FOR JEE ADV.

2026
Class : XI N.Med (MAJOR TEST - 04)
JEE ADV. [PAPER - 2] KEY + SOLUTIONS

Time: 3 hrs. Date: 23-12-2024 M.M. : 180

Class : XII N.MED. 22-07-2023

M.M. : 180
Time : 3 hrs.
INSTRUCTIONS FOR CANDIDATE
1. Read each question carefully.
2. Test Booklet consists of 51 questions. Please write your name in the space provided in this test booklet.
3. The Answer Sheet is given along with of the booklet. Please fill all the particulars on the answer sheet before
attempting the questions.
4. Each Subject will have Four sections. Section -1 will be of ONLY ONE, Section- 2 will be of ONE OR MORE THAN
ONE , Section- 3 will be of NON-NEGATIVE INTEGER and Section - 4 will be of NUMERICAL VALUE
5. Use Blue/Black Ball point pen only for writting particulars/marking responses on the OMR sheet. Use of Pencil and
is strictly prohibited.
6. Space for rough work is provided at the bottom of each page.

7. Use of any unfair means during the exam will result in disqualification from attending the test further.

DO NOT OPEN THIS BOOKLET UNTIL ASKED TO DO SO

Roll No.:

Student’s Name:

Father’s Name :

Class : Section :

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PAPER-2 RPS TEST SERIES -2024-25

CLASS - XI N.M.
JEE ADV. PAPER - 2
ANSWER KEY
Major Test- 04 (23-12-2024)

PHYSICS CHEMISTRY MATHEMATICS

1 B 18 D 35 A
2 B 19 CD 36 C
3 D 20 CD 37 B
4 B 21 A 38 B
5 CD 22 AB 39 BC
6 AD 23 BC 40 CD
7 AB 24 BC 41 ACD
8 39 25 6 42 5
9 4 26 5 43 2
10 2 27 15 44 8
11 15 28 9 45 2
12 7 29 3 46 8
13 20 30 4 47 9
14 5 31 41.75 48 5
15 1 32 0.33 49 9
16 2 33 1.24 50 720
17 0 34 4.5 51 336

XII N. MED. (JEE ADV.) Page 2/22

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TOPIC:- Gravitation, Surface Tension, Viscosity & Elasticity & Fluid Statics & Fluid Dynamics

PART – I: PHYSICS

1. There is a rectangular wire frame having a thin film of soap solution. A circular ring of massless thin
wire of area of cross-section ‘A’ is placed on the surface of the film. The radius of the ring is ‘R’. Now,
inside portion of the ring is pricked. If the surface tension of soap solution is ‘T’ and Young’s modulus
of wire is ‘Y’, then change in radius of the wire is (Assume wire wets both surfaces)

TR 2 2TR 2 TR 2 TR 2
(A) (B) (C) (D)
AY AY 2AY 3AY
Sol. (B)

2. A soap bubble is blown at the end of a capillary tube of radius a and length L. When the other end is
left open, the bubble begins to deflate. Write the radius of the bubble as a function of time if the initial
radius of the bubble was R0 Surface tension of soap solution is T. it is known that volume flow rate
a 4 P
through a tube of radius a and length L is given by poiseuille’s equation- Q 
8L

Where AP is pressure difference at the two ends of the tube and  is coefficient of viscosity. Assume
that the bubble remains spherical.
1 1
 a 4Tt  4  a 4Tt  4
(A) R  R 0 1  4
(B) R  R 0 1  4
 LR 0   2LR 0 
1 1
 3a 4 Tt  4  2a 4Tt  4
(C) R  R 0 1  4
(D) R  R 0 1  4
 2LR 0   3LR 0 

Ans. (B)
4T a 4 P
P  Q
R 8L
dV a 4T 4
  ; ButV  R 3
dt 2LR 3
dV dV dR dR 2
  4R 2
dt dR dt dt
dR a 4 T
4R 2 
dt 2LR

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R t
a 4T a4T
4  R 3dR  dt  R 4  R 04  t
R0
2 L
0
2 L

1 1
 a4T  4  a 4Tt  4
 R   R 04  t   R 0 1 
 2L   2LR 4 
  0 

3. Consider an isolated system of two rings (M, R) and (M, 2R) whose common center is at point O as
shown. A point mass m is placed at O, then

(A) Gravitational force on point mass is not zero

3GMm
(B) Gravitation force on point mass is
2R 2
2GMM
(C) Gravitational potential energy of point mass is
R
3 GMm
(D) Gravitational potential energy of point mass is
2 R
Sol. (D)

1
4. A planet of radius R = = (radius of Earth) has the same mass density as Earth. Scientists dig a well
10
R
of depth on it and lowers a wire of the same length and of linear mass density 10–3 kgm–1 into it. If
5
the wire is not touching anywhere, the force applied at the top of the wire by a person holding it in
place is (take the radius of Earth = 6 × 106 m and the acceleration due to gravity on Earth is 10 ms–2)
(A) 96 N (B) 108 N (C) 120 N (D) 150 N

Sol. (B)

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5. A container containing liquid is given some acceleration 'a' such that half of the bottom area is exposed.
The dimensions of the container and height of the liquid inside the container is shown in the figure. If
 is the angle made by the liquid surface with the horizontal. Then

3g 3 6g 6
(A) a  (B) tan   (C) a  (D) tan  
5 5 5 5
Sol. (CD)
Conceptual.
6. Container is massless. Mass of liquid filled in the container is M. There is a hole in the container as
shown. There is no friction between container and ground. Then

(A) Initial acceleration of system is less than g/2

(B) Initial acceleration of system is greater than g/2
(C) System moves with constant velocity
(D) Acceleration of system increases initially and becomes constant.
Sol. (AD)
Conceptual.
7. A conical shaft rotating on a bearing of very small clearance t (see figure). The space between the
conical shaft and the bearing is filled with a viscous fluid having coefficient of viscosity  . The shaft
is having radius R and height h. If the external torque applied by the motor is  and the power
delivered by the motor is P working in 100% efficiency to rotate the shaft with constant  . Then

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2R 3 R 2  h 2 R 3 R 2  h 2
(A) P  (B)  
2t 2t
2 3 2 3 2
 R h R h
(C) P  (D)  
2t 2t R 2  h 2
Sol. (AB)

1
8. A solid sphere of radius m is completely submerged in liquid of density 1.8 × 103 kg/m3 as shown.

Ignoring atmospheric pressure, force exerted by liquid on bottom half of sphere, is _______ × 102 N.
(take 2 = g)

Sol. (39)

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9. A light cylindrical vessel is kept fixed on horizontal surface. Base radius of cylinder is R. A small
orifice having cross section radius r is made near its bottom. Vessel is filled with liquid upto height, h.
n
 r 
Initial acceleration (magnitude) of topmost layer of liquid, is   g. Value of n, is
R

Sol. (4)

3R
10. A tunnel is dug across the earth of mass, M and radius, R at a distance from the centre of earth as
2
shown in figure. A body is released from rest from one end A of smooth tunnel. The velocity of the
1 GM
body when it reaches the centre ‘C’ of the tunnel is . Value of n, is _______.
n R

Sol. (2)

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2
11. Steel wire of original length 1 m and cross-sectional area 4.00 mm is clamped at the two ends so that it
lies horizontally and without tension. If a load of 2.16kg is suspended from the middle point of the wire,
If its vertical depression is x cm then the value of 10x is
(Y of the steel = 2.0 × 1011 Nm2, Take g = 10ms2)
Ans. (15)
2T sin  = mg
x
 2T  mg
/2
mg
T …(1)
4x
2
 
     x 2 
2 2
x2
   …(2)

T / 2
  …(3)
AY
From (1), (2) and (3)
x2  mg
 
 2AY 4x
3
   mg
x3   
 2  AY
1/3
  mg 
x  
2  AY 
1/3
1 2.16  10 
x
2  4  10  2  10 
  6 11

1/3
1  216 
x   106 
2 2 4 
1
x  [3  102 ]
2
x = 1.5 × 10–2 m
x = 1.5 × 10–1 cm
10x = 1.5 cm

Y = 2 × 1011 N/m2
g = 10 m s–2
10x = 15
12. A non-viscous liquid of density 800 kg/m3 flows in streamline motion through a tube that tapers in
A
cross-section area from A to . The pressure difference between the wide and narrow section of pipe
4
is 10375 Pa. At narrow section, the velocity (in m/s) of fluid is _______

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 XI N.M. JEE-ADV. (P-2) MAJOR TEST -04 (SOLUTIONS) RPS TEST SERIES 2024-25

Sol. (7)

13. Two wires each of radius 0.2 cm and negligible mass, one made of steel and the other made of brass are
loaded as shown in the figure. The elongation of the steel wire is _____ 10–6 m. [Young’s modulus for
steel = 2 × 1011 Nm–2 and g = 10 ms–2]

Sol. (20)

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PARAGRAPH -1

Consider a solid object of volume Vs and density s = 6gcm–3 placed inside a liquid of density  =
–3
2gcm (s   ) now vessel is accelerated in vertical x-y plane with acceleration a given by

a  (3iˆ  5j)
ˆ ms–2. (Take g = 10 ms–2)

14. If net buoyant force on solid makes an angle  with the positive x-axis then value of tan  will be ____
Sol. (5)

15. If object is released inside the vessel then component of acceleration along x-axis will be _____ m/s2
Sol. (1)

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PARAGRAPH -2
A spray gun is shown in the figure where a piston pushes air out of a nozzle. A thin tube of uniform
cross-section is connected to the nozzle. The other end of the tube is in a small liquid container. As the
piston pushes air through the nozzle, the liquid from the container rises into the nozzle and is sprayed
out. For the spray gun shown, the radii of the piston and the nozzle are 20 mm and 1 mm respectively.
The upper end of the container is open to the atmosphere.

16. I the piston is pushed at a speed of 5 mms–1, the air comes out of the nozzle with a speed of _____ m/s.

Sol. (2)

17. If the density of air is a and that of the liquid  , then for a given piston speed the rate (volume per
unit time) at which the liquid is sprayed will be proportional to ax y . x + y = _______

Sol. (0)

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TOPIC:- Chemical Equilibrium + Ionic equilibrium ( Only Concept of Acid & base), Ionic Equilibrium
(Complete) & P-Block (Group - 13 & 14)

PART – II: CHEMISTRY

18. 0.96 gm of HI was heated at 720 K till the equilibrium. The % dissociation of HI was found to be 21%.
The volume and concentration of hypo required for the liberated I2 is :
(A) 10 ml of 0.1 N Na2S2O3 (B) 20 ml of 0.02 N Na2S2O3
(C) 6 ml of 0.3 M Na2S2O3 (D) None of these
Sol. (D)

19. A 75 ml solution that is 0.1 M in HC2H3O2 and 0.1 M in NaC2H3O2 has a pH of 4.74. Which of the
following action will not change the pH of this solution?
(A) Adding 15 ml of 0.1 M HCl.
(B) Adding 0.01 mol of NaC2H3O2.
(C) Diluting the solution from 75 ml to 125 ml.
(D) Adding 25 mL, 0.1 M NaOH (aq.)
Sol. (C)

2 2
20. 2.5 mL of M weak monoacidic base (Kb = 1 × 10–12 at 25°C) is titrated with M HCl in water
5 15
at 25°C. The concentration of H+ at equivalence point is
(Kw = 1 × 10–14 at 25°C)
(A) 3.7 × 10–3 M (B) 3.7 × 10–4 M (C) 2.7 × 10–2 M (D) None of these
Sol. (C)
21. The solubility of CaCO3 is 7 mg/litre. Calculate the solubility product of BaCO3 from this
information and from the fact that when Na2CO3 is added slowly to a solution containing equimolar
concentration of Ca+2 and Ba+2, no precipitate CaCO is formed until 90% of Ba+2 has been
3
precipitated as BaCO3.
(A) 4.9 × 10–10 (B) 5.9 × 1010 (C) 4.89 × 1010 (D) None of these
Sol. (A)

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22. Ammonia is manufactured by reaction of N2 and H2 by Haber's process. An equilibrium mixture
obtained by mixing H2 & N2 contains 3.4 gm each of N2, H2 & NH3.
Select the correct option(s).
(A) Mass of N2 present initially was 6.2 gm
(B) Mass of H2 present initially was 4 gm
(C) Maximum amount of NH3 that can be produced is 22.66 gm
(D) Mass of N2 present initially was 4.8 gm

Sol. (AB)

23. N 2 O 4  2NO 2 (g), K c  4 .This reversible reaction is studied graphically as shown in figure. Select
the correct statements.

(A) Reaction quotient has maximum value at point A

(B) Reaction proceeds left to right at a point when [N2O4] = [NO2] = 0.1 M
(C) K = Q when point D or F is reached :
(D) At point C equilibrium established and Q = K
Sol. (BC)

24. A 2.5 gm impure sample containing weak monoacidic base (Mol. wt. = 45) is dissolved in 100 ml water and
th
1
titrated with 0.5 M HCl when   of the base was neutralised the pH was found to be 9 and at equivalent point
5
pH of solution is 4.5 . Given : All data at 25°C & log 2 = 0.3.
Select correct statement(s) .
(A) Kb of base is less than 10–6
(B) Concentration of salt (C) at equivalent point is 0.25 M
(C) Volume of HCl is used at equivalent point is 100 ml
(D) Weight percentage of base in given sample is 80%.
Sol. (BC)
25. An unknown volume and unknown concentration of weak acid HX is titrated with NaOH of unknown
concentration. After addition of 10.0 cm3 of NaOH solution, pH of solution is 5.7 and after the addition
of 20.0 cm3 of NaOH solution, the pH is 6.3. Calculate the pKa for the weak acid, HX. (Given: antilog
of 0.6  4)
Sol. (6)

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26. Waste water resulting from metal processing often contains significant amounts of toxic heavy metal
ions that must be removed before the water can be safely returned to the environment. One method uses
sodium hydroxide solution to precipitate insoluble metal hydroxides. Suppose that 1.00 × 102 L of
waste water containing 1.8 × 10–5 M Cd2+ is treated with 1.0 L of 6.0 M NaOH solution. The residual
concentration of Cd2+ after treatment is x ×10–12 M. Identify x.
(Ksp [Cd(OH)2] = 1.8 × 10–14) (atomic mass of Cd = 112)
Sol. (5)

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27. Following two equilibria are established on mixing two gases A2 and C.
(i) 3A2 (g)  A6(g) Kp = 1.6 atm2
(ii) A2 (g) + C(g)  A2C(g)
If A2 and C are mixed in 2 : 1 molar ratio, if Kp for the reaction (ii) is x then calculate 10x.
Given that the total pressure to be 1.4 atm and partial pressure of A6 to be 0.2 atm at equilibrium.
Sol. (15)

28.  2H2O(g) + Sn(s) at equilibrium if 45% by volume H2 is

For the reaction, SnO2(s) + 2H2(g) 
121
present in steam and H2 mixture then the equilibrium constant Kp is . Find the value of x.
9x
Sol. (9)
SnO2(s) + 2H2(g)  2H2O(g) + Sn(s)
At equilibrium if 45% H2 is present then 55% by volume H2O will present.
For gases mol % = Volume %

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2
 55 
 P 
55 45 100 T 
121
PH 2O  PT ; PH 2  PT ; K P  2

100 100  45  81
 PT
100 
29. How many of following statements are correct regarding hydrolysis of chlorosilanes?
(A) R3SiCl + H2O  Product  Undergo dimerization
(B) RSiCl3 + H2O  Product  Form cross linked polymer
(C) R2SiCl2 + H2O  Product  Form long chain linear polymer
(D) R2SiCl2 + H2O  Product  Form crosslinked polymer
Sol. (3)

30.  CuSO 4(s)  5H 2O(g) for above reaction K p  1.024  103 atm5 then find partial
CuSO 4 .5H 2O (s) 
vapour pressure H2O at equilibrium. (in atm)
Sol. (4)

PASSAGE – 1
Acid-base indicators are either weak organic acids or weak organic bases. Indicator change colour in
dilute solution when the hydronium ion concentration reaches a particular value. For example,
phenolphthalein is a colourless substance in any aqueous solution with a pH less than 8.3. In between
the pH range 8.3 to 10, transition of colour (colourless to pink) takes place and if pH of solution is
greater than 10 solution is dark pink. Considering an acid indicator HIn, the equilibrium involving it
and it’s conjugate base ( In) can be represented as : HIn  H   In 
acidic from basic form
colour P colour Q

[In  ]
pH of solution can be computed as : pH  pK ln  log
[HIn]
In general, transition of colour takes place in between the pH range, pK ln  1.
31. An indicator is a weak acid and pH range is 4.0 to 6.0. If indicator in 50% ionized in a given solution, if
the ionization constant of the acid is 10y then value of (8.35 ×y)
Sol. (41.75)

32. PCl5 dissociates into PCl3 and Cl2 : PCl5(g)  PCl3(g) + Cl2(g)
The total pressure of the system is P at a density and temperature T. If the vapour density of the gas
mixture at equilibrium has the value of 62 when the temperature is 230ºC, what is the value of P/
(atm litre /gm)
Sol. (0.33)

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PASSAGE – 2

In qualitative analysis, cations of group II as well as group IV both are precipitated as metal sulphides. Due to
low value of Ksp of group II sulphides, Group reagent is H2S in the presence of dil. HCl and due to high value of
Ksp of group IV sulphides, Group reagent is H2S in the presence of NH4OH and NH4Cl. In a solution containing
0.1 M each of Sn2+, Cd2+ and Ni2+ ions, H2S gas is passed…….
K sp of SnS  8  1029 , K sp of CdS  11028 , K sp of NiS  3 10 21 ,

K1 of H 2S  110 7 , K 2 of H 2S  11014
33. At what value of pH, NiS will start to precipitate (saturated solution of H2S is 0.1 M ?
(Given : log5.77 0.76 )
Sol. (1.24)

34. If 0.1 M HCl is mixed in the solution containing only 0.1 M Cd2+ ions and saturated with H2S, then
ab
[Cd2+] remaining in the solution after CdS stops to precipitate is a × 10b then :
2
Sol. (4.5)

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TOPIC:- Hyperbola, Permutation and Combination & Statistics
PART – III: MATHEMATICS

35. The sum of all 4-digit distinct even numbers that can be formed with the digits 1,2,3,4 and 5 is:
(without repetition)
(A) 159984 (B) 158994 (C) 159894 (D) 22264
2 2
36. If the tangent and the normal to x  y = 4 at a point cut off intercepts a1, a2 on the x-axis respectively
and b1, b2 on the y-axis respectively, then the value of a1a2 + b1b2 is:
(A) 1 (B) 1 (C) 0 (D) 4
37. If the mean of a set of observations x1, x2……, x10 is 20, then the mean of x1 + 4, x2 + 8, ……, x10 + 40
is:
(A) 34 (B) 42 (C) 38 (D) 40
38. If S1 and S2 are the foci of the hyperbola whose transverse axis length is 4 and conjugate axis
length is 6, S3 and S4 are the foci of its conjugate hyperbola, then the area of the quadrilateral S1S2S3S4
is:
(A) 24 (B) 26 (C) 22 (D) None

39. The number of non negative integral solutions of x + 2y + 2z = 21 is lies between

(A) 10 & 60 (B) 20 & 70 (C) 50 & 80 (D) 0 & 20
40. The 5 × 5 grid as shown in figure contains a collection of squares with sizes from l × l to 5 × 5. How
many of these squares contain the black center square ?

(A) 12 (B) 15 (C) greater than 10 (D) less than 20

41. If two distinct tangents can be drawn from the point (, 2) on different branches of the hyperbola
x 2 y2
  1, then
9 16
3 2 3 3
(A) |  | (B) 0    (C) 0    (D)    0
2 3 2 2
42. Out of 30 observations 10 are equal to 7  2 each, 10 are equal to 7 each and the remaining 10 are
2
equal to 7 + 2 each. If standard deviation of the data is equal to 5 , then 2|| is equal to____
3
Ans. (5)
x 2 y2
43. The tangent at a point P on the hyperbola   1 pass through the point (0, b) and the normal at
a 2 b2
point P passes through the point (2 2a, 0) . If e denote the eccentricity of hyperbola then the value of
e2 is:
Ans. (2)

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2 2
44. The tangents to hyperbola x  9 y  9 are drawn from point (3, 2), then the area of triangle that these
tangents form with their chord of contact is :
Ans. (8)
45. If the product of the length of perpendiculars drawn from any point on the hyperbola x2 – 2y2 – 2 = 0 to
k
its asymptotes is , then the value of k is:
3
Ans. (2)
46. Define a 'good word' as a sequence of letters that consists only of the letters A, B and C and in which A
never immidiately followed by B, B is never immediately followed by C, and C is never immediately
followed by A. If the number of n-letter good words is 384, then value of n is
Ans. (8)
47. Suppose five points in a plane are situated in such away that no two of the straight lines joining them
are parallel, perpendicular, or coincident. From each point perpendicular are drawn to all the lines
joining the other four points. If K is the maximum number of intersections that these perpendicular
(excluding given points) can have, then sum of digits of K is:
Ans. (9)
Passage – 1
y2
Tangents are drawn from any point on the director circles of ellipse S1 : x 2   1 to auxiliary
8
x2
circle of hyperbola S2 :  y 2  1. The locus of mid point of the chord of contact is a circle. Let
8
the line y  4 = 2(x  c) cuts the circle orthogonally. The locus of the point (h, k) for which the line
hx + ky = 1 touches the hyperbola S2 is ax2 + by2 = 1. The eccentricity of the conjugate hyperbola
of hyperbola S2, is e.
Then answer the following questions:
48. The value of c + e is:
Ans. (5)
49. The value of a  b is:
Ans. (9)
Passage-2
There are four 0s, three 1s and two 2s. Consider all possible permutations of all these
numbers. [Note :- A permutation can have its leading digit 0].
50. The permutations having the first 0 preceding the first 1 is:
Ans. (720)
51. The permutations having the first 0 preceding the first 1 and the first 1 preceding first 2 is:
Ans. (336)

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