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chap-Solution Worksheet

Chem

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27 views

chap-Solution Worksheet

Chem

Uploaded by

Vinu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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CHAPTER -1 SOLUTIONS WORKSHEET

1.State Raoults law for solution containing non-volatile solute.What type of deviation from Raoults law is shown
by a solution of chloroform and acetone and why?

2.What type of deviation observed on mixing (a)ethanol & acetone (b)chloroform & acetone.

3.Why does NaCl solution freezes at a lower temperature than water?

4.State Hery’s law.Write its one application .What is the effect of temperature on solubity of gases in liquids?

5.A solution of glucose(molar mass=180g/mol)in water has a boling point of 100.200 C.Calculate the freezing point
of the same solution.Molal constants for water Kf and Kb are 1.86 K Kg mol-1 and 0.512 K Kg mol-1 respectively.

6.When 19.5g of F-CH2-COOH (molar mass=78g/mol)is dissolved in 500 g of water the depression in freezing point
is observed to be 10 C.Calculate the degree of dissociation of F-CH2-COOH.(Kf for water=1.86 K kg mol-1)

7.Calculate the boiling point of solution when 2g of Na2SO4(M=142g/mol)was dissolved in 50g of water,assuming
Na2SO4 undergoes complete ionisation.(Kb for water=0.52Kkg/mol).

8.30g of urea is dissolved in 846g of water.Calculate the vapour pressure of water for this solution if vapour
pressure of pure water at 298K is 23.8mmHg.

9.A 0.01m aqueous solution of AlCl3 freezes at -0.0680C.Calculate the percentage of dissociation.(Kf for
water=1.86Kkg/mol).

10.3.9g of benzoic acid dissolved in 49g of benzene shows a depression in freezing point of 1.62K.Calculate the
vant hoff factor and predict the nature of solute(associated or dissociated).(Molar mass of benzoic
acid=122g/mol,Kf for benzene=4.9K kg/mol

11.If benzoic acid(M=122g/mol)is associated into a dimer when dissolved in benzene and the osmotic pressure of
a solution of 6.1g of benzoic acid in 100ml benzene is 6.5atm at 270C,then what is the percentage association of
benzoic acid?(R=0.0821 LatmK-1 mol-1.

12.A solution containing 1.9g per 100ml of KCl(M=74.5g/mol)Calculate the degree of dissociation of KCl
solution.Assume that both the solution have same osmotic pressure.

13.At 300k,30g of glucose present per litre in its solution has an osmotic pressure`of 4.98 bar.If the osmotic
pressure of another glucose solution is 1.52 bar at the same temperature,calculate the concentration of the other
solution.

14.Give reasons:

(i)At high altitudes people suffer from a disease called anoxia.In this disease, they become weak and cannot think
properly.

(ii)RBC shrink when places in saline water but swell in distilled water.

(iii)vapour pressure of a solution containing glucose in water lower than that of water?

(iv)aquatic species are more comfortable in cold water than warm water.

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