CPP

IIT-JEE
LIQUID SOLUTIONS Batch : XII

CONCENTRATION TERMS AND HENRY’S LAW

1. The solubility of O2 at a certain pressure P and temperature 298 K is 0.08 gL–1. If KH of O2 is 35 k bar, the
value of pressure P is :
(A) 1.0 bar (B) 1.58 bar (C) 3.5 bar (D) 35.0 bar

2. A sensitive toothpaste has 0.1 g F– in 100 g sample. What is its ppm concentraion?
(A) 10 (B) 100 (C) 1000 (D) 10000

(g/L) 
3. Solubility of which of the salts P and Q has H < 0?
(A) P (B) Q P

Solubility
(C) both P and Q (D) unpredictable

Temperature 

4. Density of a 2.05 M solution of acetic acid (mol mass 60) in water is 1.02 g/mL. The molality of the solution
is
(A) 3.28 mol kg–1 (B) 2.28 mol kg–1 (C) 0.44 mol kg–1 (D) 1.14 mol kg–1

5. A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g mL–1.
Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is
(A) 2 (B) 4 (C) 6 (D) 8

6. Two solutions of a substance (non-electrolyte) are mixed in the following manner ; 480 mL of 1.5 M first
solution + 520 mL of 1.2 M second solution. What is the molarity of the final mixture ?
(A) 1.20 M (B) 1.50 M (C) 1.344 M (D) 2.70 M

7. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with 250 mL of 2M HCl will be
(A) 0.875 M (B) 1.0 M (C) 1.75 M (D) 0.975 M

8. Number of atoms of nitrogen present in 100 mL solution of 0.5 M molarity of K4[Fe(CN)6] is

(A) 6.02 × 1023 (B) 3.612 × 1023 (C) 1.806 × 1023 (D) 1.806 × 1024

9. A 5.2 molal solution of methyl alcohol is supplied. What is the mole fraction of methyl alcohol in solution.
(A) 0.050 (B) 0.100 (C) 0.190 (D) 0.086

10. The molality of urea solution in which 0.0100 g of urea, (NH2)2 CO, is added to 0.300 dm3 of water at STP
is :
–2 –4
(A) 3.33 × 10 m (B) 0.555 m (C) 5.55 × 10 m (D) 3.33 m

11. Formation of a solution from two compounds can be considered as :

(i) Pure solvent  Seperated solvent molecules, H1
(ii) Pure solute  Seperated solvent molecules, H2
(iii) Seperated solvent and solute molecules  Solution, H3
Solution is ideal if Hsoln. :
(A) Hsoln. = H3 – H1 – H2 (B) Hsoln. = H1 + H2 + H3
(C) Hsoln. = H1 + H2 – H3 (D) Hsoln. = H1 – H2 – H3

FIITJEE 1
12. Available solutions are 1L of 0.1 M NaCl and 2L of 0.2 M CaCl2. Using only these two solutions what
maximum volume of a solution can be prepared having [Cl–] = 0.34 M exactly. Both electrolytes are strong :
(A) 2.5 L (B) 2.4 L (C) 2.3 L (D) None of these

VAPOUR – PRESSURE AND RAOULT’S LAW

13. A substance will be deliquescent if its vapour pressure is

(A) equal to vapour pressure of water in air (B) equal to atmospheric pressure.
(C) more than vapour pressure of water in air (D) less than vapour of water in air

14. If an azeotropic solution has higher b.p. than b.p. of both the mixed liquids, it is the case of :
(A) positive deviation from Raoult’s law (B) negative deviation from Raoult’s law
(C) perfectly obeying Raoult’s law (D) no such relation exists

15. A mixture of two volatile substances A and B at a certain temperature, shows total vapour pressure P T
(mm Hg) to be “100 – 35B”. The values of P0A and P0B (vapour pressure in pure states), respectively, are
(A) 100, 65 (B) 100, 35 (C) 65, 35 (D) 100, 135

16. A binary liquid solution is prepared by mixing n-hepane and ethanol. Which one of the following statements
is correct regarding the behavior of the solution?
(A) the solution is non-ideal, showing +ve deviation from Raoult’s law
(B) the solution is non-ideal, showing –ve deviation from Raoult’s law
(C) n-heptane shows +ve deviation while ethanol shows –ve deviation from Raoult’s law
(D) the solution forms an ideal solution

17. Which of the following liquid pairs will show positive deviation from Rault’s law?
(A) water — Hydrochloric acid (B) Water — Nitric acid
(C) Acetone — Chloroform (D) Benzene — Methanol

18. The boiling point of a mixture of ChCl3 and CH3—CO—CH3 is higher than both the liquids. The solution is
showing
(A) positive deviation from ideal behaviour (B) negative deviation from ideal beahviour
(C) no deviation from Raoult’s law (D) metastable behaviour

19. Vapour pressures of benzene and toluene at certain temperature are 400 and 150 mm Hg respectively. 3
moles of benzene and 2 moles of toluene from an ideal solution. The mole fractions of the two in the
vapour phase will be
(A) 0.3, 0.7 (B) 0.6, 0.4 (C) 0.8, 0.2 (D) 1.2, 0.3

20. At 800C, the vapour pressure of pure liquid ‘A’ is 520 mm of Hg and that of pure liquid ‘B’ is 1000 mm of
Hg. If a solution of ‘A’ and ‘B’ boils of 800C and 1 atm pressure, the amount of ‘A’ in the mixture is (1 atm =
760 mm Hg)
(A) 50 mol per cent (B) 52 mol per cent (C) 34 mol per cent (D) 48 mol per cent

21. Two liquids X and Y from ideal solution. At 300 K vapour pressure of the solution containing 1 mole of X
and 3 moles of Y is 550 mm Hg. At the same temperature, if 1 mole of Y is further added to this solution,
vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mm Hg) of X and Y in their
pure states will be, respectively
(A) 300 and 400 (B) 400 and 600 (C) 500 and 600 (D) 200 and 300

22. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressure of the two liquid
components (heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of the solution
obtained by mixing 25.0 g of heptane and 35g of octane will be (molar mass of heptane = 100 g mol–1 and
octane = 114 g mol–1)
(A) 144.5 kPa (B) 72.0 kPa (C) 36.1 kPa (D) 96.2 kPa

23. For an ideal binary liquid solution with PA > PB , which relation between XA (mole fraction of A in liquid
phase) and YA(mole fraction of A in vapour phase) is correct?
YA XA YA X A
(A) YA < YB (B) XA > XB (C)  (D) 
YB XB YB XB

FIITJEE 2
24. The exact mathematical expression of Raoult’s law is
P0  Ps n P0  Ps N P0  Ps n P0  Ps
(A)  (B)  (C)  (D) = n ×N
P0 N P0 n Ps N Ps

25. A mixture contains 1 mole of volatile liquid A ( PA =100 mm Hg) and 3 moles of volatille liquid
B ( PB = 80 mm Hg). If solution behaves ideally, the total vapour pressure of the distillate is
(A) 85 mm Hg (B) 85.88 mm Hg (C) 90 mm Hg (D) 92 mm Hg

26. The vapour pressure of a solution of a non-volatile electrolyte B in a solvent A is 95% of the vapour
pressure of the solvent at the same temperature. If the molecular weight of the solvent is 0.3 times the
molecular weight of solute, the weight ratio of the solvent and solute are
(A) 0.15 (B) 5.7 (C) 0.2 (D) 4.0

27. At a given temperature, total vapour pressure in Torr of a mixture of volatile components A and B is given
by PTotal = 120 – 75 XB hence, vapour pressure of pure A and B respectively (in Torr) are
(A) 120, 75 (B) 120, 195 (C) 120, 45 (D) 75, 45

28. The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added to the
solvent. The mole fraction of solute in solution is 0.2, what would be mole fraction of the solvent if decrease
in vapour pressure is 20 mm of Hg
(A) 0.2 (B) 0.4 (C) 0.6 (D) 0.8

29. The following diagram shows the vapor pressure vs temperature

curves for CH3OH, CH3COOH and H2CO. Which of the following
matching is correct ?
(A) I–H2CO, II–CH3OH, III–CH3COOH
(B) I-CH3COOH, II-CH3OH, III-H2CO
(C) I-CH3OH, II-CH3COOH, III-H2CO
(D) I-H2CO, II-CH3COOH, III-CH3OH

30. Solubility curves of two salts X and Y as a function of temperature are

given in the figure. Which of the following conclusions can definitely be
made ?
(I) Lattice energy of X is more than that of Y
(II) Solvation energy of X is less than that of Y.
(III) Hsolution of X is negative
(IV) Hsolution of Y is positive
(A) I & III (B) II & IV
(C) III & IV (D) All

31. Two liquids X and Y are completely immiscible. X and Y have molecular masses in the ratio 1 : 2. The total
vapour pressure over the mixture of X and Y developed upon stirring is (PX° = 200 mm, PY° = 400 mm)
(A) 365 mm (B) 600 mm (C) 475 mm (D) Data insufficient
32. Three solutions are prepared by adding ‘w’ gm each of A, B and C in 1 kg of water separately (A, B, C are
non-electrolytic). Dry air is passed from these solutions in sequence (A  B  C). The loss in weight of
solution A was found to be 2 gm while solution B gained 0.5 gm and solution C lost 1 gm. Then the relation
between molar masses of A, B and C is :
1 1 1
(A) MA : MB : MC = 4 : 3 : 5 (B) MA : MB : MC = : :
4 3 5
(B) MC > MA > MB (D) MB > MA > MC

33. An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour pressure of 1 atm
at a certain temperature. Another mixture with 1 mole of A and 3 moles of B has a vapour pressure greater
than 1 atm. But if 4 moles of C are added to the second mixture, the vapour pressure comes down to 1
atm. Vapour pressure of C, Pc0 = 0.8 atm. Calculate the vapour pressures of pure A and pure B :
(A) PA0 = 1.4 atm, PB0 = 0.7 atm (B) PA0 = 1.2 atm, PB0 = 0.6 atm
0 0
(C) PA = 1.4 atm, PB = 0.6 atm (D) PA0 = 0.6 atm, PB0 = 1.4 atm

FIITJEE 3
34. A sample of air is saturated with benzene (vapour pressure = 100 mm Hg at 298 K) at 298 K, 750 mm Hg
pressure. If it is isothermally compressed to one third of its initial volume, the final pressure of the system
is:
(A) 2250 torr (B) 2150 torr (C) 2050 torr (D) 1950 torr

35. The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torr and 10 Torr at 20°C. Which of
the following is not a possible value of the vapor pressure of an equimolar binary / ternary solution of these
at 20°C ? Assume all form ideal solution with each other.
1 2 1
(A) 48 (B) 16 (C) 35 (D) 53
2 3 2

36. Assuming the formation of an ideal solution, determine the

boiling point of a mixture containing 1560 g benzene (molar Torr
mass = 78) and 1125 g chlorobenzene (molar mass =
112.5) against an external pressure of 1000 Torr using the
following curve :
(A) 90°C (B) 100°C
(C) 110° (D) 120°C

37. Two volatile liquids A and B form ideal solution.

Considering the following vapour-pressure composition
graph
OR will be equal to :
(A) OP + OQ (B) OP + PR
(C) PQ + QR (D) OQ + PQ

Passage for question no. 38 to 40 :

The following vapour pressure data were collected over a solution of acetone and diethyl ether at 30°C :
Mole Fraction of acetone VP (Solution in mm of Hg)
0.00 86.1
0.20 83.3
0.40 78.4
0.50 74.5
0.60 69.6
0.80 58.2
1.00 37.7
Answer the following three questions based on the above mentioned information.
38. If this solution behaved ideally, what would have been its vapour pressure when mole fraction of acetone
was 0.40 ?
(A) 78.4 mm (B) 66.74 mm (C) 62.33 mm (D) 60.67 mm

39. What can be said about Hmixing of solution ?

(A) Hmixing > 0 (B) Hmixing < 0
(C) Hmixing = 0 (D) Insufficient information
40. A solution is prepared by mixing 500 mL of acetone with 500 mL of diethyl ether. What can be said about
volume of solution obtained ?
(A) Volume of solution = 1000 mL (B) Volume of solution > 1000 mL
(C) Volume of solution < 1000 mL (D) Insufficient information

FIITJEE 4
 COLLIGATIVE PROPERITES & VAN’T HOFF FACTOR

41. Which of the following aqueous solution will show maximum vapour pressure at 300 K?
(A) 1 M NaCl (B) 1 M CaCl2 (C) 1 M AlCl3 (D) 1 M C12H22O11

42. The Van’t Hoff factor for a dilute aqueous solution of glucose is
(A) zero (B) 1.0 (C) 1.5 (D) 2.0

43. The correct relationship between the boiling points of very dilute solution of AlCl3 (T1K) and CaCl2 (T2K)
having the same molar concentration is
(A) T1 = T2 (B) T1 > T2 (C) T2 > T1 (D) T2  T1

44. Assuming each salt to be 90 % dissociated, which of the following will have highest melting point?
(A) Decimolar Al2(SO4)3 (B) Decimolar BaCl2
(C) Decimolar Na2SO4
(D) A solution obtained by mixing equal volumes of (B) and (C)

45. Elevation of boiling point of 1 molar aqueous glucose solution (density = 1.2 g/ml) is
(A) Kb (B) 1.20 Kb (C) 1.02 Kb (D) 0.98 Kb

46. 1.0 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at 1 atm
is ( K b(H2O)  0.52 K kgmol1 )
(A) 274.76 K (B) 377 K (C) 376.4 K (D) 374.76 K

47. For a solution of 0.849 g of mercurous chloride in 50 g of HgCl2(l) the freezing point depression is 1.24 °C.
K1 for HgCl2 is 34.3. What is the state of mercurous chloride in HgCl2 ? (Hg – 200, Cl – 35.5)
(A) as Hg2Cl2 molecules (B) as HgCl molecules (C) as Hg+ and Cl– ions (D) as Hg22+ and Cl– ions

48. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in mole/litre will
be:
(A) 0.33 (B) 0.066 (C) 0.3 × 10–2 (D) 3
49. Consider following cases.
I: 2M CH3 COOH solution in benzene at 27°C where there is dimer formation to the extent of 100%
II: 0.5 M KCI aq. solution at 27°C, which ionises 100%
Which is/are true statements (s).
(A) both are isotonic (B) I is hypertonic (C) II is hypotonic (D) data insufficient
50. How many mili moles of sucrose should be dissolved in 500 gms of water so as to get a solution which has
a difference of 103.57°C between its boiling point and freezing point (Kb = 0.51, Kf = 1.86 for water) :
(A) 500 m moles (B) 900 m moles (C) 750 m moles (D) 650 m moles

51. The molar heat of vapourization of toluene is Hv. If its vapour pressure at 315 K is 60 torr & that at 355 K
is 300 torr then Hv = ?
(A) 37.5 kJ / mole (B) 3.75 kJ/mole (C) 37.5 J/mol (D) 3.75 J/mole

52. A solution of x moles of sucrose in 100 grams of water freezes at –0.2°C. As ice separates the freezing
point goes down to –0.25°C. How many grams of ice would have separated ?
(A) 18 grams (B) 20 grams (C) 25 grams (D) 23 grams

53. A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% solution of an unknown solute. The
molar mass of unknown solute in g/mol is :
(A) 34.2 (B) 136.2 (C) 171.2 (D) 68.4

54. A solute ‘S’ undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point
elevation of its 0.1 molal solution was found to be identical to the boiling point elevation in case of a 0.08
molal solution of a solute in the same solvent which neither undergoes association nor dissociation. To
what extent had the solute ‘S’ undergone trimerization ?
(A) 30% (B) 40% (C) 50% (D) 60%

FIITJEE 5
55. 3.24 g of Hg(NO3)2 (molar mass = 324) dissolved in 1000 g of water constitutes a solution having a
freezing point of –0.0558°C while 21.68 g of HgCl2 (molar mass = 271) in 2000 g of water constitutes a
K.Kg
solution with a freezing point of –0.0744°C. The Kf for water is 1.86 . About the state of ionization of
Mol
these two solids in water it can be inferred that :
(A) Hg(NO3)2 and HgCl2 both are completely ionized
(B) Hg(NO3)2 is fully ionized but HgCl2 is fully unionized
(C) Hg(NO3)2 and HgCl2 both are completely unionized
(D) Hg(NO3)2 is fully unionized but HgCl2 is fully ionized

56. x mole of KCl and y mole of BaCl2 are both dissolved in 1 kg of water. Given that x + y = 0.1 and kf for
water 1.85 K/molal, what is the observed range of Tf , if the ratio of x to y is vaired?
(A) 0.37° to 0.55° (B) 0.185° to 0.93° (C) 0.56 to 0.93° (D) 0.37° to 0.93°

57. Just sufficient Al2 (SO4)3 (s) is added to a 0.1 M solution of BaCl2 such that all the BaSO4 is precipitated
completely. Volume of solution is maintained constant then:
(A) Freezing point of the original solution is raised (B) Boiling point of the original solution is raised
(C) Vapour pressure of the original is raised (D) Osmotic pressure of the original solution is raised
58. If average osmotic pressure of blood is 7.8 bar at 370C, what is the concentration of aqueous KCl solution
solution that could be used in blood stream?
(A) 0.16 mol L–1 (B) 0.31 mol L–1 (C) 0.60 mol L–1 (D) 0.45 mol L–1
59. For equal molar concentrations of glucose, NaCl, BaCl2 and AlCl3, the decreasing order of measured
colligative property is
(A) Glucose > AlCl3 > BaCl2 > NaCl (B) AlCl3 > BaCl2 > NaCl > Glucose
(C) Glucose > NaCl > BaCl2 > AlCl3 (D) AlCl3 > BaCl2 > NaCl = Glucose
60. van’t Hoff’s factor for a substance ‘X’ whose molecular weight corresponds to that of ‘X2’ by colligative
properties measurement, is
(A) 1 (B) ½ (C) 2 (D) None of these

61. If acetic acid dimerises in a solvent, the van’t Hoff’s factor ‘i’ is related to the degree of association ‘’ as :
 
(A) i = 1 –  (B) i = 1 +  (C) i  1  (D) i  1 
2 2

62. Which of the following is correct for the reaction, 3X  X3?

3 2
(A)   1  i  (B)   1  i  (C)  = 2 × 3 (1 – i) (D)  = 3 (i – 1)
2 3

63. Which of the following will have highest measure of any colligative property?
(A) 1% sucrose solution (B) 1% glucose solution (C) 1% glycerol solution (D) 1% urea solution

64. The vapour pressure of acetone at 200C is 185 torr. When 0.02 g of a non-volatile substance was
dissolved in 100 g of acetone at 200C, its vapour pressure was 183 torr. The molar mass (g mol–1) of the
substance is :
(A) 488 (B) 32 (C) 64 (D) 28

65. If sodium sulphate is considered to the completely dissociated into cations and anions in aqueous solution,
the change in freezing point of water (Tf), when 0.01 mole of sodium sulphate is dissolved is 1 kg of water
is (kf = 1.86 K kg mol–1)
(A) 0.0186 K (B) 0.0372 K (C) 0.0558 K (D) 0.0744 K
–1
66. kf of water is 1.86 K kg mol . If your automobile radiator holds 1.0 kg of water, how many grams of
0
ethylene glycol (C2H6O2) must you add to get the freezing point of solution lowered to –2.8 C.
(A) 93g (B) 39g (C) 27g (D) 72g

67. What is the concentration of glucose solution in g L–1 that is isotonic with human blood having osmotic
pressure 8.2 atm at 370C?
–1 –1 –1 –1
(A) 45 gL (B) 50 gL (C) 60 gL (D) 90 gL

FIITJEE 6
68. Ethylene glycol is used as an antifreeze in a cold climate. mass of ethylene glycol which should be added
to 4 kg of water to prevent it from freezing at –60C will be :
–1 –1
(kf for water = 1.86 K kg mol and molar mass of ethylene glycol = 62 g mol )
(A) 304.60 g (B) 804.32 g (C) 204.30 g (D) 400.00 g

69. MX2 dissociates in M2+ and X–ions in an aqueous solutions, with a degree of dissociation () of 0.5 The
ratio of the observed depression of freezing point of the aqueous solution to the value of the depression of
freezing point in the absence of ionic dissociation is :
(A) 1 (B) 2 (C) 3 (D) 4

70. The degree of dissociation (), of a week electrolyte AxBy is related to van’t Hoff’s factor (i) by the
expression :
x  y 1 i 1 i 1 x  y 1
(A)   (B)   (C)   (D)  
i 1 x  y 1 x  y 1 i 1

SUBJECTIVE
I. CONCENTRATION UNITS

1. Calculate the mole fraction, molal and molar concentrations of a solution containing 20 per cent acetic acid
0 -3
by mass in water, if the density of the solution at 20 C is 1.026 g cm .
-3
2. The molarity of NH3 in aqueous solution is 11.8 mol dm . Calculate the mole fraction of NH3 in solution.
The density of the solution is 0.916 g cm-3.

II. VAPOUR PRESSURE

3. In 804 g of water, 30 g sucrose and 30 g glucose were dissolved. What is the vapour pressure of this
solution at 303 K if the vapour pressure of water at that temperature is 31.82 mm of Hg ?

4. Calculate the mole fraction of toluene in the vapour phase which is in equilibrium with a solution of
benzene and toluene having a mole fractions each 0.5. P°benzene = 119 torr, P°toluene = 37 torr.

5. Two liquids A and B form an ideal solution at temperature T. When the total vapour pressure above the
solution is 400 Torr, the mole fraction of A in the vapour phase is 0.4 and in the liquid phase is 0.75. What
are the vapour pressures of pure A and pure B at temperature T ?

6. Benzene and toluene form two ideal solutions A and B at 313 K. Solution A (total vapour pressure PA)
contains equal moles of benzene and toluene. Solution B contains equal masses of both (total vapour
pressure PB). P°benzene = 160 and P°toluene = 60 mm Hg both at 313 K. Calculate the value of PA/PB.

7. When 2 g of a non-volatile hydrocarbon containing 94.4 per cent carbon is dissolved in 100 g benzene, the
vapour pressure of benzene at 200C is lowered from 0.09954 bar to 0.09867 bar. Calculate the molecular
formula of the hydrocarbon.

8. A solution containing 0.5126 g naphthalene in 50 g CCl4, yields a boiling point elevation of 0.402 K, while a
solution of 0.6216 g of an unknown solute in the same mass of the solvent gives a boiling point elevation of
0.647 K. Find the molar mass of the unknown solute.

9. The vapour pressure of a solution containing 6.69 g of Mg(NO3)2 dissolved in 100 g of water is 747 Torr at
373 K. Calculate the degree of dissociation of the salt in the solution.

III. ELEVATION IN BOILING POINT

10. The boiling point of ethyl alcohol is 78.40C and its ∆Hvap = 39.42 kJ/mol-1. Calculate the molal boling point
elevation constant for ethyl alcohol.

11. Calculate the molal elevation constant, Kb, for water and the boiling point of 0.1 molal urea solution. Hvap
of H2O = 9.72 Kcal mol–1 at 373K.

12. Sea water is found to contain 5.85% NaCl and 9.5% MgCl2 by weight of solution. Calculate its normal
–1
boiling point assuming 80% ionisation for NaCl and 50% ionisation for MgCl2. (Kb H2O = 0.52 kg mol K).

FIITJEE 7
13. A solution containing 0.122 kg of benzoic acid in 1 kg of benzene ( boiling point-353 K ) boils at 354.5 K.
Determine the apparent molar mass of benzoic acid in the solution and the degree of dimerisation. Given
Δ vap H (benzene) =394.57 J g –1

DEPREESSION IN FREEZING POINT

14. When phenol is dissolved in a particular solvent, it is partially dimerised. If 2.58 g of phenol is dissolved in
100 g of the solvent, the freezing point of the solvent (Kf = 14.1 K kg mol-1) is depressed by 2.37 K. Find
how much of the phenol is dimerised in solution ?

IV. OSMOTIC PRESSURE

15. A 1.2% solution (w/v) of NaCl is isotonic with 7.2% (w/v) glucose solution. Calculate degree of ionisation
and van't Hoff factor of NaCl.

16. 1.25 g benzoic acid, when dissolved in 100 cm3 of benzene, produces osmotic pressure of 1.73 atm at 300
K. Benzoic acid is known to form dimer in benzene. Calculate the percentage of benzoic acid in the
associated form.

V. CORRELATION BETWEEN COLLIGATIVE PROPERTIES

17. An aqueous solution of a non-volatile solution boils at 100.17°C. At what temperature will this solution
freeze ?

18. The vapour pressure of a solution of urea is 736.2 mm Hg at 1000C. What is the osmotic pressure of this
solution at 150C ? At what temperature would the solution begin to freeze ? Kf of water = 1.86 K kg mol-1.

HENRY’S LAW

19. At 298 K , 500 cm3 of water dissolves 15.03 cm3 of CH4 (at STP) under a partial pressure of methane of 1
atm. If Henry’s law holds, what pressure is required to dissolve 0.001 mol methane in 300 cm3 water ?

*****
ANSWER KEY

1. B 2. C 3. B 4. B 5. D 6. C 7. A 8. C 9. D 10. C
11. B 12. A 13. D 14. B 15. A 16. A 17. D 18. B 19. C 20. A
21. B 22. B 23. C 24. C 25. B 26. B 27. C 28. C 29. A 30. C
31. B 32. B 33. D 34. C 35. D 36. B 37. A 38. B 39. A 40. B
41. D 42. B 43. B 44. D 45. D 46. D 47. A 48. C 49. A 50. C
51. A 52. B 53. D 54. A 55. B 56. A 57. A 58. B 59. B 60. B
61. C 62. A 63. D 64. C 65. C 66. A 67. A 68. B 69. B 70. B

SUBJECTIVE ANSWERS

-1 -3
1. (X = 0.0697, m = 4.163 mol kg , M = 3.417 mol dm ) 2. (0.229)
3. (31.65 mm of Hg) 4. (0.237)
5. (P°A = 213.33 Torr P°B = 960 Torr) 6. (0.964)
-1
7. (C14H10) 8. (96.6 g mol )
-1
9. (0.565) 10. (1.19 K Kg mol )
–1
11. (Kb= 0.512K kg mol Tb= 100.05°C) 12. (Tb of sea water = 101.976°C)
-1
13. (0.214 Kg mol , 0.86) 14. (77 %)
15. (α = 0.95 i = 1.95) 16. (62.93 %)
0
17. (–0.62°C) 18. (4.17 kPa, -3.2 C)
19. (2.485 atm)

FIITJEE 8