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Thomas Schäpers
Semiconductor Spintronics
Also of Interest
Spintronics
Tomasz Blachowicz, Andrea Ehrmann, 2019
ISBN 978-3-11-049062-6, e-ISBN 978-3-11-049063-3

Electrons in Solids
Mesoscopics, Photonics, Quantum Computing, Correlations, Topology
Hendrik Bluhm, Thomas Brückel, Markus Morgenstern,
Gero von Plessen, Christoph Stampfer, 2019
ISBN 978-3-11-043831-4, e-ISBN 978-3-11-043832-1

Plasma and Plasmonics


Kushsal Shah, 2018
ISBN 978-3-11-056994-0, e-ISBN 978-3-11-057003-8

Optical Electronics
An Introduction
Jixiang Yan, 2019
ISBN 978-3-11-050049-3, e-ISBN 978-3-11-050060-8
Thomas Schäpers

Semiconductor
Spintronics

|
2nd edition
Physics and Astronomy Classification Scheme 2010
Primary: 85.75.-d, 85.35.-p, 73.63.-b, 73.43.-f, 75.20.-g; Secondary: 85.75.Hh, 85.35.Be, 85.35.Ds,
85.35.Gv, 73.63.Hs, 73.63.Kv, 73.63.Nm

Author
Thomas Schäpers
Forschungszentrum Jülich
Peter Grünberg Institut 9
52425 Jülich
Germany
[email protected]

ISBN 978-3-11-063887-5
e-ISBN (PDF) 978-3-11-063900-1
e-ISBN (EPUB) 978-3-11-063932-2

Library of Congress Control Number: 2021932015

Bibliographic information published by the Deutsche Nationalbibliothek


The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie;
detailed bibliographic data are available on the Internet at http://dnb.dnb.de.

© 2021 Walter de Gruyter GmbH, Berlin/Boston


Cover image: kindly provided by Sebastian Heedt
Typesetting: VTeX UAB, Lithuania
Printing and binding: CPI books GmbH, Leck

www.degruyter.com
|
To Gitta, Antonia, and Paul
Preface to the second edition
In recent years, it has become apparent that topological states in solid-state materials
are becoming increasingly important for spinelectronic applications. Already in the
first edition this was taken into account by discussing in detail the physical properties
of topological insulators. In the new issue, this part has now been extended to include
Landau quantization at high magnetic fields. The possibilities to include topological
properties go even further. Combining low-dimensional materials with strong spin-
orbit interaction with superconductors, so-called Majorana states can be generated
under certain circumstances. These states emerge in pairs that are usually widely sep-
arated from each other. The exchange of these Majorana states follows special rules
which differ from those of normal fermions or bosons. These are the so-called non-
abelian anyons. This special property makes Majorana states very interesting for a
new kind of quantum computing, the topological quantum computing. In order to
take this recent development into account, the second edition now contains a new
chapter which deals with the topic of Majorana states in detail.
Besides the electrical characterization of materials relevant for spin electronics,
optical investigations play an equally important role. In order to better take this into
account, the corresponding part has been significantly expanded in the new edition.
The physical principles of the Faraday effect and the various spin dephasing processes
are now explained in detail. In addition, resonant spin amplification is discussed,
which is exploited in particular for long spin dephasing times.
Especially concerning the extension of the latter part, I am indebted to Bernd
Beschoten, who provided me with appropriate material and was available for inten-
sive discussions around the optical experiments. Furthermore, I thank Hans Lüth as a
discussion partner around the topic of Majorana fermions. Last but not least, I would
like to thank Dr. Vivien Schubert of de Gruyter for her very competent coordination of
the second edition.

Jülich, March 2021 Thomas Schäpers

https://doi.org/10.1515/9783110639001-201
Preface to the first edition
In the past decades we observed a continuous increase of performance and complex-
ity of electronic circuits. This progress is quantified by Moore’s law [1], which pre-
dicts a doubling of the number of transistors in an integrated circuit every two years.
Although it is not a law in a strict sense, it proved to be valid over more than four
decades. The tremendous number of transistor in state-of-the-art integrated circuits
comes along with a corresponding shrinkage of device dimensions, which nowadays
have feature sizes in the order of a few tens of nanometers. It is foreseeable that this
development cannot continue forever. In the International Technology Roadmap for
Semiconductors [2] these future challenges are addressed and possible solutions are
proposed. In this context, spin electronic devices, i. e. devices which make use of the
electron spin, are mentioned as a possible alternative to solely charge-based devices.
The aim of this textbook is to introduce the various materials, mechanisms, and
concepts of spintronic devices. We restrict ourself to semiconductor-based structures
and leave out pure metal-based devices, which have an older history and are already
used in various applications. The development of semiconductor spintronic devices is
still in its infant stage. Different device concepts are proposed, but they have not yet
found their way into the production of integrated circuits. Since the development of
spintronics is still on a conceptual level, the emphasis of this textbook is on the un-
derlying physical phenomena. The book should put students and researchers into a
position to understand the basic concepts of spin electronic devices. For many of the
discussed effects a profound knowledge of low-dimensional semiconductor structures
is mandatory. Therefore, an introduction to these systems is provided which serves as
a basis for the different phenomena discussed in the subsequent chapters. In addition
to subjects which have in the meantime become well established, such as spin injec-
tion or spin manipulation, we also include recent developments. Especially for the
new field of topological insulators it cannot even be foreseen what impact these ma-
terials will have on future spinelectronic devices. In any case, these materials, which
distinguish themselves from other materials by their strict spin momentum locking,
bring a new twist into the research on spintronic devices. Last but not least, in recent
years a new computation paradigm has emerged which is based on quantum mechan-
ical states. In the field of quantum computation, two-level systems, so-called quantum
bits, are used as basic elements. Here, semiconductor spintronics is a very interesting
candidate for realizing these systems, since the electron with its two spin states is a
natural candidate for a quantum bit. Moreover, the mature semiconductor nanofabri-
cation technology helps to scale up these systems.
The current textbook is based on lecture notes of the spintronics course for mas-
ters students held at RWTH Aachen University. It was a great pleasure for me to give
these lectures together with Bernd Beschoten from RWTH Aachen. As one of the real
experts in optical methods, he especially contributed to my understanding of the var-

https://doi.org/10.1515/9783110639001-202
X | Preface to the first edition

ious optical phenomena in spintronics. I am very grateful for the many stimulating
discussions with colleagues and students in Jülich and Aachen. In particular, I en-
joyed the lively and inspiring discussions with Hans Lüth and Andreas Bringer about
various aspects on quantum and spin transport in nanostructures. During these dis-
cussions I was reminded as to why I studied physics in the first place, and how much
fun it is. Especially Andreas Bringer helped a great deal in figuring out the sometimes
intricate theoretical concepts around spin-orbit coupling. I acknowledge the support
and encouragement from colleagues in Jülich and Aachen: Gustav Bihlmayer, Stefan
Blügel, Hendrik Bluhm, Nataliya Demarina, David DiVincenzo, Detlev Grützmacher,
Gernot Güntherodt, Hilde Hardtdegen, Fabian Hassler, Mihail (Mike) Lepsa, Beata
Kardynal, Gregor Mussler, Claus Schneider, and Christoph Stampfer. During various
conferences, workshops, collaborations, and visits I enjoyed having discussions on
various hot topics in spintronics and quantum transport, namely with Carlos Egues,
Sigurður Erlingsson, Michele Governale, Ewelina Hankiewicz, Stefan Kettemann, Jia
Grace Lu, Andrei Manolescu, Junsaku Nitta, Angela Rizzi, Björn Trauzettel, Paul Wenk,
Roland Winkler, and Ulrich Zülicke. Many colleagues provided figures for this book:
Irene Aguilera, Yulieth Arango, Bernd Beschoten, Gustav Bihlmayer, Hartmut Buh-
mann, Hilde Hardtdegen, Sebastian Heedt, Takaaki Koga, Jia Grace Lu, Martina Luys-
berg, Gregor Mussler, Junsaku Nitta, Lukasz Plucinski, and Lieven Vandersypen. Their
experimental and theoretical results helped greatly to better illustrate the physical ef-
fects discussed in the book. The cover picture is based on a graphics by Sebastian
Heedt. I thank my students for critical reading of the manuscript and many useful
comments to improve and clarify explanations and derivation. I am also very grateful
for the very professional support and patience of Silke Hutt and Dr. Konrad Kieling
from De Gruyter. I was aware that transferring lecture notes to a textbook is quite an
effort, but, one is still surprised how much work it is in the end. Finally I thank my wife
Gitta, who accepted the extra time I needed to work on the manuscript, in addition to
the time which is required in the normal daily life of a researcher.

Jülich, October 2015 Thomas Schäpers


Contents
Preface to the second edition | VII

Preface to the first edition | IX

1 Introduction | 1

2 Low-dimensional semiconductor structures | 6


2.1 Overview | 6
2.2 Bulk semiconductors | 7
2.2.1 Band structure | 7
2.2.2 Effective mass | 9
2.2.3 Density of states | 11
2.2.4 Intrinsic semiconductors | 13
2.3 Doped semiconductors | 15
2.4 Transport | 17
2.4.1 Classical diffusive transport | 17
2.4.2 Einstein relation | 18
2.4.3 Mobility | 19
2.4.4 Characteristic length scales | 20
2.5 Layer systems | 23
2.5.1 Semiconductor heterostructures | 23
2.5.2 Two-dimensional electron gases | 25
2.6 Quantum wires and nanowires | 27
2.6.1 Electron beam lithography | 27
2.6.2 Semiconductor nanowires | 29
2.6.3 Split-gate quantum point contacts | 30
2.7 Zero-dimensional structures: quantum dots | 34
2.7.1 Transport at small source-drain bias voltages | 35
2.7.2 Transport as a function of source-drain bias voltage | 38
2.8 Transport in a quantizing magnetic field | 39
2.8.1 Landau quantization | 40
2.8.2 Shubnikov–de Haas oscillations | 43
2.8.3 Magnetic edge states | 45
2.9 Summary | 50

3 Magnetism in solids | 52
3.1 Definitions and basics | 52
3.1.1 Definitions | 52
3.1.2 Magnetization | 52
3.1.3 Magnetic moments of electrons in atomic orbitals | 53
XII | Contents

3.1.4 The electron spin | 54


3.2 Classification | 57
3.3 Paramagnetism | 57
3.3.1 Paramagnetism of localized moments | 57
3.3.2 Hund’s rule | 61
3.3.3 Pauli paramagnetism | 62
3.4 Collective magnetism | 63
3.4.1 Exchange interaction | 63
3.4.2 Stoner model | 67
3.5 Summary | 71

4 Diluted magnetic semiconductors | 73


4.1 Overview | 73
4.2 II-VI diluted magnetic semiconductors | 74
4.3 III-V diluted magnetic semiconductors | 78
4.4 Transport properties of III-V diluted magnetic semiconductors | 87
4.5 Summary | 92

5 Magnetic electrodes | 94
5.1 Overview | 94
5.2 Formation of magnetic domains | 95
5.2.1 Magnetic stray field | 95
5.2.2 Crystal anisotropy | 96
5.2.3 Form anisotropy contribution | 97
5.2.4 Exchange energy contribution | 98
5.3 Domain walls | 98
5.4 Ferromagnetic electrodes | 101
5.5 Local Hall effect measurements | 105
5.6 Micromagnetic simulations | 107
5.7 Domain wall motion | 110
5.8 Summary | 113

6 Spin injection | 114


6.1 Overview | 114
6.2 Resistor model | 115
6.3 Local description of spin injection | 119
6.4 Optical detection of spin-polarized carriers | 126
6.5 Experiments on optical detection of spin polarization | 130
6.6 Injection through a barrier | 133
6.6.1 Free electron approximation | 134
6.6.2 Diffusive transport regime | 139
6.7 Experiments on spin injectors with interface barriers | 142
Contents | XIII

6.8 Nonlocal spin injection | 144


6.9 Optical spin generation | 148
6.9.1 Optical absorption | 148
6.9.2 Spin coherence and spin dephasing | 149
6.9.3 Optical detection of magnetization | 151
6.9.4 Pump-probe experiments | 153
6.9.5 Resonant spin amplification | 158
6.10 Summary | 161

7 Spin transistor | 162


7.1 Overview | 162
7.2 InAs-based two-dimensional electron gases | 162
7.3 The Rashba effect | 164
7.4 Strength of the Rashba spin-orbit coupling | 169
7.4.1 The k ⋅ p method | 169
7.4.2 Envelope function approach | 171
7.5 Magnetoresistance measurements | 175
7.5.1 Beating patterns due to the Rashba effect | 176
7.5.2 Gate-control of the Rashba effect | 178
7.6 Bulk inversion asymmetry | 181
7.6.1 Time-reversal symmetry | 181
7.6.2 Spatial inversion symmetry | 182
7.6.3 Dresselhaus term | 184
7.7 Rashba effect in quasi one-dimensional structures | 187
7.7.1 Rashba effect in planar quasi one-dimensional structures | 187
7.7.2 Helical energy gap | 191
7.7.3 Rashba effect in tubular structures | 194
7.8 Summary | 199

8 Spin interference | 202


8.1 Overview | 202
8.2 Electron interference effects | 202
8.2.1 Electron interference effects | 203
8.2.2 Aharonov–Bohm effect | 204
8.2.3 Altshuler–Aronov–Spivak oscillations | 208
8.2.4 Weak localization | 211
8.3 Spin interference effects | 216
8.3.1 Weak antilocalization | 216
8.3.2 Spin relaxation mechanisms | 219
8.3.3 Weak antilocalization in two-dimensional electron gases | 222
8.3.4 Weak antilocalization in wire structures | 225
8.4 Spin interference effects in ring structures | 231
XIV | Contents

8.4.1 Berry phase | 231


8.4.2 Spin-interference in a ring with Rashba spin-orbit coupling | 236
8.5 Summary | 241

9 Spin Hall effect | 244


9.1 Introductory remarks | 244
9.2 Basic phenomena | 245
9.3 Boltzmann equation and skew scattering | 246
9.3.1 Boltzmann equation | 246
9.3.2 Intrinsic spin Hall effect | 249
9.3.3 Extrinsic spin Hall effect: skew scattering contribution | 250
9.3.4 Skew scattering in a two-dimensional system | 252
9.4 Experiments on spin Hall effect in semiconductor layers | 254
9.5 Detection of the spin Hall effect by electroluminescence | 257
9.6 Summary | 260

10 Quantum spin Hall effect | 262


10.1 Introductory remarks | 262
10.2 Inverted quantum well in HgTe/CdTe | 263
10.3 Band structure | 267
10.4 Helical edge states | 269
10.5 Conductance in a normal and inverted HgTe/CdTe quantum well | 273
10.6 Edge channel transport | 275
10.7 Spin-polarized transport | 277
10.8 Summary | 279

11 Topological insulators | 282


11.1 Introductory remarks | 282
11.2 Material system | 283
11.3 Bulk band structure | 283
11.3.1 Level evolution | 285
11.3.2 Effective Hamiltonian | 286
11.3.3 Ab-initio band structure calculations | 287
11.4 Surface states | 289
11.4.1 Surface states deduced from the effective Hamiltonian | 289
11.4.2 Surface states obtained from ab initio calculations | 290
11.4.3 Topological protection of surface states | 291
11.5 Angle-resolved photo-emission spectroscopy | 292
11.6 Transport experiments | 295
11.6.1 Topologically protected surface states in nanowires | 296
11.6.2 Flux-periodic oscillations in nanowire structures | 300
Contents | XV

11.6.3 Landau quantization in two-dimensional topological surface


states | 302
11.6.4 Shubnikov–de Haas oscillations in Dirac systems | 304
11.7 Summary | 306

12 Quantum computation with electron spins | 309


12.1 Introductory remarks | 309
12.2 Basic elements of a quantum computer | 309
12.2.1 Quantum bit | 309
12.2.2 Entangled states | 311
12.3 Basic quantum gates | 312
12.3.1 Single-qubit gate | 312
12.3.2 Controlled-NOT gate | 314
12.3.3 Realization of a quantum computer | 315
12.4 Quantum algorithms | 316
12.4.1 Deutsch–Josza quantum algorithm | 316
12.5 Quantum dot spin qubits | 320
12.5.1 General concept | 320
12.5.2 Experimental realization of a quantum dot qubit | 321
12.5.3 Initialization | 323
12.5.4 Read-out | 324
12.5.5 Electron spin resonance | 326
12.5.6 Spin-control in a double dot system | 329
12.5.7 Singlet-triplet qubit | 335
12.5.8 Control of the S-T0 qubit | 337
12.6 Summary | 340

13 Majorana fermions | 341


13.1 Overview | 341
13.2 Majorana’s version of the Dirac equation | 341
13.3 Majorana modes in solid-state systems | 343
13.3.1 Many-particle states | 344
13.3.2 Bogoliubov–de Gennes equation | 346
13.4 The Kitaev chain | 349
13.5 Majorana zero modes in semiconductor nanowires | 351
13.5.1 p-wave pairing in a proximitized semiconductor nanowire | 351
13.5.2 Majorana zero modes | 354
13.5.3 Experimental realization in nanowires | 356
13.6 Topological quantum computing | 358
13.6.1 Fermion parity and degenerate ground state | 358
13.6.2 Braiding | 359
13.6.3 Braiding with two pairs of Majoranas | 362
XVI | Contents

13.6.4 Non-Abelian anyons | 363


13.6.5 Majorana qubits | 365
13.7 Summary | 366

Solutions | 369

Bibliography | 395

Index | 407
1 Introduction
In spintronics the intrinsic magnetic property of the electron, its spin, is used for
switching purpose in an electronic circuit instead of its charge. The operation prin-
ciple of spintronic devices is based on completely different physical phenomena com-
pared to their charge-based counterparts. In this textbook, we will have a closer look
at the physical mechanisms of which spintronic devices make use. The roots of spin-
tronic devices lie in the field of magneto-electronic devices. As a matter of fact, metal-
lic magneto-electronic devices are already well established in information technology.
The basic physical phenomena are giant magnetoresistance (GMR) or tunneling mag-
netoresistance (TMR). These structures contain ferromagnetic layers which are either
separated by a metallic layer or by a tunneling barrier, respectively. By keeping the
magnetization in one layer fixed and changing the magnetization in the other one with
respect to the first, the resistance is changed. This mechanism can be used for switch-
ing or detection purposes. In the meantime both effects have been implemented in
applications, e. g. GMR or TMR devices are used as read heads in state-of-the-art hard
disc drives and were responsible for the huge increase of storage capacity in recent
years. Because of its significance the Noble prize in physics was awarded to Albert Fert
and Peter Grünberg in 2007: “For the discovery of magnetoresistance” [3, 4]. The GMR
and TMR effect can also be employed in solid-state memories, i. e. magnetoresistive
random access memories (MRAMs). The memory cells can be programmed by chang-
ing the magnetization of one magnetic layer with respect to the other by means of a
magnetic field generated by two crossing current carrying lines. More recent switch-
ing schemes use spin-transfer torque. Instead of employing an external magnetic field,
here the switching is achieved by using a spin-polarized current through the memory
cell itself. The advantage of magnetic memories is that they are nonvolatile, i. e. the
stored information remains even after the power supply is switched off. MRAM chips
are already commercially available.
So far, magnetic device structures are mainly used for data storage, while the data
processing itself is performed by semiconductor devices. Here, the work horse is the
field-effect transistor. The vast majority of these transistors is made from silicon as
a semiconductor material. During the last decades one could observe a continuous
shrinkage of device dimensions following the so-called Moore’s law [1]. This allowed
the integration of more and more devices on a chip and the design of more complex cir-
cuits as well as denser solid-state memories. However, it is foreseeable that the minia-
turization of Si-based circuits will reach its limits [2, 5]. Therefore, various alternative
concepts are pursued, e. g. by extending the material base by using SiGe or by imple-
menting novel device concepts like the tunnel field-effect transistor. Above that, more
revolutionary concepts are also considered. One of them is semiconductor spintronics,
where the electron spin is the entity, which is exploited for information processing. Us-
ing the electron spin in a device promises to perform digital switching sequences faster

https://doi.org/10.1515/9783110639001-001
2 | 1 Introduction

with less power consumption [6, 7, 8, 9, 10, 11]. A prominent example of a spintronic
device is the spin field-effect transistor (spin FET), proposed by Datta and Das [6].
Although the field of semiconductor spintronics has existed for some years already,
these kind of devices have not yet found their way into electronic circuits. However,
in the meantime a working spin FET as a demonstrator has been realized [12].
Let us have a look on different physical mechanisms employed in spintronic de-
vices. Figure 1.1 (a) shows a schematic of a spin field-effect transistor.

Figure 1.1: (a) Schematic illustration of a spin field-effect transistor. Spins are injected into the two-
dimensional electron gas (2DEG) in the semiconductor. The spin orientation is manipulated by bias-
ing the gate electrode. (b) Spin light emitting diode (spin LED). Spin-polarized electrons are supplied
from the top ferromagnetic electrode. The unpolarized holes are provided by the bottom contact.
Electron hole recombination results in the emission of circularly polarized light. (c) Spin-polarized
electrons can by generated by circularly polarized light. The spin orientation can be detected by the
magnetooptical Kerr effect (MOKE). Here, the polarization direction of a reflected linearly polarized
beam of light is changed in the presence of spin-polarized carriers in the semiconductor.

Spin-polarized carriers are supplied from the ferromagnetic source contact by driving
a current between source and drain. The spins are injected into the semiconductor
material, keeping their initial spin polarization in the ferromagnet. As we will dis-
cuss in Chapter 6, this is a formidable task. Owing to the conductance mismatch and
to imperfect interfaces, spin injection is often quite inefficient. In Chapter 4, we will
1 Introduction | 3

introduce diluted magnetic semiconductors, which might be an interesting alterna-


tive to metallic ferromagnetic injectors, owing to their better conductance matching.
Once the spin-polarized carriers are injected into the two-dimensional electron gas
in the semiconductor, their spin orientation is manipulated by means of the Rashba
effect [13]. Applying a voltage to the gate electrode results in a change of the electric
field to which the electrons in the semiconductor are exposed. The electrons propagat-
ing in that electric field experience an effective magnetic field. The electron spin pre-
cesses about this effective magnetic field. The degree of spin precession depends on
the strength of the electric field and thus on the gate voltage. The underlying physical
mechanisms of a spin FET are introduced in Chapter 7. After passing the semiconduc-
tor section, the spin orientation is detected by the ferromagnetic drain contact. Ide-
ally electrons can only enter where the spin orientation matches the magnetization in
the drain contact. By biasing the gate the spin orientation of the carriers reaching the
drain contact can be controlled. This is the switching scheme of the spin field-effect
transistor. In an alternative concept electron interference can also be employed for
switching purposes. This will be discussed in Chapter 8.
Owing to the inefficiency of purely electric spin injection and detection, often op-
tical means are utilized as an alternative to measure spin-polarized carriers. A typi-
cal example is given in Figure 1.1 (b), where a spin light emitting diode (spin LED) is
shown. Spin-polarized electrons are transferred from a ferromagnetic electrode into a
quantum well layer. Here, the electrons recombine with unpolarized holes provided
by the bottom contact. Owing to the spin polarization of the electrons, circularly po-
larized light is emitted. This is due to angular momentum conservation during the
recombination process. Thus, the emission of circularly polarized light can be used to
verify spin injection from a ferromagnetic electrode into a semiconductor. Moreover,
the spin LED can also directly be used in applications, where it serves as an emitter
for circularly polarized light.
One can even move one step further and perform all-optical experiments. As
an inverse process, circularly polarized light can also be employed to generate spin-
/polarized electrons in direct band gap semiconductors. Here, spin-polarized electron-
hole pairs are excited by the irradiated light. Due to strong spin orbit coupling in the
valence band, the spin polarization of the holes decays quickly, while the electron spin
polarization remains. This is a very efficient method to generate spin-polarized elec-
trons, compared to electrical spin injection. The presence of spin-polarized carriers
in a semiconductor can also be detected by optical means, i. e. by the magnetooptical
Kerr effect (MOKE). Here, a beam of linearly polarized light is reflected at the surface.
In the presence of spin-polarized carriers, the polarization of the reflected beam is
rotated. The rotation angle is proportional to the magnetization in the semiconduc-
tor, and thus it can be employed as a parameter to quantify the magnetization in a
semiconductor. As a matter of fact, optical means are very powerful means to gener-
ate or detect spin-polarized carriers. However, conceptually one runs into problems
when it comes to miniaturization. This can be achieved much more easily by purely
4 | 1 Introduction

electrical means. Indeed, in this textbook we will mostly focus on electrical phenom-
ena, whereas optical effects will only be covered when they serve in experiments to
generate or measure spin-polarized carriers.
Recently spintronics has made a large leap towards novel phenomena and mate-
rials, such as the quantum spin Hall effect or topological insulators [14, 15, 16]. Re-
garding the first, the strong spin orbit coupling in a HgTe/CdTe heterostructure re-
sults in an inversion between the conduction and valence bands. As a consequence,
one-dimensional channels are formed at the edge of the sample, similarly to what is
known for the quantum Hall effect. The crucial difference is that these edge channels
are formed at zero magnetic field, whereas in the case of the quantum Hall effect a
magnetic field is required. Furthermore, the transport on the edges is spin polarized.
In this sense it is related to the spin Hall effect discussed later in Chapter 9, where spin-
dependent scattering of propagating electrons also results in spin-polarized carriers
at the edge of the sample.
Very similar effects to the quantum spin Hall effect are observed in three/di-
mensional topological insulators, where due to the very strong spin orbit coupling
a conductive two-dimensional surface channel is formed. This surface channel is
inherently stable, i. e. topologically protected. Quantum spin Hall systems and three-
dimensional topological insulators are completely new states of matter. The related
physical effects have not yet been fully explored. In any case, they promise a huge
potential for future spintronic devices. The properties of these materials are discussed
in Chapters 10 and 11.
Apart from more conventional circuits a new scheme for information processing
has emerged which is directly based on quantum mechanics. Instead of 0 and 1 as
two states, a bit (cf. Figure 1.2 (a)), i. e. the smallest unit of information in a conven-
tional computer, in quantum computing the quantum bit (qubit), is constituted by a
quantum mechanical two-level system. This is illustrated in Figure 1.2 (b) [17].

Figure 1.2: (a) Example of changing the bit value between the two values 0 and 1 in a conventional
computer in the course of time. (b) Representation of a quantum bit by a spin-1/2 two-level system.
The level splitting is due to the Zeeman effect in a magnetic field. Apart from the two basis states |↓⟩
and |↑⟩, superposition states α|↓⟩ + β|↑⟩ can also be realized.
1 Introduction | 5

The increase of computational power, e. g. for factorizing large numbers [18], origi-
nates from the fact that the corresponding algorithms make use of quantum mechan-
ical superposition and entangled states. Spin-1/2 systems are ideally suited to realize
a qubit, since the Zeeman split states naturally represent the required two-level sys-
tem. In practice, this two-level system can be realized in a semiconductor quantum
dot [19, 20]. Here, a single electron is electrostatically confined in the dot. Quantum
computation algorithms are implemented by changing the spin orientation by means
of an ac magnetic field or by coupling two adjacent quantum dots. The basic principles
of quantum computation as well as quantum dot qubits are discussed in Chapter 12.
Furthermore, in Chapter 13 an alternative concept, i. e. topological quantum compu-
tation, is discussed which is based on Majorana fermions.
For all these issues it is clear that a profound knowledge of semiconductor sys-
tems is required. In particular, many spintronic devices are based on low-dimensional
systems such as two-dimensional electron gases, quantum wires, or quantum dots.
Therefore, we will begin by introducing these systems in the next chapter. Further-
more, some basic knowledge of magnetism and magnetic electrodes is necessary,
which is provided in Chapters 3 and 5.
2 Low-dimensional semiconductor structures
2.1 Overview
Semiconductors can be classified as materials which usually have a much lower con-
ductivity than metals but in contrast to insulators do have a finite conductance at
nonzero temperatures. In Figure 2.1 (a)–(c), a schematic of the electronic states, i. e.
bands, is shown for all different kinds of materials. In metals the states are filled up
to the Fermi energy EF . The empty states above EF allow electronic transport. In in-
sulators the lower band is fully occupied. Since in a fully occupied band the electron
occupation cannot be rearranged, i. e. by applying an electric field, no transport is
possible here. The upper band is separated from the occupied lower band by a large
energy band gap (Eg > 4 eV). Thus, no thermal excitation is possible. In a semicon-
ductor, the band gap is smaller (0.15 eV ≤ Eg ≤ 4 eV). In that case, electrons can be
thermally excited into the upper band. These excited electrons can participate in the
transport. Furthermore, the unoccupied states in the lower band, i. e. the holes, con-
tribute to the transport as well.

Figure 2.1: Comparison between different materials. (a) Metal: the band is partially filled up to the
Fermi energy EF , so that empty states are available for electron transport. (b) Insulator: no transport
is possible, since the lower band is fully occupied and no empty states are available for transport.
The upper band is empty. The band gap is so large that no thermal excitation is possible. (c) Semi-
conductor: the band gap is sufficiently small for the electrons to get thermally excited into the upper
band, and hence electron transport is possible. (d) Chemical elements of the periodic table which
constitute semiconductor materials.

What is so special about semiconductors? First, intrinsic, i. e. pure, semiconductors


usually have low conductivity, which depends strongly on temperature. Second, in
semiconductor crystals with a small amount of incorporated foreign atoms, so-called

https://doi.org/10.1515/9783110639001-002
2.2 Bulk semiconductors | 7

dopants, the conductance can be increased by several orders of magnitude. Further-


more, the type of carriers can be changed between electrons and holes. Third, in semi-
conductors the field-effect can be employed. Here, the electron concentration can be
changed by means of an electric field. These properties are unique for semiconductors
and are not present in metals owing to their much higher electron concentration.
Depending on the application, different types of semiconductors are used in spin
electronics:
– Doping of bulk semiconductors is used to create diluted magnetic semiconductors
(DMS).
– Semiconductor layer systems consisting of layers with different materials, i. e. het-
erostructures, are employed in spin light emitting diodes.
– Low-dimensional semiconductor structures, i. e. two-, one-, and zero-dimensio-
nal structures find their applications in spin transistors and in devices for spin-
based quantum computation.

In this chapter, we will restrict ourself to the semiconductor properties relevant to


spintronic applications. More general information can be found in text books dedi-
cated to semiconductor physics [21] or on semiconductor nanostructures [22, 23].

2.2 Bulk semiconductors


As illustrated in Figure 2.1 (d), chemical elements from group II to VI are the basis of
a large variety of semiconductor materials which are employed in charge-based elec-
tronics as well as in spin electronic:
– Elementary semiconductors, i. e. Si or Ge: especially Si is the most popular mate-
rial for electronics in particular for integrated circuits.
– Compound semiconductors: here, one can distinguish between IV-IV (group IV
and group IV) semiconductors, e. g. SiC; III-V semiconductors, e. g. AlP, AlAs,
GaAs, InP, InAs, InSb, or GaN, and II-VI semiconductors, e. g. ZnO, CdS, CdSe, or
CdTe. In particular, III-V compound semiconductors are interesting for optoelec-
tronics and high speed electronics, due to their direct band gap and low effective
electron mass.
– Alloys of the semiconductors mentioned above, e. g. Six Ge1−x , Alx Ga1−x As,
Alx Ga1−x Sb, Inx Ga1−x As, or Alx Ga1−x N.

2.2.1 Band structure

In the periodic potential of a crystal the discrete atomic levels are transfered into en-
ergy bands. The energy-momentum dispersion Eν (k)⃗ of a band structure describes how
8 | 2 Low-dimensional semiconductor structures

the energy E depends on the wave vector k⃗ in a certain band ν. In most semiconduc-
tors, i. e. Si, the upper bands originate from s-type atomic orbitals. These bands are
called conduction bands. Separated by the energy gap Eg the valence bands are found.
These bands usually originate from p-type atomic orbitals. As we will see later, this has
implications for the resulting angular momentum state. Typical band structures of Si
and GaAs are shown in Figure 2.2. The band structure is plotted for different symme-
try directions in the Brillouin zone. The Γ-point corresponds to k = 0. In most cases,
electron and hole states close to the Γ-point are considered.

Figure 2.2: Band structure of (a) Si and (b) GaAs, with Eg the band gap.

The elementary semiconductors Si and Ge have an indirect band gap, which means
that the maximum of the valence band at the Γ-point in the Brillouin zone does not
match in k-space to the minimum of the conduction band. The conduction band min-
imum is found at a finite k-vector. As an example, the band structure of the indirect
semiconductor Si is shown in Figure 2.2 (a). As a consequence no direct optical tran-
sitions of electrons from the conduction band down to the valence band are possible,
since the photon cannot provide the momentum required. The semiconductors Si and
Ge crystallize in the diamond lattice, which is depicted in Figure 2.3 (a).
Most III-V semiconductors have a direct band gap. Here, the maximum of the va-
lence band is aligned in k-space to the minimum of the conduction band. A typical
example is the band structure of GaAs shown in Figure 2.2 (b). In this case direct opti-
cal transitions are possible, which is the reason why they are commonly used in opto-
electronics. The wave length of the photons emitted during transitions is determined
by the band gap Eg . For example, in spintronics, direct band gap semiconductors are
used to realize a spin light emitting diode. However, some III-V semiconductors have
an indirect band gap, such as AlAs. Most III-V semiconductors crystallize in the zinc
blende lattice, as shown in Figure 2.3 (b), e. g. GaAs or InP; however some are found
in the wurtzite lattice, e. g. GaN.
2.2 Bulk semiconductors | 9

Figure 2.3: (a) Diamond lattice of Si and (b) zinc blende lattice of GaAs.

2.2.2 Effective mass

Due to the periodic potential landscape in a crystal the carriers in a semiconductor


possess an effective mass m∗ which differs from the free electron mass m0 . This can
be understood as follows. The acceleration of a particle for the one-dimensional case,
i. e. the change of the group velocity vg = (1/ℏ)(dE/dk) with time, can be written and
rearranged as
dvg 1 d dE
= ( ) (2.1)
dt ℏ dt dk
1 d2 E
= (2.2)
ℏ dkdt
1 d2 E d(ℏk)
= 2 2 . (2.3)
ℏ dk dt
In the last term we can identify d(ℏk)/dt as the force F, with k the wavenumber. With
d(ℏk)
F= (2.4)
dt
we can write
dvg
F = m∗ , (2.5)
dt
where the effective mass m∗ can be interpreted as

1 d2 E
−1
m∗ = ( ) . (2.6)
ℏ2 dk 2
The effective mass is proportional to the inverse curvature of the band dispersion E(k).
Thus, m∗ is a direct consequence of the band structure and the corresponding periodic
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Hammond gave a smile, like that of Mr. Charles Hawtrey on the
stage when his stage mother-in-law enters and announces that she
has come to spend a stage-day with him.
“How much this time, dean?”
The Dean of Colchester drew back; then he put his head on one side
and smiled indulgently on his victim.
“He is too bad, isn’t he?” This was to Lady Victoria. “But, do you
know, I really was going to write to you this week.”
“How much?” Hammond repeated, drearily.
“Lady Victoria, I appeal to you. I am sure you must think me quite
mercenary.”
“Hadn’t you better tell him?” suggested the matter-of-fact Victoria.
The dean shook his head in protest.
“I am actually silenced. The fact is that we are just raising a fund to
restore the north tower of the Cathedral, and I thought that, as you
had been so generous before, you might possibly see your way to
give us some assistance.”
“How much?”
“No, really! But if you did feel disposed to do something, however
small—”
The voice of the machine was again heard in the offing:
“Mr. Septimus Jones!”
“You had better make haste,” said Victoria to the dean.
The dean cast an imploring look at Hammond.
“I am so ashamed! May I really throw myself on your generosity?”
“How much?”
“I couldn’t possibly—” The curtain was lifted from outside. “Well, fifty
pounds?” Hammond took out a pocket-book and began to scribble a
memorandum in it. “This is too good of you. I assure you I never
expected it.”
The curtain had admitted a pale youth, with light-colored hair, parted
in the middle, who held a pair of gloves furtively in one hand, having
plainly just made the discovery that no one else had brought gloves,
and being distracted in consequence by a desire to smuggle them
into a pocket unperceived.
Victoria greeted him with suspicious cordiality.
“It is too bad of you to come so late, Mr. Jones. I haven’t enjoyed
myself a bit.”
“No, Lady Victoria, you mustn’t blame me.” At this point he made an
effort to slip the hand which contained the gloves into a tail-pocket,
but catching the unconscious eye of the dean fixed, as he supposed,
on the offending articles, he drew them out again hastily. “I couldn’t
get here sooner. My brougham wasn’t ready.”
“You should have come in a cab.”
“No, Lady Victoria, I am sure you don’t mean that I could have come
in a horrid cab. I would as soon walk.”
“Don’t you ride a bicycle?”
“Oh yes, Lady Victoria, of course I ride a bicycle—in the morning, in
the Park, you know, but not in the streets. You don’t mean that I
could have come here on a bicycle, do you?”
By this time he had dexterously transferred the gloves to his other
hand, and was again cautiously feeling his way round to his coat-
tails, when a sudden movement of Hammond’s, who had just
completed his business with the dean, caused the unfortunate youth
to take fright and once more relinquish his half-executed design.
“I am afraid you are not in earnest, Mr. Jones.”
“Oh yes, Lady Victoria, I am very earnest. Everybody says I am very
earnest. I take life quite seriously—I do, indeed. I go to all sorts of
lectures and that kind of thing, you know, to improve my mind.”
“You will have to be careful, then,” put in Hammond as he came up,
“or they will make you give them a testimonial, and advertise you in
all the papers as a marvellous cure.”
Mr. Jones shrank back.
“Ah, now, Hammond, I am afraid of you, because you are so
sarcastic. He was sarcastic then, wasn’t he, Lady Victoria?”
“Not very,” replied the person appealed to. The next instant she gave
an imperceptible start.
“Captain Mauleverer!”
“But if you two are going to quarrel I shall go into the next room,”
Victoria went on, quickly, beginning to move away.
“Oh no, Lady Victoria,” Mr. Jones remonstrated; “I never quarrel. I
am a subscriber to the Peace Society—I really am.”
The Dean of Colchester looked round.
“Then I can leave you in perfect safety,” retorted Victoria, gliding off.
“Dear me! I am afraid that Lady Victoria is sarcastic, too,” Mr. Jones
observed, sagaciously, looking after her. “Don’t you think so,
Hammond?”
“I have suspected her of it sometimes; but she never admits it, and
it is so difficult to prove these things.”
“I will ask the dean; I am sure he is not sarcastic—are you, dean?”
“My dear fellow,” Hammond interrupted, “I am surprised that you
should ask such a question. A sarcastic dean would be a moral
outrage. You might as well speak of a malicious cathedral.”
The dean thought of his fifty pounds, and smiled like an early
Christian martyr commencing an interview with a sharp-set lion.
At this point Hammond’s attention was diverted by the entrance of
the latest arrival. As he turned away to greet him, the dean laid a
caressing hand on Mr. Jones’s arm.
“Did I hear you say just now that you were a subscriber to—”
Mr. Jones gave a glance round. He was alone with the dean, and the
dean was on the wrong side of him. There was no human eye to see
the deed. With one swift movement he succeeded in depositing his
gloves in their long-sought hiding-place, and then suffered himself to
fall an unresisting prey to the north tower of the Colchester
Cathedral.
Captain Mauleverer’s face wore a decidedly cross expression as he
came into the room. At the sight of Hammond it lighted up, and the
two shook hands like old friends.
“So you patronize my aunt’s menagerie?” the captain observed,
disrespectfully.
“Well, yes.”
“I should have thought you had too much sense.”
“My dear fellow, you are here yourself,” returned Hammond.
The captain gave an impatient shrug.
“I know, but I shouldn’t be if I could help it. It’s a beastly bore. You
can’t smoke, and you can’t drink, and you are expected to sit beside
some sentimental woman of fifty and let her gush to you over some
beastly novel you haven’t read, and wouldn’t understand if you had.”
Hammond shook his head with a reproving smile.
“Yes, but you should remember that we are not here to please
ourselves. We are here to please society.”
“Why should you care about society? You’re not a damned pauper
like me. You have everything you want.”
“No one on the face of the earth has everything he wants,”
Hammond retorted. “But I see what it is; you are out of sorts.
What’s the matter?”
Mauleverer’s only answer was a despairing shrug.
“Been backing a horse?”
“No, it’s not that.”
“What is it, then? Cards?”
“No.”
“Not drink?” in a tone of incredulity.
“No, no.”
“Tell me.”
The captain hesitated for a moment before he gave the answer:
“Girl.”
Hammond let a mild exclamation of surprise escape him. Then he
looked at his friend with a certain air of sympathy.
“What should you say if I were to tell you that you and I were in the
same boat, old man?”
“You?” The other stared at him in amazement. “You don’t mean to
say that there is any girl in England who would refuse you?”
“Suppose there were a girl whom I hadn’t the courage to ask, not
because I was afraid of her refusing me, but because I was afraid of
her accepting me?”
“I don’t understand.”
“Suppose I had to choose between her and my ambition? Suppose I
knew that if I were to ask her to be my wife I might have to
abandon my whole career, because society would forbid the banns?”
“I never thought of that,” murmured his friend.
“This very morning,” Hammond went on, “I had a letter from a man
who thinks he is acting in my interests to warn me against the
woman I love.”
“That is rather rough on you, old man.”
Hammond smiled bitterly.
“You see, even a damned millionaire can’t have everything he
wants.”
“Miss Yorke!”
The name caused a sensation. Heads were turned from all
directions, and the Dean of Colchester and his victim hurried back to
the neighborhood of the doorway where Hammond and Mauleverer
were standing. At the same time Mr. Despencer slipped in from the
next room, and stealthily approached the group.
“What Miss Yorke is that?” asked Mauleverer, innocently.
“The Miss Yorke, I believe, popularly known as Belle Yorke,”
Despencer took it on himself to answer. He affected to keep his eyes
turned away from Hammond.
“Belle Yorke!” exclaimed Mr. Septimus Jones, with enthusiasm. “Oh, I
dote upon her! I think she is perfectly lovely—don’t you,
Hammond?”
“Yes.”
The Dean of Colchester gave a sound like an ecclesiastical purr.
“Now, this is very fortunate! I have so often wished to see her, but,
of course, I daren’t go to those places where she sings. It is so
thoughtful of the marchioness to bring her here. Ahem! isn’t there
something or other said about her?”
“They say plenty of things about her, but God knows how much of it
is true,” remarked Mauleverer.
“Oh, but Mauleverer,” Mr. Jones burst in, “you know when people say
so much it must be some of it true, mustn’t it?”
Hammond turned and looked at the three men, one after the other,
and then his eyes wandered to Despencer, who was standing by,
with a sneer on his thin lips. Here were these four men all looking at
the matter from different points of view, none of them apparently
with any reason to wish ill to Belle Yorke, two of them evidently
friendly towards her, and yet they all doubted her alike.
Before he could speak he saw a sudden change come over their
faces. A man had just come hurriedly through the doorway leading
from the reception-room. It was the Marquis of Severn; and he was
in full dress, with the blue ribbon of the Garter across his shirt-front.
He caught sight of his nephew, and strode up to him, his face
working with emotion.
“Here, Gerald, come this way; I want to speak to you!” he
exclaimed, without heeding the presence of the others.
He seized Mauleverer’s arm, and half led, half thrust him out of the
room. One or two of the by-standers saw what was happening, and
smiled. Hammond turned sharply on Despencer, whose smile was
peculiarly malicious.
“I shall be obliged if you can come with me into the conservatory for
five minutes. I wish to speak to you privately,” he said.
Despencer bowed with an air of bland unconcern, and followed him,
while the voice outside sounded again:
“Alderman Dobbin!”
SCENE VII
A QUESTION OF CHEMISTRY

In order to reach the conservatory Hammond and Despencer had to


thread their way through the concert-room. But their task was
rendered easier by the fact that Belle Yorke was just standing up to
sing. The mob, attracted partly by her reputation as a singer, and
partly by the story in circulation about her and their host, whose
hurried exit on her appearance had not gone unremarked, were
crowding towards that end of the saloon where the piano stood, and
thus the two men were able to make their way round the wall at the
deserted end.
As Hammond had anticipated, they found the conservatory empty. It
was little more than a long, narrow balcony, roofed over with glass,
and running along the side of the house.
Hammond was the first to reach it, but he stood back to allow
Despencer to enter. Despencer walked past him after a deprecating
shrug and bow, and then turned to meet his questioner, who came
in quickly, shutting the door behind them.
For a moment the two men stood face to face, scrutinizing each
other like two duellists who are uncertain of each other’s play.
Hammond’s gaze was stern and threatening. Despencer’s, equally
unflinching, was that of a man who does not quite know what is
required of him, but has nothing to fear or to conceal.
The situation was exactly what he had foreseen and desired. His
former reference to Belle Yorke had had the appearance of being
accidental. He had been far too clever to seek to press it home at
the time. Now, if Hammond himself chose to revive the subject of
his own accord, anything that Despencer might say would appear to
be dragged out of him against his will. He felt perfectly satisfied with
his play, so far. He still held all his best cards in reserve, and he had
thrown the lead into his adversary’s hands.
“Well, what is the mystery?” he said, lightly, after waiting some time
for Hammond to speak.
“I want to ask you for some explanation of what you said the other
afternoon.”
Despencer was mildly amazed.
“What did I say? I really don’t remember,” he murmured.
“About Miss Yorke. You referred to some story about her—some
report connecting her name with Lord Severn’s.”
Despencer drew back; his manner became reproachful.
“Oh, but, my dear sir, you must see that that was pure inadvertence
on my part. I was not to know that the lady was a friend of yours.”
It was impossible to quarrel with a man who showed himself so
perfectly polite and, at the same time, so perfectly indifferent.
Hammond’s tone lost some of its hostility.
“That is not the point. Till you spoke, I had never heard of the
existence of this—slander.” The momentary hesitation before the
word did not escape the watchful Despencer. “You have spoken,
fortunately or unfortunately, and, now I have heard of it, I cannot
rest till I know more.”
“Is that necessary?”
The tone in which the question was put made it a friendly
remonstrance, as much as if Despencer had said: “My dear fellow,
you want to think well of this woman. Why persist in making me
undeceive you?”
Hammond felt the implied warning in all its force. Nevertheless he
answered:
“Yes, it is necessary. The matter cannot end like this; I have a
motive for pursuing it. You heard what those other men said when
Miss Yorke was announced. I must be able to satisfy myself that this
statement is without foundation.”
Despencer could not quite resist a sneer.
“I should think that was easy enough. You have only to ask the lady
if she knows Lord Severn.”
Hammond frowned impatiently as he said, aloud, but rather to
himself than to Despencer:
“And what will be her answer?”
Despencer smiled compassionately.
“Judging from my own experience in such cases, I should say that
the lady’s answer would be ‘No.’”
For a minute Hammond stood irresolute. Despencer’s sneer had
shown him where he stood. Instead of silencing a slanderer, he was
discussing the truth of the slander with the man who had uttered it.
If he had really had confidence in the woman he had undertaken to
defend, it was to her, not to this cynical stranger, that he ought to
have been addressing his inquiries. He felt bitterly conscious of his
false position, yet he could not resist going on.
“Where did you hear this rumor?” he asked, after a brief pause,
during which Despencer had closely watched every shade of
expression on his face.
“I can hardly tell you, I have heard it from so many quarters,” was
the careless reply. “I thought everybody knew it.”
“Do you mean by that that everybody believes it?” demanded
Hammond.
“Yes; but that is no reason why you should, if you would rather not.
Take my advice, treat it as a mere passing calumny, and forget all
about it.”
Hammond glanced at him questioningly.
“And you, Despencer—of course, you believe this?”
“Well, yes; but I shall be happy to withdraw it.”
Despencer’s mocking smile was lost upon Hammond. He muttered:
“I must get at the truth.”
“Far better not,” observed the cynic. “The truth is sometimes very
disagreeable. I myself much prefer to be told pleasant falsehoods.”
“And to tell them, I suppose?”
Despencer did not wince.
“I am always anxious to oblige,” he answered, pointedly.
“You have no prejudice against Miss Yorke?” was Hammond’s next
question.
“I have no prejudices at all, I can assure you. I am a most broad-
minded person.”
“It would make no difference to you, I suppose, if this report were
true? It wouldn’t injure her in your opinion?”
“On the contrary, it would greatly increase my respect for her.”
Hammond seemed to be trying to sound the depths of his
companion’s character.
“I congratulate you. But you wouldn’t marry her?”
Despencer drew back, and shook his head with an amused air.
“Oh no! I am afraid I am not broad-minded enough for that.”
“Why not?”
“I couldn’t outrage decency, you know. Society would think me
worse than the marquis.”
“Damn society!”
“Oh, it is damned already,” said Despencer, quickly. “But even down
below there are certain regulations which must be respected. There
is an etiquette of Pandemonium.”
Hammond gave him another thoughtful look.
“You are a very clever man, Despencer, but, do you know, you
almost make immorality tedious. If you are not careful, people will
begin to get bored by vice, and virtue will become the fashion.”
“That is not a bad idea. There is always something attractive in
novelty.”
Again Hammond reflected for a minute, and again he resumed his
questioning.
“Tell me, has the marchioness heard this rumor?”
Despencer had not been expecting this question, and it nearly threw
him off his guard. His eye met Hammond’s for a moment before he
answered.
“I should hardly think so, or she wouldn’t have had her here. That
would have been too daring, even for her.”
“It would be equally daring for her to come here if there were
anything in it. Surely her very presence here proves her innocence?”
“Yes; but what about Lord Severn’s absence? You saw him hurry out
the moment she arrived?”
“My God, yes!” The words were dragged from Hammond in a burst
of anguish. “There is some damned mystery in this!” he muttered
between his teeth.
“Of course, it may be a mere coincidence,” the tempter threw in,
artfully. “But I am always so suspicious of coincidences.”
Hammond was not listening. A new idea had occurred to him.
“I have a great mind to go to Severn himself, and put myself in his
hands. But, then, of course, one couldn’t trust him,” he added,
regretfully.
“He is a man of honor,” objected the other.
“And when the good name of a woman is at stake, men of honor
always lie,” was the stern retort. “Oh would to Heaven you had
either never told me this, or else proved it up to the very hilt.”
“I didn’t speak out of any zeal for morality, you may be sure. I had
simply heard the common talk, and I naturally assumed that it was
true.”
“Why?”
Despencer gave a delicate, self-satisfied smile.
“When there is any doubt, I always believe the worst. I find I am
seldom wrong.”
Hammond stepped back, with an indignant gesture. He was
beginning to feel ashamed of the discussion.
“And you can stand like that and smile away a reputation!” he
exclaimed. “I wonder what they made you of.”
“I believe a chemical analysis of me would yield the ordinary results,”
returned Despencer, with unruffled composure. “I rather think that
hydrogen is the principal ingredient.”
Hammond gave a short laugh.
“Despencer, I begin actually to respect you. It can be no easy thing
to attain to such a height of perfect brutality as yours. You must
have taken great pains with yourself.”
“You may say what you like, Hammond, as long as you are not
violent. I always draw the line at violence.”
“Do you have to draw it often?”
Even the trained and admirable temper of Despencer gave way
under this taunt, and a red flush suffused his pale cheeks.
“Hammond, do you mean to be insulting?”
“Why, do you mind much? I should have thought the hydrogen
would have stood it.”
The words were drowned in a sudden crash of music and hand-
clapping as the door behind them opened, and Captain Mauleverer
came through with Belle Yorke on his arm.
Despencer drew to one side with a bow as they approached.
“Ah, captain, taking Lord Severn’s place, I see,” he remarked, with a
sarcastic emphasis intended for Hammond’s ear, and passed back
into the concert-room.
Mauleverer stared after him as if he had been some noxious animal.
“What has that damned cad—beg pardon, Miss Yorke—been doing
here?” he demanded of Hammond.
“Oh, only taking away some one’s character.”
“Not mine, I hope,” said Belle, with a smile.
“No, not in Hammond’s hearing, I’ll swear,” said the loyal captain.
“It was too bad of you to go outside just as I was going to sing,”
said Belle to the silent Hammond. “I shall expect an explanation.”
“I have been waiting here to give it to you,” was the grave answer.
“You seem quite serious about it. I am sure Mr. Despencer has been
saying something against me.”
Captain Mauleverer put in a word.
“I can’t let you give your explanation now, because Miss Yorke has
promised to sit out this next piece with me. You must wait your turn,
old fellow.”
“What does Miss Yorke say?” asked the other.
“I say what they say at the libraries about the book of the season.
You shall have me when the captain has done with me.” She turned
merrily to the captain. “But you mustn’t skip, you know. I shall allow
you fourteen minutes for perusal.”
“I want to read you through,” said Hammond. And he went out.
SCENE VIII
CINDERELLA

“How very sober Mr. Hammond seems to-night! I hope he isn’t going
to be cross.”
Though she spoke gayly enough, a vague sense of ill was stealing
over her. She sat down on a low cane settee, over which flowering
shrubs made a sort of canopy, and a sadness seemed to breathe in
the heavy scent of tuberose and stephanotis.
Captain Mauleverer placed himself beside her, and looked at her with
a certain respectful pity as he answered:
“That isn’t likely. I’m sure it wouldn’t be easy to be cross with you,
Miss Yorke.”
Belle detected something in his voice which increased her
foreboding.
“You look as grave as Mr. Hammond. Is anything the matter?”
“Yes, I’m afraid there is.”
The moment he had spoken the words he wished them unuttered.
The light faded out of the beautiful eyes, and a pathetic sadness
took its place.
“Oh, please don’t tell me that!” she pleaded. “I am enjoying myself
so much this evening.”
“Are you? I am glad of that,” said Mauleverer, tugging uneasily at his
mustache.
“Yes; I have never been to a place like this before, you know, and it
is all so strange and beautiful. I am a little bit afraid of the
Marchioness of Severn, but every one else has been so kind that I
haven’t felt myself a stranger. I feel almost like the little chimney-
sweep who wandered by accident into the state bedroom of the
castle, and turned out to be the rightful heir. Please don’t send me
back to my chimney.”
The captain swallowed something in his throat.
“I wish I hadn’t promised to, but the fact is I have undertaken to
give you a message.”
This time Belle turned to him with a look of something like alarm.
“Can’t you put it off till to-morrow? Do let me have my dream out to-
night.”
Mauleverer shook himself.
“Hang it! I have a great mind to,” he exclaimed.
“Please do, if it is an unkind message. I didn’t think I had any
enemies.”
“You have none—at least, I don’t believe you have. It isn’t that.
What I have promised to tell you is something about yourself,
something you ought to know.”
“Something about myself! Oh, what do you mean? I haven’t been
doing anything wrong, have I?”
Captain Mauleverer bit his lip and looked more than half inclined to
run away. Then he said, slowly:
“Perhaps I should have said—something about your father.”
“My father!” She gazed at him in astonishment. “But he is dead! He
died before I was born.”
“No!”
The answer struck her dumb. She sat still and pressed her hand
against her heart. The man replied to her unspoken questions with a
grave shake of the head.
“My father is not dead? Oh, Captain Mauleverer, what are you
saying? What do you know about him?”
“I wish I didn’t have to speak to you like this. Your father is alive.”
“And they have always told me he was dead! My mother— Captain
Mauleverer, are you sure of what you say?”
“I am. I know your father.”
“Then why—” She broke off in the midst of the question and wrung
her hands. “Ah! I begin to understand. My father has done
something that has made them hide his existence from me. And you
are going to tell me what it is.”
“I—well, I promised that I would.”
She gave a half-sob.
“You may go on now. I find that I am only the little chimney-
sweeper after all. But stay!” A fresh thought struck her with
overwhelming force. “Perhaps this is some mistake after all. You say
my father is alive, but did you know that my mother had been
married again?”
The captain clenched his fists.
“God forgive me—I can’t tell you!”
“Then—then there is only one explanation, Captain Mauleverer.” She
hid her face in her hands for a minute, and then raised it again and
looked him bravely in the face. “Is that it? Tell me the truth.”
Mauleverer sprang from his seat.
“No, I’m damned if I do!”
A burst of music and a babble of tongues told them that the door
had opened again, and some one else was coming in. It was the
Marchioness of Severn, and she was alone.
Belle rose from her seat dry-eyed.
“Ah, Miss Yorke, they told me I should find you here. That will do,
Gerald. Miss Yorke and I are going to have a little talk. Pray sit down
again.”
Belle resumed her seat in silence, with an inward dread of what was
in store for her next, while Captain Mauleverer walked off with the
hang-dog air of a man who feels he has made a brute of himself.
The marchioness sat down beside her guest.
“I have to thank you for a most delightful evening. You sang most
charmingly. I almost wish I hadn’t asked you for that one called
‘Little Willy,’ though. I am so sensitive. You almost made me cry—
you did, indeed.”
Belle stole a timid glance at her.
“It is very kind of you to praise me so much. That song of mine has
always been a favorite.”
“I don’t wonder at it. Dear, sweet little thing, freezing to death like
that! Why didn’t some one give him a seal-skin jacket? And do you
really sing things like that at those dreadful places in Leicester
Square?”
Belle began to feel uncomfortable. The patronage it was difficult to
resent, but the hinted disparagement roused her courage.
“I am sorry you think them dreadful,” she said, modestly but quite
firmly, “because, you know, I have to sing there for my living.”
The marchioness’s determined good-nature was not to be turned
aside.
“No, no; of course, I ought not to have called them that before you.
But one reads such shocking things about them in the newspapers
when they apply for their licenses to the County Council. I’m sure I
hope it isn’t half of it true.”
“I hope you won’t be offended if I stand up for them,” Belle
persisted, bravely. “I must be loyal to my own profession, mustn’t I?”
“Of course! Of course! Most properly. I hope—in fact, I am sure, that
they have done you no harm. But I have heard so much about these
places, and the life, that it makes me feel the very gravest doubt. I
take an interest in you, Miss Yorke, and I should be so sorry if you
were to lower yourself by your connection with the music-halls.”
Still bleeding from the wound dealt her in all respectful kindness by
the man who had been with her just before, Belle roused herself to
ward off the more envenomed stabs of the woman who was with her
now.
“I don’t intend to lower myself, or to let myself be lowered, by any
place I may go to,” she said, with dignity, looking the marchioness in
the face.
The marchioness smiled on her like a mother.
“That is right. I am so glad to hear you say that. But you can’t be
too careful, you know. The world is so censorious. Society has very
keen ears for the least whisper against a woman’s name.”
This time Belle realized that there was some serious purpose
beneath her persecutor’s moralizing. She turned on her indignantly.
“I hope you don’t mean that society has been listening to any
whispers against my name!” she cried.
The marchioness put out her hands with a soothing gesture.
“Oh, no—not yet, at all events. Still, as I say, you cannot be too
careful in your unfortunate position. I thought I ought to take the
opportunity of giving you a friendly warning. It is so easy to check a
thing of this kind at the outset, but afterwards it may be too late.”
“I am afraid I don’t understand you yet,” said Belle, in a carefully
measured voice which would have betrayed the rising anger to a
duller ear than the Marchioness of Severn’s. “Do you mean to say
that there is anything for me to check?”
The marchioness, becoming slightly nervous, tried to beat about the
bush.
“No, no; I won’t go so far as that. I don’t put it in that way—merely
a possibility, that is all. Of course, it is very natural that the men who
go to such places should admire you, with your voice and figure;
only don’t let one particular man admire you more openly than the
rest. You understand me?”
Belle’s voice became cold and metallic.
“Do you mean that there is some one whose name has been
associated with mine as an admirer more than the rest?”
The marchioness bowed and smiled.
“That is just it. You have put it very nicely.”
“May I ask you to tell me his name?”
The marchioness threw a glance of mild reproach at her young
friend.
“Surely, my dear Miss Yorke, you must know that! Every one tells me
that his attentions have been most marked—Mr. Hammond.”
The marchioness brought out the name with a jerk, watching her
victim keenly the while. But Belle gave her no assurance, by so
much as the flutter of an eyelid, that the shaft had gone home.
“Mr. Hammond’s attentions to me have always been perfectly
respectful.”
The marchioness positively bubbled over with shame at the implied
suggestion that she had thought otherwise.
“Of course! Naturally! But you know, my dear girl, that society will
take a very different view. Society is so incredulous. It never believes
that a man’s friendship for a woman is perfectly respectful.”
“Not when he asks her to become his wife?” Belle could not resist
the question.
“That is quite different.” The marchioness suddenly became the
great lady. “We are not talking of that, as you know. Mr. Hammond is
not one of those foolish young men who marry a girl out of their
own class and regret it ever afterwards. You must put that idea out
of your head at once, believe me. I am speaking as your friend and
as a woman of the world.”
Belle looked at her friend for a moment with a silence that had
something satirical in it.
“What is Mr. Hammond’s class?”
“Don’t you know? Mr. Hammond is a millionaire. He moves in the
very best society. He could marry almost any woman in England,
except royalty. I know dukes, even, who would feel honored by an
alliance with Mr. Hammond.”
All this time it had not occurred to Belle, in her simplicity, that she
could possibly be regarded by the great lady beside her as a rival,
and a dangerous rival, to her own daughter. She only felt that
something very dear to her was at stake, and she wrestled for it
blindly.
“Is that simply because he is rich?” she demanded, with the scorn
which youth always feels for wealth.
“Not entirely,” the marchioness answered, mildly, “though, of course,
that has a great deal to do with it. But Mr. Hammond comes of a
most respectable family, I believe. I have heard that his father was
quite a gentleman towards the end of his life. And then he has a fine
political career before him; he is in Parliament, and may be in the
Cabinet. You can’t expect him to throw all that away to marry you,
my dear.”
Belle began to fear that she was going to be beaten.
“And would he? Would it be such a very great disgrace?” she
murmured below her breath.
“I don’t say that it would,” replied her deeply sympathizing friend;
“but society would consider it so. You see, we can none of us do all
that we like. There are many things that I should like to do, but I
dare not. We all feel inclined to rebel sometimes and gratify our own
inclinations, but we are restrained by a higher law.”
“What higher law is there than the loyal instinct of our own hearts?”
demanded Belle, with a flash of indignation.
“My dear, the prejudices of society! Its feelings must be respected.
We have to mould our lives accordingly.”
“Why? Why should we obey such a code? Why should we cringe to
this bogie you call society? Why should we make ourselves slaves to
one another’s shadows?”
The marchioness drew herself up and regarded her young friend
with real pain.
“Miss Yorke, you quite surprise me. I am shocked to hear you use
such language. Do you realize what you are saying? You called
society a bogie!”
“I was wrong. It is something more.”
“It is true that its dictates sometimes appear harsh and
unreasonable, but that is the same for all of us. Why should you
expect to be an exception to the rule more than others?”
“Shall I tell you?” All the bitterness of her newly acquired knowledge
rang out in Belle’s voice. “Because I am one of the victims of society;
because it placed its brand upon me before ever I was born. Society
has made me an outlaw, and therefore I owe it no allegiance, and I
will give it none. You tell me that because I am a public singer I
have no right to the friendship of an honorable man; that there are
whispers in circulation against my name already. Let them whisper! I
have done with all that. I shall not abandon my friends at society’s
bidding, and I won’t give up the man I love because it tells me—I
won’t do it!”
The marchioness rose, deeply shocked and grieved.
“Really, I can’t stay here—”
Again the sudden loudness of the sounds from the concert-room.
Again the door stood open, and John Hammond in the doorway.
SCENE IX
AND THE PRINCE

The moment she saw who had come into the conservatory the
marchioness sat down again promptly, and with a decision which
spoke volumes for her intention to remain.
Hammond advanced, and recognized the marchioness with a look of
wonder.
“Where is Mauleverer?” he inquired.
“I sent Gerald away,” replied the marchioness, with an intonation
which plainly added: “And I should like to send you away, too.”
“That was considerate of you,” retorted Hammond, with a pleasant
smile.
There was a vacant space on the seat between the two women, and
he took possession of it with a cool deliberateness which appeared
to cause the marchioness some dismay.
“I wanted to have a little private chat with Miss Yorke,” she
observed, stiffly.
“The very thing I wanted, too. You have done me out of my turn,
hasn’t she, Miss Yorke? You are positively quite a cuckoo, my dear
marchioness.”
The marchioness made a painful effort to smile.
“I am not at all sure that I shall allow you to speak to Miss Yorke,”
she responded, trying to look past him at Belle herself.
On Hammond’s entrance Belle had shrunk back with a certain
apprehension which had afforded secret satisfaction to her hostess.
She now waited in silence, nervously plucking at the leaves of a
camellia which brushed her shoulder where she sat.
“Now she is under my roof,” pursued the marchioness, “I feel in the
position of her guardian. I regard you as a very dangerous
character.”
A smile of bitter irony gleamed for a moment on Hammond’s lips.
“I rather think you must be right. I don’t know why it is, but I am
feeling in a peculiarly lawless mood this evening. If Miss Yorke were
not here, I am not at all sure that your diamonds would be safe.”
Something in the manner of this speech, rather than in the words,
caused the marchioness to move several inches farther off along the
settee. It was a distinct shock to her to hear the Severn diamonds
made the subject of coarse jocularity. The one in the centre of her
bosom had been given to the first Mauleverer by King John as a
reward for resisting the agitation for Magna Charta. Those in the
tiara above her forehead had been brought into the family by a left-
handed daughter of John of Gaunt. The value of the whole was
nearly a year’s income of the much-mortgaged Severn estates.
“Really, Mr. Hammond, you speak so strangely that if I didn’t know
you so well I should think something was the matter with you.”
It was necessary to let her ladyship see clearly that she was out of
place. Hammond cast on her a look which she had not seen in his
eyes before.
“Do you know me well? Does any of us know another well? Don’t
we, most of us, drift through life with our eyes half closed, ignorant
of our aims, ignorant of our very natures, till some shock comes to
awaken us, and in the moment of trial we find out for the first time
who and what we really are?”
A subtle instinct told him, before he had finished speaking, that his
words were being eagerly followed by the girl who sat on his right
hand. On the marchioness they fell with something of the effect of a
cold spray. She shivered and got up.
“Ah, yes, of course, all that is very true, no doubt,” she murmured,
hastily. “But I must really be going back to look after the people.”
She turned a feline glance on Belle. “I wouldn’t sit out here too long
if I were you, Miss Yorke; you may catch cold.”
“Thank you; I am not afraid of that,” was the quiet answer.
The marchioness turned her eyes from one to the other, pursed up
her lips with severity, and reluctantly retreated.
Hammond watched her exit with a sarcastic smile.
“I am afraid the marchioness believes I have been drinking,” he
observed.
The cynicism jarred on Belle as harshly as the seriousness had jarred
on the marchioness. There is no woman who can respond to a man
through all his moods, not even she who loves him best.
“I wonder how much truth there is in what you said just now?”
Hammond turned and fixed an earnest gaze on her. He saw her for
the first time in his experience with a troubled brow, but he never
guessed the cause. There is no man who can follow a woman
through all her moods, not even he who loves her best.
“That is what I wanted to ask you,” he said, in answer to her
question. “We two have known each other for some time, haven’t
we; but how much do I know of you, or you of me?”
Belle felt what was coming. She saw it in his eye, she heard it in his
voice. Desperately she resolved to meet it half-way.
“I have been finding that out this evening. Since I have come here I
have understood for the first time what you are and what I am. Mr.
Hammond, after this evening we must not meet again.”
“Belle! Why do you say that?”
There was a note of anguish in his voice. He had been fighting a
battle with himself all this time. It had never occurred to him that
there might be another to overcome besides.
She looked him steadily in the face.
“Why do you call me Belle?”
“I thought we were friends,” he said. But he blushed as he said it.
“What kind of friends? Would your friendship with Lady Victoria allow
you to call her by her Christian name? Don’t you see that the
difference between her and me makes our friendship impossible?”
“Don’t you trust me, then?” asked the man.
“You have no right to ask me for my trust. You and I belong to
different worlds. Where there is no equality there can be no
friendship. It would have been better if we had never met.”
She spoke with a certain rigidity which baffled him. He did not know
that the poor girl was but repeating the bitter lesson which had just
been taught to her.
“But why,” he eagerly demanded—“why should you suddenly take
this tone with me? I was going to ask you for your confidence. I
meant to beg you to let me take your part against your enemies,
and you rebuff me at the outset like this.”
“Have I enemies? I didn’t know that.” She spoke with a pathetic
resignation. She had heard too much within the last half-hour to be
much moved by any new disclosure. “But there is all the more
reason that I should give them no handle against me. Consider what
society is likely to think of such a friendship as ours—you, a public
man, wealthy, ambitious, honored by the world, with a great career
before you, and I a humble singer, whose very calling makes her
name a mark for every spiteful tongue.”
“Why should we be afraid of what society thinks or says?”
“You can afford to ask that. You are a man, and can defy society; I
am a woman, and to me its breath means life or death.”
Hammond sat silent for a minute; he felt that all this conversation
was insincere. It was but the preface to what he had come there to
say. How was he to pave the way for the questions he had resolved
to put?
“Tell me,” he said, earnestly, “have I ever given you cause to think of
me as other than an honorable man?”
Belle turned and looked at him.
“No,” was all she said.
“Will you let me tell you something—something that it may be
painful for you to hear?”
Belle’s eyes opened wide. The apprehension of what was coming
shone out in them, and Hammond, mistaking the meaning of that
apprehension, faltered in his purpose.
“Speak! What is it?” she commanded.
“It is something which concerns yourself.”
Was he going to repeat to her the gossip at which the marchioness
had only hinted, to tell her to her face that their names had been
joined in the world’s calumnious breath? She gazed at him in
absolute bewilderment.
“Tell it me—quickly!” she breathed.
“I am ashamed to repeat such a slander. Yet, since it is in circulation,
it is only right that you should know it, if only that you may cause it
to be crushed.”
“Yes; please go on.”
“They say—they pretend—they connect your name with—”
“With yours, sir?” She sat upright, with flashing eyes.
“Great heavens, no!” He stared back at her with little less
amazement than her own.
She sank slowly down again, the anger in her face changing to
deepest scorn.
“With whose, then?”
“With the Marquis of Severn’s.”
“What!” She started up again in sheer astonishment. “Who dares? I
have never seen nor spoken to him in my life!”
“Thank God!”
Not till he had heard the denial did the man realize what a burden it
had lifted from his heart; and yet he believed that he loyally loved
this woman.
“Who dares to slander me? Who dares to smirch my name with
falsehoods?” Come what might, he should not go away doubting her.
“It was that man Despencer who told me first.”
“And you listened to him—you, an honorable man, and my friend?”
Hammond bowed his head. He thought he could bear her
reproaches now.
“Go on; you can say nothing to me that I have not said already to
myself. I have been a brute, a fool; I know it. I did give him the lie
once, but his words rankled in my mind, and I could not rest till I
had had the charge disproved.”
“If you are satisfied, go.”
Hammond started and shivered. He had not heard that tone before;
he had not seen that deeply resolute expression, in which Belle’s
face was set like stone.
“Oh, not like this! You will forgive me, Belle? You must! This lie has
tortured me far worse than you.”
He might have made the excuse that he had only repeated the
slander for her sake, and not for the satisfaction of his own doubts.
But he scorned to stoop to subterfuge with her.
“Why should I? Your good opinion or your friendship are nothing to
me any longer.”
“My good opinion—friendship! Ah, it is more than that! You know,
you must know, that I have loved you all the time!”
“So much the worse. For you to speak of love to me is only another
insult.”
“I did not mean to insult you,” was the humble answer. “I meant to
offer you the love that a man offers to his betrothed.”
“Does a man cast suspicions on his betrothed?”
“I have not cast suspicions. My worst fault is to have listened to
those of others. There is no love without jealousy.”
“There is no love without perfect trust. If a man really loves a
woman, does he set himself to doubt her, to gather up the malicious
tattle of her enemies, and carry it to her, like an accusing judge, and
ask her to clear herself? Ah, no! If he loves her, he first crushes the
slander and the enemy together, and then comes to tell her what he
has done.”
“Listen to me.”
“Wait! But I cannot expect to be treated like that. My good name is
of no importance to me; I am public property. There would be
nothing to talk about in the club smoking-rooms if we poor singers
were to be respected. It is natural that we should be bad. And so
you come to me and repeat the accusations which you had not the
courage to despise. And that is your love!”
“I implore you—”
“No! With us poor girls it is different. We have not your prudence
and self-restraint. Where we love we do not ask for references. We
give our hearts without reserve, and from the moment we have
given them, instead of searching for stains on the character of the
man we love, we set ourselves to see only the good in him; we shut
our eyes to the evil; we screen his faults; if others attack him, we
defend him; and if the world casts him out, we cling to him all the
more.”
Her voice sank down and ended in a sob. Hammond clasped his
hands together in despair.
“Why did I ever hesitate? I was a coward. I dreaded the idea of
even a whisper being raised against my wife. Forgive me.”
“And you were right. Yes, I forgive you.”
The answer came softly, and the man’s heart was thrilled to the
core.
“And something more,” he pleaded passionately. “Tell me that you
love me like that.”
Belle slowly, gently shook her head.
“No. Why do you make it so hard for me? Leave me, I entreat you.”
Hammond turned faint.
“You do not love me, then?” he gasped.
She gave him a despairing look, and answered passionately:
“No! I don’t love you—I don’t love you!”
He rose up, without another word, and went away from her. The
next instant, as the door closed behind him, Belle sank down on the
seat, like a flower whose stem is broken, and the tears began to
come like rain.
A door at the far end of the conservatory softly opened, and a man
stepped through and came towards her, with his finger on his lips.
It was the Marquis of Severn.
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