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I DAV POLICE PUBLIC SCHOOL
New Police Lines, Panipat
Pre Board Examination-2024-25
Class: XII Subject-Chemistry

Time: 3 Hours Maximum Marks:70

General Instructions:
Read the following instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(-e) SECTION D consists of 2 case-based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) All questions are compulsory.
SECTION A
Q.1 If limiting molar conductivity of ca 2• and cI-are 119.0 and 76.3 S cm moI- , then the value
2 1

of limiting molar conductivity of CaCl2 will be

a) 195.3 S cm 2 moI- 1 b) 271.6 S cm 2 moI-1
c) 43.3 S cm 2 moI-1 d) 314.3 S cm 2 moI-1

Q.2 By reacting with which of the following, primary amines can be separated from secondary
and tertiary amines?
a) chloroform alone b) methyl iodide
c) chloroform and alcoholic KOH d) zinc dust

Q.3 The name of reaction in which CO2 reacts with phenol, NaOH, acid to give
salicylic acid is-
a) Reimer Tiemann b)Kolbe's reaction c) Wurtz reaction d)Swartz reaction

Q.4 Name the chemical used to distinguish between Benzaldehyde and Benzyl alcohol
a) NaHCO3 b) Neutral FeC'3 c) Iodine ,KOH d)Tollen's Reagent

Q.5 Which of the following ions is Coloured in aqueous solution.

[atomic number of Cu-29, Sc-21, Ti- 22, Zn- 30]
a) cu 2 • b) sc3• c) Ti 4 + d) zn2 •

Q.6 Which among the following is most acidic

a) Phenol b) 4-Nitrophenol c) cresol d) 4- Methoxyphenol

1
Q.7 If rate constant of a reaction is 2 mo1- 11it1sec-1 the order of the reaction will be
a) zero b) first c) second d) three

Q.8 The increasing order of Basic Strength of

CsHsNH2 (I) , CsHsNHCH3 (II), CH3NH2 (Ill) and (CH3)3N (IV)
(a) ll<l<lll<IV (b) ll<l<IV<II
(c) l<ll<lll<IV (d) l<ll<lll<IV

Q.9 In a dry cell, which of the following is the electrolyte?

a) Potassium hydroxide b) Sulphuric acid

c) Ammonium chloride d) Manganese dioxide

Q.10 The IUPAC name of: [Pt(NH3}3(Br)(N02)Cl]CI is

a. Triamminechlorobromonitroplatinum(IV)chlor ide

b. Triamminebromonitrochloroplatinum(IV)chlor ide

c. Triamminebromochloronitroplatinum(IV)chloride
d. Triamminenitrochlorobromoplatinum (IV)chloride

Q.11 The oxidation number of cobalt in K[Co(CO)4 ]

a) +1. b)+3. c). -1 d). -3

Q.12 The units of conductivity are:

(a) ohm- 1 (b) ohm- 1cm- 1 (c) ohm-2cm 2equiv 1
(d) ohm- 1cm2

Q.13 The hybridization involved in complex [Ni(CN)4 ] 2- (Atom·,c n b f . ·

um er o Nt= 28) is
3
a). dsp2 b). Sp c). d2sp2 d). d2sp3

Q.14 Assertion (A): Gabriel phthalimide synthesis can be used to . _

Reason (R): Aromatic amines are always less basic than aliphaticp;~are aromatic amines.
Select the most appropriate answer from the options given below: mes.

a. Both A and R are true and R is the correct explanation of A

b. Both A and Rare true but R is not the correct explanation of A.
c. A is true but R is false.
d. A is false but R is true.
Q.15 Given below are two statements labeled as Assertion {A) and Reason (R)

Assertion (A): Proteins are found to have two different types of secondary structures viz alpha-
helix and beta-pleated sheet structure. ·

Reason (R): The secondary structure of proteins is stabilized by hydrogen bonding .

Select the most appropriate answer from the options given below:

a. Both A and R are true and R is the correct explanation of A

b. Both A and R are true but R is not the correct explanation of A.

c. A is true but R is false.

d. A is false but R is true.

Q.16 Assertion: 1 M solution of KCI has greater osmotic pressure than 1 M solution

of glucose at the same temperature .

Reason: In solution, KCI dissociates to produce more number of particles.

a. Both A and Rare true and R is the correct explanation of A

b. Both A and R are true but R is not the correct explanation of A.

c. A is true but R is false.

d. A is false but R is true.

SECTION B

Q.17.a. Nitrogen gas is soluble in water. At temperature 293 K, the value of KH is 76.48 kbar.
How would the solubility of nitrogen vary (increase, decrease or remain the same) at a
temperature above 293 K, if the value of KH rises to 88.8 kbar.

b. Chlo_roform (b.p. 61.2°C) and acetone (b.p. 56°C ) are mixed to form an azeotrope. The
mole fraction of acetone in this mixture is 0.339. Predict whether the boiling point of the
azeotrope formed will be (i) 60°C (ii)64.5°C (iii)54°C.

Defend your answer with reason .

2
Q.18.The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm
mo1- 1 Calculate the conductivity of this solution.
OR

Q.18.How much Faraday is required to produce 40gm Al from Al2O3?

3
order reaction has been found to be 2.54 x 1o- sec- Calculate
1
_
1
0 9 Rate constant k for a first
its 314th life. (log 4 = 0.6020)
g:
ation for each of the followin_
Q .20 Give plausible explan_
3
 -
a) cycloh exanon e forms cya noh
ydr in in go od _yie ld but 2,2 ,6- tri~
b) there are two -NH groups et~ ylc ycl oh~ xan one doe_s not
2 in sem ica rbaz1de. Ho we ver one
1s inv olv ed m the form ation of
semicarbazones.
OR
Q.20 Although phe noxide has
mo re num ber of res ona ting
carboxylic acid is stro nge r aci d stru ctu re tha n car boxylate ion
tha n phe nol . 'Nh y? ,

Q.21 Wr ite the for mu la of rea gen

ts used in the foll owing reactio
a. Bromination of Ph eno l to 2,4 ns:
,6-t ribr om oph en ol. b. Pro pen e to pro pa nol.
c . Phenol to pic ric aci d
d. Ch loroben zen e to phenol
SE CT ION C
Q.22 a) Wh at is the differe nce bet
we en a nuc leo sid e and nuc leo
tide ?
b) The two stra nds of DN A are
not ide ntic al but com ple me nta
ry. Exp lain
Q.23 Ne eta w as exp erim ent ing
in the lab to stu dy the che mic
car ried out a deh ydr atio n rea al reactivity of alcohols. She
ctio n of pro pan ol at 140°C to
obt ain ed at the se two tem per atu 170 °C. Dif fer ent products were
res .
a. Ide ntif y the ma jor pro duc t for
me d at 140°C and the sub stit
foll ow ed in this cas e. utio n me cha nis m (SN 1 or SN 2
)
b . Ide ntif y the ma jor pro duc t for
me d at 180°C and write the equ
atio n.

Q.2 4 3.9 g of ben zoi c acid dis

solved in 49 g of ben zen e sho
of 1.6 2 K. Calculate the Va n't ws a dep res sio n in freezing poi
Ho ff fac tor and pre dic t the nat nt
dis soc iate d). ure of sol ute (as soc iated or
(G ive n: Mo lar ma ss of benzoi
c aci d= 122 g mo1- 1 Kt for be nze
ne = 4.9 K kg mo l-1)
OR
Q.2 4 Wh en 2.5 6 g of sulphu r wa
s dis sol ved in 100 g of CS2, the
0.3 83 K. Ca lcu late the form ula freez ing poi nt lowered by
of sulphu r (Sx).(Kt for CS2 = 3.8
Su lph ur =3 2 g/m ol 3 K kg mo l-1, Atomic ma ss of

Q.25 a.W hat hap pen s wh en D -

Glu cos e is treated with the follow
ing reagent?
a) HI b) Bromine wa ter
c) HNO3
OR
Q.25 a) Wr ite 2 structural and 2
functional difference between DN
b) In DN A the re are 200 Th ym ine A & RNA . .
and 150 Gu anine, calculate the
tota l number of nucleotides
in a giv en sam ple as per Ch arg
aff s rule.
Q.26 G ive rea son s :
(a) Ch lorine is EW G but it is orth
o and para dire cting for ele ctroph1. . . . .
hc subst1tut1on reactio n.
(b) Ra cem ic mix ture is optica lly
ina
(c ) Th e c _ Cl bon d length in chloroctiv e .
benzene 1s sho rte
.
r tha n tha t m CH 3 - Cl
OR

4
Q.26 What happens when
(a) Chlorobenzene is treated with Cl2/FeC'3,
(b) Ethyl chloride is treated with AgN02,
(c) 2-bromopentane is treated with alcoholic KOH?

Q.27 V\Jhat happen when:

(a). (CH3}3C-OH is treated with Cu at 573 K. (b). Anisole is treated with CH 3 Cl/anhydrous
AIC'3.
(c). Phenol is treated with Zn dust
Write chemical reactions in support of your answer.

Q.28 Predict the products of the following reactions;

H20tH• NH1 -► C.
) B ---:.......
CuCN
(il C6H5N/Cl'~ >A A
Sn+ HCI NaN0 2+HCI U.,O/H+
(ii) C6HSN02 >A
273K
>B •A ➔ C
SECTION -D

Q.29 Case Based Questions

Dependence of the rate of reaction on the concentration of reactants, temperature, and

other factors is the most general method for weeding out unsuitable reaction
mechanisms. The term mechanism means all the individual collisional or elementary
processes involving molecules (atoms, radicals, and ions included) that take place
simultaneously or consecutively to produce the observed overall reaction. For example,
when hydrogen gas reacts with bromine, the rate of the reaction was found to be
proportional to the concentration of H.2 and to the square root of the concentration ~of
Br2 . Furthennore, the rat e w.as inhibited by ·increasing the concentration of HBr as the
reaction proceeded. These observations are not consistent with a mechanism involving
bimolecular collisions of a_ single molecule of each kind. The currently accepted
mechanism is considerably more complicated, involving the dissociation of bromine
molecules into atoms followed by reactions between atoms and molecules: It is clear
from this example that the mechanism cannot be predicted from the overall
stoichiometry.
a. Predict the expression for the rate of reaction and order for the following:
H2 + Br2~ 2 HBr

What are the units of rate constant for the above reaction?

b. How will the rate of reaction be affected if the concentration of Br2 is tripled?
OR

\jVhat change in the concentration of H2 will triple the rate of reaction?

5
 was experimentally found to be first order with respect
ction between A and B, •
c. Suppose area t· .5 . Rate = k[A](B] Which of these two mechanisms is
to both A and B. So the ~ate equa ,~n '?. ?
consistent with this expenmental finding . \Nhy.
Mechanism 1 A~ C + D {slow) 1

B + C ~ E {fast)

Mechanism 2 A+ B ~ C + D {slow)

C ~ E {fast)
Q.30.Complex compounds play an important role in our daily life. Werner's theory of
complex compounds says every metal atom or ion has primary valency (oxidation state)
which is satisfied by -vely charged ions, ionisable where secondary valency
(coordination number) is non-ionisable, satisfied by ligands (+ve, -ve, neutral) but
having lone pair. Primary valency is non-directional, secondary valency is directional.
Complex compounds are named according to the IUPAC system. Valence bond theory
helps in determining shapes of complexes Based on hybridisation, magnetic properties,
outer or inner orbital complex. Complex show ionization, linkage, solvate and
coordination isomerism also called structural isomerism. Some of them also show
stereoisomerism i.e. geometrical and optical isomerism. Ambidentate ligands are
essential to show linkage isomerism. Polydentate ligands form more stable complexes
than unidentate ligands. They are called chelating agents. EDTA is used to treat lead
poisoning, cis-platin as anticancer agents. Vitamin B12 is complex of cobalt.
Haemoglobin, oxygen carrier is complex of Fe 2• and chlorophyll essential for
photosynthesis is complex of Mg2+
a). Wlat is the oxidation state of Ni in [Ni(CO)4]?
2
b) Out Cis - [Pt(en)2 Cl2] + and trans [Pt(en)2Cl2] 2+ which one shows optical isomerism?

c) What is hybridisation of [CoFs]l-? [Co= 27] Give its shape and magnetic properties.
d) Write its d configuration as per Crystal field theory. ·

SECTION E
Q.31 (a) How will you bring about the following conversions:
(i) Ethanal to 3-hydroxybutanal
(ii) Benzaldehyde to Benzophenone
(iii) Propanone to Propane

(b) Arrange the following compounds in an increasing order of their indicated property:

(i) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid 4-Metho b · • .

strength) .. · xy enzo1c acid (acid

(ii) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH (CH 3)2 CHCOOH CH

strength) . ' , 3CH2CH2COOH (acid
 OR

Q.31 a) Out of formic acid and acetic acid, which one will give the HVZ reaction? Give a suitable
reason in support of your answer and write the chemical reaction involved .

b) An organic compound A which is a Grignard reagent is used to obtain 2-methylbutan-2-ol in

reaction with a carbonyl compound 'B'. Identify A' and 'B'. Write the equation for the reaction
between A and B.

Q.32 Assign reasons for the following:

a) The enthalpies of atomization of transition elements are high.

b) The transition metals and many of their compounds act as good catalysts.
c) There i~ a gradual decrease in the atomic sizes of transition elements in a series with
increasing atomic number.

d) The transition eiements have a great tendency for complex formation.

e) Transition metals generally form Coloured compounds.

OR

Q.32 a) Write preparation of KMn04 from its ore.

b) Write the bala~ced chemical equations for the reaction of acidified KMn04 with
1) Fe2•

Q.33 a)The following curve is obtained when molar conductivity, Am is plotted against the
square root of concentration, C 112 along y and x-axis respectively for the two electrolytes X and
Y.

CL(,<)

oa. e.'t
~ · 1 fr,;ot I Lf '

i) What can you say about the nature of these two electrolytes?

ii) How do you account for the increase in /\ m for the electrolytes X and y with dilution?
iii) How can you determine /\ 00 for these electrolytes?

7
 •• • Kc) and bG for the follow ing reaction:
0

b) .Determine the values of equthbnum constant (

Ni(s) + 2Ag+ (aq)-+ Ni 2+ (aq) + 2Ag (s),

E = 1.05 V (1 F = 96500 C mol-1)

0

OR

Q.33
____ 0
_.,,~}- -----,

XC1 Y C~

a. Represen t the cell shown in the figure.

b. Name the carriers of the current in the salt bridge

c. Write the reaction taking place at the anode.

b) From the following standard potentials , arrange the metals in the order of their increasing,
reducing power.

• Zn2+(aq) + 2e- ., --···· ► Zn(s): E 0

= -0.76 V
• Ca 2+(aq) + 2e- ,. .,..,,+ Ca(s): E 0
= -2 . 87 V
• Mg2 +(aq) + 2e- . -~ Mg(s): E 0
= -2.36 V
• Ni2+(aq)+2e- -·- -- ► Ni(s): E 0
= -0. 25 V
• Ni(s) ...,,,,,.,,. • 2
Ni •(aq) + 2e- : E0 = +0.25 V
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