Aviva Ammonia Refrigerations Systems Lps
Aviva Ammonia Refrigerations Systems Lps
Ammonia
Refrigeration
Systems
Version: 1.0
Date: 1st February 2023
Aviva: Public
Ammonia Refrigeration Systems
Introduction
Ammonia (a compound of nitrogen and hydrogen - NH3) has
been
used in the food processing industry and for the storage of
perishable products, because of its thermal properties; efficiency;
low cost and ongoing operational costs; its impact on global
warming and ozone depletion; and its tolerance to
contamination.
Refrigerants are basically chemical compounds that work by
taking heat from one enclosed area and transferring it to another,
via its physical state and its thermodynamic properties.
A refrigeration system has two phases:
• A primary phase where the cold is generated
• A secondary phase where the cooling takes place
A basic refrigeration cycle involves an enclosed pumped/piped system with a controlling device. This could be a
thermal expansion valve or capillary tube, that controls the flow of the refrigerant in liquid state into the evaporator (or
cooling coil) as a low pressure, low temperature coolant. As the liquid refrigerant passes through the evaporator it
expands and evaporates into a gas/vapour, removing heat from the area where the evaporator is situated. The
-33OC for ammonia) at low temperature/pressure and
evaporate into a vapour/gas, which is drawn into a compressor pump.
The gas is compressed into a high pressure (normally around 10 bars), high temperature gas and pumped into a
condenser where the heat is removed by pipes passing through low temperature air/water-cooled units. As the heat is
removed, the gas condenses back into a high temperature/high pressure liquid (at 25 oC). The liquid is pumped into the
controlling device through a small orifice where both the pressure and temperature of the liquid falls, which then flows
into the evaporator where the cycle is repeated.
An expansion tank or receiver is sometimes installed between the condenser and the controlled metering device to
store the refrigerant until it is needed to remove heat in the evaporator.
Unused heat from the refrigeration process can then be drawn-off to heat exchangers normally installed between the
compressor and the condenser, that can be used to heat water or to heat other areas of the building.
Ammonia used in refrigeration systems must be pure anhydrous ammonia (i.e. free of water) and free from other
contaminants/substances to prevent pipe blockages.
There are two types of ammonia refrigeration systems: commonly referred to as either a Direct or Indirect system. See
example diagrams below:
Direct Systems, also referred to as Direct Expansion Systems, cool the air
directly - the evaporators are in the area being cooled, regardless of any
secondary coolant system provided.
These systems have two or more different coolants and there is no direct contact between air and the liquid being
cooled. In addition to the direct system that has the primary refrigerant (Ammonia), a control device, evaporator(s),
compressors/circulation pumps and condensers, the indirect system also has secondary refrigerants, secondary
evaporators, secondary circuit circulation pumps and piping.
One advantage to this type of system is that the coolant liquid is less likely to be mixed with any other contaminants
that may enter the system. The amount of ammonia is reduced and therefore the ammonia circuit is shorter and less
exposed to leakage. Installation costs are slightly higher than a direct refrigeration system and maintenance costs are
higher because of the additional equipment/plant.
Toxicity
Ammonia is highly toxic, requiring safe filling/handling controls and high standards of servicing and maintenance by
trained engineers.
Construction
Rooms housing ammonia equipment should be ideally detached from other main structures. If this is not possible, they
should be constructed of fire resistive or non-combustible materials with at least 1-hour fire resistant vapour tight blank
walls and floors at the interface where the room adjoins another building. Appropriate signage and labelling
(information and safety) should be displayed externally and internally.
Any pipework, cable penetrations, etc. through a communicating wall must be appropriately sealed and vapour tight, to
preserve the fire resistance. Pipework is usually constructed from steel or stainless steel and any pipe insulation should
be
non-combustible and non-absorbent.
Because of the potential for explosion, over-pressurisation or explosion relief should be provided. This should be
designed to an internationally recognised standard and discharge to a safe area, away from personnel route,
equipment, other buildings, etc.
External equipment (accumulators, receivers, condensers, etc.) mounted on or above the roof of the room should be
supported independently of the roof in case of roof collapse.
Access to the room should ideally be via external perimeter doors and should be restricted to authorised trained
personnel.
If internal doors are unavoidable these should be configured with a double door/air lock arrangement, using two sets of
vapour tight, sealed doors where one door is kept closed, whilst the other one is opened. Doors need to be fire resistant
to the same rating as the separating fire walls.
Ceiling and floor voids should be avoided.
Ventilation
Detection Systems
Detection systems in their entirety must be safe for use in potentially flammable and explosive environments. Refer to
Electrical Systems earlier in this document.
Ammonia Leak Detection
Two stage ammonia leak detection should be installed in all areas where substantial leaks could occur to provide a
phased warning with automatic interlocks:
• 25% Lower Explosion Limit (LEL) alarm and interlocked to actuate emergency ventilation system
• 50% LEL alarm and interlocked to the safe shut down of the ammonia equipment
All alarms should signal locally to a permanently occupied security room and/or engineers control room, and to a third
party
off-site monitoring and receiving centre.
Ammonia detectors should be calibrated and tested regularly, and interlocks tested at least annually.
Automatic Fire Detection
Automatic fire detection for property protection coverage (in all areas), including any ceiling and floor voids, must be
installed and interfaced with the building s main fire alarm system with local and remote alarm signalling to an off-site
insurance recognised Alarm Receiving Centre.
The ammonia equipment should be interlocked to shut down upon activation of the fire alarm.
water discharged over the area will knock ammonia out of the air. This should be actuated:
• By the 50% LEL ammonia detection system
• Manually at a safe distance from the ammonia room
Protection systems in their entirety must be safe for use in potentially flammable and explosive environments. Refer to
Electrical Systems earlier in this document.
Note: As previously indicated (see Hazards and Properties of Ammonia), Ammonia absorbed in water forms an alkaline
solution.
Housekeeping
Rooms housing ammonia equipment and any associated control rooms
combustible materials, storage, oils, etc.
Ammonia cylinder storage:
• Stores should be well separated from equipment rooms and provided with good high and low ventilation
• Oxygen or chlorine cylinders should not be housed in the same store as ammonia cylinders
o Reactive or dissimilar materials should not be stored together
• Cylinders must be secured in the appropriate position with valves uppermost
• Valve caps must be securely fitted to cylinders not in use
• Empty and full cylinders can be kept in the same storage area but must be kept spatially separate and suitably
Training
All personnel should be provided with appropriate training on the hazards of ammonia (including the signs, symptoms
and detection of an ammonia release) and emergency response procedures, including where appropriate individuals
identified and trained in the correct/safe use of breathing apparatus (if provided) and first aid. Additionally, key
individuals should receive comprehensive training on the safe operation and maintenance of the system.
Access to ammonia areas should be restricted to authorised and trained personnel.
Maintenance
Ammonia refrigeration systems should be constantly monitored 24 hours per day by a Building Management System
• Large ammonia refrigeration systems should be constantly monitored 24 hours per day remotely, off-site by a
refrigeration company. This could be mimicked to the site, e.g. on-site engineers by smart phone technologies
or SMS
Maintenance regimes for the ammonia network, refrigeration equipment and all the prevention/mitigation measures
annually and updated where necessary to ensure that the regimes in place are still effective, this is particularly
important as the system ages.
All interlocks and safety features should be confirmed at least annually.
Loss History
There have been several losses involving ammonia resulting in explosions and fire, and many more releases where there
has been injury or loss of life.
Mechanical failure is the most common cause of losses, particularly compressors. This is followed by electrical failures,
often due to short circuits, failures of compressor motors, temperature sensors, control devices and electrical arching.
➢ April 2017 - Ammonia plant in Telemark, Norway: caused by a compressor fault and oil leak inside the factory
that led to an explosion and fire. There was no ammonia escape, and no one was seriously injured. It is thought
that power was lost to the industrial area at around 3am due to a power station fault and the fire was reported
to be extinguished at around 5am.
➢ 17th April 2013 - Fertiliser plant in Texas: an explosion occurred that destroyed the entire plant and the
surrounding four blocks, killing many people. The explosion was felt up to 50 miles from the site. The plant
produced and stored a volatile and potentially dangerous form of nitrogen-based fertilizer known as
anhydrous ammonia. Cause is not known.
➢ 17th September 1984 - Frozen meat, cold storage facility in Louisiana, USA: with ammonia refrigeration
had an ammonia leak that site engineers initially tried to repair but were forced to exit the area
because of the effects of the escaping ammonia. Fire fight ers were called and entered the area of the
building (approx. 4000m² in size) to complete the emergency repair. Unfortunately, an explosion
occurred lifting part of the roof from the building and damaging the interior solid walls. The fire that
followed the explosion trapped two fire fighters who were badly burned/injured, and one later died of
their injuries. Fire investigators reported that the major contributing factors to the loss included
workers lack of proper precautions to prevent an accumulation of anhydrous ammonia, the fire fighters
lack of awareness that a hazardous amount of ammonia gas had accumulated in the room and the ignition
of the gas during the emergency repairs.
References
Safe Management of Ammonia Refrigeration Systems Guidance for the food and drinks industries and
British Engineering Services, Institute of Refrigeration and other stakeholders, with support from the Health and
Safety Executive
FM Global Property Loss Prevention Data Sheets: 7-13 Mechanical Refrigeration
XL Catlin GAP.7.2.1.2 Ammonia Hazards
https://www.ammoniaknowhow.com/review-of-global-regulations-for-anhydrous-ammonia-production-
use-and-storage/
ATEX 94/9/EC - Equipment Directive Equipment and protective systems intended for use in potentially
explosive atmospheres
ATEX 99/92/EC - Workplace Directive Minimum requirements for improving the safety and health
protection of workers potentially at risk from explosive atmospheres
BS EN 378-1 - Refrigerating systems and heat pumps - Safety and environmental requirements. Part 1-
Basic requirements, definitions, classification and selection criteria
BS EN 60079-17 - Explosive atmospheres. Part 17 - Electrical installations inspection and maintenance
Further risk management information can be obtained from Aviva Risk Management Solutions
Please Note
This document contains general information and guidance and is not and should not be relied on as specific advice.
The document may not cover every risk, exposure or hazard that may arise and Aviva recommend that you obtain
specific advice relevant to the circumstances. AVIVA accepts no responsibility or liability towards any person who
may rely upon this document.
Location
Date
Completed by (name and
signature)
6.
Does the ammonia plant room have appropriate signage and
labelling - information and safety should be displayed
externally and internally?
7. Are there any penetrations from the room into other
buildings?
• Is appropriate fire stopping provided?
• Are there any larger openings?
o Are these appropriately protected against an
ammonia leak?
8. Does the room have explosion relief?
If yes, is the:
• Relieving area away from buildings, equipment and
personnel exposures?
• Design standard known?
• Design area known?
• Relief inspected, tested and maintained?
9. Are all electrical systems and devices appropriately rated for
safe use in the expected atmosphere?
Are electrical systems/devices risk assessed?
10. Does the room have low-level air intakes and high-level air
extraction?
•
o Is this a minimum of 0.305m3/m2/min?
• Is emergency ventilation at a higher rate also
provided?
• Is the emergency extraction rate known?
o Is this a minimum of 3.05m3/m2/min?
11. Is the ventilation system monitored?
• Are there failure alarms?
• Is low flow or low volume monitored?
12. Does the room have automatic ammonia leak detection?
• Is more than one detection device provided?
• Are the locations of these devices appropriate for
ammonia?
• Is this calibrated and tested regularly?
13. Is the 1st stage of the ammonia alarm set at 25% of the LEL?
• Is the ventilation rate interlocked to increase upon
this alarm?
Please Note
This document contains general information and guidance only and may be superseded and/or subject to amendment without
further notice. Aviva has no liability to any third parties
Prevention Standards), and nor shall any third party rely on them. Other than liability which cannot be excluded by law, Aviva
shall not be liable to any person for any indirect, special, consequential or other losses or damages of whatsoever kind arising
,
exposure or hazard that may arise and Aviva recommend that you obtain specific advice relevant to the circumstances.