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Chemistry practical

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7 views

Practical Part 3.0copy

Chemistry practical

Uploaded by

vkkaiwart123
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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EXPERIMENT – 15

Aim : To prepare solution of M/40 oxalic acid. With its help determine the molarity and strength of given KMnO4
solution.
Apparatus Required : Burette, conical flask, pipette, beaker (250 ml), test tube, white tile, volumetric flask, beaker,
funnel, glass rod, weight box, wash bottle.
Chemical Required : Oxalic acid, crystal, dil H2SO4, KMnO4 solution
Indicator : KMnO4 act as a self indicator.
End point : Colourless to Pink
Theory :
(a) Preparation of standard or known solution :-
Molecular formula of oxalic acid is H2C2O4.2H2O. It is a primary standard solution. Thus its solution can be prepared
by direct weighing.
Molecular weight of oxalic acid = 126 g
To prepare 250 ml of 1M oxalic acid solution, 126 of oxalic acid is required. Thus to prepare 250 ml of 1M oxalic acid
solution (126/4)g is oxalic acid is required.
To prepare 250 ml of M/40 oxalic acid solution.
126 M
  0.7876 g of oxalic acid is needed
4 40
(b) Titration of standard solution with KMnO4 (unknown solution), KMnO4 is strong and versatile oxidising
agent. In sufficiently acidic medium, at about 60oC KMnO4 oxidises oxalic acid to CO2 and itself is reduced into
colourless Mn2+ ion.
2MnO4  5C2O42  16H  
 2Mn2  10CO2  8H 2O
Molecular equation :-
2KMnO4  3H 2 SO4 
 K 2 SO4  2 MnSO4  3H 2O  5[O]
H 2C2O4  [O] 
 2CO2  H 2O]  5
Adding both the eqn.
2KMnO4  3H 2 SO4  5H 2C2O4 
 K 2 SO4  2MnSO4  8H 2O  10CO2
Observation Table :-
1. Preparation of M/40 standard solution :-
Weight of empty watch glass (W1) 21.7260 g
Weight of watch glass + Mohr’s salt (W2)
= 21.7200+ 0.7876 = 22.5076 g
Weight of oxalic acid = W2 – W1 = 0.7876 g
Volume of oxalic acid = 250 ml
Molarity of oxalic acid = M/40
2. Titration of standard solution with KMnO4 Solution :-
S.no. Volume of Burette Reading Volume of Concordant
Mohr’s salt KMnO4 used Reading
used (V1) ml Initial final

1 20ml 0.0 ml 15.0 ml 15.0 ml


2 20 ml 0.0 ml 14.9 ml 14.9 ml 14.9 ml
3 20 ml 0.0 ml 14.9 ml 14.9 ml
Calculation : According to ionic equation .
2MnO4  5C2O42  16H  
 2Mn2  10CO2  8H 2O
1 mole of oxalic acid required 2/5 mole of KMnO4.
M1V1 = 2/5 M2V2
M1 = molarity of KMnO4 solution = ? V1 = molarity of KMnO4 solution = 14.9 ml
M2 = molarity of oxalic acid solution = M/40 V2 = volume of oxalic acid solution. = 20 ml
2 1
M 1  14.9    20  M 1  0.0135M
5 40
Strength of KMnO4 = Molarity × Mol.wt.= 0.0135 M × 158 = 2.1345 g/L
Result
1. Molarity of the given KMnO4 solution = 0.0135 M
2. Strength of the given KMnO4 solution = 2.1345 g/L
Precaution: 1. Oxalic acid should not be heated about 60oC. 2. weighing should be accurate.
CLASS- XII CHEMISTRY PRACTICAL 20
EXPERIMENT – 16
Aim : To prepare solution of M/20 oxalic acid with its help determine the molarity and strength of given
KMnO4 solution.
Apparatus Required : Burette, conical flask, pipette, beaker, test tube, weight box, white tiles, volumetric flask
beaker, funnel glass rod, weight box, wash bottle.
Chemical Required : Oxalic acid, crystal, dill H2SO4, KMnO4 solution
Indicator : KMnO4 act as a self indicator.
End point : Colourless to Pink
Theory :
(a) Preparation of standard or known solution :-
Molecular formula of oxalic acid is H2C2O4.2H2O. It is a primary standard solution. Thus its solution can be prepared
by direct weighting.
Molecular weight of oxalic acid = 126 g
 molar mass = 126 g/l
To prepare 1000 ml of 1M oxalic acid solution, 126 of oxalic acid is required
To prepare 250 ml of 1M oxalic acid solution (126/4)g is oxalic acid is required.
 To prepare 250 ml of M/20 oxalic acid solution.
126 1
  1.5750 g of oxalic acid is needed
4 20
(b) Titration of standard solution with KMnO4 (unknown solution): KMnO4 is strong and versatile
Oxidizing agent. When it is titrated against standard oxalic acid solution (reducing agent) in sufficiently acidic
medium at above 60oC, KMnO4 oxidizes acid into CO2 and itself gets reduced to colourless Mn+2ions.
Molecular Equation :
2KMnO4  3H 2 SO4 
 K 2 SO4  2 MnSO4  3H 2O  5[O]
H 2C2O4  [O] 
 2CO2  H 2O]  5
Adding both equation : 2KMnO4 + 3H2SO4 + 5 COOH . 2H2O  K2SO4 + 2MnSO4 + 8 H2O+ 10CO2
Ionic equation : MnO4  8H   5e( ) 
 Mn 2  [4H 2O]  2
C2O42 
 2CO2  2e  ]  5
2KMnO4  16H   5C2O42 
 2Mn 2  8H 2O  10CO2
Observation Table :
a) Preparation of M/20 oxalic acid solution :
Weight of water glass (W1) = 21.7200g
Weight of watch glass + weight of oxalic acid (W2) = 23.2950 g
 weight of oxalic acid (w2 – w1) = 1.5750g
Volume of oxalic acid used for each titration = 250 ml.
3. Titration of standard solution with unknown Solution :-
S.no. Volume of Burette Reading Volume of Concordant
Mohr’s KMnO4 Reading
salt used used
(V1) ml
1 2.0 ml 0.0 ml 15.1 ml 15.1 ml
2 2.0 ml 0.0 ml 14.8 ml 14.8 ml 14.8 ml
3 2.0 ml 0.0 ml 14.8 ml 14.8 ml

Calculation : According to the ionic eq.


2MnO4  5C2O42  16H  
 2Mn2  10CO2  8H 2O M1 = Molarity of KMnO4 Soln = ?
1 mole of oxalic acid required 2/5 mole of KMnO4. V1 = Volume of KMnO4 Soln = 14.8 ml
M1V1 = 2/5 M2V2 M2 = Molarity of Oxalic acid Soln = M/20
2 M 20 V2 = Volume of Oxalic acid Soln = 20 ml
   0.027 M
5 20 14.8
Strength of KMnO4 used = Molarity × molar mass = 0.027 × 158 = 4.2702 g/l
Result
1. Molarity = 0.0270 M 2. Strength = 4.2702 g/L
Precaution : 1. Weighting should be accurate .
2. Always remove funnel from burette while titrating the solution.
CLASS- XII CHEMISTRY PRACTICAL 21

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