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1.7 Sodium Hydroxide Solution (1M NaOH)

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product Name 1mol/L Sodium Hydroxide Solution

Product Code 192-02175,190-02171,196-02173
Manufacturer FUJIFILM Wako Pure Chemical
Corporation 1-2 Doshomachi 3-Chome
Chuo-ku, Osaka 540-8605,
Japan Phone: +81-6-6203-
3741
Fax: +81-6-6203-5964
Supplier FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-2029
Emergency telephone number +81-6-6203-3741 / +81-3-3270-8571
Recommended uses and For research use only
restrictions on use

Section 2: HAZARDS IDENTIFICATION

GHS classification
Classification of the substance or mixture
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Specific target organ toxicity (single exposure) Category 2
Category 2 respiratory system

Pictograms

Signal word Danger

Hazard statements
H315 - Causes skin irritation
H318 - Causes serious eye damage
H371 - May cause damage to the following organs: respiratory system

Precautionary statements-(Prevention)
•Wash face, hands and any exposed skin thoroughly after handling
•Wear protective gloves/protective clothing/eye protection/face protection
•Do not breathe dust/fume/gas/mist/vapors/spray
•Do not eat, drink or smoke when using this product
Precautionary statements-(Response)
•IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician
•IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
•Immediately call a POISON CENTER or doctor/physician
•IF ON SKIN: Wash with plenty of soap and water
•If skin irritation occurs: Get medical advice/attention
•Take off contaminated clothing and wash before reuse
Precautionary statements-(Storage)
•Store locked up
Precautionary statements-(Disposal)
•Dispose of contents/container to an approved waste disposal plant
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Others
Other hazards Not available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Single Substance or Mixture Mixture

Chemical Name Weight-% Molecular weight ENCS ISHL No. CAS RN

Wate 96 18.02 N/A N/A 7732-18-5
r
Sodium Hydroxide 4 40.00 (1)-410 * 1310-73-2
Note on ISHL No.: * in the table means announced chemical substances.

Impurities and/or Additives： Not applicable

Section 4: FIRST AID MEASURES

Inhalation
Remove to fresh air. If symptoms persist, call a physician.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediate medical attention is required.
Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control
center immediately. Do not induce vomiting without medical advice.
Protection of first-aiders
Use personal protective equipment as required.

Section 5: FIRE FIGHTING MEASURES

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment
Unsuitable extinguishing media
No information available
Specific hazards arising from the chemical product
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Special extinguishing method
No information available
Special protective actions for
fire-fighters
Use personal protective equipment as required. Firefighters should wear self-contained breathing apparatus
and full firefighting turnout gear.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other
than the people involved by, for example, using a rope. While working, wear appropriate protective
equipments to avoid adhering it on skin, or inhaling the gas. Work from windward, and retract the people
downwind.
Environmental precautions
To be careful not discharged to the environment without being properly handled waste water contaminated.
Methods and materials for contaminent and methods and materials for cleaning up
Absorb dry sand, earth, sawdust and the waste. Collect empty container that can be sealed.
Recoverly, neutralization
No information available
Secondary disaster prevention measures
Clean contaminated objects and areas thoroughly observing environmental regulations.
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Section 7: HANDLING AND STORAGE

Handling
Technical measures
Avoid contact with acidic substances Use with local exhaust ventilation.
Precautions
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging Prevent leakage,
overflow, and scattering. Not to generate steam and dust in vain. Seal the container after use. After
handling, wash hands and face, and then gargle In places other than those specified, should not be smoking
or eating and drinking Should not be brought contaminated protective equipment and gloves to rest stops
Deny unnecessary entry of non-emergency personnel to the handling area
Safety handling precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Storage
Safe storage conditions
Storage conditions Store away from sunlight in well-ventilated place at room temperature
(preferably cool).
Keep container tightly closed.
Safe packaging material Polyethylene
Incompatible substances Acids, Acidic substances

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls
In case of indoor workplace, seal the source or use a local exhaust system. Provide the safety shower
facility, and hand- and eye-wash facility. And display their position clearly.

Exposure limits
Chemical Name JSOH (Japan) ISHL (Japan) ACGIH
Sodium 2mg/m3 N/A Ceiling: 2
Hydroxide mg/m3
1310-73-2

Personal protective equipment

Respiratory protection Protective mask
Hand protection Protection gloves
Eye protection protective eyeglasses or chemical safety goggles
Skin and body protection Long-sleeved work clothes
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Form
Color colorless
Turbidity clear
Appearance liquid
Odor Odorless
Melting point/freezing point no data
available Boiling point, initial boiling point and boiling range no data
available Flammability no data
available
Evaporation rate: no data available
Flammability (solid, gas): no data available
Upper/lower flammability or
explosive limits
Upper： no data available
Lower： no data available
Flash point no data
available
Auto-ignition temperature: no data available
Decomposition temperature: no data available
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pH Strongly basic
Viscosity (coefficient of viscosity) no data available
Dynamic viscosity no data available
Solubilities water , Alcohols : miscible .
n-Octanol/water partition coefficient:(log Pow) no data available
Vapour pressure no data available
Specific Gravity / Relative density no data available
Vapour density no data available
Particle characteristics no data available

Section 10: STABILITY AND REACTIVITY

Stability

Reactivity no data available

Chemical stability Easy to absorb the carbon dioxide in the air.
Hazardous reactions
None under normal processing
Conditions to avoid
Extremes of temperature and direct sunlight
Incompatible materials
Acids, Acidic substances
Hazardous decomposition products
No information available

Section 11: TOXICOLOGICAL INFORMATION

Acute toxicity

Chemical Name Acute toxicity -oral- source Acute toxicity -dermal- source Acute toxicity -inhalation gas-
information information source information
Sodium Based on the NITE Based on the NITE Based on the NITE
Hydroxide GHS classification GHS classification GHS classification
results. results. results.

Chemical Name Acute toxicity -inhalation Acute toxicity -inhalation dust- Acute toxicity -inhalation mist-
vapor- source source information source information
information
Sodium Based on the NITE Based on the NITE Based on the NITE
Hydroxide GHS classification GHS classification GHS classification
results. results. results.

Skin irritation/corrosion
Chemical Name Skin corrosion/irritation source information
Sodium Based on the NITE GHS classification results.
Hydroxide

Serious eye damage/ irritation

Chemical Name Serious eye damage/irritation source information
Sodium Based on the NITE GHS classification results.
Hydroxide

Respiratory or skin sensitization

Chemical Name Respiratory or Skin sensitization source information
Sodium Based on the NITE GHS classification results.
Hydroxide

Reproductive cell mutagenicity

Chemical Name germ cell mutagencity source information
Sodium Based on the NITE GHS classification results.
Hydroxide
Carcinogenicity
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STOT-repeated exposure
Chemical Name STOT -repeated exposure- source information
Sodium Based on the NITE GHS classification results.
Hydroxide
Aspiration hazard
Chemical Name Aspiration Hazard source information
Sodium Based on the NITE GHS classification results.
Hydroxide

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Algae/aquatic plants Fish Crustacea

Sodium Hydroxide N/A N/A LC50 : Ceriodaphnia pulchella
40 mg/L 48 h

Other data
Chemical Name Short-term (acute) hazardous to Long-term (chronic) hazardous to
the aquatic environment source the aquatic environment source
information information
Sodium Based on the NITE GHS classification Based on the NITE GHS classification
Hydroxide results. results.

Persistence and degradability No information available

Bioaccumulative potential No information
available Mobility in soil No information
available Hazard to the ozone layer No information
available

Section 13: DISPOSAL CONSIDERATIONS

Waste from residues
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14: TRANSPORT INFORMATION

ADR/RID
UN number UN1824
Proper shipping name: Sodium hydroxide solution
UN classfication 8
Subsidiary hazard class
Packing group III
Marine pollutant Not applicable

IMDG
UN number UN1824
Proper shipping name: Sodium hydroxide solution
UN classfication 8
Subsidiary hazard class
Packing group III

Marine pollutant (Sea) Not applicable

Transport in bulk according to No information available
Annex II of MARPOL 73/78
and the IBC Code
IATA
UN number UN1824
Proper shipping name: Sodium hydroxide solution
UN classfication 8
Subsidiary hazard class
Packing group III
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Environmentally Hazardous Not applicable

Substance

Section 15: REGULATORY INFORMATION

International Inventories
EINECS/ELINCS
-
TSCA -

Japanese regulations
Fire Service Act Not applicable
Poisonous and Deleterious Not applicable
Substances Control Law
Industrial Safety and Health Act Harmful Substances Whose Names Are to be Indicated on the Label (Law
Art.57, Para.1, Enforcement Order Art.18)
Notifiable Substances (Law Art.57-2, Enforcement Oder Art.18-2
Attached Table No.9)No.319
Regulations for the Corrosive Substances (Ordinance Art.3, Ministry of Transportation Ordinance
carriage and storage of Regarding Transport by Ship and Storage, Attached Table 1)
dangerous goods in ship
Civil Aeronautics Law Corrosive Substances (Ordinance Art.194, MITL Nortification for Air
Transportation of Explosives etc., Attached Table 1)
Marine Pollution Prevention Enforcement ordinance Appendix No. 1 Noxious liquid substance Category Y
Law
Pollutant Release and Transfer Not applicable
Register Law
(~2023.3.31)
Pollutant Release and Not applicable
Transfer Register Law
(2023/4/1~)
Water Pollution Control Act Specified substances(Law Art.2 Para.4, Enforcement Order Art.3-3)
Export Trade Control Order Not applicable

Chemical Name Poisonous and Industrial Safety and Health Pollutant Release and
Deleterious Act Substances Transfer Register
Substances Control (Law Art.57-2) Law (~2023.3.31)
Law (~2024.3.31)
Sodium - Applicable -
Hydroxide
1310-73-2 ( 4 )

Section 16: OTHER INFORMATION

Key literature references and NITE: National Institute of Technology and Evaluation (JAPAN)
sources for data etc. http://www.safe.nite.go.jp/japan/db.html
IATA dangerous Goods Regulations
RTECS:Registry of Toxic Effects of Chemical Substances
Japan Industrial Safety and Health Association GHS
Model SDS
Dictionary of Synthetic Oraganic Chemistry , SSOCJ, Koudansha
Scientific Co.Ltd. Chemical Dictionary, Kyouritsu Publishing Co., Ltd.
Etc.
Disclaimer
This SDS is according to JIS Z 7253: 2019. The information provided in this Safety Data Sheet is correct to the
best of our knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
GHS Classification is according to JIS Z7252(2019). *JIS: Japanese Industrial Standards

Information provided by FUJIFILM Wako Pure Chemical Corporation.

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