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IR. Taules

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15 views2 pages

IR. Taules

Uploaded by

laguilarvi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Typical Infrared Absorption Frequencies

Stretching Vibrations Bending Vibrations


Functional
Range (cm-1) Intensity Assignment Range (cm-1) Intensity Assignment
Class
Alkanes 2850-3000 str CH3, CH2 & CH 1350-1470 med CH2 & CH3 deformation
2 or 3 bands 1370-1390 med CH3 deformation
720-725 wk CH2 rocking
Alkenes 3020-3100 med =C-H & =CH2 (usually sharp) 880-995 str =C-H & =CH2
1630-1680 var C=C (symmetry reduces intensity) 780-850 med (out-of-plane bending)
675-730 med cis-RCH=CHR
1900-2000 str C=C asymmetric stretch
Alkynes 3300 str C-H (usually sharp) 600-700 str C-H deformation
2100-2250 var C≡C (symmetry reduces intensity)
Arenes 3030 var C-H (may be several bands) 690-900 str-med C-H bending &
1600 & 1500 med-wk C=C (in ring) (2 bands) ring puckering
(3 if conjugated)
Alcohols & 3580-3650 var O-H (free), usually sharp 1330-1430 med O-H bending (in-plane)
Phenols 3200-3550 str O-H (H-bonded), usually broad 650-770 var-wk O-H bend (out-of-
970-1250 str C-O plane)
Amines 3400-3500 (dil. soln.) wk N-H (1°-amines), 2 bands 1550-1650 med-str NH2 scissoring (1°-
3300-3400 (dil. soln.) wk N-H (2°-amines) 660-900 var amines)
1000-1250 med C-N NH2 & N-H wagging
(shifts on H-bonding)
Aldehydes 2690-2840(2 bands) med C-H (aldehyde C-H)
& Ketones 1720-1740 str C=O (saturated aldehyde) 1350-1360 str α-CH3 bending
1710-1720 str C=O (saturated ketone) 1400-1450 str α-CH2 bending
1100 med C-C-C bending
1690 str aryl ketone
1675 str α, β-unsaturation
1745 str cyclopentanone
1780 str cyclobutanone
Carboxylic 2500-3300 (acids) overlap C-H str O-H (very broad) 1395-1440 med C-O-H bending
Acids & 1705-1720 (acids) str C=O (H-bonded)
Derivatives 1210-1320 (acids) med-str O-C (sometimes 2-peaks)

1785-1815 ( acyl halides) str C=O


1750 & 1820 (anhydrides) str C=O (2-bands)
1040-1100 str O-C
1735-1750 (esters) str C=O
1000-1300 str O-C (2-bands) 1590-1650 med N-H (1°-amide) II band
1630-1695(amides) str C=O (amide I band) 1500-1560 med N-H (2°-amide) II band
Nitriles 2240-2260 med C≡N (sharp)

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