.

fo rNEET
Pllysicol ChemistrY~ -- -=
- -:-:-~ -= -- - -=-- -

[ evel(l) 'Objective Problems

A revers ible reacti on i_s on~ wh
ich : (b) Pro cee ds in bo th direction
1. (a) Procee ds in on e direction s
ous (d) All the sta tem en ts are
(c) Pro cee ds spontane ly wr
f the reaction 0
ng
2. The equilibrium constant Kc
or p 4 (g) ~ 2P2(g)
·
is 1.4 at 400 oc • sup pose tha
les of p (g) an d 2 mo les of
t 3 mo 4 Pi( g) are rn·
.
container at 400°C. What is th alue of rea cti on qu oti en t (Q J?
.
IJ{ed 1·
ev ni
3 (b) 2
-
(a) - (c) 1 (d) None oft~.
3
2 . . uil "~
3. In a cheffilcal reaction eq ibrium is established wh en :
(a) Opposing rea.:tion ceases
(b) Concentrations of reacta
nts and product are eq ua1
(c) Ve1oc1•ty of opposm · g reaction is the same as tha .
t of for wa rd reaction
(d) Reaction ceases to genera
te heat
4. The equilibrium constant for
a rea qio n is K, an d the rea
cti on qu oti en t is Q. For a P .
reaction mixture the ratio K
is 0.33. This me an s tha t :
' Q
(a) the reaction mixture will
equilibrate to form mo re rea
(b) the reaction mixture wil cta nt species
l equilibrate to form mo re pro
(c) the equilibrium ratio of rea du ct species
ctant to pro du ct co nc en tra tio
(d) the equilibrium ratio of rea ns will be 3
ctant to pro du ct co nc en tra tio
5. Consider the reaction 2S0 (g) ns will be 0.33
2 + 0 2 (g) ~ 2S 0 (g) for wh ich
each of the reagents S0 (g) , 3 K, = 278 M- 1. 0.001 ir,
2 0 (g) and S0 (g) are mi xe d
reaction quotient of the system 2 3 in a 1.0 L flask. Dete nniri
and the spo nta ne ou s dir ect
(a) Q c = 1000; the equilibrium ion of the system :
shifts to the rig ht
Cb) Q c = 1000; the equilibritl
II\, shifts 'to the left
(c) Q, =0 .001; the equilibriu
m shifts to the left
(d) Q c = 0.001 ; the equilibriu
m shifts to the rig ht
6
• In Q._No. 5, if th e mixture of
gases was allowed to co me
rea ~o n vess~l was then rapidl to equilibrium. The vo\~ d
reaction quotient (Q, ) would y inc rea sed by a fac tor of tw o As a result of the
: · ·
chani
(a) increase because of the pre
(b ) ssur d
decrease because of the pressu e ecrease
(c) rem . r d
ain the same because the e ecrease
(d) increase because th .. .
. · · ~quilibnum co ns tan t is
. e reacuon is en do the rm ic ind ep en de nt of volurne
7• For the reaction A(g) + B(g
3 ) ~ '
are present in 2 litr 2 r#' '
C(g) at 2 7°C , 2 mo les of A,
e 4 moles of B and 6 .
(a) forward directionvessel. If K for th . . .
' e rea cti on is 1.2 , the rea cti __, C,·
(c) neither direction on wil l pfOCT'- ~
Cb) ba ck wa rd direction
(d) no ne of these
 EQUILIBRIUM-I : CHEMICAL EQUILIBRIUM
1 at equilibrium, if s?mc moles of H are
, 111 •'" ' hi<' ~,.. ,,o u• reuctiou N 2 3H.' .? 2NII '. 2 not
1 " ""'' 1111111her of mo b of 1 i ( r 1s trluum , isotope of Hand assume is/Jtopes do
ll1' "I ,, er parameters, theo : ·
0 , " "' d wmlml properrles ) without affecting oth
111"
1 •;111 , e.
• ~ , ""n,pic ,,f ammonia obt
ulnecl after sometime will he radioactiv
nge wil l be differe nt ns com pared to moles of. N present before
,~J ~a ,~., r>f N 1.. nfte
r~l •• r the cha 2
tlWch,rngc
v:-i lttt of K 1, or K < will cha
nw nge
11
will be same as that of old equilibrium
~
e mo lec ula r mass of new equilibrium
' n,e :ivcrag
2NH 3 in the Haber's process, the
:: ,he <)'lllhesis of ammonia by the reaction N 2 + 3H 2
predicted by the curve
f. 3(1[1·fnmenr of equilibrium is correctly
f f
j C
.Q
~: ...
(il) §~ - - - -N z (b) ~
~ fj 2
g ,,. .-- --N H3 C
8
tim e- tim e-

f f NH 3
C:
NH 3
N2
• H2
~
0
... :;:;
(c) cS
~E C:
(d) ~
N2
H2 ::E u
~ ?J C

e 8
tim e-
ijme ...

. re shows the change in concentrat

10, The f igu
· ·cies A and
ion of spe t 0.4 M
B

. A( ) _.\,. 2B( g) 5 0.3 M ---- -- ---- ---- -

/3 ru; :J function of time. reaction g ~ :;:;
t K for the !!!
The equilibrium co 115 tan ' c0.2M
iB: ~
(a) Kc > 1 (b) K < l 8 0.1 M ---- =-A

(c:) K = 1
(d) data insufficien~
Tim e-
. .
. 'brium A(g ) ~ 2C (g) + B(g ) gavne the
the equil1 t pt1·o n (% diss ociatio = fraction d1ssoc1ated xlOO)
11. Attainme nt of
. graph · Find the cor rec o
·
following 10 ........................
A
8 ................
j !

Concentration
........ ci;
(mole/lltre) 4
2

t = 5sec time ~
 u11 ..\! 1 , ~, { ·in tl!ht: 1n 11 hi-, ha n f('~•dlN I Mid 'K , 4() fl'l'lul/l ftrn),
I},\ \ 1 . ' ~.~, ,~~111h h111ml 1111c h(\f fl ll'a chrd And di~~{)("iM ion
fl/n 11 I~ . nr
,1' ,1\1 r t. ~•, i:.' 4111 J,~r 11 rt1 h1t~ l"rtv-n rrrlr hf"cl i,nd % d 1v,, w1-1riot1 r,f" • ~c~
,. , I' .l(')t,
l, 1 "'l:♦1) 1 1 · l'' t h(l{' . I

tJ ~h.'lfif n 1f"",l:--, 1 ,...-, 1w f"ni1 1 nr- n, wlrn t ;~ thr unit n( I< , for th" renct i,rn?
CII ,O H(~) ~ CO( t) , 2 H J (.({ )
( () ,\,1 '
(clJ M
13 . WhrH l, the t'l n•l c,1 >,. I fnr 1hr 1r,H t1« Hl ?
C~ i <~ ) 4 4H ; (&) ~ CH ,.(g) I 2 H ;zS(g)
2
\ ;, <' 1 m a rm Ih )
( C) l1 trn J. ( d J atrn ,

t 4 . \\~:in. :, t h<" Np1t lih,nnn c-xpn-~1on for the reaction P 4 (s) + S0 2 ( g) ~ p4 o rsJ
11
t,d ;.. 10: f (b) K c = [P4O 10 J I S[P, ](0 2 )
5
1C 1 #-. rr.,O,r l IPdl/0 :, J~ (d ) Kc= l / [O 2]
I Si., '\1 ,2--c. rhr ce3mon give n below has K , =4
1 3
NH 3 ( g) ~ - N 2 ( g) + - H 2(g)
2 2
\l\ "hat J.." tht" >,;. r for the reaction?
N 2 ( g) + 3H 2 (g) ~ 2NH 3 (g)

( ~' lo ). ( 800 R) l (b) (BOOR )-2 (c) ( 1 ~ ]2 (d) None of these

4 4 x BOOR
J6 . The eq uilibrium constant for the reaction N 2 (g) + 0 2 (g) ~ 2NO(g) at temperature (n J

4 >- JO -,; The val ue of K c for the reaction NO(g) ~ _! N 2(g) + . !.o 2(g) at the ~
2 2
tempt'rntt.ire 1s :
(a J 4 ,, .JO-'l (b) S0 (c)2.S x l0 2 (d)0.02
t 7. The equilibrium constant K r for the following reaction at 842°C is 7.90 x 10 - 3 . What is K~li
~am,e temperarure?

5 (b) 8 .26 10 -4 (c) 7.90 x lo - 2 2

(aJ 8.64 ,, 10 x (d) 7.S6 x 10 -
18. Th.: equ ilibrium consume KP for the following reaction at 19 1°c is 1.24 . What is K,?

B( s) ·I i F~(g) ~ BF3 ( g)

( <it) 6.7 (b) 0 .6 1 ( c) 8.30

(d) 7.6
19 . l•r) r 1h1: e.q u1Hbn urn SO ;iCl 2 (g) ~ SO 2 ( g) + Cl 2 ( g ), what is the temperature at which
K 1, <atrn)
. 'j 'I
Kl (M)
( 11 I U.0 2 7 K ( IJ) O.'U) K ( c) J6.5 4 r<
(d) 273 K
t(\. t\."ll th,(" tl'\'t'TI;1hk l'C'~Cl lt)I\,
'\ ;(S) • 3H :-l ,t ) ¢ 2Nl l _1(.R)
in 5:{'0'X ', rhe Vi\luc of "- r Ls I.•~ " I O \ when pnrtln
l prc5!l llrc is mens ured in atmos phere.,;. The
1
1.". C'l1~sr".1ndin~ ,·alu(' ~f #( with conce ntration In mole lirrc , Is:
2
t a) 1 +4 x 10 !- ,, o.082 '< 500) ') (b) 1.44 "' JO 5 /(83 14 ,t( 773)

le) 1.44, 10 ~ l 0.082 , n 3)

2 (ti) 1.44 y 10 c;/( 0.082 x 773) - 2
K .
of - ' 1s equal to :
2 1. fur the rencrion CO(.~) + Cl 2 (g) ~ COCI 2 ( g) the volue
KP
1
(a) , RT (b) RT (c) - (d) 1.0
RT
included in the expression of
:n. The conce ntrati on of a pure solid or liquid phase is not
equilibrium const ant becau se :
ities.
(a) density of solid and liquid are indep enden t of their quant
(b) solids and liquids react slowly.
us phase.
(c) solids and liquids at equilibrium do not intera ct with gaseo
gaseous phase.
(d) the molecules of solids and liquids canno t migrate to the
23. A catalyst is a substance which :
(a) increases the equilibrium concentration of the product.
(b) chang es the equilibrium const ant of the reaction.
(c) shon ens the time to reach equilibrium . ,.
(d) supplies energ y to the reaction.
temp eratu re, if the reaction
24.What will be the effect on the equilibrium const ant on increasing
neith er absorbs heat nor releases heat?
(a) Equilibrium const ant will rema in constant.
(b) Equilibrium const ant will decrease.
(c) Equilibrium const ant will increase.
(d) Can not be predicted.
~ 2NO( g) is 4 x 10 -4 at 200 K. In
25. The equilibrium constant for the reaction N 2 (g) + 0 2 (g)
. Therefore, the equilibrium
presence of a catalyst, equilibrium is attain ed ten times faster
const ant in presence of the catalyst at 200 K is :
(a) 40 .X lQ-4 o (b) 4 X 10-4

(C) 4 X 10 -
3 (d) difficult to comp ute witho ut more data
const ant changes with :
26. For the react ion H 2 (g) + l 2 (g) ~ 2HI(g), the equilibrium
(a) total pressure (b) catalyst
(c) conce ntrati on of H 2 and 12 (d) temp eratu re
27. Consider the reactions
(i) 2CO(g) + 2H 2 O(g) ~ 2CO 2 (g) + 2H 2 (g) ; Eqm. Cons
tant = K 1

(ji) CH ( g) + H 2 O(g) ~ CO(g) + 3H 2 (g); Eqm. Cons

tant = K 2
4
 ltr, M• I .,, .,_ ., for NIIT

ftil) CH 4(g} 2H,O(g) ~ C0 7(g) + 4H 2' g) ; Eqm. Constant =K1

i.

Wl11<:h of the follo wing rclatjo11 i~ correct?

(t1) 1( 7.
KI
(b) K 1 Kf (C) K K l K2 (d) K
3 :: ff-1 .11
_ :. 1 :::
l K, Ki 1\2
1
28. For the reaction 2NO2 ( g) + 2 0 2(g) ~ NzOs(g), if the equilJbrium constant is K th..
p' " ltij
equ,hbrtum consuint for the reaction 2N zOs( g) ~ 4N0
2(g) + Oz(g) would be :
(a } K2
2 1 , (d 1
(b) - (c) - 2 ) r;;-
r KP KP ...;KP
29. The equilibrium constant (K,) for the reaction
2HCl(g) ~ H 2(g) + C1 z(g)
is 4 >' 1O-:l-4 at 25·-c . What is the equilibrium constant
for the reaction?

IHz (g) + Iaz( g) ~ HCl(g)

2 2
(a) 2 / 10 - 17 (b) 2.5 x 10 33 (c) s'x IO 6
(d) None of these
30. Ar a cenain temperature, the following reactions
have the equilibrium constants as sbmt!l
below:
S(.s) + 0 2 (g) ~ S0 2 (g); KC =5 X 10 52
2S(s) + 30 2( g) ~ 2S0 (g); K, = 10 29
3
What ls the equilibrium constant K, for the reaction at the
same temperature ?
2SO z(g) + Oz(g) ~ 2S0 3(g)
(a; 25 /10 7~ (b) 4 /10 23
(c) 4 x 10 - 77 (d) None of these
31. Ctmsider rhr fol k,wing gaseous equilibria given
below:
OJ N:t . ,. 3H2 ~ 2NH3 ; Eqm. Cons tant = K
1
WJ ~J t + 0 2 ~ 2NO ; Eqm. Constant = K;
1
am H2 + 20:t .= H:P ; Eqm. Constant = K3

Tht equilibriu m etmHtanl for the reac:tion 2NH - + ~ 0 -

' J ~
..- 2NO + 3H 2 O m
· terms ofK , K
2 2 ·
1 2
,:1.nd K ·; will be :
K, K2
(b) --- - K K2
(c) _ 1 _3 (d) K2 K 33
K3 K2 K
32~ In th£ rtactic;n X( g)
, 10 r • Y( gJ ~ 2 Z( g), 2 mole of X 1 mole of Yand I J fl
e o Z are placed !II
I ' ·
;i tllc and a 1lt1vted
(/tt,t VJ reach equilibrium, If final conc entra tionmo
of z ·
for th,; zjvt:'n rea,11,m i.s : th K
IS 0.2 M, en c
(1iJ LfJJ (b) 80 (c) 16
3 3 (d) None of these
 EQUILIBRIUM-I : CHEMICAL EQUILIIRI 291
All equilibrium mixtu re of the reactio n 2 H S( ) ~
59, mole H2 and 0.4 mole Sz in one litre vess:l ~h~ 2H 2(g) + S2(g) had 0.5
mole 1-1 2S, 0.10
litre - 1 is : . e value of equilibrium constant (K) in mol
(a) o.004 (b) 0.008 (c) 0 .
016
, [H2]= 0.10M [H S]==0 20M d (d) 0.160
o .. , Given [CS2] =0.12 0M
'
2 · an [CH ] - 840 10 -5 M for the
;,If •
following reactio n at 900°C, at eq. Calculat th . . . 4 - • X
e e eqmhb num constant (K ) •
cs 2 (g) + 4H2(g) ~ CH4(g) + 2H2S{g) C

(a) 0.0120 (b) 0.0980 (c)

0 ·280 (d) 0.120
·1·b · ing reac • .
The eqm 1 num consta nt for the follow
35 · has [CO]= 0.250 M and [H ] -0 M Wh _non is l0. 5 at 500 K. A system at equilibrium
2 - · 120 • at 1s the [CH 3OH]?
CO(g) + 2H 2(g) ~ CH 3OH(g)
3618 . Cb) 0.0435 (c) 0.546 (d) 0.0499
(a) 0.0
t d ·· ·
36• When sulphu r (m the form of S a) is he a e at temperature T, at eqmhb num, the pressure of S 8
0
falls by 301/o from 1.0 atm, becaus e S 8 (g) is partially converted into S 2(g).
Find the value of KP for this reaction.
(a) 2.96 (b) 6.14 (c) 204.8 (d) None of these
till the following
37, 9.2 grams of N 20 4 (g) is taken in a closed one litre vessel and heated
equilibrium is reache d N 20 4(g) ~ 2NO 2(g)
(in mol litre - 1 )
At equilibrium, 50% N 20 4 (g) is dissociated. What is the equilibrium constant
(molecular weigh t of N 20 4 = 92)
(a) 0.1 (b) 0.4 (c) 0.2 (d) 2
(one litre), partially
38. Two moles of NH 3 when put into a previously evacuated vessel
the equilibrium
dissociated into N 2 and H 2. If at equilibrium one mole of NH 3 is present,
consta nt is :
2 (b) 27/ 64 mol 2 litre - 2 (c) 27/ 32 mol 2litre - 2 (d) 27/ 16 mol 2 litre - 2
(a) 3/4 mol 2litre -
up is governed by
39. In the presen ce of excess of anhydrous SrCl 2, the amoun t of water taken
KP = l O12 atm -4 for the following reaction at 273 K
SrC1 2 ·2H 2O(s) + 4H 2O(g) ~ SrC1 2-·6H 2O(s)
that contai ns
What is equili brium vapou r pressu re (in torr) of water in a closed vessel
SrC1 2 ·2H 2O(s)?
3
(b) 10 torr (c) 0.76 torr
0 (d) 1.31 torr
(a) 0.001 torr 2 the vapour pressure
40. CuSO 4 . SH 2O(s) ~ CuSO 4 -3H 2O(s) + 2H 2O(g); KP = 4 x 10-4 atm . If
data at constant
of water is 38 torr then percentage of relative humidity is : (Assume all
tempe rature )
(a) 4 (b) 10 (c) 40 (d) None of these

41. NH 4 HS(s) ~ NH3(g) + H2S{g)

The equilibrium pressure at 25°C is 0.660 ann. What is KP for the reaction?
(a) 0.109 (b) 0.218 (c) 1.89 (d) 2.18
 •uaR1uM-1 : CHEMICAL EOIIIUIRIUI 2'1
::,.~.....
~-~-~-...-----....,,;.,...:,_E-.QU
. . ·iun1 mixture of the reaction 2H 2S(g) ~ 21-I (
,q1ll111)l . . ~ 2 g) + s2(g) h d Os
,,,1 l ., d o.4 mole S 2 m one litre vessel The v a · mole H 2S, 0.10
11 , ·' 0 · 1a ue ofequ1·1·b ·
111111c' i i~ : 1 num constant (I() in mol
w·o oo4 Cb) 0.008 (c) 0.016
(~. lCS -, ] == 0.120M,[ H2] = 0.lOM, [H2S]=0 20M d (d) 0.160
Given - . o • an [CH4] =8 40 x 10 -s M t
;. ·ng reacnon at 900 C, at eq. Calculate the equ'l'b . · or the
11 mun constant (K )
ro11ow1
CS2(g)+ 4Hi(g) ~ CH4(g)+2H2SCg) C.

(a) 0.0120 . (b) 0.0980 (c) 0.280 (d) 0.120

"'he equilibnum constant for the following reaction is lO.S t 500 K .. .
"'·
1 o 250 M d [H ] o 12 a · A system at equihbnum
>' has [CO] == · an 2 = · 0 M. What is the [CH 30H]?
CO(g) + 2H2(g) ~ CH30H(g)
(a) o.03618 . (b) 0.0435 (c) 0.546 (d) 0 _0499
.,, When sulphur (m the form of S 8 ) is heated at temperatu re r., at equilibn·um, the pressure of S8
111
falls by 30% from 1.0 atm, because S8 (g) is partially converted into s 2(g).
Find the value of K P for this reaction.
(a) 2.96 (b) 6 .14 (c) 204.8 (d) None of these
37. 9.2 grams of N 20 4 (g) is taken in a closed one litre vessel and heated till the following
equilibrium is reached N 20 4 (g) ~2N0 2(g) ~
1
At equilibrium , 50% N 20 4(g) is dissociated . What is the equilibrium constant (in mol litre - )
(molecular weight of N 20 4 = 92)
(a) 0.1 (b) 0.4 (c) 0.2 (d) 2
38. Two moles of NH 3 when put into a previously evacuated vessel (one litre), partially
dissociated into N 2 and H 2. If at equilibrium one mole of NH 3 is present, the equilibrium
constant is : 2
2 2 2
(b) 27/ 64 mol 2litre - (c) 27/ 32 mol litre - (d) 27/ 16 mol litre -
2
(a) 3/ 4 mol 2litre - 2
39, ln the presence of excess of anhydrous SrCl 2, the amount of water taken up is governed by
KP = 10 12 atm -4 for the following reaction at 273 K
SrCl 2 · 2H 20(s) + 4H 20(g) ~ SrCl 2 · 6H 20(s)
What is equilibriu m vapour pressure (in torr) of water in a closed vessel that contains
()

SrC1 2 ·2H 20(s)?

(a) 0.001 torr (b) 10 3 torr (c) 0.76 torr (d) 1.31 torr
2
40, CuSO · SH 0(s) ~ CuSO 4 -3H 20(s) + 2H 2 0(g); KP = 4 x 10-4 atrn . lf the vapour pressure
4 2
of water is 38 torr then percentage of relative humidity is : (Assume all data at constant
temperatu re)
(a) 4 (b) 10 (c) 40 (d) None of these

41. NH 4 HS(s) ~ NH3(g) + H 2S(g)

The equilibriu m pressure at 25°C is 0.660 atrn. What is KP for the reaction?
(a) _ (b) 0.218 (c) 1.89 (d) 2.18
0 109
 42. For the reaction 2A(g) ~ . B(g) + 3C( g), at a given tempera ture, ~ c _::: 16. What ~
volume of the flask, if a nuxture of 2 mole each of A, B and C exist 10 equJJ·b 1
. lllUst be
1 I rturn? t~
(a) - (b) -2 (c) 1 (d) None of h
4 t ese
43. One mole of pure ethyl alcohol was treated with one mole of pure aceti .
·i·b • . . um coc acid at 25'(
The eqmhbri
One-thir d of the acid changes into ester at equi I num. • ~~mf
reaction will be : or t~(
(a) _! (b) 2 (c) 3 (d) 4
4
44. I 2 ( aq) + 1- ( aq) ~ 1- ( aq). We started with 1 mole of I 2 and 0.5 mole of in one~ r
J'
~
3
After equilibri um is reached, excess of AgNO 3 gave 0.25 mole of yellow preci .
P11ati
. . :
Equ il1'b num constant 1s
(a) 1.33 (b) 2.66 (c) 2.0 (d) 3.0
45. At 8rc, the following equilibrium is establish ed.
H 2 (g) + S(s) ~ H 2S(g); Kc =0.08

If 0.3 mole Wdroge n and 2 mole sulphur are heated to 87°C in a 2 L vessel, what will be thi
concentr ation of H 2S at equilibrium?
(a) 0.011 M (b) 0.022 M (c) Q.044 M (d) 0.08 M
46. In the equilibrium 2S0i(g) + 0 2 (g) ~ 2S0ig) , the partial pressure of SO 2 ,0 2 and so,
are 0.662, 0.10 and 0.331 atm respectively. What should be the partial pressure of oxygen ;
that the equilibrium concentr ations of SO 2 and SO 3 are equal?
(a) 0.4 atm (b) 1.0 atm (c) 0.8 atm (d) 0.25 attn
4 7. When heated, ammoni um carbama te decompo ses as follows :
NH 4 COONH i(s) ~ 2NH 3 (g) + C0 2 (g)
At a certain tempera ture, the equilibri um pressure of the system is 0.318 atm. KP for thi
reaction is :
(a) 0.128 (b) 0.426 (c) 4.76 x 10 - 3 (d) None of these

48. In a system A(s) ~ 2B(g) + 3C(g), if the con~entration of Cat equilibr ium is increased by,
factor of 2, it will cause the equilibri um concentr ation of B to change to :
(a) two times the original value (b) one half of its original value

(c) 2✓2 times to the original value (d)

2
,1 times the original value

49. A +B ~ C + D. If initially the concentr ation of A and B are both ;qual but at equilibriun
conc~ntration of D will be twice of that of A then what will be the equilibr ium constant o
react10n ?
4 9 1
(a) 9 (b) 4 (c) 9 (d) 4
so. The equilibrium constant K , for the reaction S0 2 (g) + N0 2 (g) ~ SO is 16. If
mole of each of all the four gases is taken in 1 dm vessel, thee ·i 1·b . Cg) + NO(g). (NC
3 3

would be : qui num concentration °

(a) 0 .4 M (b) 0 .6 M (c) 1.4 M
(d) 1.6 M
 .
_.,...____~-=---'. !
•~ ~,
ou u~• 1!
!!!1~U,M!1•
1 : CNIMICA1 IOU u ' ..,.. ,.,
A s q~~

tt' ll\ P('l'0 t H1 't' • t lw

rn rl' n1· 11 , rue, I
) i1 t-' " " '~11 •~ tht' nu :
J , 1 t'S
' • \ tlW ,l\ ~ l lll' l'\' /lS
\ ;'\ '
t~' .,1w1, ~ , k r t\~ lSt'~
th en d l'l 'l\ !ll St 'S
td fo ~r inct't' ~l~'t'S :md n
.'t' rt'HSt' dt'f}l'nlll ~ upo 11 th e n11111 r 0 f ' Ii t• 1t•111·1lo11
t,ll m11_, inl.'l'\': ls c o r dt. •·
•~ t•s rlw rn 1,, o f II l'l"., t l' ti on 1,y :
... <\ \\•tr11h~ r inl·,-c~ .
io11 t'l lt'l').'ty of II I(' I.C:Ut l 1011
· .
~ .
u1
t':l ~lll.\'! rh ~ nc t1v
a) in,T
' . ' , , ., ' y
- '
I ~ v~ilu c ol ra te co ns truH (k 1111d
(h) tn dt ,1~11~ r k
I.
kb)
ch·•,,o,, ~ . ,s _.,
the en1hnlpy u o '" 0 1 11 e rcncrion
c) incr t'~tsir)S
t • Lhe reaction
g th e enthalpy chnng~ of . 1
(d.) dt'O'~n sm
ly SO% HI is di .. ., 1 equilib riu m In tit <· foflowlr1Y. rcu,·11,m :
ss. :\! :1 ct?rm m l't'm pe rntu re 1 on . . ssoc111rcc at
lig )
2HI(g ) ~ H i g)
I
.. . is :
ta nt for this reac rio n
The eqmhbnum cons (c) 3. 0 (d) 0.5
(b ) 1. 0
(a) 0.25 tion
e eq uilibrium cons ta nt K,, for the reac
)4.. Th
H 0( g) -1 CO(g)
H i{ g) + CO i( g) ~ 2 rc flonk
m ole CO l .ire injccred Into a 5,(J llr ·
60°C : !ni~ ially 0.80 moJ e H2 and 0.80
is 4.0 ~t 16 m concen tration of CO
i g) ?
t th e eq m hb nu
W ha 1s (b) 0.0534 M
(a) 0. 53 3 M (d ) N one of these
g to equation
Cc) 0.53 5 M 0 de co m po ses to NO 2 accordin
a cm , 10 Jitre of 2 4
N
55. Ac 27 3 K and 1 0 (g)
N O ( g) ~ 2N 2 4 z
less than thu t o( cxlhtin
2
in al vo lu m e Is 25 %
the orig
ssociation (a ) whe n
What is de gr ee of di
(d ) 0.5
volume? (c ) 0. 66 Hvw
(a ) 0. 25
(b) 0.33
H 2O (g ) ¢ CO 2 (g ) + H;,:( g) Jij 5.
re a~tio n CO( g) + rJf CO
e eq ui librium co ns ta nt fo r th e co nt ai ne r al re ad y co ntaining 3 molet> each
56. Th re
must be added to 1 lit
many moles of CO 2 br ium co ncentra tion of CO ?
2M eq uiJi (d ) 20
and H 20 to make (c) S form
(a ) 15
(b ) 19
m ol ar ra tio of l : 3 reached cqullibriu m to 2J
ro ge n mixture initi
ally in th e ta l pressure of the sy itt C.
'TTl w aJJ
57. A ni tr og en -h yd d re ac te d. lf th e to
of the N 2 and H :.i ha
ammonia when 25 % am m onia at the equiJibriu
m was :
l pr es su re of
ann, the partia (b ) 3.0 arm
(a ) 4. 5 at m (d) 1. 5 at m
34 7 C in a d osed
11 vc1>seJ in the
(c ) 2. 0 at m is he ated to
ia un de r a pr es su re of 15 atm at 27 °C
pa rt iaJly de co mposed accord ing w the
58. Ammon s, NH 3 is
Under th e condition
st.
presence of a cataly nt where a.ts
n, the volum e re m ai ns effectivel y consta
equatio the vessel is such that <Jscd :
NH ~ N 2 + 3H 2 th e pe rcen tage of NH 3 actuaJJy deoomp
2 3
se s to 50 at m . Cal
culate
pr es su re in cr ea (b ) 61.3°/i,
,
(a ) 65 % (d ) 64%
(c ) 62 .5 %
 JIJowletl Cit,,,..,, forNEE'fr
O1 mole of N 20, ( \?) wlls ~en lcci in a tube under on~.at~ospheric conditions at 250 I
59. . mun lJer of.· mo , 1'rs o1·NO2 ( ,..u) 1>rcsen1, if rhe equ1hbrmm N20 4 (g) ~ 2No C. CI '
the 2(g)( il ~11
. , ·. kP ~'O.i,
is reached 11 fkr sc)me lltnt .-
1
(a) 1.8 ' 10 ~ (b) 2.8 x 10 2 (c) 0.034 . . . (d) 2,Bx10 ,2
60. S mol('Sof SO ;i and 5 moles of O2 are alJowe~l ~bo ~eact. ~~egm~1bnum, it Was found h
of SO :z is used up. If the pressure of the eqw J num m1 ure is one atmosphere, th~ at ~~
pressure of O 2 is: Pa~
(a) 0.52 atm (b) 0.21 atm (c) 0.4l atm (d) 0.82 atrn
61. N 2 (g) + 3Hi(g) ~ 2NH 3(g)
For the reaction initially the mole ratio was 1 : 3 of N2 : H2 • At equilibrium SO% of e
reacted. If the equilibrium pressure is P, the partial pressure of NH 3 at equilibrium th ¾
(a) P (b) P (c) p (d) P .
3 4 6 8
62. 2.0 mole of PCl 5 were introduced in a vessel of 5.0 L capacity of a particular temperature
equilibrium, PC1 5 was found to be 35% dissociated into PC1 3 and C1 2 . The value of K, for ~
reaction
PClJfg) + C1 2 (g) ~ PC1 5 (g)
(a) 1.89 (b) 0.377 (c) 1.33 (d) 13.3
63. At certain temperature compound AB i(g) dissociates
>.
according to the reaction
2AB 2 (g) ~ 2AB(g) + B 2 (g)
With degree of dissociation a, which is small compared with unity. The expression of Kp,in
terms of a and initial pressure Pis :
3 2 a3 2
(a) p ~ (b) Pa (c) P - (d) Pa
2 3 3 2
64. For the reaction
H 2 (g) + CO 2 (g) ~ CO(g) + H2 O(g) . If the initial concentration of [H 2 ] =[CO 2 ]= IM and x
moles/litre of hydrogen is consumed at equilibrium, the correct expression of KP is :
2 (1 )2 2 2
(a) x (b) +x • (c) x (d) _ x_
(1- x) 2 (1- x) 2 (2 + x) 2 1- x 2
nd
65. If Dr and D 0 are the theoretical and observed vapour densities at a definite temperature a ~
be the degree of dissociation of a substance. Then, a in the terms of D0 ,Dr and n (numbero
moles of products formed from 1 mole reactant) is calculated by the formula :
(a) a = Do -Dr (b) a = Dr -Do
(1 - n) Dr (n - 1) Dr

(c) a= D'J' -Do (d) a= D - Dr

(n - 1) D0 (n - 1) Dr

66. For the dissociation of PCI 5 into PCI 3 and Cl 2 in gaseous phase reaction, if d is the obse~ed
vapour density and D the theore tical vapour density with 'a' as degree of dissociation,
Variation of D/ d with' a' is given by which graph?
 - -- : -
QUIUIIIUM-1: CNDIJCAL 1....._

f
,, (b) n
l i
il
(c)
(d) None of these
-~
D
d Q--+
d

6i , At ~tc.
aocl .~ _atm pressure, N 204 is 20% dissociation into NO ?, What is the density of
equthbnum nuxture of N 20 4 and N0 2 at 27"C and 1 atm? -
(:l)3. 11 g/litre (b) 2.11 g/ljcre
(c) 4.5 g/litre (d) None of these
68. COCI:: g~s dissocia~es according to_the equation, COCli{g) ~ CO(g) + Cl z(g). When heated
ro 700 K the density of the gas mLxture at 1.16 attn and at equilibrium is 1.16 g/licre. The
degree of dissociation of COCl 2 at 700 K is :
(a) 0.28 (b) 0.50 (c) 0.72 (d) 0.42
69, The degree of dissociation ofl 2 molecule of 1000°C and under atmospheric pressure is 40% by
volume. If the dissociation is reduced to 20% at the same temp. total equilibrium pressure on
the gas is :
(a) 1.57 atm (b) 2.57 attn (c) 3.57 attn (d) 4.57 atm
10. Determine the value of equilibrium constant (K c) {or the reaction
A 2 (g) + B 2 (g) ~ 2AB(g)
If 1Omoles of A 2 ; 1 S moles of B 2 and 5 moles of AB are placed in a 2 litre vessel and allowed to
come to equilibrium. The final concentration of AB is 7.5 M:
(a) 4.5 (b) 1.5 (c) 0.6 (d) None of these
71. At 87°C, the following equilibrium is established -?

82 (g) + S(s) ~ H 2 S(g) ; KP= 7 x 10 -

If o. 5 0 mole of hydrogen and 1.0 mol~ ?f ~ulp~ur are heated to 87° C in 1.0 L vessel, what will
be the partial pressure of H 2S at eqmlibnum .
(b) 1.38 atm
(a) 0.966 ann • (d) atm
1
(c) 0.032~ ~nn d ced into an evacuated chamber and comes to equilibrium at 247°C and 2.0
72. Pure PCI s is I~trlibo ·umu gaseous mixmre contains 40% chlorine by volume.
aun. The eqm n .
Calculate K at 2470c for the reacnon
P PC1 5 (g) ~ Pd 3 (g) + d2(g)
(b) 4 atm
(a) 0.625 atm (d) None of these
(c) 1.6 atm
?3 For the reaction
• SnO 2 (s) + 2H 2 (g) ~ 2H 20(g) + Sn(l)
at 900 K, where the equilibrium steam-hydrogen mixture was 45% H 2 by
calculate K p
volume: (c) 0.67 (d) None of these
(b) 1.22
(a) 1.49

!! _j
 ff6 ~ ~ l e , - NBET
1 642 atm at 727°C. If
14. For the reaction XC0 3 (s) ~ XO(s)_+C02(g), KP = · 0 4 01
XCO (s) was put into a so litre con tamer and heated to 7~: ~- rn ~
3
Wha~ mole percent of the XCO 3 remains unreacted at eqm11bnum?
(:i) 20 (b) 25 (c) 50 (d) None of these
15. Fe 20 3(s) may be converted to Fe by the reaction
Fe 2 O 3 (s) + 3Hi(g) ~ 2Fe(s) + 3H 2 O(g),
for which K = 8 at temp. 720°C.
What perce;tage of the H 2 remains unreacted after the reaction has come to equilibnull]
(a) =22% (b) ==-34% (c) ==-66% (d) ==-78%
1
76. ABig) is dissociates as ABig) ~ ABi(g) + 2 B2(g).

When the initial pressure of AB 2 is 800 torr and the total pressure developed at equilibrilll]J 1.
900 torr. What fraction of AB 3 (g) is dissociated?
(a) 10% (b) 20% (c) 25% (d) 30%

77. At 1000 K, a sample of pure NO 2 gas decomposes as :

2NO 2 (g) ~ 2NO(g) + O 2 (g)
The equilibrium constant KP is 156.25 atm. Ancilysis shows that the partial pressure 0£0 2 ~
0.25 atm at equilibrium. The partial pressure of NO 2 at equilibrium is :
(a) 0.01 (b) 0.02 (c) 0.04 (d) None of these
78. Pure nitrosyl chloride (NOCl) gas was heated to 240°C in a 1.0 L container. At equilibrium the total
pressure was 1.0 attn and the NOCl pressure was 0.64 atJn. What would be the value of K/
(a) 1.02 atm (b) 16.875 x 10-3 atm
2
(c) 16 x 10- atm (d) None of these

79. At a cenain temperature the equilibrium constant K, is 0.25 for the reaction
A 2 (g) +B 2 (g) ~ C2 (g) +D2 (g)
take 1 mole of each of the four gases in a 10 litre container, what would be equilibrium
If we
concentration of A 2 (g)?
(a) 0.331 M 0
(b) 0.033 M
(c) 0.133 M (d) 1.33 M
80. At 200°C PC1 5 dissociates as follows :
PC1 5 (g) ~ PC1 3 (g) + C1 2 (g)
Ir_ was.fo~d that the equilibrium vapours are 62 times as heavy as hydrogen. The % degree of
dJSsoaaoon of PCJ 5 at 200°c is nearly :
(a) IOOA>_ . . (b) 42% (c) 50% (d) 68%
81. For the dJSsOCJation reaction N O ( )
2 4 g ~
2NO ( g,
__,lo,, ) th degree of dissociation (a) in terms 0f
K d taJ .. . 2 e
P an to equil1bnum pressure p is :
(a) a = J4P + KP (b)a= ~
(c) a =
Kp
{if;
v~
vw (d) None of these

f ur4/
 t ,. . ~

~:,;,..,_,,___,_~----~-•~ou1u1a1u■-1 : CIIIMICAL EOUIUIRIUM 297 ,...___ _

ftt<' ~r,"lp.h which represen~ nll the equili brium concentrations for the reaction
,. ,. N .i0 4 (g) ~2N0 2 (g)

:~,,r tll<' ,ell/ he correct ruphfor concent rnt iol s of No , against concentrations of NO , :

(b) ~ ....____ (c) ~ (d ) ~ \

.,~ 'ft..' ,-apour pressure of mercury is 0.002 mm Hg at 27°C. Kc for the process Hg(l) ~ Hg(g)
~
~:
lJ) 0.002 (b) 8.12 x 10 - S
tc) 6.48 " 10 -s (d) 1.068 x 10 - 7
s-4- cakulare the equilibrium constant (Kc) for the reaction below if they are present at
c4uilibrium 5.0 mole of A 2 , 3 mole of B 2 and 2 mole of AB 2 at 8.21 atm and 300 K
Ai( g) + 2B i( g) ~ 2AB 2 (g) + Heat
(a) 1.333 (b) 2.66
(c) 20 (d) None of these
as. For the reaction (1) and (2) >.
A(g) ~ B(g) + C(g) ... (1)
X(g) ~ 2Y(g) . .. (2)
Given, KPi : Kp2 =9: 1
If the degree of dissociation of A(g) and X(g) be same then the total pressure at equilibrium
(1) and (2) are in the ratio :
(a) 3 : 1 (b) 36: 1
(c) 1 : 1 (d) 0.5 : 1
86. Given the following reaction at equilibrium, N 2 (g) + 3H 2 (g) ~ 2NH 3 (g). At constant
pressure if some inert gas added to the system. Then :
(a) More NH 3 (g) is produced a Cb) Less NH 3 (g) is produced
(c) No affect on the equilibrium (d) KP of the reaction is decreased
87. Change in volume of the system does not alter the number of moles in which of the following
equilibrium?
(a) N i( g) + 0 2 (g) ~ 2NO( g) (b) PC1 5 (g) ~ PCl 3 (g) + C1 2 (g)
(c) N i(g) + 3Hi{g) ~ 2NH 3(g) (d) SO 2Cl 2 (g) ~ SO 2 (g) + Cl 2 (g)
88. For the reaction
N ?( g) + 3H 2(g) ~ 2NH3(g) ; Ml= -93.6 kJ mo1 - 1
the number of moles of H 2 at equilib1ium will increase if :
(a) volume is increased (b) volume is decreased
(c) argon gas is added at constant volume (d) NH 3 is removed
 S 9 . fh c , c1l1111w t)I 1111' ic:icti o n ve s~
el co nt nini ng a n eq ui li
tnl ln, \ lrl ~ 1 C ,l C I 1011 br iu m mi xtu re is incr
e;i~"d
SO 2 Cl 2 (g ) ~ SO 2( g) + - in
Cl 2( g)
\\' he n cq ni liht il ttn i:- rc-e
sta blish cd :
(,1 ) th e Jm ou nt of
Cl1 (g ) re ma ins un ch a ng
(h ) th e :im ou nt of CJ (g ed
2 ) inc re as es
lC ) th e ::i mo un t of
SO 2 CJ2 ( g) in cr ea se s
(d ) rh e a mo un t o f SO
2 ( g) de cr ea se s
90 . Some in er t ga s is ad de d
at
co ns ta nt vo lu m e to th e fo
lJo wi ng re ac tio n at equiLibri
NH 4 HS(s) ~ NH (g um
Pr edict th e effect of ad di 3 ) + H 2S (g )
ng th e in er t ga s :
(a ) th e eq ui lib riu m sh
ift s in th e fo rw ar d di re cti
(b ) th e eq ui lib riu m sh on
ift s in th e ba ck wa rd di re
(c) th e eq ui lib riu m re m ain cti on
s un af fe cte d A
(d ) th e va lu e of K P is
in cr ea se d
91 Co ns id er th e re ac tio
n wh er e K P == 0. 49 7 at 50
0 K
PC1 5 (g ) ~ PC1 (g ) + Cl
If th e th re e ga se s ar
3 2 (g )
e mi xe d in a rig id co nt ai
in iti all y 1 at m . W hi ch is ne r so th at th e pa rti al pr
tru e ? ess ure of each gas 5
(a ) M or e PC] will be pr
5 od uc ed
(b ) M ore PCJ wjJ] be
3 pr od uc ed
(c) Eq ui lib riu m wiJJ be
es tab lis he d wh en 50 % re
(d ) No ne of th e ab ov ac tio n is co m pl ete
e
92 . Th e prep a ra tio n of SO 3 ( g) by
SO 2 (g ) + ~ O ( g) ~ re ac tio n
2 SO 3 ( g ) is an ~o th e
rm ic re ac tio n. If th e
prep ar ati on folJows so
th e foJlowing
re la tio n sh jp fo r its % yie
Th e co n-ect op tio n is
te m
ld, th en fo r te m pe ra tu re
pe
s
ra tu re- pr es su re
T1 , T 2 an d T •
t40
: 3 -o 30
Qj
(a ) T.1 ,,, T > T
2 1 ·;;. 20
( b) 7·1 > ·r ✓. > ·r 1 0~

(c ) 1' , -= 1''1. :- 'f.J 10

,- -- ,- -r ..-
( d) N oLhin g co uld b e 1 2 3 4
pred i cte d a bo ut te m pe ra
in fo rm at io n tu re th ro ug h g ive n - Pressure (aim)
93 . An eq 11i
l ib ri11111 rni x tu rc al 70 ·n
0 K of 0 .05 M N (g ), 0.3
: , t ·1 >n ta ine r. No w
if thi s eq ui lib riu m is di 2 M H :,l g) a nd 0 .2 M NH
s tu r be d by a dd in g N ( (
3 g) is pres~~~~fl
h ~·c.:ome i:; 0 . 1S M ju s t
a fte r ,1d dit io n th e n wh 2 g) so th at its concenu~ove
<. 1t 1 i;11 Ion m o rl.'
ap pr op ria t ely : ic h of Lh c fo llo wi ng gr ap
hs re presents the a
 --- .., ' . vntMICAL EQUILIBRIUM 299
ln11ial E:lCJ :Now r.q
03 ' ............. .i'...... .... .
,...._ j NH1 (g)
--
~
0.2
(b) ~
u
0.1

Time
Time

Initial eq. :New eq.

Initial eq. =New eq
0.3 i·········.. ····(·········· H (g)
2
,.... ,...._ 0.3 r - - - -...;,~ ··············r ······· ··· NH3 (g)
~ o.2 1- --- --: .... .... .. \··· ·· ·••NH (g) 2
l)
(c) § : :
3
N2(9) (d) g
0.2 f-------o1; . .H (g) 2
u 0.1 ....................... ................,............. 0
u 0.1 ............... ........ ·············· +············ N2(g)

Time )
Time
4, ln a vessel containing N ~, H
2 and NH 3 at equilibrium , some helium gas
total pressure increase while temperatu is introduced so tha t
re and yolume remain constant. Accordi
Chatelier's principle, the dissociation of NH ng to Le
3 :
(a) increases
(b) decreases
(c) remains unaltered
(d) changes unpredictably
5. Le-Chatelier principle is not applicable
to :
(a) Hi( g) + 12 (g) ~ 2Hl (g) (b) Fe(s) + S(s) ~ FeS(s)
(d) N 2(g) + 0 (g) ~ 2NO (g)
2
6. Consider the following reactions. In
which cases is the product formation
decreased pressure? favoured by
(1) CO (g) + C(s) ~ 2 CO(g); 0
2 Af-£ = + 172.5 kJ
(2) Ni( g)+ 3H (g) ~2 NH (g); 0
2 3 Af-l = - 91. 8kJ
(3) N 2 (g) + 0 ( g) ~ 2NO (g) ; 0
2 Af-l 0 = l8l kJ
(4) 2H 0(g ) ~ 2H i(g) + 0 ( g);
2 2 Af-1 ° = 484 .6 kJ
(a) 2, 3 (b) 3, 4 (c) 2, 4 (d) 1, 4
7. Consider the following reactions. In
which cases is product formation favoure
tempera d by decreased
ture?
(1) N (g) + o (g) ~ 2NO(g) ; Af-[O = 181 kJ
2 2
(2) 2CO (g) ~ 2CO(g) + 0 2Cg); Af-[O = 566 kJ
2
(3) H 2 (g) + 1 (g) ~ 2Hl (g); Af-[O = -9.4 kJ
2
(4) H i(g) + F (g) ~ 2HF (g); Af-[ O = - 541 kJ
2
(a) 1, 2 (b) 2 onl y
(c) l , 2, 3 (d) 3, 4
 • •
, ..
98 . 'P'0t wh kh 0f th f' fol1 ow1·ng rcn ctto ns rn Prod uct for ma tio n fav ou red by lo
w Pr
17(' -mp t'Nl \UN " ? essure
(A) H ~L~) t l ,1 (~) ~ 2
~H 0
::: - 9.4 kJ
I-H(.'!); ~ I
Af1 ° :!:- 17 2.S kJ
(h) CC1 :, (R) ➔ C(:~) ~ 2~~ (i~l(l)
; ~H 0
- 21 .7 kJ
( C) CO (~) ➔· 2H 2(R ) c,dt-
:::
Cl <J Af-/ 0 =28 5 kJ
ld) 30 2(g ) ~ 20 3(g ).;
99 . Po r ,vh ich of the fo lloWtng . is pro du ct for ma tio n fav ou red
reactJOn by low
tem per nru re? Pressure a
(a) C0 2(g )+C (s) ~ ZC O(g wo = 17 2.5 kJ 141 ·
1
); Af-f 0 -- 21 7k J
(b) CO (g) + 2H 2(& ) ~ CH 30H
(c) 20 3 (g) ~ 30 2(g );
; wo
wo
=- 285
-- 54
kJ
lk J
( d) H ( ) + F 2 (g) ~ 21-lF(g); .
2 g - .
10 0. Co nsi der the following rea
cti ons at eq m·11·br~u · m an d de tem un e wh ich of th
- ·
will cau se the rea cti on to pro cee th e Indicateq ch,.
d to e ng ht.
(1) CO(g) + 3H 2(g ) ~ CH ·~.
4(g ) + H2 0(g ) (ad d CH 4)
(2) N 2Cg) + 3H 2(g ) ~ 2N H3 (g)
(re mo ve NH 3)
(3) H (g) + F (g) ~ 2H F(g )
2 2 (ad d F2)
(4) BaO(s) + S0 (g) ~ Ba S0
3 4 (s) (ad d Ba O)
(a) 2, 3 (b) 1, 4 (c) 2, 4 (d) 2, 3, 4
10 1. If the pre ssu re in a rea cti
on vessel for the fol low ing rea cti
vo lum e, wh at wil l hap pen to the on is inc rea sed by decreasmg---
co nc en tr:t ion s of CO an d CO 2?
H 20(g ) + CO(g) ~ H (g) + C0
(a) bo th the [CO] an d [CO ] wil
2 2(g) + He at
2 l dec rea se
(b) nei the r the [CO] no r the
[CO ] wil l cha ng e
(c) the [CO] will dec rea se an d 2
the [CO 2 ] wil l inc rea se
(d) bo th the [CO] an d [CO ] wil
2 l inc rea se
10 2. Co nsi der the following
rea cti on an d de ter mi ne wh ich
equ ilib riu m po siti on to the rig ht? of the conditions will shift t:

4NH 3(g) + 50 2 (g) ~ 4N O( g)

+ 6H 2 0( g) + He at
(a) inc rea sin g the tem per atu re
(b) inc rea sin g the pre ssu re
(c) ad din g a cat aly st
a (d) no ne of the se
10 3. Th e con ver sio n of ozo ne int
o ox yg en is exo the rm ic. Un de r wh
sta ble ? at con dit ion s is ozone the m~

20 3(g ) ~ 30 2(g )
(a) At 1ow pre ssu re an d low tem
pe rat ure (b) At hig h pre ssu re an d high tem erature
(c) At hig h pre ssu re an d low tem p
pe rat ure (d) At low pre ssu re an d high tem
10 4. A sys tem at equ ilib riu m is peranire
des cri bed by the eq ua tio n of fix
ed tem pe rat ure T.
. . . S0 2Cl 2 (g) ~ S0 (g) + Cl (g)
Wh~~ e~ ect wil l an mcre~ses m the 2 2 aveon tbl
eq mh bn um ? tot al pre ssu re cau sed by a de cre
· ase in volume h
(a) Co nce ntr ati on of SO cl (g)
2 inc rea ses . creases
(c) Co nce ntr ati on of Cl (g) 2inc (b) Co nc en tra tio n of SO 2(g) 1n:
2 rea ses eases
(d) Co nc en tra tio n of all gases
incr
 ., ,. '!'., . . . .~--
.,;,....,..--=----•.. o. :. u.:.1; .;: u..,.
__
1. . _
,... ... . ee.t l.......

uirb . .
2 0 4 (g) is an exothennic eq h I mun. Tius means that :
·on 2ND i( g ) ~ N will be slower at
g tem
hi
perature
gas mixtu.re
111cre:i~~b1·atioll of th.is m ole f NO temperature
t"1uil1 • occu py tw ice the volume of a 0 2 at the same
r~l of N2o4 w ill th . .
an equilibriu m llllX
.
ture 1s cooled
~ JJ10 Ie
.
uiJibriurn will. . . ove to e nght if
. m . gas pressure
1~1 ·
rhe eq ill move to the left with •mcreasmg
o f eq m ltbn um w
tel posi tion . 2.3 g m /m L
rite am on d an d gr ap hite are 3.5 and
(d) . . of di • ) mol
,11s1oes (gra ph ite ; .1 rH = - 1. 9 k.J/
iJt . nd) ~ C • : hite are
c(d1aJllo fo r formation of grap mperature
ble co nd ition s
d l (b ) lo w pressure and high te
ure ture
fd,roura
(a) high pressure
an ~w temperat (d ) lo w pres ~u re and low tempera
u re . ue?
(c) high p~~ss~re
and high ~ m p er at ch o f th e follow mg statements is tr
(s) ~ H 20CO,
whi
ran equil1bnum H 20 not affect the equi
librium
su re ch an ge s do
·: The pres em is increased
su re on th e sy st
pres
MMore of ice melts if creased
s if pr es su re on the system is in ocess
(c) More of liquid
free ze
» th e de gr ee of ad vancement of the pr
decrease
e pr es su re ch an ge s may increase or
(d) Th e:
s co ok in g tim e for food becaus
.Apressure cooker
redu ce
co ok er cr ushe s the food material
(a) the higher pres
sure inside the
s he lp ed by a ri se in temperature
ge
(b) cooking involv
es chemical chan
di st ri bu te d in the cooking space
even ly
(c) beat is more
in vo lv ed in co oking is increased
(d) boiling point
of water :
in a d o se d co nt ainer depends on
,The vapour pressu
re of a liquid
(1) temperature o
f liquid
(2) quantity of liq
uid
(3) surface area of
the liquid (b) 2 only
(a) I only (d) 1, 2 and 3 held
d 3 on ly is re du ce d w hile the temperature is
(c) I an le poin t
su re on a sa m pl e of water at its trip
IO, The pres
hi ch ph as es ch an ges are favoured?
;onstanr. W
Dmelting of ice
(II ) sub11· mat1o· n of ice
· · n of liquid water (d) TI and I1I
fUI) Va Ponz
(a) atio (c) n only
1 (b ) III only
11, An e only
n is re pres en te d by the graph :
Xorhemuc reactio

(d )
(a) ':(0. (c)
s (b ) 1/T
1/T
1/T
1/T
 301 .Plt.Vttit:til Oh~mfat"1 µ,r NEET
. ,. · ,. rese nted by the graph :
1 1 2. An t'lH'iot IH't m 1c n'fl C' I mn 1s re P

~ )
(c) (d)
( h) s

- --
--1/T - . ·
- - -....
. - 1fT 1rr
. show 1'l, ,
rse of temper ature for a reacfton 1s
113. A sch em at ic pl o t o f In K rri vet ,c;us rnve n b,.,r,,;

the reaction must be :

(a) Exother mic
(b) Endothe rmic
( c) One with negligib le enthalp y change
(d) Highly spontan eous at ordinar y tempera ture
,i
114. vVhat is the correct relation ship betwee n free energy change and equilibrium consram
reaction ?
(a) ~G =RT In K0 ., (b) t1.G 0 = -RT In K

(c) ~G =RT In K (d) 13.G =-RT In K

t
115. For the chemica l equilibr ium CaC0 3 (s) ~ CaO(s) + C0 2 (g), Mi~ can be detennined
which one of the followin g plots ?

(a) ! ~ · !/
~._____
1fT
(b)
0'-----
- T
(c) !~ log 10T
(d) 1// 1/T

has the value of 10 - atm and 10-4 atrn at 298 Kand 323 K respecti vely fortherea(tic;
6 3 3
116. KP

cuso-4 -3H 2 0(s) ~ CuS0 4 (s) + 3H 2 0(g)

~ rH for the reaction is :
0

(a) 7.7 kJ/mol (b) -147.41 kJ/mol

(d) None of these K~
(c) 147.41 kJ/mol nd i'
. n sh ows the effect of temper ature on equilibr ium constan ts K a
117. van ' t H o· ff:s equat10 c

KP varies with tempera ture accordi ng to the relation :

(a) log KP2

K PI
= Mio
2.303 R
(T1T -T2J
T
KP2 -
(b) log K PI -
mo
2.303 R
(~J
T1 T2
1 2
 EOUILIIRIUM._ I,
• CNIMICAL IQUILIIIIIUM 303
,; /\ Er- ( '1' 1 • Ti )
hl~ ,-; r: · 2. 303 R r 1~
r2 (d) Non e: of th ese
1
t' ri
io n. the value of K 1, increases with .
n ' :1 f t increase i
~11 .~ wnuId be : · n temperature . The 6 H fo r the
-p,)11
a~ • .
., , i11VC (b) negative
l~) pO,
., 7cro . . . . (d) ca nnot be predicted
11 t ,table oxides of mtrogen will be .
,tr 1110~ ' '
~10 ,( 1?") ~ N 2(g)+2O2(g); K = 67 x lO J6 I ·l
A1 21, ~ • • mo L
I'
'I N,o (g) ~ 2N 2 (g) + 50 2 (g); K = 1.2 x 1024 mols L-s
ihl /,J L
5
•

.,r-.iQ(g) ~ N 2Cg) + O2(g); K=2.2 x l03o

1d ,:,I '

(ci) 2N P (g) ~ 2N 2Cg) + 02(g); K =3.5 x 1033 mo11-1

lfhW 1 mole ~f pure e thyl_ alcohol ( C 2H sOH) is mixed with 1 mole of acetic acid at 2s c, the 0

equilibrium mixture contams 2/3 mole each of ester and water

C 2H 5 OH(l) + CH3COOH(l) ~ CH 3 COOC 2H 5 (l) + H 0(l)
2
The fl G0 for the reaction at 298 K is :
(a) 3435 J (b) 4 J (c) -343!; J (d) Zero
.Thevalue of /1 G for a reaction in aqueous phase having Kc = l , would be :
0

(a) -RT (b) -1 (c) 0 (d) +RT

Aplot of Gibbs energy of a reaction mixture against the extent of the reaction is :
(a) minimum at equilibrium (b) zero at equilibrium
(c) maximum at equilibrium (d) None of these
Rlr the reaction at 300 K
A(g) ~ V(g) + S(g)
1 1-1
/1 H 0 =-30kJ/mol, /1rS 0 =-0.lkJ.K - .mo
r

What is the value of equilibrium constant? • (d) None of these

(a)o (b) 1 (c) 10
Solid Ca(HCO 3 ) 2 decomposes as
Ca(HC0 3) 2(s) ~ CaCO 3 (s) + CO2(g) + H20(g) d fr ergy change for the given
st nd
ff ilie total pressure is 0.2 bar at 420 K, what is the a ar ee en
reaction (Li rGo )? 8 kJ/mol (d) 16.083 kJ/mol
(a) 840 kJ/mol (b) 3.86 kJ/mol (c) 6.9 kJ t 298 K. Calculate the value of
,Th . 15 · ~Go - -115 a
eStandard free energy change of a reaction -
10 1
1
&1oKP (R = 8.314 JK- mol- ) (d) 13.83
(a) 20.16 (b) 2.303 (c) 2.016