Assignment-2. Introducation to Analytical Chemistrydocx
Assignment-2. Introducation to Analytical Chemistrydocx
Q 4. How many significant figures are in each of the following quantities ? a. 45.26 ft b. 0.109 in c. 0.00025 kg
d. 2.3659 × 10-8 cm e. 52.0 cm3. f. 0.00020 kg. g. 8.50 × 104 mm. h. 300.0 cg
Q 5. Express the following quantities in exponential terms. a. 0.0003498. b. 235.4678 c. 70000.0 d. 1569.00
Q 6. Find out the molar masses of the following compounds : a. Copper sulphate crystal (CuSO4 .5H2 O), b.
Sodium carbonate, decahydrate (Na2 CO3 .10H2 O) c. Mohr’s salt [FeSO4 (NH4 )2 SO4 .6H2 O]
Q 7. Perform the following operations : a. 3.971 × 107 + 1.98 × 104 ; b. 1.05 × 10-4 - 9.7 × 10-5 ; c. 4.11 × 10-3
+ 8.1 10-4 ; d. 2.12 × 106 - 3.5 × 105 Q 8. What is a limiting reagent ? Explain in details
Q 10 The density of 3M solution of NaCl is 1.25 g mL-1 Calculate molality of the solution.
Q 11 Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water to form
250 mLof the solution.
Q 12 A solution is prepared by adding 2 g of a substance A to 18 g of water. Calculate the mass percent of the
solute.
Q 13 Calculate the mass of carbon dioxide and water formed on complete combustion of 24 g of methane
gas. (Atomic masses, C = 12 u, H = 1 u, O = 16 u)
Q 14 The three identical samples of potassium chlorate are decomposed. The mass of oxygen is determined
to be 3.87 g, 3.95 g and 3.89 g for the set. Calculate absolute deviation and relative deviation.
Q 15 In laboratory experiment, 10 g potassium chlorate sample on decomposition gives following data ; The
sample contains 3.8 g of oxygen and the actual mass of oxygen in the quantity of potassium chlorate is 3.92 g.
Calculate absolute error and relative error
Q 18 What is analysis.
Q 20. Calculate the percentage composition of the elements in HNO3 (H=1, C=12, N=14)
Q 21. Find the percentage composition of constituent green vitriol crystals (FeSO4.7H2O). Also find out the
mass of iron and the water of crystallisation in 4.54 kg of the crystals. (At. mass : Fe = 56; S = 32; O = 16)
Q 22. A compound with molar Mass 159 was found to contain 39.62 % copper and 20.13 % sulfur. Suggest
Molecular formula for the compound (Atomic masses: Cu = 63, S = 32 and O = 16).
Q 23. 6 g of H2 reacts with 32 g O2 to yield water. Which olis the limiting reagent? Find the mass of water
produced and the amount of excess reagent left.
Q 24. A mixture of 18 g water and 414 g ethanol. What are the mole fraction of water and ethanol?
Q 25. Calculate the molarity of 1.8 g HNO3 dissolved in 250 mL aqueous solutions.