SAFETY DATA SHEET

Section 1. Identification
Product name : CRO195 CORROSION INHIBITOR
Product code : CRO195

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Corrosion inhibitor

Print date : 1/12/2023

Validation date : 1/12/2023
Version : 2.02

Supplier's details : Baker Petrolite LLC

12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)

number (with hours of Baker Petrolite: 800-231-3606
operation) (001)281-276-5400
CHEMTREC Int'l 01-703-527-3887 (International 24 hour)
BPC

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
AQUATIC HAZARD (ACUTE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification

Hazard statements : Flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
Causes damage to organs. (optic nerve)
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves: > 8 hours (breakthrough time):
Nitrile or Neoprene gloves.. Wear protective clothing. Wear eye or face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-
sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-
ventilated area. Avoid release to the environment. Do not breathe vapor. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling.
Response : Collect spillage. IF exposed: Call a POISON CENTER or doctor. IF INHALED:
Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER or doctor. IF SWALLOWED: Immediately call a POISON CENTER
or doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water. Immediately call a
POISON CENTER or doctor. Wash contaminated clothing before reuse. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified
Additional information
The NIOSH IDLH (Immediately Dangerous to Life and Health) value for hydrogen sulfide is 100 ppm. Hydrogen sulfide
odor is not a good warning property. The human sense of smell may become "fatigued" after a few minutes of exposure to
hydrogen sulfide and no longer be able to detect the odor. See Section 11 for more detailed information on health effects
and symptoms.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Light aromatic naphtha 30 - 40 64742-95-6
1,2,4-Trimethylbenzene 20 - 30 95-63-6
Phosphates 5 - 10 Trade secret.
Quaternary ammonium chloride 5 - 10 Trade secret.
1,3,5-Trimethylbenzene 5 - 10 108-67-8
1,2,3-Trimethylbenzene 1-5 526-73-8
Xylene 1-5 1330-20-7
Amine derivative 1-5 Trade secret.
Methanol 1-5 67-56-1
Cumene 0.1 - 1 98-82-8
Ethylbenzene 0.1 - 1 100-41-4
Hydrogen sulfide 0 - 0.1 7783-06-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.

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Section 3. Composition/information on ingredients

There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified and hence require reporting in this section.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Additional information
The 0.1% (1000 ppm) maximum hydrogen sulfide (H2S) content shown above is for the liquid phase. The headspace of
containers of this product may contain levels of H2S higher than this.
** Since this chemical is a sub-component of a solvent added to this product, it is not a WHMIS regulated component of
this controlled product.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes
while holding the eyelid(s) open. Check for and remove any contact lenses. Chemical
burns must be treated promptly by a physician.
Inhalation : Call a poison center or physician. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under medical surveillance
for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected
area with soap and mild detergent for at least 20 - 60 minutes. Flush contaminated skin
with plenty of water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Chemical burns must
be treated promptly by a physician. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Chemical
burns must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Causes damage to organs following a single exposure if inhaled. Can cause central
nervous system (CNS) depression. May cause drowsiness or dizziness. May cause
respiratory irritation.
Skin contact : Causes severe burns. Causes damage to organs following a single exposure in contact
with skin.
Ingestion : Causes damage to organs following a single exposure if swallowed. Can cause central
nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : respiratory tract irritation,coughing,nausea or vomiting,headache,drowsiness/fatigue,
dizziness/vertigo,unconsciousness

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Section 4. First aid measures

Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
from the chemical fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back. This material is toxic to aquatic life with
long lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides,phosphorus oxides
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

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Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.
Additional information
Released material may contain residual sulfides. Spray residual material left after initial clean up with weak (approximately
5 percent) hydrogen peroxide to oxidize sufides. Recover as much solution as possible. A respirator suitable for H2S may
be necessary in the event of a spill.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in a dry, cool and well-ventilated area, away from incompatible materials (see
incompatibilities Section 10). Store in original container, protected from direct sunlight. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. See
Section 10 for incompatible materials before handling or use.
Additional information

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Section 7. Handling and storage

Avoid inhalation of vapors near openings on storage containers and manufacturing equipment. This product should be
transferred under negative pressure.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Light aromatic naphtha None.
1,2,4-Trimethylbenzene NIOSH REL (United States, 10/2020).
TWA: 125 mg/m³, 0 times per shift, 10 hours.
TWA: 25 ppm, 0 times per shift, 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 125 mg/m³, 0 times per shift, 8 hours.
TWA: 25 ppm, 0 times per shift, 8 hours.
ACGIH TLV (United States, 1/2022).
TWA: 10 ppm 8 hours.
Phosphates None.
Quaternary ammonium chloride None.
1,3,5-Trimethylbenzene ACGIH TLV (United States, 1/2022).
TWA: 123 mg/m³, 0 times per shift, 8 hours.
TWA: 10 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 125 mg/m³, 0 times per shift, 10 hours.
TWA: 25 ppm, 0 times per shift, 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 125 mg/m³, 0 times per shift, 8 hours.
TWA: 25 ppm, 0 times per shift, 8 hours.
1,2,3-Trimethylbenzene ACGIH TLV (United States, 1/2022).
TWA: 123 mg/m³, 0 times per shift, 8 hours.
TWA: 10 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 125 mg/m³, 0 times per shift, 10 hours.
TWA: 25 ppm, 0 times per shift, 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 125 mg/m³, 0 times per shift, 8 hours.
TWA: 25 ppm, 0 times per shift, 8 hours.
Xylene ACGIH TLV (United States, 1/2022).
TWA: 20 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 655 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Amine derivative None.
Methanol ACGIH TLV (United States, 1/2022). Absorbed through
skin.
STEL: 328 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 262 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
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Section 8. Exposure controls/personal protection

STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 10 hours.
TWA: 200 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
Cumene ACGIH TLV (United States, 1/2022).
TWA: 5 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020). Absorbed
through skin.
TWA: 245 mg/m³, 0 times per shift, 10 hours.
TWA: 50 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018). Absorbed through
skin.
TWA: 245 mg/m³, 0 times per shift, 8 hours.
TWA: 50 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
TWA: 245 mg/m³, 0 times per shift, 8 hours.
TWA: 50 ppm, 0 times per shift, 8 hours.
Ethylbenzene ACGIH TLV (United States, 1/2022). Ototoxicant.
TWA: 20 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
STEL: 545 mg/m³, 0 times per shift, 15 minutes.
STEL: 125 ppm, 0 times per shift, 15 minutes.
TWA: 435 mg/m³, 0 times per shift, 10 hours.
TWA: 100 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 545 mg/m³, 0 times per shift, 15 minutes.
STEL: 125 ppm, 0 times per shift, 15 minutes.
TWA: 435 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
Hydrogen sulfide ACGIH TLV (United States, 1/2022).
STEL: 5 ppm, 0 times per shift, 15 minutes.
TWA: 1 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020).
CEIL: 15 mg/m³, 0 times per shift, 10 minutes.
CEIL: 10 ppm, 0 times per shift, 10 minutes.
OSHA PEL 1989 (United States, 3/1989).
STEL: 21 mg/m³, 0 times per shift, 15 minutes.
STEL: 15 ppm, 0 times per shift, 15 minutes.
TWA: 14 mg/m³, 0 times per shift, 8 hours.
TWA: 10 ppm, 0 times per shift, 8 hours.
OSHA PEL Z2 (United States, 2/2013).
AMP: 50 ppm, 0 times per shift, 10 minutes.
CEIL: 20 ppm, 0 times per shift, 0 hours.

Consult local authorities for acceptable exposure limits.

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Section 8. Exposure controls/personal protection

If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles. If inhalation hazards exist, a full-face respirator may be
required instead.
Hand protection : Chemical-resistant gloves: Nitrile or Neoprene gloves.
Skin protection : Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin
contact.
Respiratory protection : Hydrogen sulfide accumulates in the headspace of containers of this product. During
sealed transfer of this product under well-ventilated conditions, where inhalation
exposure potential is minimal, respiratory protection is not expected to be necessary.
However, if after a thorough hazard assessment respiratory protection is deemed
necessary an appropriate supplied air respirator must be utilized.
Additional information
Prior to handling containers of this product, make sure to be wearing a hydrogen sulfide (H2S) monitor that is in sound
working condition.

Section 9. Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid.
Color : Amber.
Odor : Mercaptan
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial Boiling Point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: 38°C (100.4°F) [SFCC ASTM D 3828]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability : Flammable in the presence of the following materials or conditions: open flames, sparks
and static discharge and heat.

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Section 9. Physical and chemical properties

Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure : 23.4 kPa (175.8 mm Hg (3.4 psig)) @ 54.44°C (130 F) (Reid)
Relative vapor density : >1 [Air = 1]
Relative density : 0.9 (16°C)
Density : 7.5 (lbs/gal)
Solubility in water : Dispersible
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic (16°C): 4.4 cP

VOC : Not available.

Pour Point : -40°C (-40°F)
Particle characteristics
Median particle size : Not applicable.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, reducing
materials and acids.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Light aromatic naphtha LD50 Oral Rat 2900 mg/kg -
1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³ 4 hours
LD50 Oral Rat 5 g/kg -
Phosphates LD50 Dermal Rabbit >8000 mg/kg -
LD50 Oral Rat 9200 mg/kg -
Quaternary ammonium LD50 Dermal Rat 1664 mg/kg -
chloride
LD50 Oral Rat 295 mg/kg -
1,3,5-Trimethylbenzene LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LD50 Oral Rat 5000 mg/kg -
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Section 11. Toxicological information

Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 29 mg/l 4 hours
LD50 Dermal Rabbit 20000 mg/kg -
LD50 Dermal Rabbit >1700 mg/kg -
LD50 Oral Male rat 3523 mg/kg -
LD50 Oral Rat 3287 mg/kg -
Amine derivative LD50 Dermal Rabbit >23500 mg/kg -
LD50 Oral Rat >19000 mg/kg -
Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours
LC50 Inhalation Gas. Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
LD50 Oral Human 500 mg/kg -
LD50 Oral Rat 5600 mg/kg -
Cumene LC50 Inhalation Vapor Mouse 10000 mg/m³ 7 hours
LC50 Inhalation Vapor Rat 39000 mg/m³ 4 hours
LD50 Dermal Rabbit 10600 mg/kg -
LD50 Oral Rat 2.9 g/kg -
Ethylbenzene LD50 Dermal Rabbit 15400 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Hydrogen sulfide LC50 Inhalation Gas. Rat 444 ppm 4 hours
LC50 Inhalation Vapor Rat 700 mg/m³ 4 hours
LCLo Inhalation Gas. Man 634 ppm 1 hours
Irritation/Corrosion
No available toxicity data.
Sensitization
No available toxicity data.
Mutagenicity
No available toxicity data.
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Cumene - 2B Reasonably anticipated to be a human carcinogen.
Ethylbenzene - 2B -
Reproductive toxicity
No available toxicity data.
Teratogenicity
No available toxicity data.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Light aromatic naphtha Category 3 - Narcotic effects
1,2,4-Trimethylbenzene Category 3 - Respiratory tract
irritation
1,3,5-Trimethylbenzene Category 3 - Respiratory tract
irritation
1,2,3-Trimethylbenzene Category 3 - Respiratory tract
irritation
Xylene Category 3 - Narcotic effects
Methanol Category 1 oral optic nerve
Cumene Category 3 - Respiratory tract
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Section 11. Toxicological information

irritation
Hydrogen sulfide Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Ethylbenzene Category 2 - hearing organs
Aspiration hazard
Name Result
Light aromatic naphtha ASPIRATION HAZARD - Category 1
1,2,3-Trimethylbenzene ASPIRATION HAZARD - Category 1
Xylene ASPIRATION HAZARD - Category 1
Cumene ASPIRATION HAZARD - Category 1

Information on the likely : Routes of entry anticipated: Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Causes damage to organs following a single exposure if inhaled. Can cause central
nervous system (CNS) depression. May cause drowsiness or dizziness. May cause
respiratory irritation.
Skin contact : Causes severe burns. Causes damage to organs following a single exposure in contact
with skin.
Ingestion : Causes damage to organs following a single exposure if swallowed. Can cause central
nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : respiratory tract irritation,coughing,nausea or vomiting,headache,drowsiness/fatigue,
dizziness/vertigo,unconsciousness
Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
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Section 11. Toxicological information

Numerical measures of toxicity

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
CRO195 CORROSION INHIBITOR 2762 6689.7 132834.9 49.9 Not
available.
Light aromatic naphtha 2900 Not Not Not Not
available. available. available. available.
1,2,4-Trimethylbenzene 5000 Not Not 18 Not
available. available. available.
Phosphates 9200 Not Not Not Not
available. available. available. available.
Quaternary ammonium chloride 500 1664 Not Not Not
available. available. available.
1,3,5-Trimethylbenzene 5000 Not Not 24 Not
available. available. available.
Xylene 3287 1100 5000 29 Not
available.
Methanol 100 300 64000 3 Not
available.
Cumene 2900 10600 Not 39 Not
available. available.
Ethylbenzene 3500 15400 Not 11 Not
available. available.
Hydrogen sulfide Not Not 444 0.7 Not
available. available. available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
1,2,4-Trimethylbenzene Acute LC50 4910 µg/l Marine water Crustaceans - Elasmopus 48 hours
pectenicrus
Acute LC50 22.4 mg/l Fresh water Fish - Tilapia zillii 96 hours
Phosphates Acute EC50 0.48 mg/l Algae - Skeletonema 72 hours
Acute LC50 3.2 mg/l Fish 96 hours
Quaternary ammonium Acute LC50 0.145 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
chloride
1,3,5-Trimethylbenzene Acute LC50 12520 to 15050 µg/l Fresh Fish - Carassius auratus 96 hours
water
Chronic NOEC 400 µg/l Fresh water Daphnia - Daphnia magna 21 days
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 10000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours
Cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
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Section 12. Ecological information

Acute LC50 7400 to 11290 µg/l Fresh Crustaceans - Artemia sp. 48 hours
water
Acute LC50 30500 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2700 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 2930 to 4400 µg/l Fresh Daphnia - Daphnia magna 48 hours
water
Acute LC50 5200 µg/l Marine water Crustaceans - Americamysis 48 hours
bahia
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 1000 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Hydrogen sulfide Acute EC50 62 µg/l Fresh water Crustaceans - Gammarus 2 days
pseudolimnaeus
Acute LC50 2 µg/l Fresh water Fish - Coregonus clupeaformis - 96 hours
Yolk-sac fry

Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
Phosphates - 28 % - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Phosphates - - Inherent

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Light aromatic naphtha - 10 to 2500 high
1,2,4-Trimethylbenzene 3.63 243 low
1,3,5-Trimethylbenzene 3.42 161 low
1,2,3-Trimethylbenzene 3.66 194.98 low
Xylene 3.12 8.1 to 25.9 low
Methanol -0.77 <10 low
Cumene 3.55 94.69 low
Ethylbenzene 3.6 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.

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Section 14. Transport information

DOT Classification TDG Classification IMDG IATA
UN number UN2924 UN2924 UN2924 UN2924

UN proper FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID,

shipping name CORROSIVE, N.O.S. CORROSIVE, N.O.S. CORROSIVE, N.O.S. CORROSIVE, N.O.S.
(Contains: Methanol, (Contains: Methanol, (Contains: Methanol, (Contains: Methanol,
Quaternary ammonium Quaternary ammonium Quaternary ammonium Quaternary ammonium
chloride) chloride) chloride) chloride)
Transport 3 (8) 3 (8) 3 (8) 3 (8)
hazard class(es)

Packing group III III III III

Environmental Yes. Yes. Yes. Yes. The
hazards environmentally
hazardous substance
mark is not required.

Additional information
DOT Classification : This product is not regulated as a marine pollutant when transported on inland
waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes,
provided the packagings meet the general provisions of §§ 173.24 and 173.24a.
Reportable quantity 2658.5 lbs / 1207 kg [354.28 gal / 1341.1 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3), 2.40-2.42 (Class 8), 2.7 (Marine pollutant
mark).
The marine pollutant mark is not required when transported by road or rail.
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules F-E S-C
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments
DOT Reportable Xylene, 354 gal of this product.
Quantity

Marine pollutant Light aromatic naphtha

1,2,4-Trimethylbenzene

North-America NAERG : 132

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Section 15. Regulatory information

U.S. Federal regulations : TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are active or exempted.
Clean Water Act (CWA) 307: ethylbenzene; naphthalene
Clean Water Act (CWA) 311: xylene; ethylbenzene; naphthalene; hydrogen sulphide
United States - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :
List name Status Ingredient name Name on list Conc.
United States - Clean Air Act Section Listed Xylene Xylenes 1-5
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Methanol Methanol 1-5
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Cumene Cumene 0.1 - 1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Ethylbenzene Ethyl benzene 0.1 - 1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Naphthalene Naphthalene 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed 1,4-Dioxane 1,4-Dioxane; 1,4-Diethyleneoxide 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)

SARA 302/304
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
Hydrogen sulfide 0 - 0.1 Yes. 500 - 100 -
SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SARA 313
Product name CAS number %

Supplier notification 1,2,4-Trimethylbenzene 95-63-6 20 - 30

Xylene 1330-20-7 1-5
Methanol 67-56-1 1-5
Cumene 98-82-8 0.1 - 1
Ethylbenzene 100-41-4 0.1 - 1
California Prop. 65
WARNING: This product can expose you to chemicals including cumene, ethylbenzene, naphthalene and
1,4-Dioxane, which are known to the State of California to cause cancer, and methanol, which is known to the State
of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.
gov.
Canada
Canada (CEPA DSL): : All components are listed or exempted.

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Section 16. Other information

National Fire Protection Association (U.S.A.)

2 Flammability BPC
Health 3 0 Instability
Special

History
Date of printing : 1/12/2023
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

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