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11 views36 pagesChemical Kinetics Class 12 O.L Classes
This is important for 12 class preparation it's totally based on ncert pattern
This notes is written by Ajit Shukla.
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0% found this document useful (0 votes)
11 views36 pagesChemical Kinetics Class 12 O.L Classes
This is important for 12 class preparation it's totally based on ncert pattern
This notes is written by Ajit Shukla.
Uploaded by
shivmishra8812Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 36
a
Chemice Keineticg r Which ae ith
—_Ztudy of sanction. “'
a TER. [Chena wu
= Bereies el TR ae Collec]
—Chembea)—detnclics_
Wi fe aie 2 et See Cee cin
Giswek Ward ‘Kinesis? tnecining rm overmovef
eb Kak Ff a Kent cof Sao
g
CD Some sucactions Auch o4 tonto oancttond oct
Mesy —Pesh- a
CO ES 32a ee E
|? 2 Rg NOx (aa)
Some weactens are eae A low-
WERE = Stush et len:
eee ee *
©
Tho wuedte ef decrease Gn concentration of any
ne of He ceactants or
Tho sute of Guoeose fr Concentration Fay
one of tho pro duct?.
a> ?P
XN. Bede ct
Roo: de 45 Rae ae
DS Ses
Ate = (Ray) — TE
2S = Tee Pe
‘ Rate of cisabbearonce, of oO
Peersase ar toncentration of R -aGa
Sime daken. aS
~ATO
= CR IP) gt =
ee
a cea
Rate af abpeasance ot Pe
= moense tn Concentatton of PAC
| “Tine taken at
| Le A a (&3 =e
| Tht ( Ag- £1) stay = OS Gh Se
, A= si
{aon _ 4h) _ 0G)
Bt be Ben p a.
Serest By Ox cart oH Tages Sox (ant BhHL0 Ce) ile
a iia z ik eee mo
Rates = El Ses = RL A
Se tone e yn f -
Dur a FARA Aa ESP ag I ee | ic q r
to_O-pam by acu coabntes Hla sag
: Ciake [a Aux} M
i L of \ woe Boal oN URE Sf Mi
You Ge 2 b
= i
eve) aR) = (O-{e)
| At = RHR ~
> t Ways = RAL =
Rat ; .
| (Ajz 063m. (Ra = O-0ImM, — pde Armin
a
[ : 7
| Yov = RR =
] Pe as002 = 5:93) a | r
I AS a5 _ O6
You = aed ee dalam k
PSS ies Le
aos
— Lk.
O04 KIRK mint ae
SNE ea
os A eee |
| eee
Crna tos) i
. ott cn oe
60
0667 x oTY sd -
C (xrtaet 4
CRS) Fa a eeaion aS Prededs Hh toncenbalin
lof A decreases —Rom of Mmott-) do oy mal
fy do MY autes + Colcelate the site doe
[Sis Gtesval.2 ee (07 SXLOR MoT
is XRIOFT 7 '
—_ Sa
—|_ : a
— Factase @ Tn Fluendieg Rote of a Reaction 4
e | E
__ | Pale st eaction clepencr Upon FRE
‘ Qopestei premted Conditiory Auch ah Cme-
It of seach,
<) Dependence of Suse on Concenpaon y
>is vo brasentafion sf sole of S.eaction
{ iy fesms of pencenhration tthe swactencty
[as TEnson oy Rocke > flaw o- Rate CAuation
, . OC Rate Sgalesiey -
La)
@iKek Expession an Sate Concerts
[Rak Pa seq thin baa Ube
| CnfenPation of swactants~ RELELALATRND
Cae (eV 7.
| Sa. > ——
Reale = KR PAX (ete
Seem
| Qnto Ere, Danes
Ke Rate Congtank7 |
:
©)
Rak = KEno} Ga
aie TNs) oy)
at
Some O
Fig example 992 given Gelves-
oO cud FoR SD alee
E
|
5
epee eee
feck Ceres Couy™ }
ee c
aegis take free > Chae e
_ | ee Ca
—————<—— sss acy =
9 Seasener
are:
Oprdey Saf XH saoatton J
¢
3
Q
+
a + ~ —
[The hum af Powey 6 the con cena
of the secctaute Gn the “suste [al
ecpaession _Bcalled Ya ordi" oP i
Chemfical ovwaction- _ a
_ ee an
oul es it ee i. | _—_—
Bete = K CA ies a
a. ant secant - i ian
Ordey of = Seaction, =(=+4 9
’ a
{Ordes, oP eo Swacton Cin be 0/3 and
even _a-fraction. 7
a
Example - Calculote Phe oyeeatt onda of >
meal a seactten which has Te a
I crate ¢ypression+ : “3
I
| @ kek «TEE q
{| a
i @ Rke= Fea yt 7"
i )
i
(ay Q_ Rete = CCS TF
= ty ae
enw ate a sp = Q (Second
CE orden +) = hath wv eters 10
= 2
- Cr) Were aie ea ae st
= San ttt ey
- |
al F
. OA be ess Gee a
——t :
ee
eee cs b
Be ee eg
. | tye Cdr THe sean !
_— 1 os
ke Rate
St Be
H a k= Concentration - i aN
j Hime (ten Cenbation )”
ae Rs aes ee es ees
Thos EF nth of Con cenhation = Met}r= matt
}
Hime oe
[Zero order Reaction 4 nie,
“k= Mae. vale
Ss trrociy™
1 i
ea Saou a a macs |
= a \
(of 11
25 pac ores Reection, He 4
—_@) Seend ode Reaction) He Dd
~
= ay L
i le Heo % (Em)
| T
be mot t= ae
| Si Cra ty
| Ye res
|
I SX mea? CE
i pass
UZ a 7 cs
mor GL Xmol® ets-+
Mol25s' / 12
Gol esti J wnbo
fl Eee
Se
23 XS ee
a uF order Roadion
cs
[ Meleculastty— OF & vswattion J
ae g
-[Tka__mombes oft eseackin pecies (alone, fon,
—— | O77 _melecafer ) | tak} leat th Oh elenerfery —
} steaction, whitch must cilice 2? mulbaneous
Qn Ondey sto bin abeck a chemical
vwaction UA called "decal [aes
Te ramble = Re sroactto. Conbe BLA
When One ae Apeves
GrNolvedl «
NHN — > #atne (Uicimelecctoy)
7 a The reactions tan be Bimulecate
uscactt Abed 14 tesclud @
QHr
Thseo
| cone ot Ge ues
ones
eee cine
LL oe )
sf
eactions Gnkeleamele clas ewactlony whe
pe eur
k__4nvolvect. =
two
[Te veactios Con be leg obken mere of
eee Ou Gracie te &
“fsb Or2 vol =|
|
i KCl O3 FC FesoG TSS KE BERGER
|
i
_ Lntey 14 een
DATE
2 ee a,
a
rate aa acaicel de SAS Pata
Ses Lgival by aa
| { eer odo af
SE -
Ordey of reaction = ‘lag es
i
| i
Tt = ste = La
E =
Oe GnYe2.cton or mecaler xX fey Wns
; os Ordo Rircticg iC oe
a9 pases 4a thier dines how win Va
ae : ae toe ot -fosmedtion of ¥ 2
= aks ET
Second ader
Rate = Beas
Ree = ETae
Oz 84%
; (oe gees
Late E@ay
eae 15 Fe
DATE:
roma, [ alas leg yale wrecte Sra i)
c equations
: Sr the ewactions of fi
el aes
GD [eee Orda Peactions ~/
oe _ SRA of the seacton kK _|p0 poxtionap)
— Zero powea of the concentration of —-
I cwocant - :
a
i Conider ie seactten -
1
iM
! eae
Rak = —
t F
| Ratez kee
fecte~ —4ce) Eee
| oF Ree
RS Saeco:
[e5, = 2
fot
iti) Conc of
Hee swactaf
fea = et
ae ea)
ale Bdemple -
=
|_ eo Hs GSS @ Shag ae
T ee Cakeiy st =
nce rz
I
i Rede = FCNAa
j f
pe
a Cer ii (a
Ria
AZ Peat ode Reactions |
a
{he sale SE the Seachoy VW _pssspesctional
| Bo ~tho Fog fowex7 HY (iene
| of =the seeackeus _R.
I R33? 18
PPASEY) 2
ee
| — Rae
= Re eg ie
_|
= Ay a ihad
eee
J aoa ee ST
i Jeo R= Bs
ee ae ete oe
palemies enlikNc)
BR= isk EA. falee
Pics) Be
“De
[ar
|
7 ae ee
SS
‘i ae —— 19 gsr YY
DATE
- ! AL Prve KR
ee —kR + PB
et Ree
ae nce = —FXi F hag,
i b= wey = — FX —CKR)
ba CPDy K(k ~ 2) )
(8.
= =
tok es
ESky TOL \
||
| > aan
I] or aE
| Pe aaa aR RSs [Ry = CRs
T Ths. roti (ones OT Noos Paofke ee
sk 08d Heaction Nos => QNo ee
tons | By XlovAmott"! af Sip le Th
Conc of Ngoc after 60 minty was cael
Mmoatt Cetcotele Ho ale Congtauf of the
reactor ed Sib K-
fe ie IRE Eanycto-R mg ET
bo punude PA] =< 0-aoxX jo-A mot *
tf
ah a Bso3 t le - ees eres an
a Go a
oe es a
Sa ave LST |
i | Hatr— Dee ots & swaction 4
Zh 4 . |
7 [holttot® = Oife of a Seaction IR AT Tne Fraley
| Ave ConcentraHon oF
{| 12 Om het of Ge intHa) Concentration. 7
a owactaut= yy Seduced
| a xe fregeted|
abla Eg bah a’
; = sees
{ee 4
{| 7
[ las ae (RI = alte ]
|
F | k= CR3o-- =
||
°
at R= aOR
| / a
|| Ye 5) essog) t
- (eauaslo
Su [R\
Ae en ee oe
ec = 30S SSS To \Blo
fa d= leo
“a aS
Pa.
F
Fag 2 BSS
tb
leq ir 24
J} HS Pet ord ceeaction
Finaene,
toa tS
SA = eat - have a
EPS AOS¢ | OU Ea
tconclant Kk
__ wrote
ERG hoe = Dike of =the sueaction.
oo Ly a GES
i K kk ase 104
EROS
— SKIT
iy = 0-633 10 CiscceBs Y
acca
| Sho FRET &
PlecP Onde creation |
—H ne swaptrced “toy Completion Of 44-q4.
| Leas of had Lip (Lipo) o
| Pho setaction « ¢ r 7
| SR) ARES ease
]
I
] Ge 323 — ae (eR a
| k= h.a03 Log _
Zz (RL= 0-994 |Rlo
K
+303
sae a =e
E = SRT = a
Fin le OR,
mc Pet Srey oueachond |
coe, not qt albfesed
| 2 ko Cone of water
| | ‘ees dung Hla Course Sp fee SaockOn
a> He Sea hen behets OF fisck ode”
owaction: ;
rae, oe |
aerials EES Cektnoe TF ee el
I Thc X 10" ser Foo lerg sil 54
I ike wwactouwl — feke fo S0duce ce 3
(RD Rates J fox ta
\Rlo = S9
| (eee
= |
| Ke ebaes aed,
ae
[ste
I 1X10 = eat yay
i —
loge = 0, So
Loft See aS.
i OAR! lo.
| pee “ begs 0 979)
f ©6990
fiz Lag Hoag x 103 OUI
ig gar
Ae RBBX ARG x gB -
[1S X 105
DISA TERT = Y44.38S
[geo
4
Fate oe ah (Se) Bai eye oe,
{ cfecom| xe L039 G late
___ See Frtiof mouse tn bo erie
Lp She SEB only | nh acai! eer
swatton || alewtolel Gs | ule | Gnakadt= oF
Aho soctton. ae ae cae
( Kia |
as wa have Hayy = Go Pinufes—
7 [ 0693
| is : 60 fun
cer
eee CTE ae
) Go,000
(ar 0-68 et
6
[c= 0-000 146 i
—s
re 28
a empetafuro fy = :
lca # : eben dence oP
