Scribd
Upload
4 views

T10AnsA

Uploaded by

thakuradarsh4226
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
4 views

T10AnsA

Uploaded by

thakuradarsh4226
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

Chemistry Point a coaching for 11, 12, IIT-JEE (Mains & Adv.

) NEET SET-A

Time: 1½ hr Amines and Biomolecules Marks: 50

A.01 (i)(d), (ii) (d), (iii) (d), (iv) (d), (v)  (a)
A.02 (i)(c), (ii) (c), (iii) (a), (iv) (a), (v)  (d)
A.03 (i) In aniline due to resonance, the lone pair of electrons on the N-atom are delocalized over the benzene ring.

Due to this, electron density on the nitrogen decreases. On the other hand, in CH3NH2, +I effect of CH3
increases the electron density on the N-atom. Consequently aniline is a weaker base than methylamine and

hence its pKbvalue is higher than that of methylamine.


(ii) n-Propylamine has two H-atoms on the N-atom and hence undergoes intermolecular H-bonding, thereby

raising its boiling point. Trimethylamine, (CH3)3N, being a tertiary amine does not have any H-atom on the

N-atom. As a result, it does not undergo H-bonding and hence its boiling point is low.
A.04 (i) It forms gluconic acid.
–
(ii) Methylamine being more basic than water, accepts a proton from water, liberating OH ions. These ions
3+
combine with Fe ions present in H2O to form brown precipitate of hydrated ferric oxide.

A.05 (i) A peptide linkage is an amide (–CO–NH–) linkage is formed between –COOH group of one -amino acid and

–NH2group of other –amino acid by loss of a water molecule.

(ii) The six-membered cyclic structure of glucose is called pyranose structure (- or -), in analogy with
heterocyclic compound pyran.
A.06 Anomers are those which have difference of orientation of OH group at –C. Ex- – and –glucose.
A.07 (i) Fibrous (ii) H Bonding
A.08

A.09 (i) A = Aniline, B = Benzene diazonium chloride, C = Iodobenzene


(ii) A = Methyl cyanide, B = Ethyl amine, C = Ethyl isocyanide
A.10 (i) The linkage between two monosaccharides through oxygen atom in an oligosaccharide or a polysaccharide is
known as Glycosidic Linkage.
(ii) Phosphate Linkage present in DNA and RNA
(iii) Carbohydrates which on hydrolysis give two to ten molecules of monosaccharides are called
oligosaccharides. Example- Sucrose.

By Sunil Ameta
Chemistry Point a coaching for 11, 12, IIT-JEE (Mains & Adv.) NEET

A.11

A.12

+
A.13 (i) In –amino acids the acidic group is – NH3, instead of –COOH group as in carboxylic acids and basic group is
–
–COO instead of –NH2 group as in amines. That is why they have low values of Ka and Kb.

(ii) (iii) Glycine (iv) Valine, Leucine


(v) (a) Amino acids are water soluble. (b) They have high melting point.

A.14 (i) C6H5NH2< NH3< C6H5CH2NH2< C2H5NH2< (C2H5)2NH


(ii) dimethylamine < methylamine < N-methylaniline < aniline.
(iii) p-nitroaniline < aniline < p-toluidine < N, N-dimethyl-p-toluidine
(iv) Due to delocalization of the lone pair of electrons of the N-atom of aniline over the benzene ring, aniline is
more acidic than ammonia.
(v) The basicity of amine in aqueous solution depends upon the stability of the substituted ammonium cation.

Here the combination of three factors, +ve I effect of CH3 groups, hydrogen bonding and steric hindrance
favour greater stability for ammonium cation of dimethyl amine than ammonium cation of trimethyl amine.
Hence dimethyl amine is stronger base than trimethyl amine.
A.15 (i) (a) 2, 4, 6-Tribromoaniline (b) Anilinium Chloride (c) Acetanilide

(ii) (CH3)3N < C2H5NH2< C2H5OH

(iii) Dimethyl amine and trimethyl amine can be distinguished by using Hinsberg’s reagent i.e. C6H5SO2Cl.
o
When treated with Hinsberg’s reagent dimethylamine being at 2 amine gives N, N-dimethyl benzene
o
sulphonamide which is insoluble in aqueous KOH solution while trimethyl amine being at 3 amine does not

react with Hinsberg’s reagent.

By Sunil Ameta
Mob No: 8058251118 Page 2

You might also like