cl g  NaCl s  most polar character
1. C - O 2. C - Br 3. C - F 4. C - S
 
4) NaCl s   Na  g   Cl  g  19. A b on d wi t h m axi m u m c ov al en t
12. An atom with atomic number 20 is most ch arac t e r b e t w ee n n o n - me t a ll i c
likely to combine chemically with the elements is formed
atom whose atomic number is 1. between atoms of same size
1.11 2. 16 3. 18 4. 10 2. between identical atoms
13. Wh i c h o f t h e fo ll owi n g i s a p o or 3. between chemically similar atoms
conductor of electricity 4. between atoms which widely differ in
their electronegativities
1. CH 3COONa 2. C 2 H 5OH
20. Which of the following substance is not
3. NaCl(aq) 4. KOH(aq)
a covalent polymer
14. Which of the following is the correct 1. Silica 2. Diamond
word to indicate the ionic substance
3. Glucose 4. Silicon carbide
1. Molecular weight 21. Silicon has 4 electrons in the outermost
2. Formula weight orbit. In forming the bonds
3. Equivalent weight 1. It gains electrons2. it loses electrons
4. All 3. It shares electrons
4. It donates electron pair
12
Chemistry For NEET By Prince Sir
22. Weakest interactions are involved in
1. Dative bond 2. Metallic bond DATIVE BOND
3. Hydrogen bond 4.Vander waals forces
31. Water acts as a powerful ionizing solvent
23. Multiple bond is not present in
due to its high
1. Nitrogen 2. Oxygen
1. Polar nature 2. ionic nature
3. Diamond 4. Carbondioxide 3. dielectric constant 4. Covalent nature
24. W h i ch o f t h e fo l lo wi n g m ol ec u l e 32. The bond formed between a lewis acid
deviates form Octet rule with respect to and a lewis base is
central atom 1. ionic bond 2. covalent bond
1. SF6 2. PCl5 3.dative bond 4.Hydrogen bond
3. BrCl5 4. All the above
33. According to octet rule SO3 contains ---
25. Molecule having an incomplete octet in
--number of dative bonds
the central atom is
1)1 2)2 3) 3 4) 4
1. PCl5 2. NH 3 3. BCl3 4. H 2O
34. Co ord i nat e covalen t coompou nd s
26. Which of the following cannot give a dissolve more in
precipitate with an aqueous solution of
1)polar solvents
AgNO 3
2)non polar solvents
1.KI 2. K2SO 4 3. CHCl3 4. KCl
3)both polar and nonpolare compounds
27. According to Fajan’s rule covalent bond 4)water only
is favoured by (1998 M)
1. Small cation and large anion
VALENCE BOND THEORY
2. Small cation and small anion
3. Large cation and large anion 35. In a nitrogen molecule, the two atoms
4. Large cation and small anion of nitrogen are bounded by (1987 E)
28. The bond between chlorine and bro- 1. One sigma bond and Two pi bonds
mine in BrCl is 2. One sigma bond and one pi bond
1) ionic 2) non - polar 3. Two sigma bonds and one pi bond
3) polar with negative end on Br 4. Three sigma bonds
4) polar with negative end on Cl 36. According to valence bond theory the
predicted bond angle for H 2O
29. A polar covalent bond shows 50% ionic
character. Then the electronegativity 1. 90 0 2. 109 028
difference of the atoms that form the 3. 107 018 4. 104 028
bonds 37. Which is not the characteristic of Pi-
1. more than 1.7 bond
2. equal to 1.7 1. pi bond is formed when a sigma bond
already exists
3. less than 1.7
2. pi bonds are formed from hybrid orbitals
4.much greater than 1.7
3 . pi bo nd ma y be fo r med by t he
30 Odd electron bond is present in overlapping of p-orbitals
1. NO 2. NO 2 4. pi bond results from lateral overlap of
3. ClO 2 4. All the above atomic orbitals
13
Chemistry For NEET By Prince Sir
38 How many sigma and pi bonds are 44. BCl3 molecule is planar while NCl3
present in tetra cyano ethylene ?
molecule is pyramidal because
(M.P-PMT)
(CBSE)
1. nine  and nine 
1. BCl3 does not have lone pair on B but
2. five  and nine 
3. nine  and seven  NCl3 has one on N.
4.eight  and eight  2. B-Cl bond is more polar than N-Cl
39. For compounds, bond
3. N atom is smaller than B
A) Tetracyanoethene B) Carbon dioxide
4. N-Cl bond is more covalent than B-Cl
C) Benzene D) 1,3-Butadiene
bond
Ratio of  and  -bonds is in order
45. Assertion (A) : Geometry of ICl3 is tet-
1) A=B<C<D 2) A=B<D<C rahedral
3) A=B=C=D 4) C<D<A<B Reason ( R) : Its shape is T-shape, due
40 The strength of bonds by 2s-2s, 2p-2p, to the presence of two lone pairs
2s-2p, 1s-1s overlap has the order 1. Both ‘A’ and ‘R’ are true and ‘R’ is the
1. 1s-1s > 2p-2p > 2s-2p > 2s-2s correct explanation to ‘A’.
2. 2p-2p > 2s-2p > 2s-2s > 1s-1s 2. Both ‘A’ and ‘R’ are true but ‘R’ is not
3. 2s-2s > 1s-1s > 2s-2p > 2p-2p the correct explanation to ‘A’.
4. 2s-2p > 2s-2s > 2p-2p > 1s-1s 3. ‘A’ is true but ‘R’ is false.
4. ‘A’ is false but ‘R’ is true.
41. Which of the following has pp - d p
bonding?
HYBRIDIZATION
1) NO3- 2) SO32- 3) BO33- 4) CO32-
46. Hybridisation noticed in CO 2 and CO is
VSEPR THEORY 1. sp 3 2. dsp 2 3. sp 4. sp 2
47. The compound in which carbon uses sp3
hybridisation for bond formation
42. The shape of AB3 E molecule (B=bond
1. H-COOH 2.(NH 2) 2C=O
pair,E=lonepair)
3. H-CHO 4. CH 3CH 2 OH
1)Tetrahedral 2)pyramidal
48. The total number of sp 2 hybrid orbitals
3)Angular 4)T-shape used in bonding of ethylene molecule
43. The effect of repulstion between the two is
lon e p ai rs of elect ron s p resen t on 1. 5 2. 6 3. 7 4. 8
oxygen in water molecule is
(1996 E) 49 Carbon atoms in C2 (CN )4 are :
1. No Change in H – O – H bond angle 1) sp hybridized
2. Decrease in H – O – H bond angle 2) sp 2 hybridized
3.increase in H – O – H bond angle
3) sp and sp 2 hybridized
4. All atoms will be in one plane.

14
Chemistry For NEET By Prince Sir
4) sp, sp 2 and sp 3 hybridized 2. Atomic size of Chlorine is comparatively
large.
50. On catalytic hydrogenation, ethylene 3. Atomic size of nitrogen is comparatively
gives ethane during this reaction large
1. Hybridization of carbon atoms changes 4. Electron affinity of chlorine is highest
from sp 2 to sp 3 60. Ethyl alcohol is highly miscible with
2. bond angle decreases from1200 to 109.50 water because it forms the following
3. C-C bond length increases from1.34 A0 bond with water
to 1.54A0 1. Covalent bond 2. Ionic bond
4.all of these. 3. Hydrogen bond 4. Dative bond
51. For which hybridization, there are two 61. Acetic acid exists as dimer in benzene
unequal bond angles due to
1. sp 3 2. sp 2 3. sp 4. sp 3d 1. Condensation reaction
-
52. H - B - H bond angle in BH 4 is : 2. hydrogen bonding
1) 180° 2) 120° 3) 109° 4) 90° 3. presence of carboxyl group
53 The hybrid orbital having equal amounts 4. presence of hydrogen atom at  carbon
of s and p - characters is 62. (A) : O - Hydroxy benzaldehyde is
1. sp 2. sp 3 3. sp 2 4. sp 3d steam volatile but not P-hydroxy
54. On hybridisation of one ‘s’ and one ‘p’ benzaldehyde
orbitals we get (R) : Intramolecular hydrogen bond is
1. Two mutually perpendicular orbitals present in orthohydroxy benzaldehyde
2. Two orbitals at 180 o but intermolecular hydrogen bond in
3. Four orbitals directed tetrahedrally parahydroxy benzaldehyde
4. Three orbitals in a plane 1) Both (A) and (R) are true and (R) is
55 Hybridisation in SO 2 molecule is the correct explanation of (A)
1. sp 2. sp 2 3. sp 3 4. sp 3d 2) Both (A) and (R) are true and (R) is
not the correct explanation of (A)
HYDROGEN BONDING 3) (A) is true but (R) is false
4) (A) is false but (R) is true
56. Which of the following does not exhibit
hydrogen bonding in liquid phase MOLECULAR ORBITAL THEORY
1. Phenol 2. liq.NH 3
3. water 4. liq.HCl 63. A bonding molecular orbital is pro-
57. Strongest hydrogen bond is present in duced by
1. H 2O 2. NH 3 3. H 2S 4.C 2H 5OH 1) Destrictive interference of wave func-
58. Hydrogen bonds are present even in tions
vapour state of 2) Constructive interference of wave
functions
1) H 2 O 2) HF
3) Parinig of electrons with opposite spins
3) p-hydroxy benzaldehyde 4) Combination of +ve and -ve wave
4) C2 H 5OH functions.
59. E ve n t h ou gh e le ct ro n e ga t i vi t y o f 64. The wave function of a molecular
chlorine is equal to that of nitrogen, orbital formed by reinforce of wave
chlorine is unable to form hydrogen functions of  A and  B of atomic
bonds. It is due to orbital A and B is represented as
1. Cl has three lone pairs on it
1)  A   B 2)  A   B
15
Chemistry For NEET By Prince Sir
3)  A   B 4) 2 A   B < E (s 2 p ) < E (p * 2 px ) = E (p * 2 p y ) < E (s * 2 p )

65. In the formation of a homo diatomic 70. Which of the following facts regarding
neutral molecule, if ‘N’ atomic orbitals change in bond length is correct?
combine, then the total number of 1) Increases in going from N 2 to N 2+ ,
bonding molecular orbital formed is
decreases in going from O2 to O2+ .
1) 2N 2) N 3) N/2 4) N/4
66. In an anti - bonding molecular orbital, 2) decreases in going from N 2 to N 2+ ,
electron density is minimum increases in going from O2 to O2+ .
1) around one atom of teh molecule 3) increases in going from
2) between two nuclei
N 2 to N 2+ and O2 to O2+ .
3) at a point away from nuclei of the
4) decrease in going from
molecule
4) at no place N 2 to N 2+ and O2 to O2+
67. The bond order of individual carbon 71. Among the following groupings which
bonds in benzene is rep re se n t s the co ll ec t i on of
isoelectronic species
1) one 2) two
3) Between one and two 1. CO, NO  , CN  , C 22
4) one and two alternately 2. N 2 , C 22 , CO, NO
68 . N2 and O2 are convert ed i nt o
3. NO, CN  , N 2 , O2 
monoanions, N 2 and O2 respectively..
4. NO  , C22  , O2  , CO
Which of the following statements is
wrong ?
DIPOLE MOMENT
1) In N 2 , N  N bond weakens

2) In O2 , O  O bond order increases 72. Dipole moment is shown by

1) 1,4-dichlorobenzene
3) In O2 , O  O bond order decreases 2) cis 1,2-dichlorobenzene
3) trans 1,3-dichlorobenzene
4) N 2 becomes paramagnetic 4) trans 2,3-dicholoro-2-butene
69. Which of the following statements is not 73. Which of the following hydrocarbons has
correct from the viewpoint of molecular the lower dipolemoment ?
orbital? H3C CH3
1) Be 2 is not a stable molecule 1) C
+ H H
2) He 2 is not stable but He is expected2
to exist 2) CH 3C º CCH 3
3) Bond strength of N2 is maximum amongst 3) CH 3CH 2C º CH
t he ho monuclear diat o mic molecules
4) CH 2 = CH - C º CH
belonging to the second period.
4) The order of energies of molecular 74. Which one of the following pairs of
orbitals in F2 molecule is molecules will have permanent dipole
moment for both members?
E (s 2 s ) < E (s * 2 s ) < E ( p 2 p x ) = E ( p 2 p y )
1) SiF4 and NO2 2) NO2 and CO2
16
Chemistry For NEET By Prince Sir
3) NO2 and O3 4) SiF4 and CO2 4) Dipole moment & H- bonding
78. The dipole moment of hydrogen chloride
75. From the following given statements, the
with bond distance 127 pm is 1.03 D. The
order of dipolemoments
percent ionic character of its bond is
i) HF  H 2O  NH 3 about
ii) CH 3Cl  CH 2Cl2  CHCl3  CCl4 1) 15 2) 17 3) 19 4) 21
79. A d i at omi c molecu le h as a d i p ole
moment of 1.2 D, if the bond distance is
o
1 A . , what percentage of electronic
charge exists on each atom.
iii) 1) 25% of e 2) 29% of e
3) 19% of e 4) 12 % of e
80. Dipole moment of H 2 X is 1.0D. If the
The correct combination is
bond angle is 900 , the approximate
1) all are correct 2) i, ii are correct
3) only iii is correct 4) only i is correct bond moment of H-X bond is (Cos 450
76. T h e e le ct ro n e ga t i vi t y d i f fe re n c e = 0.7)
between N and F is greater than N and 1) 0.4D 2) 0.5D 3) 0.7D 4) 0.6D
H, yet the dipole moment of NH 3 (1.5 D) 81. Which bond angle , q would result in the
ma xi mu m d i p o le m om en t fo r t h e
is greater than that of NF3 (0.2 D). This triatomic molecule XY2 shown below:
is because :
1) In NH 3 as well as NF3 , the atomic
dipole and bond dipole are in opposite
direction
2) In NH 3 , the atomic dipole and bond 1) q = 90° 2) q = 120°
dipole are in the opposite direction, where 3) q = 150° 4) q = 180°
as in NF3 these are in same direction
LEVEL - III
3) In NH 3 , as well as in NF3 the atomic
dipo le and bo nd dipo le ar e in same
direction.
IONIC BOND

4) In NH 3 , the atomic dipole and bond 1. Covalency for central atom is maximum
dipole are in same direction where as in NF3 in
these are in opposite direction. 1. BF3 2. SO 2Cl23. POCl3 4. BeCl2
77. The critical temperature of water is 2. Which of the following exhibits variable
valency
higher than that of O2 because the H 2O
1. Na 2. K 3. Al 4. S
molecule has:
3. In Covalency (C.P.M.T.)
1) Fewer electrons than O2 1.Transfer of electrons takes place
2) Two covalent bonds 2.Sharing of electrons takes place
3) V - shape 3.Sharing of electrons by one atom only

17
Chemistry For NEET By Prince Sir
4.None of these take place. 4. Electron affinity
4. Valency of the metal atom with respect 12. The best ionic compound among the
to oxygen is maximum in following is
1. Mn2O 7 2. OsO 4 3. MnO 2 4. CrO 3 1. Silica 2. Aluminium fluoride
5. An element A is tetravalent and another 3. Carborundum 4. Aluminium Chloride
element B is divalent. The formula of 13. Which of the following is not correct
t h e co mp ou n d f orme d b y t h e re gard i n g t h e p ro p e rt i es of i on i c
combination of these elements is compounds (2004-E)
1. A2 B 2. A B 3. A B 2 4. A2 B 3 1. Ionic compounds have high melting and
6. A n at om A h as 2K , 8L a n d 3 M
boiling points.
electrons. Another atom B has 2 K and
6 L elect ron s. Th e formu la of th e 2. Their react ion velocit y in aqueous
compound formed between A and B is medium
1. A B 2. A2 B 3 3. A3B2 4. AB 2 is very high.
7. Born Haber cycle may be used 3. Ionic compounds in their molten and
1. to find out electron affinity of non-metal a qu eo us s o lut io ns d o no t co nd uc t
atoms electricity.
2. to find out lattice energy of the ionic 4. They are highly soluble in polar solvents.
compounds 14. The ion which is isoelectronic with CO
3. for the preparation of ammonia in is
industries 1. CN  2. O2  3. O2  4. N 2 
4. both 1 and 2
15. The polarisation power is maximum for
8. Ionic compounds like AgCl, CaF2 and which of the following ion
BaS are insoluble in water. This is 1. Mg +2 2. K+ 3. Cs+ 4. Al3+
because, 16. Polarisation is the distortion of the
1) ionic compounds are insoluble in water shape of anion by an adjacently placed
2) the dielectric constant of water is very c at i o n . W h i ch o f t h e fo ll ow i n g
high statement is correct
3) water is not a good ionising solvent 1. Maximum polarisation is brought about
4) these molecules have high lattice en- by cation of high charge
ergy than hydration energy 2. Maximum polarisation is brought about
2+
9. If Na + ion is larger than Mg ion, and by Cation of Low charge
2– –
S ion is larger than Cl ion, which of
3. A large cation is likely to bring about a
the following will be less soluble in water
large degree of polarisation
1. NaCl 2. Na 2S 3. MgCl2 4. MgS
4. A small anion is likely undergo a large
10. The number of unit cells present in 1 degree of polarisation
mole of NaCl crystal is
17. Ionic reactions are
1) 6 . 023  1023 2) 1.5 10 23
1. Fast 2. Slow
3) 4 4) 1 .
3. Very slow 4. medium
11.Stability of ionic compound is influenced
by 18. KCl easily dissolves in water because
1. Electronegativity 1. It is a salt of potassium
2. Lattice energy 2. It reacts with water
3. Sublimation energy 3. It is an electrovalent compound
4. Its ions are easily solvated
18
Chemistry For NEET By Prince Sir
deviates from octet rule with respect to
central atom
1. PCl3 2. H 2S 3. NH 3 4. XeF4
29. The compound having more covalent
COVALENT BOND nature is
1. BaCl2 2.MgCl2 3. SrCl2 4. BeCl2
19. Pure covalent bond is present in
1. H - Cl 2. Cl - Cl3. C - Cl 4. Na - Cl DATIVE BOND
20. The electronegativity values of C,H,O,N
and S are 2.5, 2.1, 3.5, 3.0 and 2.5 30. Co-ordinate covalent bond is formed by
respectively. The most polar bond is 1. Transfer of electrons
1. S - H 2. O - H 3. N - H 4. C - H 2. Sharing of electrons
21. If the electron pair forming a bond 3. donation of electrons
between two atoms A and B is not in the 4. None of these process
centre, then the bond is 31. NH 4 CN contains
1. Single bond 2.Polar covalent bond 1. ionic bond 2. covalent bond
3. Non-polar bond 4. pi-bond 3. Dative bond 4. All
22. The m.p. of SiO 2 is very high since the 32. Dative bond is not present in
type of bonding in it is 1. BF3 2. N 2O 3. BCl3 4. B 3N 3H 6
1. ionic 2. covalent (polymer) 33. BF 3 forms an adduct with NH 3 because
3. Dative 4. Hydrogen bond (1995 E)(995
1. Nitrogen has high electronegativity
23. An element A belongs to IIA group and
another element B b elongs to VIA 2. Boron has high electronegativity
group. The compound formed between 3. Boron has an empty p-Orbital and
A and B contains Nitrogen has lone pair of electrons
1. A++, B - - ions 2. A++, B -- ions 4. Boron has electro positive nature.
3. A--, B ++ ions 4. A+, B -- ions 34. In the coordinate covalency
1. Electrons are equally shared by the atoms
24. Vander waal’s forces of attraction are
maximum in 2. Elect rons of one at om are shared
between the two atoms
1. ethane 2. glucose
3. Hydrogen bond is formed
3. Urea 4.Methane
4. None of the above
25. Which of the following is not a property
of covalent compounds
VALENCE BOND THEORY
1. They have low melting points
2. They are not electrical conductors 35. Triple bond is not present in
3. They exhibit space isomerism 1. Cyanogen 2. propyne
4. They undergo chemical reactions quickly 3. Nitrous Oxide 4. Nitrogen dioxide
26. Pure covalent double bond is present in 36 Valence bond theory of Pauling and
1. acetylene 2. carbon dioxide S l at e r acc ou n t s fo r t h e fo llo wi n g
3. ethylene 4. Ethane characteristic of covalent bond
27. Expanded octet can be observed in the 1.directional 2. ionic
valency shell of the central atom in 3. Strength 4. hybrid
1. NH 3 2. CH 4 3. PCl5 4. BeCl2 37 Shape of molecule is decided by
28. W h i ch o f t h e fo l lo wi n g m ol ec u l e 1. Sigma bonds
19
Chemistry For NEET By Prince Sir
2. pi bonds the correct explanation to ‘A’.
3. both sigma and pi bonds 3. ‘A’ is true but ‘R’ is false.
4. neither sigma nor pi bonds 4. ‘A’ is false but ‘R’ is true. .
38. In Ethyne molecule between two carbon
atoms has (N.C.E.R.T.)
HYBRIDIZATION
1.One  and two 
2.One  and one  45 The mode of hybridisation of carbon in
3.Two  and one  C 3O2 is
4.Two  and no  1. sp 2. sp 2 3. sp 2 4. None
39 The number of sigma bonds in ethane 46. In which of the following species the
formed by the overlap of sp 3 and s u n d e rl i n ed ca rb on h a vi n g sp 3 -
orb i t a ls i s( 19 99 M )
hybridisation?
1. 5 2. 6 3. 7 4. 4
40. The type of overlapping in Br - F bond 1) CH 3 - COOH 2) CH 3 CH 2OH
in BrF3 molecule is 3) CH 3 COCH 3 4) CH 2 = CH - CH 3
1. sp 3 - p 2. sp 2 - p 3. sp 3d - p4.sp 3d 2 - p 47. The ratio of pure orbitals to hybridized
orbitals in ethylene is
VSEPR THEORY 1) 2 : 3 2) 3 : 1 3) 1 : 1 4) 1 : 3
48. Which one of the following is a correct
41. Which of the following 1molecule / ion set? (2003-E)
is pyramidal (1985 E)
1. H 2 O, sp 3 , angular
1.BF3 2.SO 3 3.PCl3 4. CO 3-2
42. A molecule having 3 bonds pairs and 2 2. H 2O, sp 2 , linear
lo n e p ai rs will h a ve ?
3. NH 4 , dsp 2 , square planar
(Delhi , PMT)
1. T-shape geometry 4. CH 4 , dsp 2 , tetrahedral
2. trigonal planar geometry 49. What is the hybridisation state of the
3. linear geometry central atom in the conjugate base of
4. square pyramidal geometry NH 4 ion? (2002-E)
43. The shape of formaldehyde molecule as 1. sp 2. sp 3 3. sp 2 4. dsp 2
per the VSEPR theory is
1. Linear 2. Planar triangle
3. Pyramid 4. Tetrahedron 50. In piperidine , the hybrid state
44. Assertion (A) : (CH 3 ) 3 N geometry is
assumed by N is
pyramidal but incase of SiH 3 3 N , it is
planar. 1) sp 2) sp 2 3”) sp 3 4) dsp 2
Reason ( R) : The maximum covalaeney 51. The shape of CH 4; SO 4-2; PO 4-3 is
of ‘Si’ is ‘Six’ but that of ‘C’ is four. 1. Trigonal planar 3. Angular
1. Both ‘A’ and ‘R’ are true and ‘R’ is the 3. Tetrahedral 4. Trigonal Bipyramidal
correct explanation to ‘A’.
52. A sp 3 hybrid orbital contains
2. Both ‘A’ and ‘R’ are true but ‘R’ is not 1. 1/4 th s - character
20
Chemistry For NEET By Prince Sir
2. 1/2 th s - character and it destabilizes the molecule.
3. 2/3 th s - character 2) The energy of the bonding M.O is less
4. 3/4 th s - character than the combining atomic orbital and it
stabilizes the molecule.
53. Th e orb i t als of same en ergy level
providing the most efficient overlapping 3) The increase in the energy of anti
are bonding molecular orbital is same as the
decrease in the energy of bonding mo-
1. sp 3-sp 3 2. sp-sp 3. sp 3-sp 2 4. All
lecular orbital
4) None
HYDROGEN BONDING
62. For a homodiatomic molecule with a
54. In which of the following substance, total number of electrons 14, after
hydrogenbonding is absent? (2001 M) filling  * 2s M.O, the next electron
1. HF 2. H 2O goes to
3. CCl4 4. Salicylaldehyde
1)  2 pz 2)  2 px
55. Strongest hydrogen bond is present in
1. CH 3OH 2. CHCl3 3)  2 py 4)  2 px or  2 py
3. [CH 3]2CHOH 4. [CH 3] 3COH 63. Which of the following ion has not bond
56. The maximum number of hydrogen order of 2.5 ?
bonds that can be formed by water
molecules is 1) O2 2) O2 3) N 2 4) N 2
1) 1 2)2 3) 3 4) 4 64. The common features among the species
57. Hydrogen bond energy is about CN - , CO and NO+ are :
1. 10 K.Cal 2. 10 Joules
3. 10 ergs 4. 10 e.v. 1) Bond order 3 and isoelectronics
58. The force responsible for the union of 2) Bond order 3 and weak field ligands
two ice blocks as a single block is 3) Bond order 2 and p - acceptor
1. Vanderwaals force 4) Isoelectric and weak field ligands
2. Hydrogen bonds 65. Which of the following species has the
3. dipole interaction shortest bond length?
4. vanderwaals repulsion 1) N 2+ 2) N 2 3) N 2- 4) N 22-
59. Which of the following has the lowest
66. Among th e following wh ich one is
boiling point? (2000 M)
paramagnetic
1. CH 4 2. H 2O 3. HF 4. C 2H 5OH
60. If the boiling point of ethanol (molecular 1) He2 3) O22 
2) O 2 4) Ne2
weight -46) is 780 C , what is the boiling 67. Which of the following should be most
p o i n t of d i et h yl et h er ( m ole cu l ar stable?
weight=74)? (2004-M) 1) He2 2) H 2 3) He2 4) H 2+
1. 1000 C 2. 780 C 3. 860 C 4. 340 C .
DIPOLE MOMENT
MOLECULAR ORBITAL THEORY

61. Which one of the following statement 68. Dipole moment of CO2 is zero which
regarding molecular orbital is incorrect? implies that
1) The energy of the anti bonding M.O is 1) Carbon and oxygen have equal electro
more than the combining atomic orbital negativities

21
Chemistry For NEET By Prince Sir
2) Carbon has no polar bond 2) BeCl2 < MgCl2 < BaCl2 < CaCl2
3) CO2 is a linear molecule 3) BeCl2 < BaCl2 < MgCl2 < CaCl2
4) Carbon has bond moments of zero value. 4) BaCl2 < CaCl2 < MgCl2 < BeCl2
69. In which of the following bond is polar 3. Which of the following is not an ionic
but molecule is non-polar compound
1. CaC 2 2. NaH 3. Be C 4. BF3
1) H 2 S 2) NH 3 3) SO2 4) CO2 2
4. M ol t en sod i u m ch lori d e c on d u ct s
70. The molecule having non-zero dipole electricity due to the presence of
moment is 1. Free electrons 2. Free ions
1) H 2O2 2) CH 4 3) C2 H 6 4) BF4- 3. Free molecules
71. Dipolemoment is not zero for 4. Atoms of sodium and chlorine
5. When an element of very low ionization
1) PCl5 2) ClF3 potential reacts with an element of very
3) XeF4 4) C2 H 5 C  CC 2 H 5 high electron affinity
1. A weak ionic bond is formed
72. In which of the following bond is polar
2. A strong ionic bond is formed
and molecule also polar
3. A polar covalent bond is formed
1) H 2 S 2) CO2 3) CH 4 4) XeF4 4. No bond is formed
73. Which of the following unit conversion of 6. Which of the following is a highly ionic
dipole moment is correct? compound
1) 1D = 3.3356 C m 1. KCl 2. NaBr 3. KF 4. CsF
7. The compound havi ng least lattice
2) 1D= 3.3356´ 10- 30 C m
energy i
3) 1 C m = 3.3356 D 1. Potassium iodide2. Sodium bromide
- 30
4) 1 C m = 3.3356 ´ 10 D 3. Rubedium iodide 4. Sodium fluoride
74. Bond - length of HCl is ; 8. An h y d rou s AlCl3 i s c ov al en t b u t
1.275 Ao (e = 4.8´ 10- 10 esu ).If m = 1.02 D hydrated AlCl3 .6 H 2O is ionic because
then HCl is : 1) AlCl3 dissolves in CS 2
1) 100% ionic 2) 83% covalent
2) AlCl3 has planar structure
3) 50% covalent 4) 40% ionic
3) IE of Al is low
75. The dipole moment of HBr is 0.78´ 10- 18
4)Hydration energy of Al compensates the
esu cm. The bond length of HBr is 1.41A0 IE
The ionic character of HBr is 9. Octet rule is mostly violated in the
1) 7.5 2) 11.52 3) 15 4) 27 compounds formed by
1) Alkali metals
LEVEL - IV 2) Alkaline earth metals
3) p-block elements
1. The least stable in the following is : 4) Transition elements
10. The most ionic compound among the
1) Li 2) Be- 3) B- 4) C - following is
2. The correct order of increasing lonic 1. KCl 2. NaCl 3. CsI 4. CsF
character is 11. Melting point is low for
1) BeCl2 < MgCl2 < CaCl2 < BaCl2 1. Calcium fluoride

22
Chemistry For NEET By Prince Sir
2. Calcium iodide electrons on A is (1994 M)
3. Calcium Chloride 1. Planar triangular 2. pyramidal
4. Calcium bromide 3.tetrahedral 4.square planar
12. The electrons generally involved in 19. Central atom of the following compound
bonding has one lone pair of electrons and three
1. are those that lie closest to the nucleus bond pairs of electrons (JIPMER)
2. are those for which t he ionizat ion
1. H 2 S 2. AlCl3 3. NH 3 4. BF3
energies are small
3. belongs to inner shells 20. Some statements about valence bond
4. are free electrons theory are given below
13. Two atoms X and Y have 5 and 7 valence i) The strength of bond depends upon
electrons. The formula of the compound extent of overlapping
formed by their combination is ii) The theory explains the directional
1. X Y 2. X Y 2 3. X Y 3 4. X 3 Y nature of covalent bond
14. Electron configuration of an element A iii) According to this oxygen molecule
i s 1 s 2 2 s 2 2p 6 3 s 1 an d e le c t ro n i c is paramagnetic in nature
configuration of another element B is 1) all are correct
1s 22s 22p 63s 23p 4 . The possible compound 2) only i and ii are correct
that can be formed between A and B is
3) only i and iii are correct
1. A B 2. A B 2 3. A2B 4. A2B3
4) all are wrong
15. How many unit cells are present in a
cube shaped ideal crystal of NaCl of 21. The formal charges on the three oxy-
mass 1g? (atomic masses : Na=23, gen atoms in O3 molecule are
Cl=35.5)
1) 0, 0, 0 2) 0, 0, -1
1) 1.7 10 21 unit cells 3) 0, 0, +1 4) 0, +1, -1
2) 2.57 10 21 unit cells
22. In PO43- , the formal charge on each
3) 5.14 10 21 unit cells oxygen atom and the P-O bond order
4) 1.28 10 21 unit cells respectively are
16. NH 3 and BF3 form an adduct readily 1) -0.75, 0.6 2) -0.75, 1.0
because they form 3) -0.75, 1.25 4) -3 , 1.25
1. A co-ordinate covalent bond 23. Which one of the following has the
2. A covalent bond regular tetrahedral structure?
3. An ionic bond 1) BF4 2) SF4 3) XeF4 4)  Ni(CN ) 4 
2

4. A hydrogen bond
(Atomic nos: B= 5 , S = 16 , Ni= 28, Xe =
17. Fluorine molecule is formed by
54)
1) the axial p-p orbital overlap
24. Which of the following statements is/are
2) the sideways p-p orbital overlap
true
3) the s - s orbital overlap
4) the s - p orbital overlap 1) PH 5 and BiCl5 donot exist
18. According to VSEPR theory, the shape 2) pp - d p bond is present in SO2
of AB 3 molecule with one lone pair of

23
Chemistry For NEET By Prince Sir
3) I 3+ has bent geometry 30. Th e geomet ry arran gemen t of CN
2-
groups around Ni in [Ni (CN )4 ] is
4) SeF4 and CH 4 have same shape
1) tetrahedron 2) square planar
1) 1, 2, 3 2) 1, 3 3) 1 and 2 4) 1, 2, 4 3) trigonal bipyramid 4) octahedron
25. If x-axis is the molecular axis of a 31. Consider the following statements:
diatomic molecule, then, p molecular i) A sigma ( s ) bond is formed when two
orbital are formed by overlap of s-orbitals overlap
1) s-atomic orbitals ii) A pi( p ) bond is formed when two p-
2) s and px atomic orbitals orbitals axially overlap
iii) A s -bond is weaker than p - bond.
3) p y and p y - orbitals
Which of the above statements is/are
4) px and pz - orbitals correct?
26. The molecular shapes of SF4 , CF4 and XeF4 1) i and ii 2) ii and iii
3) i alone 4) ii alone
are
1) different with 1,0 and 2 lone pairs of 32. Th e AsF5 m ol ec u l e i s t ri go n a l
electrons on the central atom, respectively bipyramidal. The atomic orbitals used
2) different with 0,1 and 2 lone pairs of by the As atoms for bonding are :
electrons on the central atom, respectively 2
1) d x2 - y2 , d z , s, px , p y 2) d xy , s , px , p y , pz
3) the same with 1,1 and 1 lone pair of
electrons on the central atom, respectively 3) s, px , p y , pz , d z2 4) d x2 - y2 , s, px , p y
4) the same with 2,0 and 1 lone pair of
electrons on the central atom, respectively 33. A square planar complex is formed by
27. Which formulae does not correctly hybridisation of which atomic orbitals ?
represents the bonding capacity of the 1) s , px , p y , d yz 2) s, px , p y , dx 2 - y 2
atom involved :
3) s , px , p y , d z 2 4) s , px , pz , d xy
34. In XeF2 , XeF4 and XeF6 , the number of
1. 2. lone pairs on Xe are respectively
1) 2, 3, 1 2) 1, 2, 3
3) 4, 1, 2 4) 3, 2, 1
35. According to VSEPR theory, the most
3. 4. probable shape of the molecule having
4 electron pairs in the outer shell of the
28. CO2 has the same geometry as: central atom is
A) HgCl2 , B) NO2 , 1) Linear 2) Tetrahedral
3) Hexahedral 4) Octahedral
C) SnCl2 , D) C2 H 2
36. KF combines with HF to form KHF2 .
1) A and C 2) B and D
3) A and D 4) C and D The compound contains the species
29. Which of the following are isoelectronic 1) K + , F - and H + 2) K + , F - and HF
and isostructural: NO3- , CO32- , CIO3- , SO3 3) K + , and [ HF2 ]- 4) [ KHF ]+ and F2
1) NO3- , CO32- 2) SO3 , NO3- 37. A s bonded molecule MX 3 is T-Shaped.
The number of non bonded pair of
3) CIO3- , CO32- 4) CO32- , SO3 electrons is
24
Chemistry For NEET By Prince Sir
1) 0 2) 2 3) H 2C = C = C = CH 2
3) 1
4) can be predicated only if atomic number
4)
is known
38. Considering greater polarisation in LiCl 44. Co n s i d er the c h e mi ca l sp ec i e s
than in NaCl which of the following is
wrong. NO3- , NO2+
1) Fused LiCl would be less conducting than
and NO2- and point out the correct
fused NaCl
2) LiCl has lower melting point than NaCl statement given below.
3) LiCl dissolves more in organic solvents 1) The hybrid state of N in NO2+ is sp 2
whereas NaCl does not
4) LiCl would ionise in water more than 2) The hybrid state of N in all the species is
NaCl the same
39. Among the following compounds the one 3) The shape of both NO2+ and NO2- is
that is polar and has the central atom
bent while NO3- is planar
with sp 3 hybridization is :
1. H 2CO3 2. SiF4 3. BF3 4. HCIO2 4) The hybrid state of N in
40. Which statement is incorrect for OSF4 ? NO3 and NO2 is the same.
1) S atom has sp 3d hybridization 45 The states of hybridisation of boron and
2) OSF4 have distorted trigonal pyramidal oxygen atoms in boric acid ( H 3 BO3 ) are
geometry respectively.
3) O atom at one of the two axial positions
having bond 1) sp 3 and sp 2 2) sp 2 and sp 3
4) O atom at one of the equatorial position
having bond 3) sp 2 and sp 2 4) sp 3 and sp 3
41. The structure and hybridization of Si (CH 3 )4 46. The maximum number of 90° angle
is between bond pair bond pair of electrons
is observed in
1) bent, sp 2) trigonal , sp 2
1) dsp 2 hybridization
3) octahedral, sp 3 d 4) tetrahedral, sp 3
42. Each carbon in carbon suboxide C3O2  2) sp 3 d hybridization
is 3) dsp 3 hybridization
1) sp 2 - hybridized 2) sp 3 - hybridized
4) sp 3 d 2 hybridization
3) sp - hybridized
4) sp 2 - hybridized but linked with one co- 47. P in PCl5 has sp 3 d hybridization which
ordinate bond of the following statement is wrong
43. Which of the following represents the about PCl5 structure :
g i v en m od e of h y b ri d i s at i o n 1) Two P - Cl bonds are stronger and
2 2
sp - sp - sp - sp from left to right ? three P - Cl bonds are weaker
1) H 2C = CH - C º N 2) Two P - Cl bonds are axial and larger
2) HC º C - C º CH
25
Chemistry For NEET By Prince Sir
than three P - Cl equitorial bonds 1) s 2s 2) p 2 py 3) p 2* py 4) s 2* px
3) PCl5 has trigonal bipyramidal geometry
with non-polar nature 54. Th e number of p ossib le reson an ce

4) In PCl5 Bond angles are 90 & 120 structure for CO32- is

48. Specify the coord inat ion geometry 1) 2 2) 3 3) 6 4) 9
around and hybridisation of N and B 55. The bond order in NO is 2.5 while that
atoms in a 1:1 complex of BF3 and NH 3 in NO + is 3, Which of the following
statements is true for three two species?
1) N : tetrahedral, sp 3 ; B : tetrahedral, sp 3 1) Bond length in NO  is equal to that in
NO
2) N : pyramidal, sp 3 ; B : pyramidal, sp 3 2) Bond length in NO is greater than in
3) N : pyramidal, sp 3 ; B : planar,, sp 3 NO 
3) Bond length in NO  is greater than in NO
4) N : pyramidal, sp 3 ;B : tetrahedral, sp 3
4) Bond length is unpredictable
49. In which compound vacant orbital take 56. In which of the following ionization
part in hybridization p roc es se s , t h e b o n d o rd er h as
1) B 2H6 2) Al2Cl6 3) C 2H 5Cl 4) H 3BO 3 increased and the magnetic behaviour
has changed ?
50. The correct stability order for N 2 and
1) N 2  N 2  2) C2  C2 
its given ions is :
3) NO  NO  4) O2  O2 
1) N 2 > N 2+ > N 2- > N 22-
57. The correct order of increasing C-O
2) N 2- > N 2+ > N 2 > N 22- bond length of CO, CO32- , CO2 is
3) N 2+ > N 2- > N 2 > N 22- 1) CO32- < CO2 < CO
4) N 2 > N 2+ = N 2- > N 22- 2) CO2 < CO32- < CO
51. The correct order in which the O __ O 3) CO < CO32- < CO2
bond length increases in the following : 4) CO < CO2 < CO32-
1) H 2O2 < O2 < O3 2) O3 < H 2O2 < O2 58. Whi ch of t h e followin g overlap i s
correct?
3) O2 < H 2O2 < O3 4) O2 < O3 < H 2 O2
1)
52. The O __ O bond length in O2 , O2 [ AsF4 ]

and K [O2 ] is : 2)
1) O2 [ AsF4 ] < O2 < K [O2 ]
3)
2) O2 [ AsF4 ] < K [O2 ] < O2 4) None of the above.
OH
3) O2 < O2[ AsF4 ] < K [O2 ]
59. The vapour pressure of
4) K [O2 ] < O2 < O2 [ AsF4 ] NO 2
53. Wh i ch of t h e followi n g molecu lar
orbitals has two nodal planes ?

26
Chemistry For NEET By Prince Sir
OH
due to
is higher than is 1.5 D. The dipole moment of
O 2N
1) Dipole moment
2) Dipole - dipole interaction
3) H - bonding is
4) Lattice structure
60. Which statement is wrong about H 2O 1) 2.86 D 2) 2.25 D
1) It has high specific heat relative to other 3) 1.5 D 4) 0 D
liquids or solids due to strong intermolecular 65. Arrange the following compounds in
H - bonding order of increasing dipole moment:
2) H 2O molecule has capacity to form 4 H I) Toluene II)m-dichlorobenzene
III) o-dichlorobenzene IV)p-dichlorobenzene
- bonds
1) I < IV < II < III 2) IV < I < II < III
3) H 2O has open cage like structure due 3) IV < I < III < II 4) IV < II < I < III
to intermolecular H - bonding which give
rise to low density to ice than liquid H 2O
4) H 2O has maximum density at 4° C since
upto 4°C , the intermolecular
H - bonding persists more and there by
decreasing volume and increasing density

61.

Here (a) and (b) are hydrogen bond and

covalent bonds, their lengths are
1) 0.97 Ao , 0.97 Ao 2) 1.73 Ao ,0.97 Ao
3) 1.73 Ao ,1.73 Ao 4) 0.97 Ao ,1.73 Ao
62. W h i ch o f t h e fo l lo wi n g p ai rs o f
molecules will have permanent dipole
moments for both members?
1) NO2 and CO2 2) NO2 and O3
3) SiF4 and CO2 4) SiF4 and NO2
63. Wh i c h on e of t h e f ol lo wi n g
arrangements of molecules is correct on
the basis of their dipole moments?
1) BF3  NF3  NH 3 2) NF3  BF3  NH3
3) NH 3  BF3  NF3 4) N H 3  NF3  BF3
64. The dipole moment of chlorobenzene

27
Chemistry For NEET By Prince Sir
LEVEL-V (A) BF3 (B) SiF4
(C) SF4 (D) XeF4
PART-1
9. The correct sequence of increasing covalent
(PREVIOUS YEAR NEET/AIPMT) character is represented by [CBSE AIPMT 2005]
1. Which of the following statement is not correct for (A) LiCl < NaCl < BeCl2 (B) BeCl2 < NaCl < LiCl
sigma and pi-bonds formed between two carbon (C) NaCl < LiCl < BeCl2 (D) BeCl2 < LiCl < NaCl
atoms ? [CBSE AIPMT 2003]
(A) Free rotation of atoms about a sigma bond is 10. In which of the following molecules are all the bonds
allowed but not in case of a pi-bond not equal ? [CBSE AIPMT 2006]
(B) Sigma bond determines the direction between (A) ClF3 (B) BF3
carbon atoms but a pi-bond has no primary effect (C) AlF3 (D) NF3
in this regard 11. Which of the following species has a linear shape ?
(C) Sigma bond is stronger than a pi-bond [CBSE AIPMT 2006]
(D) Bond energyies of sigma and pi-bonds are of the
order of 264 kJ/mol and 347 kJ/mol. respectively (A) NO 2 (B) SO2
2. Among the following, pair in which the two species
are not isostructural, is [CBSE AIPMT 2004] (C) NO 2 (D) O3
(A) SiF4 and SF4 (B) lO3– and XeO3 12. The number of unpaired electrons in a paramagnetic
(C) BH4– and NH4+ (D) PF6– and SF6 diatomic molecule of an element with atomic number
16 is [CBSE AIPMT 2006]
3. In a regular octahedral molecule, MX6 the number of
X –M – X bonds at 180° is [CBSE AIPMT 2004] (A) 2 (B) 3
(A) 3 (B) 2 (C) 4 (D) 1
(C) 6 (D) 4 13. Which of the following is not isostructural with SiCl4?
[CBSE AIPMT 2006]
4. In an octahedral structure, the pair of d orbitals
involved in d2sp3 - hybridisation is (A) SCl4 (B) SO 24
[CBSE AIPMT 2004]
d ,d (C) PO34 (D) NH 4
(A) x 2  y2 z2 (B) d xz ,d x 2  y2
(C) d z2 ,d xz (D) d xy ,d yz 14. The electronegativity difference between N and F is
greater than that between N and H yet the dipole
5. H2O is dipolar, whereas BeF2 is not. It is because moment of NH3 (1.5 D) is larger than that of NF3 (0.2
[CBSE AIPMT 2004] D). This is because [CBSE AIPMT 2006]
(A) the electronegativity of F is greater than that of O (A) in NH3 as well as in NF3, the atomic dipole and
(B) H2O involves hydrogen bonding wherease BeF2 bond dipole are in the same direction
is a discrete molecule (B) in NH3, the atomic dipole and bond dipole are in
(C) H2O is linear and BeF2 is angular the same direction whereas in NF3 these are in
opposite directions
(D) H2O is angular and BeF2 is linear
(C) in NH3 as well as NF3, the atomic dipole and bond
6. In BrF3 molecule, the lone pairs occupy equatorial dipole are in opposite directions
positions to minimise [CBSE AIPMT 2004] (D) in NH3 the atomic dipole and bond dipole are in
(A) lone pair-bond pair repulsion the opposite directions whereas in NF3 these
(B) bond pair-bond pair repulsion are in the same directions
(C) lone pair-lone pair repulsion and lone pair-bond
15. Which of the following is not a correct statement ?
pair repulsion
[CBSE AIPMT 2006]
(D) lone pair-lone pair repulsion
(A) The electron deficient molecules can act as Lewis
7. Which of the following molecules has trigonal acids
planar geometry ? [CBSE AIPMT 2005] (B) The canonical structures have no real existence
(A) IF3 (B) PCl3 (C) Every AB5 molecule does infact have square
(C) NH3 (D) BF3 pyramid structure
(D) Multiple bonds are always shorter than
8. Which of the following would have a permanent
dipole moment ? [CBSE AIPMT 2005]

28
Chemistry For NEET By Prince Sir
corresponding single bond (D) Ml > MBr > MCl > MF
16. The correct order of C–O bond length among CO, 23. In which of the following molecules/ions BF3, NO2– ,
NH2– and H2O, the central atom is sp2 hybridised ?
CO32 , CO2 is [CBSE AIPMT 2007]
[CBSE AIPMT 2009]
(A) CO2  CO32  CO (B) CO  CO32  CO 2 (A) NO2– and NH2– (B) NH2– and H2O
(C) NO2– and H2O (D) BF3 and NO2–
(C) CO23  CO 2  CO (D) CO  CO 2  CO32
24. What is the dominant intermolecular force on bond
17. In which of the following pairs, the two species are that must be overcome in coverting liquid CH3OH to
isostructural ? [CBSE AIPMT 2007] a gas ? [CBSE AIPMT 2009]
(A) SF4 and XeF4 (B) SO23 and NO3 (A) Hydrogen bonding
(B) Dipole-dipole interaction
(C) BF3 and NF3 (D) BrO3 and XeO3
(C) Covalent bonds
18. The angular shape of ozone molecule (O3) consists (D) London or dispersion force
of [CBSE AIPMT 2008]
25. In which one of the following species the central
(A) 1 sigma and 2 pi-bonds atom has the type of hybridisation which is not the
(B) 2 sigma and 2 pi-bonds same as that present in the other three ?
(C) 1 sigma and 1 pi-bonds [CBSE AIPMT 2010]
(D) 2 sigma and 1 pi-bonds (A) SF4 (B) I3–
19. The correct order of increasing bond angles in the (C) SbCl52–
(D) PCl5
following triatomic species is 26. The correct order of increasing bond angles in the
[CBSE AIPMT 2008] following species is [CBSE AIPMT 2010]
(A) NO 2  NO 2  NO2 (A) Cl2O < ClO2 < ClO2–
(B) ClO2 < Cl2O < ClO2–
–
(C) Cl2O < ClO2 < ClO2 (D) ClO2– < Cl2O < ClO2
(B) NO 2  NO 2  NO2
27. Which one of the following species does not exist
(C) NO 2  NO2  NO 2 under normal conditions ? [CBSE AIPMT 2010]
(A) Be2+ (B) Be2
(D) NO 2  NO2  NO2 (C) B2 (D) Li2
20. Four diatomic species are listed below in different 28. In which of the following pairs of molecules/ions,
sequences. Which of these presents the correct order the central atoms have sp2 hybridisation ?
of their increasing bond order ? [CBSE AIPMT 2010]
[CBSE AIPMT 2008] (A) NO2– and NH3 (B) BF3 and NO2–
(A) O 2  NO  C22  HE 2 (C) NH2– and H2O (D) BF3 and NH2–

(B) NO  C22  O 2  He2 29. Which of the following has the miniumum bond length
? [CBSE AIPMT 2011]
(C) C22  He2  NO  O 2 (A) O 2 (B) O22
(D) He2  O 2  NO  C22 (C) O2 (D) O 2
21. According to molecular orbital theory which of the 30. Which of the following is least likely to behave as
following lists rank the nitrogen species in terms of Lewis base ? [CBSE AIPMT 2011]
increasing bond order ? [CBSE AIOMT 2009] (A) NH3 (B) BF3
(A) N 2  N 2  N 22 (B) N 22  N 2  N 2 (C) OH– (D) H2O

(C) N 2  N 22  N 2 (D) N 2  N 22  N 2 31. Whcih of the two ions from the list given below, have
the geometry that is explained by the same
22. In the case of alkali metals, the covalent character hybridisation of orbitals, [CBSE AIPMT 2011]
decreases in the order [CBSE AIPMT 2009] NO 2 , NO3 , NH 2 , NH 4 ,SCN  ?
(A) MCl > Ml > MBr > MF
(B) MF > MCl > MBr > Ml (A) NH 4 and NO3 (B) SCN  and NH 2
(C) MF > MCl > Ml > MBr
29
Chemistry For NEET By Prince Sir
(A) H+ (B) Li+
(C) NO2 and NH 2 (D) NO2 and NO3
(C) Na+ (D) Mg2+
32. Considering the state of hybridisation of carbon 43. Which of the following options represents the
atoms, find out the molecule among the following correct bond order ? [CBSE AIPMT 2015]
which is linear ? [CBSE AIPMT 2011]
(A) CH3 – C  C – CH3 (A) O 2  O2  O 2 (B) O 2  O2  O 2
(B) CH2 = CH – CH2 C  CH
(C) O 2  O2  O 2 (D) O 2  O2  O 2
(C) CH3 – CH2 – CH2 – CH3
(D) CH3 – CH = CH – CH3 44. Which of the following pairs of ions are isoelectronic
and isostructural ? [CBSE AIPMT 2015]
33. The pari of species with the same bond order is
[NEET 2013] (A) CO32 ,SO32 (B) ClO3 ,CO32
(A) O22 , B2 (B) O2 , NO (C) SO32 , NO3 (D) ClO3 ,SO32
(C) NO, CO (D) N2, O2
45. Which of the following species contains equal
34. Which of the following species contains three bond number of  and -bonds ? [NEET 2016, Phase II]
pairs and one lone pair around the central atom ? (A) HCO3– (B) XeO4
[NEET 2013] (C) (CN)2 (D) CH2(CN)2
(A) H2O (B) BF3
(C) NH2– (D) PCl3 46. Which of the following pairs of ions is isoelectronic
and isostructural ? [NEET 2016, Phase II]
35. Bond order of 1.5 is shown by [NEET 2013]
(A) O2+ (B) O2– (A) CO32 , NO3 (B) ClO3 , CO32
(C) O22– (D) O2
(C) SO32 , NO3 (D) ClO3 ,SO32
36. Which of the following is paramagnetic ?
[NEET 2013] 47. The hybridisations of atomic orbitals of nitrogen in
(A) CO –
(D) O2 NO2+, NO3– and NH4+ respectively are
[NEET 2016, Phase II]
(C) CN– (D) NO+
(A) sp, sp3 and sp2 (B) sp2, sp3 and sp
37. Which of the following is a polar molecule ? (C) sp, sp2 and sp3 (D) sp2, sp and sp3
[NEET 2013]
48. Which one of the following compounds shows the
(A) BF2 (B) SF4
presence of intramolecular hydronge bond ?
(C) SiF4 (D) XeF4
[NEET 2016, Phase II]
38. Which one of the following molecules contain no (A) H2O2
-bond ? [NEET 2013] (B) HCN
(A) CO2 (B) H2O (C) Cellulose
(C) SO2 (D) NO2 (D) Concentrated acetic acid
39. Identify the correct order of solubility in aqueous 49. Consider the molecules CH4, NH3 and H2O. Which
medium. [NEET 2013] of the given statements is false ?
(A) CuS > ZnS > Na2S (B) ZnS > Na2S > CuS [NEET 2016, Phase I]
(C) Na2S > CuS > ZnS (D) Na2S > ZnS > CuS (A) The H–O–H bond angle in H2O is larger than the
H–C–H bond angle in CH4
40. Which one of the following species has plane (B) Then H–O–H bond angle in H2O is smaller than
triangular shape ? [CBSE AIPMT 2014] the H–N–H bond angle in NH3
(A) N3 (B) NO3– (C) The H–C–H bond angle in CH4 is larger than the
(C) NO2– (D) CO2 H–N–H bond angle in NH3
41. Which of the following molecules has the maximum (D) The H–C–H bond angle in CH4, the H–N–H bond
dipole moment ? [CBSE AIPMT 2014] angle in NH3 and the H–O–H bond angle in H2O
(A) CO2 (B) CH4 are all greater than 90°
(C) NH3 (D) NF3
50. Predict the correct order among the following.
42. Be2+ is isoelectronic with which of the following ions [NEET 2016, Phase I]
? [CBSE AIPMT 2014]
30
Chemistry For NEET By Prince Sir
(A) lone pair -lone pair > bond pari-bond pair > lone PART-2
pair-bond pair
(B) bond pair-bond pair > lone pair-bond pair > lone (PREVIOUS YEAR AIIIMS)
pair-lone pair 1. Which of the following compounds possesses the
(C) lone pair-bond pair > bond pair-bond pair > lone C–H bond with the lowest bond dissociation
pair-lone pair energy ? [2003]
(D) lone pair-lone pair > lone pair-bond pair > bond (A) Toluene
pair-bond pair
(B) Benzene
51. Which one of the following pairs of species have the (C) n-Pentane
same bond order ? [NEET 2017]
(D) 2, 2 - Dimethylpropane
(A) CO, NO (B) O2, NO+
(C) CN–, CO (D) N2, O2– 2. Which of the following are arranged in the
decreasing order of dipole moment ? [2003]

52. Magnesium reacts with an element (X) to form an (A) CH3Cl, CH3Br, CH3F
ionic compound. If the ground state electronic (B) CH3Cl, Ch3F, CH3Br
configuration of (X) is 1s2 2s2 2p3, the simplest (C) CH3Br, CH3Cl, CH3F
formula for this compound is. [NEET 2018]
(D) CH3Br, CH3F, CH3Cl
(A) Mg2X (B) MgX2
(C) Mg2X3 (D)Mg3X2 3. The ONO angle is maximum in [2004]

(A) NO3 (B) NO2

53. Consider the following species:
CN+, CN–,NO and CN (C) NO2 (D) NO2
Which one of these will have the highest bond
order ? [NEET 2018] 4. Among the following, the species having squear pla-
nar geometry for central atom are [2006]
(A) CN+ (B) CN– (C) NO (D) CN
(i) XeF4, (ii) SF4, (iii) [NiCl4]2–, (iv) [PdCl4]2–
54. In the structure of CIF3, the number of lone pairs of
electrons on central atom 'Cl' is. [NEET 2018] (A) (i) and (iv) (B) (i) and (ii)
(C) (ii) and (iii) (D) (iii) and (iv)
(A) four (B) two (C) one (D) three
5. In [Ag(CN)2]–, the number of  bonds is [2006]
55. The correct order of N-compounds in its decreas-
(A) 2 (B) 3
ing order of oxidation states is [NEET 2018]
(C) 4 (D) 6
(A) HNO3, NH4 Cl, NO, N2
(B) HNO3, NO, NH4 Cl, N2 6. Bond length order is [2007]

(C) HNO3, NO, N2, NH4 Cl (A) O2 < O3 < O22– 2–

(B) O2 < O2 < O3
(D) NH4 Cl, N2, NO, HNO3 (C) O22– < O3 < O2 (D) O2 = O22– > O3

7. Which of the following does not contain any

56. Which of the following oxides is most acidic in
coordinate bond ?
nature ? [NEET 2018]
(A) BaO (B) BeO (A) H3O+ (B) BF4
(C) MgO (D) CaO
(C) HF2 (D) NH 4

8. The correct order of diople moment is [2008]

(A) CH4 < NF3 < NH3 < H2O
(B) NF3 < CH4 < NH3 < H2O
(C) NH3 < NF3 < CH4 < H2O
(D) H2O < NH3 < NF3 < CH4

31
Chemistry For NEET By Prince Sir
9. The molecule having the same hybridisation, shape 17. Which of the following represents the correct bond
and number of lone pairs of electrons are [2009] order ? [2014]
(A) SeF4, XeO2F2 (B) SF4, XeF2 (A) O 2  O 2  O22 (B) O 2  O22  O 2
(C) XeOF4, TeF4 (D) SeCl4, XeF4
(C) O 22  O 2  O2 (D) O 2  O2  O22
10. Which of the following conditions is not correct for
resonanting structures ? [2010] 18. Which of the following molecules has more than one
(A) The contributing structures must have the same lone pair ? [2016]
number of unpaired electrons. (A) SO2 (B) XeF2
(B) The contributing structures should have similar (C) SiF4 (D) CH4
energies.
19. Four diatomic species are listed below in different
(C) The contributing structures should be so written sequences. Which of these represents the correct
that unlike charges reside on atoms that are far order of their increasing bond order ? [2016]
apart.
(A) C 22  He 2  NO  O 2
(D) The positive charge should be present on the
electropositive element and the negative charge (B) He 2  O2  NO  C 22
on the electronegative element.
(C) O 2  NO  C 22  He 2
11. CaO and NaCl have the same crystal structure and
(D) NO  C 22  O 2  He 2
apporximately the same ionic radii. If U is the lattice
energy of NaCl, the approximate lattice energy of CaO 20. Hybridisation states of C in CH3+ and CH4 are
is [2010] (A) sp2 & sp3 (B) sp3 & sp2
2 2
(C) sp & sp (D) sp3 & sp3 [2017]
(A) U/2 (B) U
(C) 2U (D) 4U 21. Which of the following cantain at least one lone pair
in all of its halide
12. Decreasing order of bond angle is [2011]
(A) Xe (B) Se
(A) BeCl2 > NO2 > SO2 (B) BeCl2 > SO2 > NO2 (C) Cl (D) N [2018]
(C) SO2 > BeCl2 > NO2 (D) SO2 > NO2 > BeCl2
22. Which is incorrect regarding S and P mixing (along Z
13. The dipole moment is minimum in [2012] –axis.)
(A) NH3 (B) NF3 (A) Nodal plane(s) present in ABMO
(C) SO2 (D) BF3 (B) Nodal plane is absent in BMO
(C) MO formed may have higher energy than parent
14. Total number of antibonding electrons present in O2 AO
will be [2013] (D) MO formed are asymmetric [2018]

(A) 6 (B) 8
(C) 4 (D) 2

15. In BF3, the B–F bond length is 1.30 Å, when BF3 is

allowed to be treated with Me3N, it form an adduct,
Me3N  BF3, the bond length of B–F in the adduct is
[2013]

(A) greater than 1.30 Å (B) smaller than 1.30 Å

(C) equal to 1.30 Å (D) none of these

16. In O3 molecule, the formal charge on the central O-

atoms is [2014]

(A) 0 (B) –1
(C) –2 (D) +1

32
Chemistry For NEET By Prince Sir
ASSERTION AND REASON
ANSWER KEY
In each of the following questions, two statement
are given one is assertion and the other is reason.
Examine the statement carefully and mark the correct LEVEL - I
answer according to the instruction given below
(A) If both the assertion and reason are true and
reason explains the assertion 1) 3 2) 2 3) 2 4) 3 5) 4
(B) If both the assertion and reason are true but 6) 1 7) 4 8) 3 9) 2 10) 2
reason does not explain the assertion 11) 4 12) 4 13) 1 14) 1 15) 2
(C) If assertion is true but reason is false 16) 4 17) 1 18) 2 19) 2 20) 1
(D) If assertion is false but reason in true
21) 4 22) 1 23) 1 24) 2 25) 1
(E) Both assertion & reason are false
26) 1 27) 4 28) 1 29) 3 30) 3
23. Assertion : All F – S – F angle in SF4 is greater than 31) 3 32) 3 33) 1 34) 3 35) 2
90° but less than 180°. 36) 2 37) 2 38) 4 39) 3 40) 3
Reason : The lone pair-bond pair repulsion is weaker 41) 4 42) 2 43) 4 44) 2 45) 3
than bond pair-bond pair repulsion.
46) 1 47) 4 48) 4 49) 2 50) 2
[2004]
51) 1 52) 3 53) 4 54) 4 55) 1
24. Assertion : Molecular nitrogen is less reactive than
56) 4 57) 3 58) 2 59) 1 60) 1
molecular oxygen
61) 3 62) 3 63) 2 64) 2 65) 4
Reason : The bond length of N2 is shorter than that
66) 1 67) 1 68) 4 69) 1 70) 2
of oxygen. [2006, 2015]
71) 1 72) 2 73) 3 74) 4 75) 4
25. Assertion : SeCl 4 does not have a tetrahedral 76) 3 77) 2 78) 2 79) 4 80) 2
structure. 81) 1 82) 3 83) 2 84) 4 85) 2
Reason : Se in SeCl4 has two lone pairs. 86) 1 87) 2 88) 3 89) 1 90) 2
[2008] 91) 3 92) 1 93) 4 94) 3 95) 2
26. Assertion : Bond energy and bond dissociation en- 96) 4 97) 3 98) 4 99) 3 100) 2
ergy have identical value for diatomic molecules. 101) 2 102) 1 103) 2 104) 2 105) 3
Reason : Greater the bond dissociation energy, less 106) 3 107) 1 108) 2 109) 4 110) 3
reactive is the bond. [2010]
111) 1 112) 1 113) 3 114) 4 115) 4
27. Assertion : CIF3 has T-shape structure. 116) 1 117) 1 118) 1 119) 3 120) 2
Reason : It has two lone pairs arranged at 180° angle. 121) 4 122) 1 123) 1 124) 2 125) 3
[2012] 126) 4 127) 2 128) 1 129) 1 130) 2
28. Assertion : O2 is paramagnetic. 131) 2 132) 1 133) 4 134) 2 135) 3
Reason : It has one unpaired electron. [2012] 136) 3 137) 2 138) 2 139) 4 140) 3
141) 3 142) 3 143) 3 144) 4 145) 1
29. Assertion : Both rhombic and monoclinic sulphur
146) 1 147) 4 148) 1 149) 3 150) 4
exist as S8 but oxygen exists as O2. [2017]
151) 2 152) 3 153) 2 154) 3 155) 2
Reason : Oxygen forms p – p multiple bond due to
156) 2 157) 1 158) 4 159) 2 160) 4
small size and small bond length but p – p bonding
161) 3 162) 1 163) 1 164) 4 165) 3
is not possible in sulphur.
30. Assertion : Lithium carbonate is not so stable to
heat. [2017] LEVEL - II
Reason : Lithium being very small in size polarizes
large CO32 ion leading to the formation of more stable 1) 3 2) 2 3) 2 4) 3 5) 3
Li2O and CO2 6) 1 7) 2 8) 3 9) 3 10) 1

33
Chemistry For NEET By Prince Sir
11) 3 12) 2 13) 2 14) 2 15) 4 26) 1 27) 4 28) 3 29) 1 30) 2
16) 4 17) 4 18) 3 19) 2 20) 3 31) 3 32) 3 33) 2 34) 4 35) 2
21) 3 22) 4 23) 3 24) 4 25) 3 36) 3 37) 2 38) 4 39) 4 40) 3
26) 3 27) 4 28) 4 29) 2 30) 1 41) 4 42) 3 43) 1 44) 4 45) 2
31) 3 32) 3 33) 2 34) 2 35) 1 46) 4 47) 1 48) 1 49) 1,2 50) 1
36) 1 37) 2 38) 1 39) 1 40) 1 51) 4 52) 1 53) 3 54) 2 55) 2
41) 2 42) 2 43) 2 44) 1 45) 4 56) 3 57) 4 58) 1 59) 3 60) 4
46) 3 47) 4 48) 2 49) 3 50) 4 61) 2 62) 2 63) 4 64) 3 65) 2
51) 4 52) 3 53) 1 54) 2 55) 2 LEVEL - V
56) 4 57) 1 58) 2 59) 2 60) 3 ( PART - I)
61) 2 62) 1 63) 2 64) 1 65) 3
1. D 2. A 3. A 4. A 5. D 6. D 7. D
66) 2 67) 3 68) 2 69) 4 70) 1
8. C 9. C 10. A 11. C 12. A 13. A
71) 1 72) 2 73) 2 74) 3 75) 2 14. B 15. C 16. D 17. D 18. D 19. B 20. D
76) 4 77) 4 78) 2 79) 1 80) 3 21. B 22. D 23. D 24. A 25. C 26. D
81) 1 27. B 28. B 29. D 30. B 31. D 32. A 33.
A 34. D 35. B 36. B 37. B 38. B 39. D
40. B 41. D 42. B 43. B 44. D 45. B 46.
A,D 47. C 48. C 49. A 50. D 51. C 52. D
LEVEL - III 53. B 54. B 55. C 56. B
1) 2 2) 4 3) 2 4) 2 5) 3
LEVEL - V
6) 2 7) 4 8)4 9) 4 10) 2
( PART - II)
11) 2 12) 2 13) 3 14) 1 15) 4
16) 1 17) 1 18) 4 19) 2 20) 2
1. A 2. B 3. D 4. A 5. C 6. A 7. C
21) 2 22) 2 23) 2 24) 2 25) 4 8. A 9. A 10. C 11. D 12. A 13. D
26) 3 27) 3 28) 4 29) 4 30) 3 14. A 15. A 16. D 17. D 18. B 19. B 20.
A 21. A 22. B 23. C 24. A 25. C 26. B
31) 4 32) 3 33) 3 34) 2 35) 4
27. C 28. C 29. A 30. A
36) 1 37) 1 38) 1 39) 2 40) 3
41) 3 42) 1 43) 2 44) 2 45) 1
46) 2 47) 3 48) 1 49) 2 50) 3
51) 3 52) 1 53) 1 54) 3 55) 1
HINTS & SOLUTIONS
56) 4 57) 1 58) 2 59) 1 60) 4
61) 4 62) 4 63) 1 64) 1 65) 2
66) 2 67) 2 68) 3 69) 4 70) 1 LEVEL - I
71) 2 72) 1 73) 2 74) 2 75) 2
1. Conceptual
2. Formation of a bond is exotheermic process
LEVEL - IV
3. Chemical bond formation is exothermic.
4. Atoms are unstable hence highly energetic
1) 2 2) 1 3) 4 4) 2 5) 2
5. Be3  1s1
6) 4 7) 3 8) 4 9) 4 10) 4
11) 2 12) 2 13) 3 14) 3 15) 2 6. Conceptual
16) 1 17) 1 18) 2 19) 3 20) 2 7. As outermost electrons enters into same
21) 4 22) 3 23) 1 24) 1 25) 3 orbit, No.of valency electrons increases
w.r.t.oxygen.
34
Chemistry For NEET By Prince Sir
8. W.r.t.Oxygen valency increases left to right 33. In solid state ions are tightly packed
in a period. 34. urea doesnot ionise
9. Excited state, Electronic configuration of Si 35. Isomerism is exhibited by only covalent
is [Na] 3s1 3 p 3 compounds
36. One units cell 4 Nacl ionic pairs are
10. The element belongs to V group . It doesnot
present
exceed group number .
37. eit her free ions or free electrons are
11. Electrovalency of K is 1 & S is 2.
required for conducting electricity.
12. E lec t r o va le nc y of
38. Higher the Hydeation energy than Lattice
Na=1,Ca=2,Mg=2,Al=3.
energy more is sotuble.
13. The EN difference = 2.3,Which is greater
39. Conceptual
than 1.7 .
40. Electronegative difference between I and Cl is very
14. IA : most electro positive elements little.
VIIA : most electro negitive elements 41. Nitrogen molecule has one sigma bond and
15. due to large  E.N. two pi-bonds.
16. In Rubedium ion no of electrons is 36& in 42.
Br  ion no.of electrons. 43. Greater the size of cation more the ionic
17. Lower the IP value greater is the ease of nature.
formation of cation, 44. Be caus e o f s mall size ( les s e lect r o
18. positivity)
ca 2  ion has inertgass configuration while
45. In ammonium ion nitrogen forms 3 covalent
zn 2  has pseudo inertgas configuration bonds and one dative bond.
19. E.C. of Cu 1s 2 2s 2 2 p 6 3s 2 3 p 6 4 s 0 3d 10 46. Because of non availability of d-orbitality.

20. EN difference = 3.1, EN of Na = 0.9,EN 47. In ethane 7 bonds are present (7x2=14 EN)
of F =4. 48. In HC  N one bond is present between
21. small cation and large anion. three bonds between carbon and nitrogen.
22. Conceptual 49. In SF6 six bond pairs are present.
1 50. Smaller cation causes more polarization of
23. u  H f  S N a  I Na Dcl  U Nacl
2 2 anion.
24. KI is insoluble in benzene being ionic 51. Ionic character follows the order HF>HCl>
compound HBr >HI
25. CsCl has B.C.C structure 52. More no.of atoms involved with less EN
26. CsCl unit cell contains one formula unit difference.
27. Co-ordination no,of cation in FCC lattice 53. H 2O2 has 3 covallent bond.
is six. 54. Larger the size of anion the nore is the
28. Co-ordination no.of Cs  ion in CsCl = 8. polarizability.
55. Sum of the electrons are odd in number.
29. Cl- ions are at corners & face centre 56. The electronegativity of S is least among
30. Conceptual others. Hence H-S bond is least polar in
31. The radius ratio of cation is 0.225 to 0.414. nature.
32. Ionic compounds have high M.P and B.P hence they 57. is non-planar and polar..
are less volatile

35
Chemistry For NEET By Prince Sir
58. The central atom of Be contains 4 electrons 85. Hybridisation of nitrogen in nitrate ion is sp 2
59. The central atom of Be contains 4 electrons
60. sigma bond is stronger than pi bond. 86. sp 3 d 3
61. pi bond is formed by the lateral overlaping’ 87. Hybridisation of Bromine in BrF5 is sp 3 d 2
62. pi bond is formed by the pure orbitals.
63. In alka ne s ca r bo n unde r g o e s 88. sp 3 d 2
89. hybrid orbitals form sigma bonds only.
sp 3 hybridisation
90. More the S-character smaller the size
64. P -P overlap gives strongest bond
65. s-orbital of hydrogen and p-orbit al of 91. I n et ha ne c ar bo n unde r g o e s sp 3
fluorine overlaps. hybridisation
66. half filled P-orbital of sulphur overlap with 62
half filled S-orbital of H-atom 92. In Cl2O T .P.   4  sp 3 
2
67. Conceptual
93. sp 3 hybridization , hence s - character is
68. Pz  Pz overlap
25%
69. Order of overlapping is
 p p s p ss 94. In H 3O  oxygen has sp 3 hybridization
70. N  C C  N 95. CO2 -sp-linear
71. H 2 S has bent structure. 96. Hybridisation of Bromine in BrF5 is sp 3 d 2
72. SnCl2 has angular structure 97. sp 3
73. sp 3 d hybridisation. 98. C-H bond is  sp 2  s
74. sp 3 -1 C-H bonds,3 C-Cl bonds. 99. In XeF4 ,Xe has 4 BP& 2LP..
75. 4 BP, 0Lp.
100. Xe has 8 electrons in outermost shell, two
3 2
76. sp d - square planar electrons participate in bonding and six
electrons exists as 3 lone pairs.
77. Cl has 3 bond pairs and 1 lone pair in ClO3
101. Sulphur has six electrons in outer most shell,
78. OF 2 has 2 bond pairs and 8 lone pairs. two electrons participating bonding and four
electrons exist as two lone pairs.
102 In Ammonia N has 3 BP & 1LP
103. In propene 10 hybrid orbitals (3+3+4) are
79. Structure of NO3 is present.
104. In decane 4x10=40 hybrid orbitals present.
80. Orientation of Hybrid orbitals in water is tetrahydral 105. Conceptual
and shape is angular 106. In carbon atoms TP = no. of sigma bonds
81. Conceptual 107. bond angle  s- character
82. Oxygen cannot expand its octet because 108. Angular shape
of non availability of d - orbitals. 109. B3 N 3 H 6 has 3 dative bonds.
83. In hybridisation combination and re distri
110. In a complex dative bonds are present
bution of atomic orbitals takes place.
between metal and ligand.
84. sp 3 d 2
111. CCl4 is cov alent & CaH 2 is ionic

36
Chemistry For NEET By Prince Sir
112 In CuSO 4 only four H 2O act as ligand or 135. Conceptual
co-ordination number for cu2+ is four. 136. Conceptual
113. Conceptual 137. No.of molecular orbitals formed is equal to
114. o-Salicylaldehyde has intermolecular H- No.of atomic orbitals.
bonding. 138. since Anti bonding orbitals are formed by
115. In p-nitrophenol ‘OH’ and NO2 groups are subsraction of orbitals
139. In O2 paired electrons are 14 , and unpaired
farfrom each other and it has intermolecular
electrons are 2 .
H-bonding.
140. Conceptual
116. F has highest EN.
141. Conceptual
117. H-bond by simply vander waal’s attraction.
118. Ionic bond > covalent bond > Hydrogen 142. O2 2 confairs .4 Anti bonding and 5 bonding
bond > vander waals forces > metallic electron pairs.
bond. 143.  1s 2 *1s1
119. F has highest EN.
144. Species with odd number of electrons have
120. Ammonia has hydrogen bonds fractional bond order.
121. Because of high EN of ‘O’ 145. antibonding electrons in
2 1 1  2
B.O.    0.5 forms intermolecular O2  7 , O2  6, O2  8
2 2
146. Isostructured species will have same bond
H-bonding.
order
122. Intermolecular H-bonding in ethanol.
147. If B.O. = 0 (or) < 0
123. Ethyl alcohol has hydrogen bonds.
Molecule does not exist.
124. b.p. increases from top to bottom but b NH 3
148.  2 p z have lower energy for O 2
has high b.p. due to H-bonding.
125. NH 3 has intermolecular H-bonding. 149. O2  has one unpaired electron.
126. Bromine has no hydrogen bonds. 150. Bond order  Bond strength
127. 2 lone pairs of ‘O’ and 2’H’ atoms in H 2O 1
151. Bond order = ( Nb  N a )
molecule involve in H-bonding 2
128. Ice occupies more volume than water Bond order of
129. More number of H-bonds
Li2  1, N 2  3, Be2  0, O2  2
130. Because o-nitrophenol has intramolecular
H-bonding. 2 1 1
152. B.o.    0.5
131. C2 H 5OH can form int ermolecular H- 2 2

bonding with H 2O . B.o.of O2  2


132. Because base units in DNA has H,N & O O2  2.5
153.
as component elements. 
O2  1.5
133. in co pper sulphat e cr yst al 4 wat er
molecules bonded to copper ions through 10  5 5
dat ive bonds, o ne wat er molecule is 154. B.O    2.5
2 2
attached to sulphate ion through hydrogen
155. ‘NO’ has 15 electrons
bonds.
134. Coceptual 156. Both O2 and O2 are paramagnetic bond

37
Chemistry For NEET By Prince Sir
order of O2  2.5 and O2  2 10. unit cell of NaCl contains 4 ionicpairs
4 X 58.5 amu
157. NO  has 16 electron system bond order 11. Conceptual
=2 12. A. N 2 0=C a, A- N 16 =S , Ca S is t he
NO  , CN  , N 2 are isoelectronic with CO. compound.
 All have same bond order = 3 13. C2 H 5OH is covalent compound.
158. O2 has one unpaired electron 14 As it contains ions
15. Ionic bond is non direction
Nb  N a 8  2 16. HCl ionises only in aqueous solution
159. Bond order =  3
2 2 17. In pure covalent bond electrons are equally
160. Conceptual shared
161. Conceptual 18.  E .N .  polarity.
162. Symmet r ic st r uct ur e have least
19. Lesser the electro negativity difference more
dipolemoment
covallent.
163. S in H 2S shows sp 3 hybridization with
20. Glucose is not polymer.
angular V-Shape due to the presence of two
lone pairs of electrons on S-atom . Also 21. Because of low electronegativity.
22. Vander waal forces are physical forces
 0
hence weekest.
164. greater the bond moment , greater is  23. Diamond has only C - C bonds.
165. SiF4 symmetrical molecule
24. BrCl3 , SF6 , PCl5 have 10,12,10 electrons in
centralatoms
LEVEL - II
25. BCl3 has 6 electrons in valence shell of B

1. As it fo r ms 6 co va le nt bo nds w it h 26. CHCl3 is covallent hence does not give Cl 

neighbours 27. According to Fajan, covelent bond is
2. Differentiating electrons enters into (n-1)d favoured
electrons participate in bonding. by small cation & large anion.
3. 28.
Sr 2  S 2  (two electrons are transfered)
4. In peroxide oxygen valency is one. 29. If  E.N . = 1.9 ionic charecter 50%.
5. A is a VII A group and C is a I A group 30. Sum of the electrons are odd in number.
element 31. Dielectric constant is directly proportional
 The compound is ionic. to the ionising power of solvent.
6. 2 electrons from x participate in bond 32. In dative bond electron pair is donated.
formation with one unpaired electron of y. 33. Conceptual
34. Conceptual
z z
7.  35. N  N has triple bond
rc  ra
8. Hydration energy of BaSO4 is less. So it is less 36. p y , pz are perpendicular to each other..
soluble in water 37. hybrid orbitals do not form pi bonds.
9. Conceptual
38.  N  C 2  C  C   C  N  2
39. Conceptual
40. Order of overlapping is
38
Chemistry For NEET By Prince Sir
 p  p   s  p   s  s , 1 s- 1s bo nd is 61. Intermolecular H-bonding.
stronger because 1s orbital is close to the 62. Conceptual
nucles. 63. Conceptual
41. Only d of S and P of O can be involved in 64. Conceptual
 bonding. 65. Conceptual
42. Repulsion between LP-LP and LP-BP 66. Conceptual
43. Repulsion between the electron pairs results 67. Bond order =
the decreasing bond angle. no of bonds betw een a set of tw o atom s in all canonical form s
2 3 no of canonical form s
44. In BCl3 ( sp ),in NCl3 ( sp )
45. Conceptual 68. B.O. in O2 =2
46. In CO2 & CO has sp hybridization. B.O. in O2  =1.5
47. CH 3CH 2OH is saturated hence all carbon 69. Conceptual
70. Conceptual
atoms are sp 3 hybridized.
2
71. CO, NO  , CN  & C2 contain 14 electrons
48. In C2 H 4 , no. of HO’s = 3 + 3 = 6
each.
49. C2 (CN ) 4 is 72. Cis 1,2 dichloro benzene

C C is sp2 hybridised and C N is Will have some value for  .

sp hybridised.
73.  C .CH 3 is symmetrical and linear .
CH 3 .C
50. Ethylene on hydrogenation into ethane :
hybradization , bond angle & C - C bond Hence  = 0
length change 74. NO 2 and O 3 have V-Shape or bent shape
 They have some dipolemoment.
51. sp 3 d has bond angles 900 &1200
75. Conceptual
52.
53. s-character = 50% ; 76.
p-character = 50%
54. sp hybridisation is formed.
60
55. In SO2 T .P.   3  sp 2 
2
56. Due to large size of Cl, it cannot involve in
H-bonding.
57. O has high EN . .
58. In vapour state HF exist as 6 molecular cluster
59. High EN and small size of atoms can only
participate in H-bonding. 77. Dipolemoment & hydrogen bonding

60. H O form intermolecular H-bonding. 78. cal = q x d

2

39
Chemistry For NEET By Prince Sir
obs 1
%
cal
 100 15. polarising power  size of cation

16. Polarisation
  ed
 1.2 D 1.2 1018 esu cm 1
e   
79. d 1.0 A 1.0 10 8 cm size of cation & size of anion
 1.2  1010 cm. 17. Conceptual
18. L.E<S.E
Percentage of electronic charge
19.  E.N . = 0
1.2 10 10 esu 20.  E .N .  polarity.
 100  25%
4.8 1010 esu 21. In non-polar covalent bond electrons are
 inequally.
80.   n  bond moment  cos
2 22. Silica is covallent polymer.
23. Valency of VIA group is = 2, and valency
81.   12   22  2 1  2 cos  of A is =2.
24. Vander waal’s forces  molecular weight.
If   90 ,  is maximum
25. The reactions of covalent compounds are
very
LEVEL - III slow due to breaking and making of bonds.
26. In Ethylene carbon- carbon double bond is
1. covalency of S is 6. present.
2. S can exhibit more than one valency. 27. PCl5 has 10 electrons in valence shell of P..
3.
28. XeF4 has 10 electrons in valence shell of
4. Valency is double to the number of oxygen
atoms reacting. Xe
5. Valency of A is 4, B is 2 29. Less size of cation less is the ionic nature
and more is the covalent nature.
 AB2 is formula. 30. donation of electrons is involved in dating
6. No.of outermost electrons in A is 3 and in bond.
B is 2. 31. Conceptual
7. Conceptual 32. BCl3 has covalent bond.
8. Ionic compounds are soluble when H.E > L.E
33. Ammonia boron trifluoride is formed by the
9. MgS has high lattice energy formation of dative bond.
10. 4 NaCl formula units present in 1 unit cell 34. In dative bond electrons are donated by
23 (1 mole) formula units present
6.023  10 in ? only one atom.
35. oxygen cannot form triple bond.
6.023  1023
= 36. Overlapping of atomic orbitals determines
4 direction of the bond.
11. Lattice energy  stability.. 37. sigma bond is directional .
12. Large cation and small anion. 38. In acetylene C  C is present .
13. Ionic compounds are good conductors in
their 39. In ethane 6  sp 3  s bonds are present.
molten & aqueous states. 40. Hybridisation of Bromine in BrF3 is sp 3 d
14. CO & CN  each contains 14 electrons.
40
Chemistry For NEET By Prince Sir
41. sp 3 hybridisation 68. Conceptual
69. Conceptual
42. sp 3 d 70. H 2O2 has open book structure ( non linear)
43. In aldehydes hybridisation of carbon = sp 2 71. Conceptual
72. Conceptual
44. Conceptual
73. 4.8 e.s.u cm = 1.6  1029 cm
45. C3O2  O  C  C  C  O  all carbon atoms
1.6 1029
undergo sp hybridisation. 1 e.s.u. cm =
4.8
46. In CH 3CH 2OH the underlined corban is
fo r ming 4 bo nd s. He nc e sp 3 = 0.33  1029 cm
hybridization in others it is sp2 hybridization.  3.33  1030 cm
47. No of hybrid orbitals 2 X 3 = 6
74.     d ( in esu, d in cm and
No of pure orbitals 4(s) + 2 (p) = 6
 in esu cm;1D  10 18 esu cm)
48. In H 2 O , hybridization is sp 3 and the
shape is angular due to 2 bp & 2 lp 1.02 10 18   1.275 108
 5  4 1 1.02
49. In NH 4 T .P.   4( sp 3 )  1010 esu
2 1.275
1
50. Hybridization of N  [5  3  0  0]  4 If 4.8  1010 esu charg then 100% ionic
2
 sp 3 1.02
If  1010 esu charge then
51. All of them have total four electron pairs 1.275
with 0 lp . Hence tetrahedral in shape. 100  1.02 10 10
 16.66% ionic (or)
52. A sp 3 hybrid orbital has 1/4 s-character.. 1.275  4.8 1010
53. Extent of overlaping  size of hybrid orbital 83.4% covalent.
54. Carbon cannot form H-bond.
55. Due to  I effect, as alkyl change in creases 75. DM  4.8 1010  1.41 108
strength of hydrogen bond decreases,
56. Conceptual  6.768  10 18 e.s.u cm
57. Hydrogen bond energy is about 10 Kcal. 0.78  1018
% ionic character   100
58. I nt er mo lecular H- bo nding is for med 6.768  1018
between H 2O molecules.  11.52
59. CH 4 has no hydrogen bonds
60. ether has no hydrogen bond. LEVEL - IV
61. Conceptual
62. Conceptual
63. B.O.of O2   1.5, N 2   2.5, 1. Li :1s 2 , 2 s 2 ( EA1   ve);
  Be :1s 2 , 2 s 2 2 p1 ( EA2   ve)
O2  2.5, N 2  2.5
64. Conceptual 2. Electro +ve character and size increases
65. Conceptual do wn t he group, t he ionic charact er
66. Conceptual increases
67. Conceptual
41
Chemistry For NEET By Prince Sir
3. BF3 is a covalent Compound.
23. XeF4 ( Sp 3 d 2 square planar ),
4. Conceptual
[ Ni(CN ) 4 ]2 (dsp 2 square planar ),
5. Conceptual
BF4 (sp 3 tetrahedral ),
6. Conceptual
SF4 ( sp 3 d see saw shaped )
1
7. u
rc  ra 24. I 3 has linear structure & SeF4 has distorted
8. The hydrated Aluminium chloride trivalent trigonal bypyramidal & CH4 has tetrahedral
complex ion [ Al.6 H 2O]3 , formation of which 25. A  bond is formed by orbitals having
is exothermic process. The energy released same symmetry about the internuclear axis.
is sufficient to cause the ionisation of Al. 26. conceptual
9. Conceptual 27. One carbon has three bonds and other five
10. Large cation and small anion. whereas each should have four bonds
11. Due to low lattice energy 28. Both HgCl2 and C2 H 2 are linear like CO2
1 because of sp hybridization.
12. Size of cation 
IP 29. Both NO3 and CO3 have 32 electrons and
13. No.of e participating in bond in x is 8- central atom in each is sp 2 hybridization.
5=3 and in y is 8-7=1.
14. One unpaired electron of each of A atom 30. CN  is a strong ligand . Hence it forms
part icipat e in bond format ion wit h 2 inner orbital complex dsp 2 hybridization.
electrons of B atom. 31. conceptual
15. 4  58.5g contain 6.023  1023 unitcells 32. As F5 is trigonal bipyramidal and sp 3 d
 1g _______? hybridised.
6.023  1023 33. dsp 2 hybridisation involves dx 2  y 2 .
=
4  58.5 34. In XeF2 Total number of valence electrons
16. conceptual of Xe = 8, two electrons shared with 2F
17. 3 BP, 1LP atoms, 6electrons left hence 3 lone pairs,
in XeF4 4shared with 4 F atoms,4 left hence
18. Nitrogen undergoes sp 3
2 lone pairs; in XeF6 6 shared with 6F atoms
hybridisation,3BP,1LP 2 left hence 1 lone pair.
20. Conceptual
1 35. Tetrahedral
21.  N BP 
Q f  N A  N lp 
36. S ince F fr o m H- bo nd [ HF2 ] exist s.
2
22. No o f r e so na t ing st r u ct ur e fo r Therefore KHF2 gives K   HF2
PO43 are 4 . Bond order 37. For T-Shape geometry the molecule must
Numbers of bonds 5 have 3 bonded pair and 2 lone pair of
= Number of Resonating structures  4  1.25 electrons.
Three unit negative charge is being shared 38. LiCl is covalent in nature due to small size
by four O atoms. Formal charge = - 3/4. of Li  ion hence LiCl will ionise less than
NaCl.
39. (Carbon in H 2CO3 has sp 2 hybridization

42
Chemistry For NEET By Prince Sir
and non-polar . BF3 has sp 3 hybirdization lesser is (O-O) bond length.

but non-polar SiF4 and HClO2 has sp 3

hybridization but HClO2 is polar.)
40. O-atom being less electronegative occupies 53.
one of the three equitorial position.
41. Hybridization in Si (CH 3 )4 is sp 3 which is
It has two nodal planes. It is *2py
tetrahedral.
42. O=C=C=C=O is sp hybridised.
43. 3  bonds (sp 2 hybridization); 2  bonds
(sp-hybridisation) 54.
C1  3  bonds , C2  3  bonds,
C3  2  bonds. 55. The lower the bond order the greater the
bond length and vice verse.
44. Hybridisation in NF3 and H 3O  is sp 3 and 56. NO: bond order 2,5 paramagnetic
they have pyramidal shape. Hybridisation in NO +: bond order 3, diamagnetic
NO3 and BF 3 is sp 2 and t hey have 57. The bond order of C-O in CO, CO 2 and
triangular planar shape. CO32  is 3,2 and 1.33 .Hence bond length
45. In H 3 BO3 hybridisation of B is follows the order CO< CO 2< CO32  .
2 3
sp and O is sp . 59. Ortho-nitrophenol has intramolecular H-
46. conceptual. bo nding and par a - nit r o pheno l has
47. I n PCl 5 two axial bonds are larger and weaker intermolecular H-bonding.Hence former is
and therefore PCl5 dissociates into PCl3 and more volatile than latter.
Cl2. 60. Upto 4°C , the intermolecular H-bonding
48. H 3 N  BF3 , where both N, B ar attaining keps on breaking and there by decreasing
tetrahedral geometry. the volume and increasing the density.
61. Hydrogen bond length > covalent bond length
5 
50. Thus bond order for N 2  3, For N  , 2 62. Both NO2 and O3 have angular shape and
2
hence will have net dipole moment.
5
For N 2  (with one more antibonding 63. Conceptual
2
electron than N 2 ) and for N 22 = 2
respectively. Thus bond order is 64. Hint:
N 2  N 2  N 2  N 22 and stability order
will be N 2  N 2  N 2  N 22 . Dipo le moment s of 2Cl and 5Cl are
51. (O-O bond length in vectorically cancelled.It is due
O2 is 120.7 pm, O3 is 127.8 pm, 1CI and 3Cl   12  22  2 12 cos 
H 2O2 is 147.5 pm = (1.5)2  (1.5) 2  2  1.5  1.5cos 120.
52. Bnd order for O2 , O2 and O2 are 2,2.5 and    1.5D
1.5 respectively. Greater is bond order ***
43