ORGANIC CHEMISTRY

Daily Practice Problems

Target JEE 2018
Class : XIII Marks : 34 Date : 15-16/09/2017 Time : 45 Min. DPP. NO.-16
Q.1 Match the column : [4]
Column I Column II
CH3 CH3 CH3 H
C=C C=C
(A) Compound (I) have more heat (P) H H , H CH3
(I) (II)
of hydrogenation than compound (II)

CH3 CH3 H
C = CH2 C=C
(B) Compound (I) have less heat (Q) CH3 , H CH3
(I) (II)
of hydrogenation than compound (II)

(C) Compound (II) has greater melting point

CH3 CH3 CH3
C=C C = CH2
than (I) (R) H ,
H CH3
(I) (II)
(D) Compound (I) has greater boiling point
than (II)

Q.2 Column I Column II [4]

(A) and Et – C = CH2 (P) Ring - chain isomerism

Et
(B) CH3– C – NH2 & CH3– C = NH (Q) Chain isomerism
O OH
(C) CH3COOCH3 & CH 3 – CH – CHO (R) Tautomerism

OH
(D) C – C – C & C – C – C (S) Functional isomerism
CN CN
(T) Position isomerism
Q.3 How many hydrogens can be replaced by D in following deuterium exchange reaction? [3]

O
D / D 2O ( excess)
 
( long time )

O
(A) 4 (B) 2 (C) 3 (D) 5
 O

H
Q.4 Major tautomer (enol form) is [3]

OH OH OH OH

(A) (B) (C) (D)

Q.5 Which of following has correct order of % enol content ? [3]

O O
O O O O
(A) > (B) >
O O
O O O O

(C) > (D) >

Q.6 Tautomerism is not possible in [3]

O O
O O
Et
(A) (B) (C) (D)
Ph H
Q.7 Which statement(s) is/are true about the relation between the following compounds? [3]

(a) (b) (c)

(I) a and b are tautomers (II) b and c are resonating structures

(III) a and c are resonating structures (IV) a and c are tautomers
(A) I & III (B) II & IV (C) I, II & III (D) I & IV
Q.8 Among these organic acids which is the strongest ? [3]
(A) Benzoic acid (B) 2-chlorobenzoic acid
(C) 4-methylbenzoic acid (D) 2-hydroxybenzoic acid

Q.9 Which reaction should have Keq > 1 ? [3]


NH2 
NH3
NH2 NH
(A) +  +

(B) C H 3Li  CH 3  OH  CH 3OLi  CH 4

O O
|| ||
(C) CH 3  C  O Na 
+ CH 3  S  OH  H 3C  C  OH + 3
H C  S  ONa 
|| || || ||
O O O O
(D) HCl + CH 3  C  ONa  H 3C  C  OH + NaCl
|| ||
O O

Q.10 How many total number of structural isomers of C4H6Cl2 are possible having cyclic structures. [5]
 ORGANIC CHEMISTRY
Daily Practice Problems
Target JEE 2018
Class : XIII Marks : 33 Date : 18-19/09/2017 Time : 45 Min. DPP. NO.-17
Q.1 Column I Column II [4]

(A) (P) Position isomers

(B) (Q) Geometrical isomers

Me OH Me
C=N C=N
(C) OH (R) First is E and second is Z form

OH OH
(D) (S) Structural isomer
OH
OH
Q.2 Tautomer of which compound can show geometrical isomerism? [3]
O O
(A) (B) (C) (D) N=O
O
Q.3 Which of the following compound can not show geometrical isomerism? [3]
Me Me – CH2 F
(A) C = N – OH (B) C=C
Et Et Cl

(C) (D) H – N = N – H

Q.4 How many geometrical isomers are possible by [3]

H3C – CH = CH – CH = CH – CH = C = C = CH – CH3
(A) 32 (B) 4 (C) 8 (D) 6
Q.5 Among the following pair of compounds geometrical isomers are? [3]
O O
O–C–Me O–C–Me
(A) O & O
O–C–Me C–O–Me
Me Me H H

(B) &
H H Me Me
Me Me Me H
(C) C=C=C & C=C=C
H H H Me
(D) None of these
Q.6 Correct order for enolic content for a compound [3]
O
O
O OH OH
OH O O
(I) (II) (III)
(A) I > II > III (B) III > II > I (C) II > I > III (D) I > III > II

Q.7 Theoritically, valid Resonating structure of which of the following compound will not show geometrical
isomerism? [3]
OCH3
N
(A) CH3 – COOCH3 (B) C
CH3 CH3
(C) CH3–CONH2 (D)

Paragraph for question nos. 8 to 9

Following alkenes are possible for C5H10 molecular formula. [6]
(A) CH2= CH – CH2 – CH2 – CH3 (B) CH3– CH = CH – CH2 – CH3
CH 3 CH 3
| |
(C) H 2C  C  CH 2  CH 3 (D) H 2C  CH  CH  CH 3
CH 3
|
(E) CH 3  C  CH  CH 3
Answer the following questions based on alkenes.

Q.8 Which of these can show Geometrical isomerism.

(A) B (B) C (C) D (D) E

Q.9 Which of these will have highest heat of hydrogenation.

(A) A (B) B (C) C (D) D

Cl

Q.10 How many stereoisomers are possible for ? [5]

Cl Cl
Cl