SAMANVAY TUTORIALS

Worksheet Name: Solution Mcq 1 Standard: 12th Science Subject: Chemistry

Q1. Which of the following have least vapour pressure?

A 0.1M NaCl sol B 0.1M urea sol
C 0.1M AlCl3​sol D 0.1M KCl sol
Q2. The pressure at which liquid and vapour can coexist at equilibrium is called the :
A Limiting vapour pressure B Real vapour pressure
C Normal vapour pressure D Saturated vapour pressure
Q3. Henry’s law constant for molality of methane is benzene at 298K is 4.27 × 105mm Hg. The mole fraction of methane is
nenzene at 298K under 760mm Hg is:
A 1.78 × 10-3 B 17.43 C 0.114 D 2.814
Q4. For a binary ideal liquid solution, the variation in total vapour pressure versus composition of solution is given by which of
the curves?
A B C D

Q5. For an ideal liquid solution, which of the following is unity?

A Activity coefficient B Fugacity coefficient C Fugacity D Activity
Q6. Which of the following would have the lowest vapor pressure in the pure state?
A Sodium hydroxide because of the strong B Methanol because of the hydrogen bonding in the
interparticle forces of ionic solids functional group along with the non-polar nature of
the carbon hydrogen bonds
C Water because of the very strong hydrogen bonding D Ammonia because of the unbonded pair of electrons
in the substances on the central atom coupled with hydrogen bonding
in the substance.
Q7. At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is __________.
A Less than the rate of crystallisation. B Greater than the rate of crystallisation.
C Equal to the rate of crystallisation. D Zero.
Q8. When heating of a miscible solution begins, vapours formed will be:
A Of liquid lower in boiling point B Of liquid higher in boiling point
C Of both liquids with a higher concentration of liquid D None of the above
having low boiling point
Q9. The mass of a non - volatile non - electrolyte solute (molar mass = 50g mol−1) needed to be dissolved in 114g octane to
reduce its vapour pressure to 75% is:
A 37.5g B 75g C 150g D 50g
Q10.The law which indicates the relation’-hip between solubility of a gas in liquid and pressure rs:
A Raoult’s law B Henry’s law
C Lowering of vapour pressure D Van’t Hoff law
Q11.Which of the following plot does not represent the behaviour of an ideal binary liquid solution of A and B?
A Plot of pA​vs xA​is linear B Plot of pB​ vs xB​is linear
C Plot of ptotal​ vs xA​is linear D Plot of ptotal​ vs xB​ is parabola
Q12.To an aqueous solution of NaI, increasing amounts of solid HgI2​ is added, the vapour pressure of the solution:
A Decreases to a constant value. B Increases to a constant value.
C Increases first and then decreases. D Remains constant because HgI2​is sparingly soluble
in water.
Q13.Partial pressure of a solution component is directly proportional to its mole fraction. This is known as:
A Henry’s law B Raoult’s law C Distribution law D Ostawald’s dilution
law
Q14.A mixture of benzene and toluene forms:
A An ideal solution B Non-ideal solution C Suspension D Emulsion
Q15.Which of the following conditions is not correct for ideal solution:
A No change in volume on mixing B No change in enthalpy on mixing
C It obeys Raoults law D Lonisation of solute should occurs to a small extent
Q16.The vapour pressures of two liquids A and B in their pure states are in the ratio of 1 : 2. A binary solution of A and B contains
A and B in the mole proportion of 1 : 2. The mole fraction of A in the vapour phase of the solution will be:
A 0.33 B 0.2 C 0.25 D 0.52
Q17.Equipment needed for measuring the vapour pressure of a liquid:
A Buret B Calorimeter C Manometer D Geiger counter
E Voltmeter
Q18.Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a
positive deviation from Raoult’s law?
A Methanol and B Chloroform and C Nitric acid and water. D Phenol and aniline.
acetone. acetone.
Q19.An ideal binary solution is prepared by two liquids A and B, with P ∘ > P ∘ . Then:
A B
A A - B interactions are stronger than A - A and B - B. B A and B have same molecular masses.
C A - B interactions are similar to A - A and B - B D Both A and B are non - polar substances.
interactions.
Q20.If two liquids A and B form minimum boiling azeotrope at some specific composition then ____________.
A A–B interactions are stronger than those between B vapour pressure of solution increases because more
A–A or B–B. number of molecules of liquids A and B can escape
from the solution.
C vapour pressure of solution decreases because less D A–B interactions are weaker than those between A–
number of molecules of only one of the liquids A or B–B.
escape from the solution.
Q21.At a certain temperature, the vapour pressure of water is 50mm. The relative lowering of vapour pressure of a solution
containing 36g of glucose in 900g of water is:
A 0.1 B 0.5 C 0.004 D 3.75
Q22.Identify which of the following statements is FALSE.
A The vapor pressure of a liquid decreases with B The value of an equilibrium constant is dependent
increasing atmospheric pressure. on temperature.
C The rate of a spontaneous reaction cannot be D During a phase transition, the temperature of a
determined solely by its Gibbs free energy. substance must be constant.
Q23.On the basis of information given below mark the correct option.
Information:
In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type
interactions.
In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.
In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.
A Solution (B) and (C) will follow Raoult’s law. B Solution (A) will follow Raoult’s law.
C Solution (B) will show negative deviation from D Solution (C) will show positive deviation from
Raoult’s law. Raoult’s law.
Q24.Which of the following binary mixtures will have same composition in liquid and vapour phase?
A Benzene-Toluene. B Water-Nitric acid. C Water-Ethanol. D n-Hexane -n-Heptane.
Q25.A closed vessel is maintained at a constant temperature. It is first evacuated and then vapour is injected into it continuously.
The pressure of the vapour in the vessel is:
A Increases continuously B First increases and then remains constant
C First increases and then decreases D None of the above
Q26.100 mL of liquid A and 25mL of liquid B are mixed to formal solution of volume 125mL. Then the solution is___________.
A ideal B non-ideal with positive deviation
C non-ideal with negative deviation D cannot be predicted
Q27.H2S is a toxic gas used in qualitative analysis. If solubility of H2S in water at STP is 0.195m. what is the value of KH?
A 0.0263 bar B 69.16 bar C 192 bar D 282 bar
Q28.When a solution is diluted at constant temperature, its vapour pressure:
A Increases B Decreases
C Remains same D May increase or decrease
Q29.The volume occupied by a single gas in a mixture at the same temperature and pressure is referred to as the single - gas
volume.
A Absolute volume B Partial volume
C Total volume of a gas mixture D None of the mentioned
Q30.At equilibrium the rate of dissociation of a solid solute in a volatile liquid solvent is:
A Less than the rate of crystallisation B Greater than the rate of crystallisation
C Equal to the rate of crystallisation D Zero
Q31.A liquid is kept in a closed vessel. If a glass plate (negligible mass) with a small hole is kept on top of the liquid surface, then
the vapour pressure of the liquid in the vessel is :
A More than what would be if the glass plate were B Same as what would be if the glass plate were
removed removed
C Less than what would be if the glass plate were D Cannot be predicted
removed
Q32.Which has the lowest boiling point at 1atm pressure?
A 0.1 M KCl B 0.1 M Urea C 0.1 M CaCl2 D 0.1 M A1Cl3
Q33.1 mole of liquid A and 9 moles of liquid B are mixed to form a solution. If \text{P}^\circ_\text{B}​=400_\text{mm} of Hg
and \text{P}^\circ_\text{B}​=200_\text{mm} of Hg at a temperature 'T' and normal boiling point of liquid B is 300K then
answer the questions that follow.
Given data: Kb ​= 2.7K kg mol−1, Molar mass of B = 100
If 'A' is perfectly non-volatile and it dimerises to an extent of 60% then what will be the vapour pressure of the solution.
A \text{360}\text{mm}\ \text{of}\ \text{Hg} B \frac{3600}{9.7}\text{mm}\ \text{of}\ \text{Hg}
C \frac{4000}{9.7}\text{mm}\ \text{of}\ \text{Hg} D 36\text{mm}\ \text{of}\ \text{Hg}
Q34.Which of the following units is useful in relating concentration of solution with its vapour pressure?
A Mole fraction. B Parts per million. C Mass percentage. D Molality.
Q35.The vapour pressure of water at 300K in a closed container is 0.4 atm. If the volume of the container is doubled, its vapour
pressure at 300K will be:
A 0.8 atm B 0.2 atm C 0.4 atm D 0.6 atm
Q36.The pressure that a single component in a gaseous mixture would exert if it existed alone in the same volume as the mixture
and at the same temperature as the mixture is referred to as.
A Absolute pressure B Partial pressure
C Total pressure of a gas mixture D None of the mentioned
Q37.Vapour pressure of a pure liquid X is 2atm at 300K. It is lowered to atm on dissolving 1 gof Y in 20g of liquid X. If molar mass
of X is 200, what is the molar mass of Y?
A 20 B 50 C 100 D 200
Q38. A 746cm3 B 697cm3 C 750cm3 D 300cm3
 A zinc metal sample containing zinc chloride as impurity was made to react with an excess of dilute hydrochloric acid at 27°C.
Liberated hydrogen gas is collected at 760mm Hg pressure that occupies 780.0cm3 volume. If the vapour pressure of water
at 27°C is 14mm Hg, what is the volume of H2​at STP? The Standard pressure is 760mm Hg (molar volume of gas at standard
temperature and pressure, STP = 22.4dm3)
Q39.A cylinder filled with a movable piston contains liquid water in equilibrium with water vapour at 25oC. Which one of the
following operations results in a decrease in the equilibrium vapour pressure?
A Moving piston downward a short distance B Removing a small amount of vapour
C Removing a small amount of the liquid water D Dissolving salt in the water
Q40.Which of the following solutions shows positive deviation from Raoult’s law?
A Acetone + Aniline B Acetone + Ethanol C Water + Nitric acid D Chloroform + Benzene
Q41.Value of Henry’s constant KH __________.
A Increases with increase in temperature. B Decreases with increase in temperature.
C Remains constant. D First increases then decreases.
Q42.Two containers, X and Y at 300K and 350K with water vapour pressures 22mm and 40mm respectively a are connected,
initially closed with a valve. If the valves opened.
A The final pressure in each container is 31mm. B The final pressure in each container is 40mm.
C Mass of H2​O(l) in X increases. D Mass of H2​O(l) in Y decreases roar.
Q43.Calculate the vapour pressure of aqueous 0.1m glucose solution at 300K temperature, the vapour pressure of water is
0.03bar at 300K temperature.
A 0.5bar B 0.29bar C 0.3bar D 0.03bar
Q44.Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene
molecules. For a mixture of benzene and toluene, which of the following are not true?
A \Delta_{\text{mix}}\text{H}=\text{zero} B \Delta_{\text{mix}}\text{V}=\text{zero}
C These will form minimum boiling azeotrope. D These will not form ideal solution.
Q45.The vapour pressure of a dilute solution of a solute is not influenced by:
A Temperature of solution B Melting point of solute
C Mole fraction of solute D Degree of dissociation of solute
Q46.The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows:
A No deviation from Raoult’s Law. B Positive deviation from Raoult’s Law.
C Negative deviation from Raoult’s Law. D That the solution is unsaturated.
Q47.Raoult's law is obeyed by each constituent of a binary liquid solution when:
A The forces of attractions between like molecules are B The forces of attractions between like molecules are
greater than those between unlike molecules. smaller than those between unlike molecules.
C The forces of attractions between like molecules are D The volume occupied by unlike molecules are
identical with those between unlike molecules. different.
Q48.A solution made up of numerous components in which each component’s property is the weighted sum of its separate
properties. The answer is:
A Ideal Solution B Non - Ideal solution C Real Solution D None of the
mentioned
Q49.If PCl5​is 80% dissociated at 250 then its vapour density at room temperature will be:
A 56.5 B 104.25 C 101.2 D 52.7
Q50.3 moles of P and 2 moles of Q are mixed, what will be their total vapour pressure in the solution if their partial vapour
pressures are 80 and 60 torr respectively?
A 80 torr B 140 torr C 72 torr D 70 torr
Q51.Which of the following solutions does not show positive deviation?
A Acetone and Ethanol B Toluene and Benzene C Water and Ethanol D Water and Methanol
Q52.18g glucose (C6​H12​O6​) is added to 178.2g of water. The vapour pressure of this aqueous solution at 1000C in torr is:
A 7.60 B 76.00 C 752.40 D 759.00
Q53.On the basis of information given below mark the correct option.
Information: On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.
A At specific composition methanol-acetone mixture B At specific composition methanol-acetone mixture
will form minimum boiling azeotrope and will show forms maximum boiling azeotrope and will show
positive deviation from Raoult’s law. positive deviation from Raoult’s law.
C At specific composition methanol-acetone mixture D At specific composition methanol-acetone mixture
will form minimum boiling azeotrope and will show will form maximum boiling azeotrope and will show
negative deviation from Raoult’s law. negative deviation from Raoult’s law.
Q54.The incorrect statement is:
A Vapour pressure of a liquid always increases by B Vapour pressure only depends on temperature and
increasing temperature. not on the nature of substance.
C Vapour pressure does not depend on the quantity of D Vapour pressure is not a colligative property & is
the liquid taken and the surface area of the liquid. independent of the concentration of the liquid.
Q55.The rate of vapourisation of water depends upon:
A Temperature B Surface area of container
C kinetic energy of liquid molecules D All of the above
Q56.Two beakers of capacity 500mL were taken. One of these beakers, labelled as “A”, was filled with 400mL water whereas the
beaker labelled “B” was filled with 400mL of 2M solution of NaCl. At the same temperature both the beakers were placed in
closed containers of same material and same capacity as shown in. At a given temperature, which of the following statement
is correct about the vapour pressure of pure water and that of NaCl solution.

A vapour pressure in container (A) is more than that in B vapour pressure in container (A) is less than that in
container (B). container (B).
C vapour pressure is equal in both the containers. D vapour pressure in container (B) is twice the vapour
pressure in container (A).
Q57.A solution of benzene and toluene is an example of ________ solution.
A Ideal B Non ideal C Azeotrope D None
Q58.Among the following substances the lowest vapour pressure is exerted by:
A Water B Alcohol C Ether D Mercury
Q59.The value of Henry’s constant KH is ___________.
A Greater for gases with higher solubility. B Greater for gases with lower solubility.
C Constant for all gases. D Not related to the solubility of gases.