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Fundamentals of
Charged Particle
Transport in Gases and
Condensed Matter
Monograph Series in Physical Sciences
Recent books in the series:
Exchange Bias: From Thin Film to Nanogranular and Bulk Systems
Surender Kumar Sharma
By
Robert E. Robson, Ronald D. White and
Malte Hildebrandt
Cover Image: Simulations of energy deposition of positrons in liquid water, often used in modeling as a
surrogate for human tissue. Points of higher (lower) energy deposition are indicated by blue (red) spheres,
while trajectories of positrons between collisions, represented by black lines, are biased towards the direc-
tion of an applied electric field. Eventually the positrons slow down sufficiently to annihilate with the elec-
trons of the medium, producing two back-to-back gamma rays, as in PET (positron emission tomography)
investigations. (Courtesy of Wade Tattersall)
CRC Press
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1 Introduction ............................................................................... 1
1.1 Boltzmann’s Equation .................................................... 1
1.1.1 A little history .................................................... 1
1.1.2 From the “golden” era of gas discharges to
modern times..................................................... 1
1.1.3 Transport processes: Traditional and modern
descriptions ....................................................... 3
1.1.4 Theme of this book ............................................. 4
1.2 Solving Boltzmann’s Equation ........................................ 4
1.2.1 The path to solution............................................ 4
1.2.2 A complementary approach: Fluid modelling ....... 6
1.3 Experiment and Simulation ............................................ 6
1.3.1 An idealized apparatus ....................................... 6
1.4 About this Book ............................................................ 9
Additional General Reading Materials ..................................... 9
vii
viii Contents
References....................................................................................... 377
This monograph series brings together focused books for researchers and
professionals in the physical sciences. They are designed to offer expert
summaries of cutting edge topics at a level accessible to non-specialists.
As such, authors are encouraged to include sufficient background infor-
mation and an overview of fundamental concepts, together with presen-
tation of state of the art theory, methods, and applications. Theory and
experiment are both covered. This approach makes these titles suitable
for some specialty courses at the graduate level as well. Subject matter
addressed by this series includes condensed matter physics, quantum sci-
ences, atomic, molecular, and plasma physics, energy science, nanoscience,
spectroscopy, mathematical physics, geophysics, environmental physics,
and other areas.
Proposals for new volumes in the series may be directed to Lu Han,
senior publishing editor at CRC Press/Taylor & Francis Group (lu.han@
taylorandfrancis.com).
xvii
Preface
The foundations of modern transport theory were laid 150 years ago in
a seminal paper presented to the Royal Society of London by J. Clerk
Maxwell. He formulated the equations of change for the physical prop-
erties of a gas, represented as moments or averages over a velocity distri-
bution function and paid particular attention to the influence of collisions.
Six years later, Ludwig Boltzmann, undoubtedly influenced by Maxwell’s
results, presented a kinetic equation to the German Physical Society in
Berlin, whose solution furnished the required distribution function. In
spite of early criticism and subsequent intense scrutiny, Boltzmann’s equa-
tion has withstood the test of time and has gone on to become a main-
stay in the field of non-equilibrium statistical mechanics, in general, and
charged particle transport, in particular, the subject of this book. The key
to the success and longevity of Boltzmann’s equation is not only its ability
to furnish accurate theoretical values of experimentally measured quan-
tities, but also its remarkable flexibility and adaptability to systems and
physics that Boltzmann could not possibly have foreseen. Thus, there are
generalizations of the kinetic equation to condensed matter, as discussed
in this book, and to quantum and relativistic systems, discussed elsewhere.
In addition, there are many adaptations and applications of Boltzmann’s
equation to traditional and contemporary areas of basic physics research
and technology. To take just one example of cutting edge science: laser
acceleration of particles to very high energies over distances several orders
of magnitude smaller than conventional accelerators has been modelled
through methods which are similar, at least in principle, to the ideas of
Boltzmann and Maxwell. It would take several volumes to do justice to
all of the fields on which the Boltzmann equation has had an impact and
any single exposition, like the present, is necessarily circumscribed. Nev-
ertheless, the scope of this book is broad and, moreover, the treatment is
unique in that we provide a unified approach to the transport theory of
particles of various types (electrons, ions, atoms, positrons, and muons) in
various media (gases, soft-condensed matter, and amorphous materials).
The applications are many and diverse, ranging from traditional drift tube
experiments, positron emission tomography, and muon-catalyzed fusion,
through to recent developments in materials physics.
One of the problems in writing a book such as this has been to over-
come the perception that transport theory, beyond the simplistic mean free
path arguments of some undergraduate books and courses, is somehow
xix
xx Preface
xxi
xxii About the Authors
Symbol Meaning
xxiii
xxiv Glossary of Symbols and Acronyms
Symbol Meaning
BGK Bhatnagar–Gross–Krook
μCF muon-catalyzed fusion
PET positron emission tomography
MTT momentum transfer theory
GER generalized Einstein relation
CHAPTER 1
Introduction
1
2 Fundamentals of Charged Particle Transport in Gases and Condensed Matter
Figure 1.1 The equation S = k log W linking entropy S with the number of
microstates W of a system appears on Boltzmann’s memorial headstone in Vienna.
That Cross gives the Infinite a colour which it did not have before.
So, even from the point of view of the most hardened and thorough-
going psychologist, Paul’s statement that “through one act of
righteousness, the free gift came unto all men” is literally accurate.
It is true—and that not in any conjuring-trick sense, but in a sense
which fulfils on highest levels life’s basic laws—that “by the grace of
one man” “the gift has abounded to the many,” entincturing and
altering the whole universe, and hence the whole experience, of
every receptive soul; atoning for the faulty attitude, the imperfect
love, of average man.
But still this is not all. There are other laws of life gathered up in,
and redistributed from, this great lens. Essentially the idea which the
Christ of the Gospels seems to have had of His own death is the idea
of a making good of some general falling-short on life’s part: a
“filling-up of the cup” of sacrifice and surrender, to balance the other
overflowing cup of error and sin. It is not only man’s unaccomplished
aim, but God’s unaccomplished aim in life, which He is represented
as fulfilling; and the fact that this conception owes a good deal to
Old Testament prophecy need not invalidate its mystical truth. If we
accept this idea, then, as well as showing individual man the way to
perfect union with God—“building the bridge and reforming the road
which leads to the Father’s heart,” as St. Catherine of Siena has it—
Christ in His willing death is somehow performing the very object of
life, in the name of the whole race. The true business of an atoner is
a constructive one. He is called upon to heal a disharmony; bridge a
gap between two things which, though separate, desire to be one.
Even the sacrificed animal of primitive religions seems most often to
be a reconciling victim, the medium of union between the
worshipper and his deity. In religions of a mystical type, then, the
Atoner or Redeemer will surely be one who makes patent those
latent possibilities of man which are at once the earnests of his
future blessedness and the causes of his present unrest. He will
achieve the completion and sublimation of our vague instinct for
sacrifice and love, and thus bridge the space between that which is
most divine in humanity and that which is most human in divinity;
filling up the measure of that “glory,” that real and divine life, of
which we all fall short, yet without which we can never be content.
Is not this again what St. Paul feels that Christ did? What he seems,
at bottom, to see in the Passion—though the imagery by which he
tries to communicate it often sounds harsh in our ears—is, the
mysterious fulfilment of all cosmic meanings; the perfect surrender
to infinite ideals of Man, the compound inhabitant of two possible
orders of reality, who by this painful self-loss achieves perfect
identification with the Divine will. This fulfilment was, as he distinctly
says, the duty and destiny of the human soul. All creation looks for it
“with outstretched neck.” But all have fallen short. Christ, the perfect
man, does it, does what man was always meant to do; and because
of the corporate character of humanity, in His utter transcendence of
self-hood and of all finite categories He inevitably lifts up, to share
His union with God, all who are in union with Him. The essence of
the Atonement, then, would not lie so much in the sacrificial act as
in the lift-up of the human spirit which that act guarantees; the new
levels of life which it opens for the race. “Much more, being
reconciled, shall we be saved in his life,” says Paul.
“In his life” a new summit has been conquered by humanity. But are
we to stop there? Is not the attainment of that same summit, the
achievement of that life-giving surrender to the Universal Spirit—“a
life-giving life,” Ruysbroeck calls it—just what the great mystics,
following as well as they can the curve of the life of Christ, try to do
according to their measure? Theirs, after all, is the vision which sees
that “there is no other way to life but the way of the Cross,” and that
the human life of Christ is “the door by which all must come in.”
Thus the spiritual victory of the Cross is for them not so much a
unique, as a pioneer act. It is the first heroic cutting of a road on
which they are to travel as far as they can; not merely the vicarious
setting-right of the balance between God and man, upset by man’s
wilful sin. In their ascent towards union with God, are not they road-
makers, or at any rate road-menders, too? Are they not forging new
links between two orders of reality, which are separate for the once-
born consciousness? If so, then we may regard each one of them as
a bit of the slowly achieved atonement of the race; that gradual
pressing-on of humanity into the heart of the Transcendent Order.
For Christians, this movement was initiated by Christ. But surely it is
continued and helped by every soul in union with Him, even those
who knew not His Name; and Julian of Norwich was right when she
said that she knew she was “in the Cross with Him.”
Two things are perpetually emphasized in modern presentations of
religion. First, the stress tends more and more to be upon
experience. Nothing which authority tells us is done for us truly
counts, unless we feel and realize it as done in us. In so far as this is
so, the tendency is to a mystical concept of religion; and, speaking
generally, to just the concept of religion which is supposed to conflict
with the idea of atonement as usually understood. But, secondly, the
social and corporate character of Christianity is strongly emphasized;
and, where this corporate character is admired more than it is
understood, mysticism is harshly criticized as the religion of the
spiritual individualist, a “vertical relation,” the “flight of the alone to
the Alone.” St. Paul’s “completing opposites,” in fact, are still in the
foreground of our religious life; and so perhaps some re-statement
of the solution by which he found room for both of them, and hence
both for personal responsibility and atonement, may be possible and
fruitful for us, too.
And first we notice that those enthusiasts for the corporate idea who
condemn the mystics as religious egoists seem to forget that they
are contradicting themselves; that if their vision of the Church of
Christ as a mystical body be true, then the mystic’s ascent to God
cannot be a flight of the Alone. The poisonous implication of that
phrase—true in its context but always misunderstood—has stuck like
mud to the white robes of the saints. But the mystic is not merely a
self going out on a solitary quest of Reality. He can, must, and does
go only as a member of the whole body, performing as it were the
function of a specialized organ. What he does, he does for all. He is,
in fact, an atoner pure and simple: something stretched out to
bridge a gap, something which makes good in a particular direction
the general falling-short. The special kind of light or life which he
receives, he receives for the race; and, conversely, the special
growth which he is able to achieve comes from the race. He depends
on it for his past; it depends on him for its future. All are part of life’s
great process of becoming; there are no breaks. Although there is
perfect individualization, there is interpenetration too. His attainment
is the attainment of the whole, pressing on behind him, supporting
him. Thus—to take an obvious example—the achievement of
peculiar sanctity by the member of a religious order is the
achievement of that order in him; and this not in a fantastic and
metaphorical sense. The support of the Rule, the conditions of the
life, the weight of tradition, the special characters which each
religious family inherits from its Patriarch, have all contributed
something to make the achievement possible; and are factors
governing the type which that achievement assumes. We recognize
the Cistercian stamp upon St. Bernard, the Dominican on Suso and
Tauler, the Carmelite on St. John of the Cross. Each such case
vindicates once more the incarnational principle; it is the true spirit
of the community, flowering in this representative of theirs, which
we see. Thus, as we may regard Christ from one point of view as
supremely ideal Man incarnate—the “heavenly man” as Paul calls
Him—summing up, fulfilling, lifting to new heights all that came
before, and therefore actualizing all that humanity was ever intended
to do, and changing for ever more the character of its future
achievements; so, in a small way, we may regard St. Teresa as
Carmel, the ideal Carmel, incarnate. Each is a concrete fact which
atones for the falling-short of a whole type, and yet is conditioned by
that type. The thought of what the Carmelite life was meant to do,
the pressure of that idea seeking manifestation, did condition
Teresa’s achievement. Are we not also bound to say that the thought
of the Jewish visions of an ideal humanity, of the Son of Man and
the Suffering Servant, did condition the external accidents of the life
and death of Christ?
So as to the past. Still more as to the future are the corporate and
individual aspects of spiritual life inextricably twined together. As that
done by one is an outbirth of the whole, so that done to one may
avail for the whole. Only by staying within the circle of this thought—
a thought which surely comes very close to the doctrine of
Atonement—can we form a sane and broad idea of what the mystic,
and the mystic’s experience, mean for the race. Consider again the
case of Teresa. As, even in a time and place of considerable
monastic corruption—for no one who has read her life and letters
can regard the Convent of the Incarnation as a forcing-house of the
spiritual life—still the idea of her order conditioned her great and
Godward-tending soul, and her dedicated life filled up the measure
of its glory; yet more has Teresa’s own, separate, unique
achievement conditioned the spirit of her order ever since. All the
saints which it has nourished have been salted with her salt. All that
she won has flowed out from her in life-giving streams to others.
She has been a regenerator of the religious life, has achieved the
ideal of Richard Rolle, and become a “pipe of life” through which the
living water can pass from God to man. Is not this, too, rather near
the idea of Atonement, a curiously close and faithful imitation of
Christ; especially when we consider the amount of unselfish
suffering which such a career entails?
The objective of the Christian life, we say, is union with God: that
paradoxical victory-in-surrender of love which translates us from
finite to infinite levels. Most of us in this present life and in our own
persons fall short of the glory of this. We are not all equally full of
grace; we do not all grow up to the full stature of the Sons of God;
and it is no use pretending that we do. But the mystical saint does
achieve this, and by this act of mediation—this “vicarious”
achievement, if you like to put it so—performed by a member of our
social organism, the gift does really “abound unto the many.” For
what other purpose, indeed, are these apparently elect souls bred
up? What other social value can we attribute to them than that
which we see them actually possessing in history—the value, that is,
of special instruments put forth by the race, to do or suffer
something which the average self cannot do, but which humanity as
a whole, in its Godward ascent, must, can, and shall do; ducts, too,
whereby fresh spiritual energy flows in to mankind; eyes, open to
visions beyond the span of average sight; parents of new life. Carlyle
said that a hero was “a man sent hither to make the divine mystery
more impressively known to us”—to atone, in fact, for the
inadequacy of our own perception of Reality, our perpetual relapses
to lower levels of life; to make a bridge between us and the
Transcendent Order. And when the hero as mystic does this, is he
not in a special sense a close imitator of Christ?
We seem to have here the highest example of a principle which is
operative through the whole of the seething complex of life, for
there is a sense on which every great personality fulfils the function
of an atoner. On the one hand he does something towards the
making good of humanity’s “falling short” in one direction or
another; on the other hand, he gives to his fellow-men—adds to
their universe—something which they did not possess before. Burke,
speaking of the social contract, has said that society is a partnership
in all science, all art, every virtue, and all perfection; and, since the
ends of such a partnership cannot be obtained but in many
generations, it is a partnership between the living, the dead, and the
unborn. “Each contract of each particular state,” he says, “is but a
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