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10+1 Chem Organic Chemistry-some basic MM : 45 10+1 Chem Organic Chemistry-some basic MM : 45
Section A (Objective 10 marks) Section A (Objective 10 marks)
Section B (Subjective 35 marks) Section B (Subjective 35 marks)
Section A Section A
1. The IUPAC name for 1. The IUPAC name for

(a) 1 -Chloro-2-mtro-4-methylbenzene (a) 1 -Chloro-2-mtro-4-methylbenzene

(b) 1 -Chloro-4-methyl-2-nitrobenzene (b) 1 -Chloro-4-methyl-2-nitrobenzene
(c) 2-Chloro-1-nitro-5-methylbenzene (c) 2-Chloro-1-nitro-5-methylbenzene
(d) m-Nitro-p-chlorotoluene (d) m-Nitro-p-chlorotoluene
2. Electronegativity of carbon atoms depends upon their state of hybridisation. In 2. Electronegativity of carbon atoms depends upon their state of hybridisation. In
which of the following compounds, the carbon marked with asterisk is most which of the following compounds, the carbon marked with asterisk is most
electronegative? electronegative?
(a) CH3 - CH2 - *CH2 -CH3 . (b) CH3 - *CH = CH - CH3 (a) CH3 - CH2 - *CH2 -CH3 . (b) CH3 - *CH = CH - CH3
(c) CH3-CH2-C=*CH (d) CH3-CH2-CH=*CH2 (c) CH3-CH2-C=*CH (d) CH3-CH2-CH=*CH2
3. Which of the following compounds contain all the carbon atoms in the same 3. Which of the following compounds contain all the carbon atoms in the same
hybridisation state? hybridisation state?
(a) H—C  C—C  C—H (b) CH3—C  C—CH3 (a) H—C  C—C  C—H (b) CH3—C  C—CH3
(c) CH2=C=CH2 (d) CH2=CH—CH=CH2 (c) CH2=C=CH2 (d) CH2=CH—CH=CH2
4. In the organic compound: 4. In the organic compound:
1 2 3 4 5 6 1 2 3 4 5 6
C H2= C H— C H2— C H2— C  C H, the pair of hybridised orbitals involved in the C H2= C H— C H2— C H2— C  C H, the pair of hybridised orbitals involved in the
formation of C2—C3 bond is: formation of C2—C3 bond is:
(a) sp - sp2 (b) sp - sp3 (c) sp2-sp3 (d) sp3-sp3 (a) sp - sp2 (b) sp - sp3 (c) sp2-sp3 (d) sp3-sp3
5. In the Lassaigne’s test for nitrogen in an organic compound, the Prussian blue 5. In the Lassaigne’s test for nitrogen in an organic compound, the Prussian blue
colour is obtained due to the formation of: colour is obtained due to the formation of:
(a) Na4[Fe(CN)6] (b) Fe4[Fe(CN)6]3 (a) Na4[Fe(CN)6] (b) Fe4[Fe(CN)6]3
(c) Fe2[Fe(CN)6] (d) Fe3[Fe(CN)6]4 (c) Fe2[Fe(CN)6] (d) Fe3[Fe(CN)6]4
6. Which of the following carbocation is most stable? 6. Which of the following carbocation is most stable?
   
(a) (CH3)3C· C H2 (b) (CH3 )3 C (a) (CH3)3C· C H2 (b) (CH3 )3 C
   
(c) CH3CH2 C H2 (d) CH3 C HCH2CH3 (c) CH3CH2 C H2 (d) CH3 C HCH2CH3
7. The best and latest technique for isolation, purification and separation of organic 7. The best and latest technique for isolation, purification and separation of organic
compounds is: compounds is:
(a) Crystallisation (b) Distillation (a) Crystallisation (b) Distillation
(c) Sublimation (d) Chromatography (c) Sublimation (d) Chromatography
8. The reaction: CH3CH2I + KOH(aq)  CH3CH2OH + KI is classified as: 8. The reaction: CH3CH2I + KOH(aq)  CH3CH2OH + KI is classified as:
(a) electrophilic substitution (b) nucleophitic substitution (a) electrophilic substitution (b) nucleophitic substitution
(c) elimination (d) addition. (c) elimination (d) addition.

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9. Assertion (A): Components of a mixture of red and blue inks can be separated by 9. Assertion (A): Components of a mixture of red and blue inks can be separated by
distributing the components between stationary and mobile phases in paper distributing the components between stationary and mobile phases in paper
chromatography. chromatography.
Reason (R): The coloured components of inks migrate at different rates because Reason (R): The coloured components of inks migrate at different rates because
paper selectively retains different components according to the difference in their paper selectively retains different components according to the difference in their
partition between the two phases. partition between the two phases.
10. Assertion (A): Lassaigne’s test is not shown by diazonium salts. 10. Assertion (A): Lassaigne’s test is not shown by diazonium salts.
Reason (R): Diazonium salte lose N2 on heating much before they react with fused Reason (R): Diazonium salte lose N2 on heating much before they react with fused
Na metal. Na metal.
Subjective Subjective
1. Explain the terms inductive and electromeric effects. Which electron 1. Explain the terms inductive and electromeric effects. Which electron
displacement effect explains the following correct orders of acidity of the displacement effect explains the following correct orders of acidity of the
carboxylic acids? [4] carboxylic acids? [4]
(a) CI3CCOOH> CI2CHCOOH > CICHCOOH (a) CI3CCOOH> CI2CHCOOH > CICHCOOH
(b) CH3CH2COOH > (CH3)2CHCOOH > (CH3)3C.COOH (b) CH3CH2COOH > (CH3)2CHCOOH > (CH3)3C.COOH
2. What is hyper conjugation? Give hyperconjugating structures of the 2. What is hyper conjugation? Give hyperconjugating structures of the
   
following: (a) CH3  C H2 (b) CH3  C H2 (c) CH3  CH  CH2 following: (a) CH3  C H2 (b) CH3  C H2 (c) CH3  CH  CH2
(1+2+2+2) (1+2+2+2)
3. What is the resonance effect. Give +R and –R effect by giving example. [3] 3. What is the resonance effect. Give +R and –R effect by giving example. [3]
4. Explain stability of carbocations, free radicals and carbanions [1º, 2 º, 3 º] 4. Explain stability of carbocations, free radicals and carbanions [1º, 2 º, 3 º]
[3+3+3] [3+3+3]
5. What is homolytic fission. Differentiate nucleophile & electrophile. [2+2] 5. What is homolytic fission. Differentiate nucleophile & electrophile. [2+2]
6. Explain structure and formation of carbanion. [3] 6. Explain structure and formation of carbanion. [3]
7. What is isomerism? Explain metamerism. [3] 7. What is isomerism? Explain metamerism. [3]
8. On complete combustion, 0.246 g of an organic compound gave 0.198 g 8. On complete combustion, 0.246 g of an organic compound gave 0.198 g
of carbon dioxide and 0.1014 g of water. Determine the percentage of carbon dioxide and 0.1014 g of water. Determine the percentage
composition of carbon and hydrogen in the compound. [2] composition of carbon and hydrogen in the compound. [2]

9. What is the difference between distillation, under reduced pressure and 9. What is the difference between distillation, under reduced pressure and
steam distillation? [2] steam distillation? [2]
10. In Dumas' method for estimation of nitrogen, 0.3g of an organic compound gave 10. In Dumas' method for estimation of nitrogen, 0.3g of an organic compound gave
50mL of nitrogen collected at 300 K temperature and 715 mm pressure. 50mL of nitrogen collected at 300 K temperature and 715 mm pressure.
Calculate the percentage composition of nitrogen in the compound. (Aqueous Calculate the percentage composition of nitrogen in the compound. (Aqueous
tension at 300 K=15 mm)? [2] tension at 300 K=15 mm)? [2]
11. During estimation of nitrogen present in an organic compound by Kjeldahl's 11. During estimation of nitrogen present in an organic compound by Kjeldahl's
method, the ammonia evolved from 0.5 g of the compound in Kjeldahl's method, the ammonia evolved from 0.5 g of the compound in Kjeldahl's
estimation of nitrogen neutralized 10 mL of 1M H2SO4. Find out the percentage estimation of nitrogen neutralized 10 mL of 1M H2SO4. Find out the percentage
of nitrogen in the compound. [2] of nitrogen in the compound. [2]
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10+1 Chem. Organic Chemistry-some basic MM : 33 7.
Answers Key
Objective
1. (b)
2. (c)
3. (a) and (d)
4.

8.

5.

6.

9. (a)
10. (a)

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Subjective
1.

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2.

9 10
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3.

11 12
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4.

13 14
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5.

15 16
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6.

7.

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8. Percentage of carbon = 12 x 0.198 x 100 = 21.95%

44 x 0.246
Percentage of hydrogen = 2 x 0.1014 x 100 = 4.58%
18 0.246
9.

10. Volume of nitrogen collected at 300K and 715mm pressure is 50 mL

Actual pressure = 715 - 15 = 700 mm
Volume of nitrogen at STP = 273 x 700 x 50 = 41.9 mL
300 760
22,400 mL of N2 at STP weighs = 28 g
41.9 mL of nitrogen weighs = 28 x 41.9 g
22400
Percentage of nitrogen = 28 x 41.9 x 100 = 17.46%
22400 x 0.3

11. 1 M of 10 mL H2SO4 =1M of 20 mL NH3

1000 mL of 1M ammonia contains 14 g nitrogen
20 mL of 1M ammonia contains 14 x 20 g nitrogen
1000

Percentage of nitrogen = 14 x 20 x 100 = 56.0%

1000 x 0.5

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