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1 6 lle-binodal-MMIC

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18 views5 pages

1 6 lle-binodal-MMIC

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15.koli.siddhi.dmce
Copyright
© © All Rights Reserved
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EXPT. NO.

: 6 DATE:
LIQUID – LIQUID EXTRACTION
(Miscible Solvents)

Aim : To prepare the ternary phase diagram of Binodal curve and tie line
relationship for ternary system.
Apparatus : Burette, pipette, conical flask, beaker, separating funnel.
Chemicals : Chloroform, Acetic acid, 0.1 N NaOH, Phenolphthalein.
System used : Water- Chloroform-acetic acid
Theory : The separation of compounds of liquid mixture by treatment with solvents in
which one or more compounds are preferably soluble is known as Liquid-Liquid Extraction.
It is complementary to distillation and two methods together unable almost all separation to
be achieved. The overall process of :-
1) To bring the solvent and solute in intimate contact
2) Separation of resulting two phases
The formation of new mixtures can be shown on the bimodal curve. This represents
two phases region which will split into two layers in equilibrium with each other. The
composition of this layer can be represented by tie line PQ and point F on bimodal curve
represented as a single phase known as plait point.

Procedure : 1) Add 2 cc of chloroform to 10 cc of water in a conical flask which is


immiscible in water.
2) Add slowly acetic acid to the flask through burette till homogeneous phase is
obtained.
3) 2 cc of chloroform is added to the same flask and titrate against acetic acid to
obtain homogeneous phase.

4) Same procedure is repeated till 10 cc chloroform is added to the flask.


5) Take 10 cc chloroform in the flask and add 2 cc of water to this. Treat this
mixture against acetic acid through burette to get the homogeneous phase.
6) Add 20 cc of water to this and titrate against acetic acid. Repeate this procedure
till 10 cc is added to the flask.
7)
Procedure for tie- line:
1) Add 20 ml water and 10 ml chloroform to the homogeneous phase.
2) So that the mixture contains 30 ml of water 20 ml of chloroform and x ml( Burette
reading) acetic acid.
3) Allow to settle in the separating funnel for 15 minutes and then separate the layers.
4) Measure the volumes and weight of the layers.
5) Titrate 10 ml of each layer against 1N NaOH.

Observation :
Density of acetic acid = 1.038 gm/cc
Density of water = 1 gm/cc
Density of Chloroform = 1.4 gm/cc

Observation Table:
Phase 1
CHLOROFORM WATER ACETIC ACID

Phase 1(Weight% calculation)


Weight% CHLOROFORM Weight% WATER Weight% ACETIC ACID
Phase 2
CHLOROFORM WATER ACETIC ACID

Phase 2(Weight% calculation)


Weight% CHLOROFORM Weight% WATER Weight% ACETIC ACID
Volume (ml) Weight (gm) Weight %

H2 O CHCl3 AA H2 O CHCl3 AA H2 O CHCl3 AA

Calculations :
Weight % of acetic acid in water layer (Extract)
N1V1 = N2V2
Where N2= Normality of NaOH
V2= Volume of NaOH (Burette reading)
V1= Volume of extract
 gm of acetic acid in extract (W1) = N1x Eq.wt. x Vol. of extract / 1000
Weight % of acetic acid in extract = (W1x WE) x100
Same procedure is repeated to calculate wt% acetic acid in raffinate.

Result : Binodal curve is obtained as shown. The concentration of acetic acid in extract
and raffnate is calculated and tie line is drawn.

Plot :

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