Thermo Scientific AquaSensors™

DataStick™ Measurement
System
User Guide

AV38 interchangeable
Local Display communication interchangeable
4-20 mA relays sensor heads
adapters
PLC

Toroidal
PDA MODBUS
Resistivity
PC
USB/RS-232 universal
SCADA Conductivity
sensor module
RS-485
Ozone
DCS
ProfiBus ORP

MODBUS Dissolved
PLC Oxygen

DeviceNet pH
ROSS and the COIL trade dress are trademarks of Thermo Fisher Scientific Inc. U.S. patent 6,793,787.
AQUAfast, Cahn, ionplus, KNIpHE, No Cal, ORION, perpHect, PerpHecT, PerpHecTion, pHISA, pHuture, Pure Water, Sage, Sensing the Future,
SensorLink, ROSS, ROSS Ultra, Sure-Flow, Titrator PLUS and TURBO2 are registered trademarks of Thermo Fisher.
1-888-pHAX-ION, A+, All in One, Aplus, AQUAsnap, AssuredAccuracy, AUTO-BAR, AUTO-CAL, AUTO DISPENSER, Auto-ID, AUTO-LOG, AUTO-READ,
AUTO-STIR, Auto-Test, BOD AutoEZ, Cable-Free, CERTI-CAL, CISA, DataCOLLECT, DataPLUS, digital LogR, DirectCal, DuraProbe, Environmental Product
Authority, Extra Easy/Extra Value, FAST QC, GAP, GLPcal, GLPcheck, GLPdoc, ISEasy, KAP, LabConnect, LogR, Low Maintenance Triode, Minimum
Stir Requirement, MSR, NISS, One-Touch, One-Touch Calibration, One-Touch Measurement, Optimum Results, Orion Star, Pentrode, pHuture MMS,
pHuture Pentrode, pHuture Quatrode, pHuture Triode, Quatrode, QuiKcheK, rf link, ROSS Resolution, SAOB, SMART AVERAGING, Smart CheK,
SMART STABILITY, Stacked, Star Navigator 21, Stat Face, The Enhanced Lab, ThermaSense, Triode, TRIUMpH, Unbreakable pH, Universal Access are
trademarks of Thermo Fisher.
Guaranteed Success and The Technical Edge are service marks of Thermo Fisher.
PerpHecT meters are protected by U.S. patent 6,168,707.
PerpHecT ROSS electrodes are protected by U.S. patent 6,168,707.
ORION Series A meters and 900A printer are protected by U.S. patents 5,198,093, D334,208 and D346,753.
ionplus electrodes and Optimum Results solutions are protected by U.S. patent 5,830,338.
ROSS Ultra electrodes are protected by U.S. patent 6,793,787.
ORP standard is protected by U.S. patent 6,350,367.
No Cal electrodes are protected by U.S. patent 7,276,142.
© 2010 Thermo Fisher Scientific Inc. All rights reserved. All trademarks are the property of Thermo Fisher Scientific Inc. and its subsidiaries.
The specifications, descriptions, drawings, ordering information and part numbers within this document are subject to change without notice.
This publication supersedes all previous publications on this subject.
 Preface

This user guide serves to explain the use of the Thermo Scientific AquaSensors DataStick measurement
system and is written to cover as many applications as possible. Please do not hesitate to contact
Thermo Fisher Scientific or an authorized representative with questions or concerns.

The information presented in this user guide is subject to change without notice as improvements
are made, and does not represent any commitment whatsoever on the part of Thermo Fisher Scientific.

Thermo Fisher Scientific cannot accept any responsibility for damage or malfunction of the sensor due
to improper use.

Contact Information

To contact Thermo Scientific AquaSensors Technical Support:

Within the United States call 1.800.225.1480 or fax 978-232-6015.

Outside the United States call 978.232.6000 or fax 978.232.6031.

In Europe, the Middle East and Africa, contact your local authorized dealer.

Visit us on the web at www.thermoscientific.com/water

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 1

 Safety Information

The Thermo Scientific AquaSensors DataStick measurement system shall

be installed and operated only in the manner specified. Only a skilled,
trained or authorized person should carry out installation, setup and operation
of the system.

Before using the sensor, make sure that the sensor cable is connected
as specified. Failure to do so may result in permanent damage to the sensor
or controller.

Protection against electric shock will be achieved only by observance of the

corresponding installation rules.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 2

 TABLE OF CONTENTS
1 INTRODUCTION......................................................................................................................................................................................6
1.1 GENERAL INFORMATION .....................................................................................................................................................................6
1.2 INTENDED USE ..................................................................................................................................................................................7
1.3 SAFETY INSTRUCTIONS ......................................................................................................................................................................7
1.4 SENSOR CALIBRATION AND REFURBISHMENT EXCHANGE PROGRAM .....................................................................................................7
1.5 REMOVAL FROM SERVICE / CORRECT DISPOSAL OF THE SENSOR .........................................................................................................8
1.5.1 Removal from Service ............................................................................................................................................................8
1.5.2 Correct Disposal of Unit..........................................................................................................................................................8
2 PRODUCT DESCRIPTION......................................................................................................................................................................9
3 INSTALLATION.....................................................................................................................................................................................14
3.1 UNPACKING .....................................................................................................................................................................................14
3.2 MOUNTING ......................................................................................................................................................................................14
3.2.1 Pipe Tee Mounting ...............................................................................................................................................................15
3.2.2 Union Mounting ....................................................................................................................................................................16
3.2.3 Immersion Mounting .............................................................................................................................................................17
3.2.4 Sanitary Tee Mounting .........................................................................................................................................................18
3.3 COMMUNICATIONS ADAPTER WIRING ................................................................................................................................................20
3.4 DATASTICK USER INTERFACE OPTIONS ............................................................................................................................................21
3.4.1 Network Host Protocols ........................................................................................................................................................21
3.4.2 AV38 Local Display ..............................................................................................................................................................21
3.4.3 AquaComm™ Windows® Software.......................................................................................................................................22
3.4.4 Open Protocol Commands ...................................................................................................................................................23

4 MEASUREMENTS.................................................................................................................................................................................24
4.1 DIFFERENTIAL PH MEASUREMENT ....................................................................................................................................................25
4.1.1 pH Interface Overview ..........................................................................................................................................................26
4.1.2 pH Configuration...................................................................................................................................................................26
4.1.3 pH Calibration.......................................................................................................................................................................30
4.1.4 pH Sensor Diagnosis............................................................................................................................................................38
4.1.5 pH Sensor Maintenance .......................................................................................................................................................39
4.2 DIFFERENTIAL ORP MEASUREMENT .................................................................................................................................................42
4.2.1 ORP Interface Overview.......................................................................................................................................................42
4.2.2 ORP Configuration ...............................................................................................................................................................43
4.2.3 ORP Calibration....................................................................................................................................................................45
4.2.4 ORP Sensor Maintenance....................................................................................................................................................47
4.2.5 ORP Spare Parts..................................................................................................................................................................49
4.3 TWO ELECTRODE CONDUCTIVITY AND RESISTIVITY ............................................................................................................................49
4.3.1 Contacting Conductivity/Resistivity Overview.......................................................................................................................49
4.3.2 Configuration of Contacting Conductivity Sensors ...............................................................................................................50
4.3.3 Contacting Conductivity Calibration......................................................................................................................................62
4.3.4 Contacting Conductivity Maintenance ..................................................................................................................................65
4.4 TOROIDAL CONDUCTIVITY ................................................................................................................................................................66
4.4.1 Toroidal Conductivity Overview ............................................................................................................................................66
4.4.2 Configuration of Toroidal Sensors ........................................................................................................................................67
4.4.3 Toroidal Conductivity Calibration..........................................................................................................................................78
4.4.4 Toroidal Conductivity Maintenance ......................................................................................................................................81
4.5 DISSOLVED OXYGEN (PPM AND PPB) AND OZONE ...........................................................................................................................82
4.5.1 Dissolved Oxygen / Ozone Interface Overview ....................................................................................................................82
4.5.2 Configuration of Dissolved Oxygen and Ozone Sensor Heads............................................................................................83

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 3

 4.5.3 Dissolved Oxygen Calibration ..............................................................................................................................................87
4.5.4 Dissolved Oxygen Maintenance ...........................................................................................................................................91
4.6 TURBIDITY .......................................................................................................................................................................................91
4.6.1 Drinking Water Turbidity .......................................................................................................................................................92
4.6.2 Wide-Range Turbidity Measurement System.......................................................................................................................92
4.7 TEMPERATURE CALIBRATION ............................................................................................................................................................93
5 DIAGNOSTICS AND TROUBLESHOOTING........................................................................................................................................95
5.1 DIAGNOSTICS ..................................................................................................................................................................................95
5.2 TROUBLESHOOTING .........................................................................................................................................................................96
5.2.1 pH Sensor Head inspection..................................................................................................................................................97
5.2.2 ORP Sensor Head inspection...............................................................................................................................................97
5.2.3 Dissolved Oxygen and Ozone Sensor Head inspection.......................................................................................................98
5.2.4 Contacting Conductivity Sensor Head inspection.................................................................................................................98
5.2.5 Toroidal Conductivity Sensor Head inspection.....................................................................................................................98
6 PROGRAMMING GUIDE - COMMANDS AND RESPONSES..............................................................................................................99
7 FREE CHLORINE CONCENTRATION CALCULATION ....................................................................................................................107
8 COMPLIANCE INFORMATION...........................................................................................................................................................109
9 LIMITED WARRANTY.........................................................................................................................................................................110
10 TERMS AND CONDITIONS ................................................................................................................................................................111

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 4

 Tables of Figures and Tables

Table of Figures
Page
Figure Number and Caption
Number
Figure 1: Three Parts of the DataStick 9
Figure 2: The Universal Body
10
Figure 3: Full Array of DataStick Options
10
Figure 4: Configured Analytical Measurements
11
Figure 5: Drinking Water Turbidity System
11
Figure 6: DataStick Interface Options
12
Figure 7: Communications Adapter
12
Figure 8: Mounting Hardware Overview
13
Figure 9: The inner workings of the User-Entered Concentration Table.
61
Figure 10: The inner workings of the User-Entered Concentration Table.
77

Table of Tables
Page
Table Number and Description
Number
Table 1: 10 Point Conductivity Vs. Concentration Table
57
Table 2: Concentration Vs Conductivity after Editing
60
Table 3: 10 Point Conductivity Vs. Concentration Table
73
Table 4: Concentration Vs Conductivity after Editing
76
Table 5: Data Reporting
99
Table 6: Change Measurement Configuration Settings
100
Table 7: View Configuration Settings
101
Table 8: Calibration Commands
102
Table 9: Diagnostics and System Information
105

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 5

1 INTRODUCTION
1.1 General Information

Thank you for purchasing the Thermo Scientific AquaSensors DataStick Analytical Measurement System. This is a very robust and
versatile product intended for continuous use in industrial applications and complies with safety regulations currently in force. Unique
features include:
• Pre-calibrated sensors for plug and play capability.
• Direct connection to computer control systems without the need for analyzer electronics boxes.
• Sensor heads are easily serviced and replaced in the field minimizing downtime.
• Any sensor type in the DataStick family can be used with any DataStick thus making it possible to convert
a measurement point from pH to toroidal conductivity (for instance), simply by changing sensor heads.
• Performance is not affected by cable length and can be run up to 3,000 feet depending on the selected
communications protocol.

Thermo Fisher Scientific does not accept any liability for damage that may
arise if information in this user guide is not followed. Therefore, the operating
instructions and specifications must be read and understood by all persons
involved in installation and operation of this equipment.

This user guide identifies safety instructions and additional information by means of the following symbols:

This symbol draws attention to safety instructions and warnings of

potential danger, which if neglected, could result in injury to persons
and/or damage to property.

This symbol identifies additional information and instructions,

which if neglected, could lead to inefficient operation and possible
loss of production.

It is recommended that this user guide be made accessible to everyone who may need it as a reference.
Please contact Thermo Fisher Scientific or an authorized representative with any questions.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 6

1.2 Intended Use

The DataStick Analytical System is designed for continuous industrial applications. Interchangeable measurement and communications
components allow for quick replacement or reconfiguration.
Any other use, or use not mentioned here, that is incompatible with the technical specifications is deemed inappropriate. The operator
is solely responsible for any damage arising from such use.
Other prerequisites for appropriate use include:
• Observing the instructions, notes and requirements set out in this user guide.
• Observing all local safety regulations.
• Observing all warnings and cautions in the documentation regarding all products used in this measurement system,
including the sensor, mounting hardware, and cabling.
• Observing the prescribed environmental and operational conditions.
• Observing chemical compatibility with all wetted materials.

1.3 Safety Instructions

The DataStick Analytical System should be installed and operated only by personnel familiar with
the sensor and qualified for such work.

A defective sensor should be returned to Thermo Fisher Scientific for repair or replacement.
Contact Thermo Fisher Scientific to obtain a Return Material Authorization (RMA) number.

No modifications to the DataStick Analytical System components are allowed. The manufacturer/
supplier accepts no responsibility for damage caused by unauthorized modifications. The risk is borne
entirely by the user.

1.4 Sensor Calibration and Refurbishment Exchange Program

DataStick sensor heads are pre-calibrated and can be exchanged in the field to maintain accuracy. Thermo Fisher Scientific provides
service to refurbish and calibrate used sensors and return them for service. Please call the factory to inquire about the program.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 7

The following advisories and warnings must be followed with all DataStick Products:

This equipment is suitable for use in Class I, Division 2,

Groups A, B, C, d or Non-Hazardous Locations Only

The equipment shall be supplied from a Class 2 power input.

The supply is from an isolated source, maximum 30 VDC.

DataStick bodies constructed from polymeric materials Noveon Corzan

Type 3218 shall not be used in applications exceeding a maximum
operating ambient of 50C.

Input and output wiring must be in accordance with Class I, Div.2 wiring
methods and in accordance with the authority having jurisdiction.

Warning: Explosion Hazard – Substitution of components may impair

suitability for Class I, Division 2.

Warning – Explosion Hazard – Do not disconnect equipment unless power

has been switched off or the area is known to be non-hazardous.

1.5 Removal from Service / Correct Disposal of the Sensor

1.5.1 Removal from Service

Disconnect the cable wiring. The method for doing this will depend on the termination hardware that is chosen. In the case of a USB
connection, just remove the connector. In the case of a screw terminal block, remove the black ground wire last.
Remove the sensor from the mounting hardware.
1.5.2 Correct Disposal of Unit
When the sensor is taken out of service, observe the local environmental regulations for correct disposal.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 8

2 PRODUCT DESCRIPTION
The DataStick analytical measurement system consists of three highly customizable parts designed for direct connection to control
systems without the need for intermediate analyzer electronics. A communications adapter plugs into the back of the system and provided
direct interactive communication of measurement, configuration, calibration and diagnostic information with computers and networks.
A full family of sensor heads plug into the front of the system and automatically provide calibrated high-resolution measurements.
Please refer to performance specifications in parameter specific datasheets.

Communications Adapter
Provides power and direct interactive communication
with control systems and computers.
Communications Selections: RS-232 ASCII, RS-232 DF1,
RS-485 MODBUS, PROFIBUS, DEVICENET, ETHERNET,
USB, WIRELESS…
Body Material: 316-Stainless Steel, CPVC, Ryton®, PEEK®
Cable length and termination: 10 feet to 1000 feet
(Consult the factory for other material choices).

DataStick Sensor Body

Universal conversion of sensor signals. Interactive
communication for data reporting, configuration
and calibration.
Insertion, submersion and sanitary fittings.
Body Material: 316-Stainless Steel, CPVC, Ryton®, PEEK®
(Consult the factory for other material choices).

DataStick Sensor Head

Pre-calibrated sensor heads can be replaced
at any time.
Sensor head offering includes:
Two electrode conductivity, two electrode
resistivity, toroidal conductivity, differential pH,
differential ORP, dissolved oxygen, turbidity
and ozone.
New sensor parameters are continually being
added to the DataStick family. Check with the
Figure 1: Three Parts of the DataStick factory for a complete list.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 9

The heart of the DataStick measurement system is a 1-inch tube body with encapsulated measurement electronics that automatically convert sensor
signals into calibrated engineering units. This single tube body in essence takes the place of a full family of analyzer electronics boxes. The DataStick
works seamlessly with a variety of communications adapters so that it can operate directly with any computer system. These features allow for quick
changes to the measurement system without significant down time.

Insert communications
adapter this end. Wrench Flats

Flat for sanitary adapters

1-inch NPT Threads
(Immersion) 1-inch NPT Threads
(Insertion)

Insert sensor head

this end.

Figure 2: The Universal Body

This family of plug and play communications adapters and sensor heads makes the DataStick the most versatile and accurate analytical
measurement system on the market. Any sensor type can be plugged in to obtain calibrated data. Any computer system can be set up to
communicate directly by configuring the DataStick system with the appropriate communications adapter. If local display and standard 4-20
milliamp data reporting is desired then the DataStick can be connected to Thermo Scientific AquaSensors AV38 Local display as shown in
the upper left corner of Figure 3. The AV38 can work with multiple DataSticks running the Modbus protocol.

Figure 3: Full Array of DataStick Options

DataStick system components can be exchanged in the field. Sensor heads will remain calibrated when moved from one DataStick
to another making it possible to perform calibrations in the laboratory and then just exchange sensor heads in the field. Systems are
shown here in stainless steel and PEEK® but are also offered in Ryton® and CPVC for a wide spectrum of applications.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 10

Interchangeable pre-calibrated sensor heads make it possible to quickly configure a DataStick for any application with a full series
of analytical measurements as shown in Figure 4.

Dissolved Oxygen
Differential pH Series ORP Series and Ozone Series

Turbidity
Two Electrode Toroidal 0 to 4000 NTU
Conductivity Series Conductivity Series

Figure 4: Configured Analytical Measurements

DataStick systems can also be configured into more complex systems. Drinking water turbidity measurements are provided using
a DataStick installed in a specially designed sample chamber that has a white light source in the lid. The system provides very accurate
turbidity measurements that can be calibrated and configured locally using the AV38 display or it can be networked directly to a computer
system for measurement, calibration, configuration and diagnostics.

Figure 5: Drinking Water Turbidity System

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 11

Schematically as shown in Figure 6, any DataStick system can be connected directly to a computer network to obtain 24 bit data and
interactive measurement, configuration, calibration and diagnostic capability.

Digital Gateway
PC, PLC, DCS or PDA

Digital Gateway

Modbus

2 Isolated mA Loops DataStick

Power: 24VDC
2 Form C Relays or 120/240 VAC
AV38 Local Display

Figure 6: DataStick Interface Options

Interchangeable communications adapters currently supported include:

Communications
Suggested Application Standard Software Interface Reference
Adapter
Laboratory PC ASCII Commands and Responses shown
USB ASCII AquaComm™, HyperTerminal
Field Diagnostics with Laptop in the appendix of this user guide.

ASCII Commands and Responses shown

RS-232 ASCII Laboratory PC AquaComm™, HyperTerminal
in the appendix of this user guide.
Modbus RTU AV38 Local Display AV38 User guide
over RS-232 AquaComm™, ModScan32
or RS-485 PLC with Modbus Network Modbus Communications User guide

DeviceNet Communications User guide

DeviceNet PLC with DeviceNet Network DeviceNet PLC Tools
Electronic Data Sheet (EDS file)
CANopen PLC with CANopen Network CANopen PLC Tools CANopen Communications User guide
Profibus DP V1 PLC with Profibus Network Profibus Gateway Tools Modbus/Profibus Gateway User guide
Ethernet/IP Web connected Web ready Ethernet User guide

Figure 7: Communications Adapter

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 12

DataStick systems use 1-inch NPT threads for insertion and immersion applications. The threads on the back-body are used for
submersion and Thermo Scientific AquaSensors Union Mount hardware and the front threads are used for insertion into standard plumbing
tees. A variety of sanitary mounts are available with DataSticks that have a special retaining ring just below the hex flats. PEEK® sensor
heads with sanitary face seals should be used in sanitary applications along with stainless steel sensor bodies that have special mounting
rings between the wrench flats and the NPT threads.

Tee Mount
Use the front threads for
Union Mount insertion into pipe tees.

Use special Thermo Scientific

AquaSensors Union Mount fittings
for applications that require frequent
removal for calibration.

Submersion
Use the back threads of DataStick for
extension pipes. Integral junction Sanitary
boxes are used for wire termination. For Sanitary applications use
Thermo Scientific
AquaSensors fittings.
Ball Valve
For applications requiring
extraction in a pressurized line

Figure 8: Mounting Hardware Overview

Use a 1-¼ inch wrench to turn the sensor body into pipe fittings that have internal 1-inch NPT threads. Use Teflon tape on all threads
to insure a proper seal. Do not use liquid thread compounds on DataStick threads.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 13

3 Installation
DataStick sensors are designed for installation in a variety of insertion, immersion and sanitary applications. Although the communications
cable is sealed and strain relieved for all communications adapters, we recommend that the cable be protected from process and heat
by being run through conduit or cable trays. User interface software should be installed on a chosen computer or a local smart junction box
should be installed for local calibration and monitoring.
3.1 Unpacking
Inspect the equipment and packing materials for signs of shipping damage. If there is any evidence of damage, notify the transit carrier
immediately. After unpacking, it is recommended to save the shipping carton and packing materials in case the measurement equipment
must be stored or re-shipped.
Sensor heads with wetted parts are shipped with yellow caps and include pH, ORP, DO and Ozone measurements. If these sensor heads
are to be stored for more than two weeks before installation they should be inspected to be sure the electrodes remain moist. The cap
should contain moist absorbent material that is in physical contact with the electrode when the cap is installed or secured. It the sensor
head has dried out, refer to the maintenance and refurbishment sections of this user guide.

Save the protective cap and use it to keep

electrodes hydrated whenever the sensor
is removed from service.

3.2 Mounting
Use a 1-¼ inch wrench to turn the sensor body into pipe fittings that have internal 1-inch NPT threads. Use Teflon tape on all threads
to insure a proper seal. Do not use liquid thread compounds on DataStick threads.
DataStick systems use 1-inch NPT threads for insertion and immersion applications. The threads on the back-body are used for
submersion and Thermo Scientific AquaSensors Union Mount hardware. The front threads are used for insertion into standard plumbing
tee’s. PEEK® sensor heads with sanitary face seals should be used in sanitary applications along with stainless steel sensor bodies that
have special mounting rings between the wrench flats and the NPT threads.
We recommend the Thermo Scientific AquaSensors Union Mount hardware for applications where the sensor is removed more than once
per week for calibration or maintenance.

The sensor should be positioned at least

15° up from horizontal. This will insure that
entrained air does not form a pocket around
the sensor head.

DO NOT USE PIPE SEALANT. Pipe

sealants may not provide adequate sealing
or may react with different plastic materials.
Use Teflon® thread tape.

DO NOT OVER TIGHTEN!

Maximum torque: 65 lbs⋅inch (7 N⋅m)

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 14

3.2.1 Pipe Tee Mounting
Normally available pipe tees vary widely in construction dimensions. CPVC pipe tees are most generally available with schedule 80 walls.
Stainless steel tees have thinner walls that change the final position of the sensor. Common mounting arrangements are shown.

Detailed Pipe Tee Installation Instructions

1. Wiring:
a. Route the cable either through conduit or on a cable tray.
b. Insert the sensor cable into junction box through a watertight cord grip.
c. Connect the sensor wires into the terminal block as specified on the cable label.

2. Mount:
a. Apply Teflon® tape to the sensor body threads.
b. Insert the sensor into the tee and slowly turn clockwise until secure. Tighten the
sensor with a wrench until snug to prevent leaking. Be sure the pipe remains full
when the sensors are installed.

The sensor head is pre-calibrated at the factory and should not require additional calibration
on initial installation unless the DataStick has been in storage for more than two weeks.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 15

3.2.2 Union Mounting
Union mount hardware makes it easy to remove and insert the sensor for applications where calibration and/or cleaning are frequent.
Union Mount Advantages:
• Optimal positioning of sensing surface.
• Trouble-free installation.
• Quick disconnect.
• No cable twisting during installation.
• Easy maintenance.

Detailed Union Mount Installation Instructions

1. Wiring:
a. Apply Teflon® tape to the rear sensor body threads and pass the cable through the adapter. Thread the adapter onto the sensor
clockwise until it is secure.
b. Pass the union collar over the cable and onto the adapter with the threads facing the front of the sensor.
c. Route the cable either through conduit or on a cable tray.
d. Insert the sensor cable into the junction box through a watertight cord grip.
e. Connect the sensor wires into the terminal block as specified on the cable label.
2. Mount:
a. Assemble the lower portion of the mounting hardware by threading the pipe nipple into the threaded flange and the tee.
Apply Teflon® tape to the threads.
b. Inspect the O-ring on the union-mounting threaded flange for imperfections or particles of dirt that may prevent the O-ring seal
from seating properly.
c. Carefully insert the sensor into the Thermo Scientific AquaSensors union-mounting tee. Turning the retaining collar clockwise
and hand tighten until snug. Be sure the pipe remains full when the sensor is installed.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 16

3.2.3 Immersion Mounting
For immersion mounting applications the sensor is connected to a 1 inch to 1.5 inch reducing coupling. A 1.5 inch extension pipe is added
to protect the cable from damage.

Detailed Insertion Mount Installation Instructions

1. Wiring:
a. Route the sensor cable through the 1.5 inch extension pipe.
b. Apply Teflon® tape to the sensor threads.
c. Attach the sensor to the 1.0 inch NPT reducing coupling
by turning the sensor in a clockwise direction until secure.
d. Route the cable to the junction box and use an extension cable.
e. Connect the extension wires into the computer terminal block.

2. Mount:
a. Secure the pipe assembly so that the sensor is fully immersed
in the process. Handrail mounting hardware can be ordered from
Thermo Fisher Scientific.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 17

3.2.4 Sanitary Tee Mounting
For sanitary mounting applications the sensor is connected to an adapter with a retaining collar and clamped into a short-branch
sanitary tee.

Detailed Sanitary Mount Installation Instructions

Wiring:
a. Thread the retaining collar over the cable and onto the sensor
with the threads facing the front of the sensor.
b. Route the cable either through conduit or on a cable tray.
c. Insert the sensor cable into the junction box through
a watertight cord grip.
d. Connect the sensor wires into the terminal block as shown
on the cable label.

Mount:
a. Insert the sensor into the adapter making sure the front o-ring
on the sensor is seated.
b. Thread the retaining collar into the adapter and tighten with
a wrench until the face of the sensor head is flush with the
adapter and the o-ring forms a seal.
c. Place a sanitary gasket on the branch flange.
d. Insert the sensor with the adapter into the branch of the tee;
be sure the pipe remains full while installing to minimize trapped air.
e. Install and tighten the sanitary clamp to retain the sensor and
adapter in the tee.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 18

Insertion Mounting Hardware (Ball valve)
The Thermo Scientific AquaSensors Insertion Mounting Hardware allows the DataStick measurement system to be inserted and extracted
from a pressurized process line without stopping the flow in the pipe. The mounting hardware is available in user guide and air/water
assisted units in both Stainless Steel and CPVC. The air/water assisted mounting hardware is fitted with a 3-way control for air or water
assist with a maximum pressure of 120 psi. The user guide mounting hardware does not have a valve but a drain valve may be added
by replacing the ¼” NPT plug with a valve.
Maximum pressure for the insertion mounting hardware is determined by the material, construction and maximum temperature.
Please consult the Insertion Mounting Hardware User guide for details.

Please refer to Insertion Mounting Hardware User guide for detailed instructions.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 19

 3.3 Communications Adapter Wiring
Each communications adapter has a label printed at the end of the cable that indicates the supported protocol and the corresponding
wiring chart. The standard cable length is 10 feet with the idea that the cable will terminate in a junction box. It is however possible
to order the communications adapter with any length of cable up to the maximum allowed by the particular protocol being used.
In practice all adapters have four wires and a shield. Any Class 2 DC power supply that provides 24VDC can be used.
For DeviceNet, Modbus and RS-232 cables, the RED and BLACK wires are for power, the BLUE and WHITE wires are for
communications, and a bare shield wire is connected to EARTH GROUND for safety and electromagnetic immunity and emissions.
RS-232 ASCII

Modbus RTU
Color DeviceNet over RS-232 RS-232
or RS-485

RED 24 VDC 12 to 30 VDC 12 to 30 VDC

BLACK Signal Ground Signal Ground Signal Ground
BLUE CAN_L Comms (–) Rx
WHITE CAN_H Comms (+) Tx
SHIELD Earth Earth Earth

USB, Profibus and Ethernet Adapters are provided with standard connectors and discrete wiring for these adapters is not needed.

O-Ring seal should be Partial List of Available Adapters

free of dirt when inserted Adapter Standard Cable Computer / Recommended
in the DataStick. Protocol Connection Software Power Source
PC / AquaComm 5 VDC
USB USB Type 1A
or ASCII (USB Standard)
RS-232 Stripped wires PC / AquaComm
12 VDC (Type 2)
ASCII for terminal block or ASCII
Modbus RTU PC / AquaComm
Stripped wires
over RS-232 24 VDC (Type 2)
Retaining Ring: for terminal block PLC / Ladder Logic
or RS-485
Insert the Adapter into
the DataStick and rotated Modbus/Profibus
Profibus DP PLC / Ladder Logic 24 VDC (Type 2)
until it engages. Gateway
Potted Serial
number and Stripped wires for
Tighten the retaining ring DeviceNet PLC / Ladder Logic 24 VDC (Type 2)
Part number. terminal block
to lock down the adapter.
Use a 15/16 inch (24mm) 24 VDC (Type 2)
wrench. Rotate clockwise Ethernet RJ-45 PLC / Ladder Logic
POE Standard
to tighten.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 20

The communications adapters are keyed and plug into the end of the DataStick marked “Communication Adapter”. Insert the
communications adapter until it bottoms out. Rotate the adapter until it engages with the connector. Push in gently and then tighten
the retaining ring with a 15/16-inch wrench.
Communications adapters can be inserted into the “Sensor Head” end of the DataStick but the adapter is not long enough to reach
the internal connector. Likewise, any sensor head can be inserted into the communications adapter end of the DataStick but it will
be too long for the retaining ring to be engaged.
3.4 DataStick User Interface Options
The DataStick measurement system can be connected to an AV38 Local Display, or it can be connected directly to a computer system
for interactive measurement, calibration configuration and diagnostics.
3.4.1 Network Host Protocols
When connected directly to a computer a number of different protocols are available. When using Host Communications, please refer
to the selected communications user guide for specific protocol setup and use.

Host Protocol Reference User guide to Set up Address, Baud Rate and Parity
Modbus RTU over
Modbus Communications Adapter User guide (258481-001)
RS-232 or RS-485
DeviceNet DeviceNet Communications Adapter User guide (258482-001)
RS-232 DataStick User guide (258480-001; this document): 9600 bps, no parity, 8 data bits, 1 stop bit
USB AquaComm USB driver with settings to 9600 bps, no parity, 8 data bits, 1 stop bit (258490-001)
Profibus Modbus/Profibus Gateway User guide (258488-001)
Other Look for addendums on setting up other protocols that may be configured.

3.4.2 AV38 Local Display

The AV38 is a universal display interface for DataStick sensor systems. The enclosure has ¼-DIN dimensions for easy mounting
and is rated NEMA 4X for outdoor use. It uses a liquid crystal display (LCD) with a high contrast backlight for best readability and
is powered with 24 volts DC.
The AV38 automatically recognizes the type of DataStick connected to the system and provides the
appropriate calibration, configuration and diagnostic menus. It has options for two 4-20 current loops,
two alarm/control relays and network communications to a host computer. In addition, the AV38 can
address up to 247 DataStick sensors.

DataStick sensors connected to the AV38 communicate via Modbus RTU. As such, the AV38 can
be used to select one of several DataStick sensors on the bus for display, current output reporting
and relay alarms by selecting the desired station address. When there is no DataStick sensor connected
at the selected network address, the measure screen will show dashed lines.

The AV38 can operate in “single sensor mode” with current outputs and relays, or it can be operated in “multi-sensor mode” with
digital communications to a host computer. Host communication options include, Modbus, DeviceNet, RS-485 ASCII, Profibus
and others. The host protocol is independent of the Modbus RTU protocol used by the AV38 to communicate
with the DataSticks.

In the multi-sensor mode the AV38 can be used as a switch that allows a host computer to measure calibrate, configure and diagnose
all DataSticks connected to the AV38. In this mode the AV38 measure screen displays the measure data that the host computer
is currently asking for. If the menu key on the AV38 is pressed, control of the local network of DataSticks is transferred to the AV38.
The host computer regains control after the user navigates back to the measure screen.

There are seven keys for menu navigation. The MENU key is used to toggle between the menu and the measure screen. Pressing the
Menu key provides options for calibration, configuration, communications, outputs and relays. Refer to the AV38 User guide for Details.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 21

3.4.3 AquaComm™ Windows® Software
Thermo Fisher Scientific offers a full-featured Windows® based software tool called AquaComm™ to interface with DataSticks from a PC.
The program has a logging feature and can run multiple measurements with basic USB, RS-232, RS-485 and Modbus connections.
Load AquaComm™ on any Windows® based computer and open up as many instances of the program as there are sensors connected.
The program can be set up with any communications port and will recognize station addresses. The display will automatically provide
the features needed for the sensor currently connected to the DataStick system. Sensors heads can be “hot-swapped” and the display
system will change accordingly.
Shortcut Icon:

The first time the program is launched it will most likely come up with blanks in the screen. Select FILE and the NEW CONNECTION
to connect the program to the DataStick. If there is more than one DataStick connected, set the first one up and then open up another
instance of the program to establish a connection with the next sensor. Once these applications close, the connection configuration
will be saved.

To configure AquaComm™ for use after installing the program, select the FILE menu:

Select NEW CONNECTION or OPEN CONNECTION to set up the port and protocol. When necessary, the station number, baud rate
and parity will also be set. Thermo Scientific AquaSensors communcations adapters are preset for baud rate, parity and station number.
These variables can be changed to match network requirements as described in the programming section of this user guide.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 22

 In the EDIT CONNECTION or NEW CONNECTION screen insert a unique name for the sensor.
Select the communications port that is connected to the DataStick.
Be sure to select the protocol, baud rate, parity and station number that matches the DataStick being connected.

Once the connection has been established, the display fields will be populated with current measurement data from the DataStick.
Pull-down windows will provide calibration, configuration and diagnostic choices specific to the sensor head that is connected to the
DataStick. Data logging options are available under FILE. Calibration, configuration and diagnostic choices are not available when
logging is active.

3.4.4 Open Protocol Commands

Open protocol ASCII commands are available with all communications adapters. The ASCII command set for the DataStick is available
for any application and the programming guide is detailed SECTION 7, “Commands and Responses”.
ASCII commands can be typed into any terminal program and with the correct communications setting; data can be obtained very quickly.
Communications setups vary depending on the protocol chosen. Some examples:
• RS-232 ASCII: 9600 Baud, 8 data bits, no parity, 1 stop bit.
• RS-485 MODBUS: Station address, baud rate, and parity.
These ASCII commands can be used directly with network protocols like Modbus or DeviceNet but it is much more effective to use the
standard maps for these protocols.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 23

4 Measurements
The DataStick sensor heads are interchangeable with any sensor body and retain calibration. This makes it possible to convert sensor
features in the field without the need to recalibrate or reconfigure. When calibration is needed, the DataStick architecture provides
a number of options. The sensor can be calibrated locally with a smart junction box, it can be calibrated remotely by the computer it is
connected to, or it can be exchanged for a new calibrated sensor head of the same type or a different type. Exchanged sensor heads
can then be calibrated in the controlled environment of the lab. Thermo Fisher Scientific offers a wide range of measurements and the
system architecture makes it possible to develop new measurement types on request and make them compatible with installed systems.
The sensor head (transducer) is keyed and plugs into the end of the DataStick marked “Transducer Module”. Insert the sensor head until
it bottoms out. Rotate the adapter until it engages with the connector. Push in gently and then tighten the retaining ring with a 15/16-inch
wrench. Sensor heads can be inserted into the “Communications Adapter” end of the DataStick but will be too long for the retaining ring
to engage.

Communications Adapter and Cable (Installed)

DataStick Universal Body

Sensor Head (Transducer) Ready for Insertion

Pre-calibrated sensor heads include differential pH and ORP, two electrode conductivity, two electrode resistivity, toroidal conductivity,
dissolved oxygen and ozone. Additional sensor types include turbidity, chlorine and others. Just plug them in and tighten the retaining ring.
Sensor heads are available in different materials and with different electrode profiles.

pH ORP Conductivity Toroidal

DO Ozone Turbidity Resistivity

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 24

The AquaComm™ menu system is used in this document to fully describe sensor calibration and configuration features.
AquaComm™ user interface software can be loaded into most desktop, laptop and hand-held computers. Multiple instances of this
program may be opened when more than one sensor is connected through multiple communications ports or multiple station numbers.
The measurement, configuration and calibration features described here are also easily loaded into PLC’s and other industrial computers.
Please refer to the individual protocol user guides for details.
Information displayed in the AquaComm™ measure screen includes sensor value, sensor units, temperature value, temperature units,
serial number, sensor type and data logging status.
Configuration and calibration pull-down menus are used to access all functions necessary to configure and calibrate sensor heads.
Data logging functions must be turned off during this process by accessing the FILE pull-down menu and turning off log files. Display
selections automatically change when a new sensor head is installed.

Once a DataStick has been configured for the desired units of measure, data filters and calibration standards, sensor head calibrations
can be performed at any time.
Measurement accuracy is maintained when transferring the sensor head from one DataStick to another. This makes it possible to set up
a DataStick system in the laboratory for calibration and test purposes. Sensor heads can then be carried to the field site and exchanged
with heads that need recalibration or refurbishment. This process reduces down time and actually extends the life of the sensor. Normal
field calibrations can be done through the AquaComm™ interface in local interface boxes.

4.1 Differential pH Measurement

The pH sensor head has a number of physical features that should be noted. The connector is keyed so it can only be inserted one
way into the DataStick. The key provides protection for the pins during installation. To insure that pins remain free of moisture and dirt,
a rubber boot is supplied with replacement sensor heads and should be kept in place when the sensor is being transferred or placed
in storage. In very humid or dirty environments, we also recommend applying some electrical grease to the connector pins.
O-Ring
Keep the O-Ring Water tight seal.
Connector Key Retaining Ring
and the shaft
Locks the sensor head
of the sensor free
into the DataStick body.
of dirt. Be sure
the DataStick
cavity is also free Gold Pins
pH Glass electrode
of dirt and moisture
inside concentric
prior to insertion.
ground rod

Encapsulated Quad-Junction
Product Number/ Allows ion exchange
Serial Number to reference chamber.
Removable
Salt Bridge
(Other bridge profiles, materials
and salt formulas available).

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 25

4.1.1 pH Interface Overview
When a pH sensor head is installed in the DataStick, AquaComm™ will automatically display pH, temperature, sensor type and
DataStick serial number. Pull-down menus will also automatically provide calibration, configuration and diagnostic choices for pH.

Factory default configurations for a pH sensor head are:

• Units of measure: pH (options include mV)
• Units for temperature: °C (options include °F)
• Sensor Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Temperature Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Buffer Standards: 4 pH, 7pH, and 10pH (options include DIN 19267: 1.09pH, 4.65pH, 6.79pH, 9.23pH and 12.75pH)
When configuration information is changed in a DataStick, the information remains with the DataStick. If a new sensor head is
installed, the configuration will remain as programmed by the user. It will not revert to default values. When calibrating the pH
measurement, be sure that the current configuration settings are well understood.
Calibration options for the differential pH sensor are:
• 2-point Buffer Calibration: Sensor placed in two buffer standards and automatically adjusts offset and span.
• 1-point Buffer Calibration: Sensor placed in one buffer standard and automatically adjusts measurement offset.
• 2-point Sample Calibration: Desired reading entered for two samples at least 3 pH units apart; adjusts offset and span.
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
Calibration options for temperature are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
4.1.2 pH Configuration
The AquaComm™ CONFIGURE functions can be accessed from a pull-down menu that automatically changes based on the
sensor type connected to the DataStick. When a pH sensor is connected, settings for data filters, units of measure and buffer
standards can be viewed or changed.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 26

4.1.2.1 CONFIGURATION OF BUFFER STANDARDS

Select BUFFER STANDARD from the Configuration pull-down menu to view or change the buffer standard that will be used
as a reference for buffer calibrations.
There are two pre-defined standards currently used with the DataStick system. The Thermo Scientific AquaSensors buffer
standard is the default when the system is reset.
Thermo Scientific AquaSensors Buffer Standards: 4 pH, 7 pH and 10 pH. (DEFAULT).
DIN 19267 Buffer Standards: 1.09 pH, 4.65 pH, 6.79 pH, 9.23 pH and 12.75 pH.

When using a buffer standard that is not included in the pre-defined buffer standard, use the
‘2-point sample’ calibration method.

ASCII Command to View Buffer Settings

Function Command Response Explanation
Get Standards GPHBUF 0 4/7/10 pH Standards
1 DIN pH Standards

ASCII Commands to Set Buffer Settings

Function Command Explanation
Set Standard to 4/7/10s SPHBUF 0 Sets buffer calibration based on 4, 7 and 10 pH standards
Set Standard to DIN SPHBUF 1 Sets buffer calibration based on DIN Standards
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.1.2.2 SENSOR FILTER

Select SENSOR FILTER from the Configuration pull-down menu to view or change the sensor filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the sensor filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely unfiltered reading.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 27

4.1.2.3 TEMPERATURE FILTER

Select TEMPERATURE FILTER from the Configuration pull-down menu to view or change the temperature filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the temperature filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely unfiltered reading.

Although temperature and sensor filter constants are independently controlled the best results are
generally achieved when both filters are set to the same constant.

ASCII Commands to View Sensor and Temperature Filter Settings

Function Command Response Explanation
Get Sensor Filter GSFIL A number between 0 and 100. Number of seconds.
Get Temp Filter GTFIL A number between 0 and 100. Number of seconds.

ASCII Commands to Set Sensor and Temperature Filter Settings

Function Command Explanation
Set Sensor Filter SSFIL X Where X is a number between 0 and 100. Units are in seconds.
Set Temp Filter STFIL X Where X is a number between 0 and 100. Units are in seconds.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.1.2.4 SENSOR UNITS

Select SENSOR UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the sensor units window are active. To change units or to review options, scroll the selection list. Click on the
desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the
change, click CANCEL.

For pH sensors, the units of measure can be set to pH or millivolts. The default units are pH.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 28

 ASCII Commands to View Sensor units
Function Command Response Explanation
View Sensor Units GSUNITS 0 Data reported in pH units
1 Data reported in mV units

ASCII Commands to Set Sensor units

Function Command Explanation
Set to pH SSUNITS 0 Sensor data will be reported in pH units
Set to mV SSUNITS 1 Sensor data will be reported in mV units
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.1.2.5 TEMPERATURE UNITS

Select TEMPERATURE UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the temperature units window are active. To change units or to review options, scroll the selection list. Click on the
desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the change,
click CANCEL.
Temperature can be displayed in °C or °F. Default units are °C.

ASCII Commands to View Temperature units

Command Response Explanation
GTUNITS 0 Data reported in °C
1 Data reported in °F

ASCII Commands to Set Temperature units

Command Explanation
STUNITS 0 Sensor data will be reported in °C
STUNITS 1 Sensor data will be reported in °F
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 29

4.1.3 pH Calibration
When a pH sensor is connected to the DataStick, calibration choices specific to pH are automatically available. After a calibration,
the sensor-head can be moved to another DataStick and measurement accuracy will be maintained. For the most accurate measurements
a 2-point buffer calibration should be performed.
Sensors are calibrated at the factory. When field calibrations are necessary, 1-point buffer, 2-point buffer, 1-point sample and 2-point
sample calibrations are available.

4.1.3.1 1-POINT BUFFER METHOD

Select 1-POINT BUFFER from the calibration menu to begin a calibration in a known buffer standard.
In a buffer calibration, the DataStick assumes that the sensor has been placed in a pre-defined buffer standard and automatically
equates the current reading to the closest standard value. For a 1-point pH buffer calibration, instructions are shown in the status
box on the left side of the calibration screen. The sensor and temperature values are shown on the right side of the screen.

Place the pH DataStick sensor into the buffer solution. Wait for the sensor and temperature readings to stabilize. Press the
CALIBRATE button and the sensor will begin the process of changing the current pH reading to the closest buffer standard
reading as defined by the buffer standard selected.
Once the calibration has been initiated it will take between 30 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active Abort button.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 30

 When the calibration is complete, the abort option is no longer available.

When the point has been successfully calibrated, measured values will be based on the new calibration. The rate of
change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered
in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to Initiate a pH 1-Point Buffer Calibration

Function Command Explanation
1-Point Buffer CALS1PB Initiates a 1-point calibration for pH sensors
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted

The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.1.3.2 2-POINT BUFFER METHOD

Select 2-POINT BUFFER from the calibration menu to begin a pH calibration sequence.
A 2-point buffer calibration is the recommended calibration method for most accurate results and requires 2 buffer standards
at least 3 pH units apart. Every pH sensor is calibrated this way when it leaves the factory and will maintain accuracy for a period
of time when the sensor head is kept wet.
Either Thermo Scientific AquaSensors pH standards or DIN pH standards can be selected from the configuration menu for this
calibration method. This process allows calibration to be done without entering any numbers but requires that the buffer standards
used for the calibration match the standard family that is selected in the configuration menu. The default standards are 4 pH, 7 pH
and 10 pH.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 31

 The first buffer should generally be a 7 pH standard to set the measurement offset.

After selecting the 2-point pH buffer calibration method, the sensor should be placed in the first standard and when sensor
and temperature readings are stable, click the CALIBRATE button to initiate the calibration or click EXIT to return to the main
measure screen.

Once the calibration has been initiated it will take between 15 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active Abort button.

Once the 2-point buffer calibration has successfully completed storage of the first point, the status box will prompt the user to place
the sensor in the second solution before initiating calibration of the second point. Please note that the reading will not be adjusted
after the first calibration point. Calibration changes will only take effect after both calibration points have been accepted.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 32

 Once the sensor has been placed in the second buffer standard and sensor and temperature readings have stabilized,
click the CALIBRATE button to initiate the calibration of the second buffer standard.

While the calibration is in progress the operation can be aborted at any time. The abort will take the system back to normal
measurements using the previous calibration values.

Once the calibration for both points is successful, the displayed sensor value will be based on the new calibration.

Exiting the calibration function will return the display to the measure screen. In this case the measured value of 4.01 pH confirms
that the sensor calibration in 4.01 pH buffer solution was successful.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 33

 ASCII Command to initiate a 2-Point Buffer Calibration

Function Command Explanation

2-Point Buffer CALPH2PB 0 Initiates 1st point of a 2-point buffer calibration
CALPH2PB 1 Initiates 2nd point of a 2-point buffer calibration
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted

The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.1.3.3 2-POINT SAMPLE METHOD

Select 2-POINT SAMPLE from the calibration menu to begin the calibration sequence.
If buffer standards are not available or if it is desired to calibrate to process values, the 2-point sample calibration method may
be appropriate. This calibration method requires the input of desired values for a given measurement. The points must be 3 pH
units apart and the readings must be stable before calibration can be successful.
When the 2-point sample method is chosen, the status box will prompt the user to enter the desired calibration value. Stable
temperature and sensor readings will help to establish an accurate calibration.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor and
temperature values are stable and near expected values, click the CALIBRATE button to initiate the calibration of the first sample
point or click EXIT to return to the main measure screen.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 34

 Once the calibration has been initiated it will take somewhere between 30 seconds and 2 minutes depending on sensor
and temperature measurement stability. During this period, the abort sequence can be initiated as shown with the active
ABORT button.

When the first calibration point is accepted, the status box will prompt the user to place the sensor in the second solution
of known value.

Wait until the sensor and temperature values are stable in the second solution.

Enter the desired value and initiate calibration by clicking the CALIBRATE button.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 35

 Once the calibration has been initiated it will take somewhere between 30 seconds and 2 minutes depending on sensor
and temperature measurement stability. During this period, the abort sequence can be initiated as shown with the active
ABORT button.

When the second point has been successfully calibrated, measured values will be based on the new calibration. The rate of
change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered in the
configuration menu.

Exiting the calibration menu will return the display to the measure screen.

ASCII Command to initiate a 2-Point Sample Calibration

Function Command Explanation
2-Point Sample Initiates 1st point of a 2-point sample calibration;
CALPH2PS 0 X
First Sample Where X is the desired pH value.
2-Point Sample Initiates 2nd point of a 2-point buffer calibration;
CALPH2PS 1 Y
Second Sample Where Y is the desired pH value.
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted

The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 36

4.1.3.4 1-POINT SAMPLE METHOD

Select 1-POINT SAMPLE from the calibration menu to begin a calibration.

When the 1-point sample method is chosen, the status box will prompt the user to enter the desired calibration value.

Stable temperature and sensor readings will also help to establish an accurate calibration.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor and
temperature values are stable and near expected values, click the CALIBRATE button to initiate the calibration or click EXIT
to return to the main measure screen.

Once the calibration has been initiated it will take somewhere between 30 seconds and 2 minutes depending on sensor
and temperature measurement stability. During this period, the abort sequence can be initiated as shown with the active
ABORT button.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 37

 When the point has been successfully calibrated, measured values will be based on the new calibration. The rate of
change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered
in the configuration menu.

Exiting the calibration menu will return the display to the measure screen.

ASCII Command to initiate a 1-Point Sample pH Calibration

Function Command Explanation
1-Point Sample CALS1PS Initiates a 1-point calibration of the pH sensor
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted

The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.1.4 pH Sensor Diagnosis

ASCII Command to View pH Sensor Slope

Function Command Response Explanation
The pH sensor slope based
Get Sensor
GSSLOPE A number between 0 and –100 on the most-recent calibration
Slope
in mV/pH
This command is available in DataStick firmware D3.22 or later. The DataStick firmware version can be obtained using
the GCVSN command.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 38

4.1.5 pH Sensor Maintenance
In order to maintain accurate measurement values, the sensor will need occasional maintenance. The harsher the process, the more
maintenance the sensor will require. Proper and regular maintenance will yield a longer sensor life.
The recommended pH sensor cleaning procedure is as follows:
1. Remove sensor from service and rinse or spray it with warm water to remove heavy deposits.

2. Soak the sensor in a container of hot detergent water for 30 minutes. Do not use detergents that contain oily skin softeners
like aloe or lanolin that can coat the glass electrode. Powdered Alconox™ and Dawn™ dishwashing liquid work well.

3. Use a soft-bristled brush, such as a soft toothbrush, and hot detergent water to scrub the entire electrode end of the sensor,
being careful not to scratch or break the glass electrode.

4. Rinse the electrode end with clean warm water.

5. If deposits are still present on glass electrode repeat steps 2 and 3. In the case of lime or other mineral deposits a weak
solution (about 0.1 M) of hydrochloric acid may be used. In some cases, a dilute solution (about 10:1) of water and chlorine
bleach or a solution of water and EDTA may also work. Stubborn oil or grease deposits may require cleaning with a solvent
such as acetone or alcohol. Assure that the sensor body in compatible with the solvent. Protein deposits may be cleaned with
a pepsin-based cleaning solution. Bacterial or mold growths may be removed with dilute chlorine bleach.

Note: Cleaning can be process-specific. Some users will have to develop a procedure that works
best for them.

Caution: Ensure that a dangerous chemical reaction will not occur between process deposits and
the cleaning solution, such as compounds of cyanide, and the hydrochloric acid. Cyanide is often
used in electroplating and in gold refining. If in doubt check with a chemist.

Caution: When using dangerous chemicals such as hydrochloric acid or chlorine bleach, use all
appropriate safety precautions, especially eye protection.

Before returning the sensor to service, allow it to soak in water or buffer at ambient temperature for about an hour to stabilize.
After cleaning the sensor, always calibrate the sensor head before installing in the process.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 39

4.1.5.1 PH SENSOR REFURBISHMENT –
REPLACING THE SALT BRIDGE AND REFERENCE SOLUTION.

If the sensor head has been cleaned and calibration cannot be achieved, replace the salt bridge and reference
solution.
Hold the sensor firmly with the electrode tip facing upwards. Remove the existing salt bridge by using
a 15/16 wrench (24mm) and turning it counterclockwise. Dispose of the salt bridge using an approved method.
Pour out the old reference filling solution. Rinse the reservoir with distilled or de-ionized water.
Slowly fill the reservoir with Thermo Scientific AquaSensors Reference Filling Solution (P/N RCS02)
so the solution just covers the reference O-ring.

Do not overfill. Overfilling will lead to

excessive pressures that will affect the
junction potentials of the reference.

Slowly screw the new salt bridge clockwise onto the sensor head until secure. Tighten the salt bridge with a 15/16
wrench (24mm) until snug.

Do not over tighten.

Maximum torque: 10 lbs⋅in (1.1 N⋅m)

After replacing the salt bridge and reference solution, calibrate the sensor.

If after cleaning and refurbishment sensors still have slow responses, low measurement slopes or are
seriously abraded or scratched, they must be replaced. Contact your local distributor or call Thermo Fisher
Scientific Customer Service.

There are several salt bridge replacement options. Protected and unprotected electrodes (with face seals for sanitary
applications). CPVC and PEEK® material. Custom salt bridge chemistry can be provided on request. The salt bridge
options can also be used on ORP sensor heads.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 40

4.1.5.2 PH SPARE PARTS

Description Part Number

Reference Cell Filling Solution (500 ml) RCS02

Protected PEEK® Salt Bridge
SBS01
(O-ring included)
Flat PEEK® Salt Bridge
SBS02
(O-ring included)
Protected CPVC Salt Bridge
SBS03
(O-ring included)
Flat CPVC Salt Bridge
SBS04
(O-ring included)
pH Sensor Storage Solution SBS09
Protective Cap SBC01

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 41

4.2 Differential ORP Measurement
The ORP sensor head has a number of physical features that should be noted. The connector is keyed so it can only be inserted one way
into the DataStick. The key provides protection for the pins during installation. To insure that pins remain free of moisture and dirt, a rubber
boot is supplied with replacement sensor heads and should be kept in place when transferred or placed in storage. In very humid or dirty
environments, we also recommend applying some electrical grease to the connector pins.
Keep the O-Ring and the shaft of the sensor free of dirt. Be sure the DataStick cavity is also free of dirt and moisture prior to insertion.

O-Ring
Water tight seal Retaining Ring
Connector Key Locks the sensor head
into the DataStick body

Gold Pins
Platinum electrode inside
concentric stainless steel
ground rod
Encapsulated
Product Number/
Serial Number
Quad-Junction
Allows ion exchange
to reference chamber
Removable
Salt Bridge
(Other bridge profiles, materials
and salt formulas available).

4.2.1 ORP Interface Overview

When an ORP sensor head is installed in the DataStick, AquaComm™ will automatically display millivolts, temperature, sensor type
and DataStick serial number. Pull-down menus will also automatically provide calibration, configuration and diagnostic choices for ORP.

Factory default configurations for an ORP sensor head are:

• Units of measure: millivolts (mV)
• Units for temperature: °C (options include °F)
• Sensor Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Temperature Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 42

 When configuration information is changed in a DataStick, the information remains with the DataStick. If a new sensor head
is installed, the configuration will remain as programmed by the user. It will not revert to default values.
Calibration options for the differential ORP sensor are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
Calibration options for temperature are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.

4.2.2 ORP Configuration

The AquaComm™ CONFIGURE functions can be accessed from a pull-down menu that automatically changes based on the sensor type
connected to the DataStick. When an ORP sensor is connected, settings for data filters and units of measure can be viewed or changed.

4.2.2.1 SENSOR FILTERS

Select SENSOR FILTER from the Configuration pull-down menu to view or change the sensor filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the sensor filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely
unfiltered reading.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 43

4.2.2.2 TEMPERATURE FILTER

Select TEMPERATURE FILTER from the Configuration pull-down menu to view or change the temperature filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the temperature filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely unfiltered reading.

ORP and temperature measurements are completely independent of one another and filter constants
can also be independent.

ASCII Commands to View Sensor and Temperature Filter Settings

Function Command Response Explanation
Get Sensor Filter GSFIL A number between 0 and 100. Number of seconds.
Get Temp Filter GTFIL A number between 0 and 100. Number of seconds.

ASCII Commands to Set Sensor and Temperature Filter Settings

Function Command Explanation
Set Sensor Filter SSFIL X Where X is a number between 0 and 100. Units are in seconds.
Set Temp Filter STFIL X Where X is a number between 0 and 100. Units are in seconds.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted.

4.2.2.3 SENSOR UNITS

The SENSOR UNITS selection is not available for ORP measurements. Units of measure are in millivolts (mV).

4.2.2.4 TEMPERATURE UNITS

Select TEMPERATURE UNITS from the Configuration pull-down menu to view or change units of measure.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 44

 Units shown in the temperature units window are active. To change units or to review options, scroll the selection list. Click on the
desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the
change, click CANCEL.
Temperature can be displayed in °C or °F. Default units are °C.

ASCII Commands to View Temperature units

Function Command Response Explanation
View Temperature Units GTUNITS 0 Data reported in °C
1 Data reported in °F

ASCII Commands to Set Temperature units

Function Command Explanation
Set °C STUNITS 0 Sensor data will be reported in °C
Set °F STUNITS 1 Sensor data will be reported in °F
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted.

4.2.3 ORP Calibration

When an ORP sensor is connected to the DataStick, calibration choices specific to ORP are automatically available. After a calibration,
the sensor-head can be moved to another DataStick and measurement accuracy will be maintained.

Sensors are calibrated at the factory. When field calibrations are necessary a 1-POINT SAMPLE calibration can be done when the sensor
is in process liquid. The ORP measurement is not compensated by temperature. Temperature is offered as an independent measurement.

4.2.3.1 1-POINT SAMPLE CALIBRATION

Select 1-POINT SAMPLE from the calibration menu to begin an ORP calibration.
When the 1-point sample method is chosen, the status box will prompt the user to enter the desired calibration value. Use
calibration solutions with millivolt potentials that are similar to those used in the process measurement. Solutions of opposite
polarity may react on the sensor electrode and cause it to foul.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 45

 For best calibration results, do not calibrate in both negative and positive millivolt solutions. Even after
thorough rinsing, positive and negative ORP solutions can react and foul the ORP salt bridge.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor value
is stable and near the expected value, click the CALIBRATE button to initiate the calibration or click EXIT to return to the main
measure screen.

Once the calibration has been initiated it will take somewhere between 30 seconds and 2 minutes depending on sensor
measurement stability. During this period, the abort sequence can be initiated as shown with the active ABORT button.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 46

 When the point has been successfully calibrated, measured values will be based on the new calibration. The rate of
change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered
in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to initiate a 1-Point Sample Calibration

Function Command Explanation
1-Point Sample CALS1PS Initiates a 1-point calibration
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.2.4 ORP Sensor Maintenance

In order to maintain accurate measurement values, the sensor will need occasional maintenance. The harsher the process, the more
maintenance the sensor will require. Proper and regular maintenance will yield a longer sensor life.
The recommended ORP sensor cleaning procedure is as follows:
1. Remove sensor from service and rinse or spray it with warm water to remove heavy deposits.
2. Soak the sensor in a container of hot detergent water for 30 minutes. Do not use detergents that contain oily skin softeners
like aloe or lanolin that can coat the glass electrode. Powdered Alconox™ and Dawn™ dishwashing liquid work well.
3. Use a soft-bristled brush, such as a soft toothbrush, and hot detergent water to scrub the entire electrode end of the sensor,
being careful not to scratch or break the glass electrode.
4. Rinse the electrode end with clean warm water.
5. If deposits are still present on glass electrode repeat steps 2 and 3. In the case of lime or other mineral deposits a weak
solution (about 0.1 M) of hydrochloric acid may be used. In some cases, a dilute solution (about 10:1) of water and chlorine
bleach or a solution of water and EDTA may also work. Stubborn oil or grease deposits may require cleaning with a solvent
such as acetone or alcohol. Assure that the sensor body in compatible with the solvent. Protein deposits may be cleaned with
a pepsin-based cleaning solution. Bacterial or mold growths may be removed with dilute chlorine bleach.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 47

 Caution: When using dangerous chemicals such as hydrochloric acid or chlorine bleach,
use all appropriate safety precautions, especially eye protection.

Before returning the sensor to service, allow it to soak in water or buffer at ambient temperature for about an hour to stabilize.
After cleaning the sensor, always calibrate the sensor head before installing in the process.

4.2.4.1 ORP SENSOR REFURBISHMENT –

REPLACING THE SALT BRIDGE AND REFERENCE SOLUTION.

If the sensor head has been cleaned and calibration cannot be achieved, replace the salt bridge and
reference solution.
Hold the sensor firmly with the electrode tip facing upwards. Remove the existing salt bridge by using
a 15/16 wrench (24mm) and turning it counterclockwise. Dispose of the salt bridge using an approved method.
Pour out the old reference filling solution. Rinse the reservoir with distilled or de-ionized water.
Slowly fill the reservoir with Thermo Scientific AquaSensors Reference Filling Solution (P/N RCS02) so the solution
just covers the reference O-ring.

Do not overfill. Overfilling will lead to

excessive pressures that will affect the
junction potentials of the reference.

Slowly screw the new salt bridge clockwise onto the sensor head until secure. Tighten the salt bridge with
a 15/16 wrench (24mm) until snug.

Do not over tighten.

Maximum torque: 10 lbs⋅in (1.1 N⋅m)

After replacing the salt bridge and reference solution, calibrate the sensor.

If after cleaning and refurbishment sensors still have slow responses, low measurement slopes or are
seriously abraded or scratched, they must be replaced. Contact your local distributor or call Thermo Fisher
Scientific Customer Service.

There are several salt bridge replacement options. Protected and unprotected electrodes (with face seals for sanitary
applications). CPVC and PEEK® material. Custom salt bridge chemistry can be provided on request. The salt bridge
options can also be used with pH sensor heads.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 48

4.2.5 ORP Spare Parts

Description Part Number

Reference Cell Filling Solution (500 ml) RCS02

Protected PEEK® Salt Bridge
(O-ring included) SBS01
Flat PEEK® Salt Bridge
(O-ring included) SBS02
Protected CPVC Salt Bridge
(O-ring included) SBS03
Flat CPVC Salt Bridge
(O-ring included) SBS04
ORP Sensor Storage Solution SCS04
Protective Cap SBC01

4.3 Two Electrode Conductivity and Resistivity

The two electrode contacting conductivity sensor head series has a number of physical features that should be noted. The connector
is keyed. The key provides protection for the pins during installation. To insure that pins remain free of moisture and dirt, a rubber
boot is supplied with replacement sensor heads and should be kept in place when the sensor is being transferred or placed in storage.
In very humid or dirty environments, we also recommend applying some electrical grease to the connector pins.
Keep the O-Ring and the shaft of the sensor free of dirt. Be sure the DataStick cavity is also free of dirt and moisture prior to insertion.
O-Ring
Water tight seal
Connector Key

Gold Pins Retaining Ring

Locks the sensor head

Encapsulated
Product Number/
Serial Number Resistivity (Cell K = 0.1) Conductivity (Cell K = 1.0)

4.3.1 Contacting Conductivity/Resistivity Overview

When a contacting conductivity sensor head is installed in the DataStick, AquaComm™ will automatically display conductivity or resistively,
temperature, sensor type and DataStick serial number. Pull-down menus will also automatically provide calibration, configuration and
diagnostic choices for conductivity.

Conductivity (Cell K = 1.0) Resistivity (Cell K = 0.1)

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 49

 Factory default configurations for contacting conductivity / resistivity sensor heads are:
• Units of measure: µS/cm (options include %, ppm and MΩ·cm)
• Units for temperature: °C (options include °F)
• Sensor Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Temperature Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Cell Constant: 1.0 for Conductivity electrodes, 0.1 for Resistivity electrodes
• Reference Temperature: 25°C (options include 0°C to 100°C)
• Compensation Slope: 2% / °C (options include 0 to 9.9 %/°C)
• Concentration Table (10 Points Capability): Point 1 is (0 µS/cm, 0%), Point 2 is (20,000µS/cm, 99.99%)
When configuration information is changed in a DataStick, the information remains with the DataStick. If a new sensor head
is installed, the configuration will remain as programmed by the user. It will not revert to default values.
Calibration options for the toroidal conductivity sensor are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
• Zero: Sets the zero point for the sensor in dry air. Be sure the sensor is clean and dry.
Calibration options for temperature are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.

4.3.2 Configuration of Contacting Conductivity Sensors

The AquaComm™ CONFIGURE functions can be accessed from a pull-down menu that automatically changes based on the sensor type
connected to the DataStick. When a conductivity sensor is connected, settings for data filters, units of measure, reference temperature,
temperature compensation and concentration tables can be viewed or changed. It is also possible to manually adjust the cell constant of
the connected sensor if a user guide adjustment of the measure value is desired. It is best to view the adjusted cell constant after
performing a 1-point sample calibration.

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4.3.2.1 SENSOR FILTER

Select SENSOR FILTER from the Configuration pull-down menu to view or change the sensor filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the sensor filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely
unfiltered reading.

4.3.2.2 TEMPERATURE FILTER

Select TEMPERATURE FILTER from the Configuration pull-down menu to view or change the temperature filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the temperature filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely
unfiltered reading.

Although temperature and sensor filter constants are independently controlled the best results
are generally achieved when both filters are set to the same constant.

ASCII Commands to View Sensor and Temperature Filter Settings

Function Command Response Explanation
Get Sensor Filter GSFIL A number between 0 and 100. Number of seconds.
Get Temp Filter GTFIL A number between 0 and 100. Number of seconds.

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 ASCII Commands to Set Sensor and Temperature Filter Settings
Function Command Explanation
Set Sensor Filter SSFIL X Where X is a number between 0 and 100. Units are in seconds.
Set Temp Filter STFIL X Where X is a number between 0 and 100. Units are in seconds.

4.3.2.3 SENSOR UNITS

Select SENSOR UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the sensor units window are active. To change units or to review options, scroll the selection list. Click on the
desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the
change, click CANCEL.
For contacting conductivity sensors, conductivity measurements can be set to conductivity in µS/cm, concentration in %,
total dissolved solids in ppm and resistivity in MΩ•cm.
Default units of measure are µS/cm.
Concentration measurements are converted from the data points entered in a 10-point concentration table that can be viewed
and edited from the Configuration pull-down menu.

ASCII Commands to View Sensor units

Function Command Response Explanation
View Sensor Units GSUNITS 0 Data reported in µS/cm units
1 Data reported in % concentration
2 Data reported in ppm (total dissolved solids)
3 Data reported in MΩ·cm units

ASCII Commands to Set Sensor units

Function Command Explanation
Set to µS/cm SSUNITS 0 Sensor data will be reported in µS/cm units
Set to % SSUNITS 1 Sensor data will be reported in % units
Set to ppm SSUNITS 2 Sensor data will be reported in ppm units
Set to MΩ▪cm SSUNITS 3 Sensor data will be reported in MΩ·cm units
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

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4.3.2.4 TEMPERATURE UNITS

Select TEMPERATURE UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the temperature unit’s window are active. To change units or to review options, scroll the selection list. Click on
the desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the
change, click CANCEL.
Temperature can be displayed in °C or °F. Default units are °C.

ASCII Commands to View Temperature units

Function Command Response Explanation
View Temperature Units GTUNITS 0 Data reported in °C
1 Data reported in °F

ASCII Commands to Set Temperature units

Function Command Explanation
Set °C STUNITS 0 Sensor data will be reported in °C
Set °F STUNITS 1 Sensor data will be reported in °F
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.3.2.5 CELL CONSTANT

Select CELL CONSTANT from the Configuration pull-down menu to view or change the conductivity reference temperature.
The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK. To abort
the change, click CANCEL.
The value shown in the edit box is used as a calibration value. Changing it will change the measured value. If the sensor type
is a nominal 0.1 Cell for RESISTIVITY measurements, values can be changed from 0.05 to 0.15. If the sensor type is a nominal
1.0 Cell for low range conductivity measurements, values can be changed from 0.5 to 1.5. It is important to clean the sensor
electrodes in detergent that does not contain Lanolin or Aloe prior to calibration.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 53

 ASCII Command to View Cell Constant
Function Command Response Explanation
Limits depend on nominal cell
Get Cell GCELL Cell constant
type – 0.1, 1.0, or 5.0

ASCII Command to Set Cell Constant

Function Command Explanation
Set Cell SCELL X Where X is the desired cell constant
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.3.2.6 CONDUCTIVITY TEMPERATURE COMPENSATION TYPE

The commands in this section are available in DataStick firmware D3.32 or later. The DataStick firmware version can be obtained using
the GCVSN command.
ASCII Command to View Conductivity Temperature Compensation Type
Function Command Response Explanation
The type of temperature compensation used
0
is Linear (default)
View conductivity
temperature GCTCTYPE The type of temperature compensation used
1
compensation type is Natural Water
The type of temperature compensation used
2
is None

ASCII Commands to Set Conductivity Temperature Compensation Type

Function Command Explanation
Set conductivity
The type of temperature compensation used will be Linear and
temperature
SCTCTYPE 0 it will be based on the reference temperature and slope set with
compensation type
the SCRTEMP and SCCSLOPE commands, respectively
to Linear
Set conductivity
temperature The type of temperature compensation used will be
SCTCTYPE 1
compensation type Natural Water
to Natural Water
Set conductivity
temperature
SCTCTYPE 2 The type of temperature compensation used will be None
compensation type
to None
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted.

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4.3.2.7 CONDUCTIVITY REFERENCE TEMPERATURE

Select REFERENCE TEMPERATURE from the Configuration pull-down menu to view or change the conductivity
reference temperature.
The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK.
To abort the change, click CANCEL.
The default reference temperature for conductivity is 25°C. The system will accept any number between 0 and 100
with up to one decimal place.

ASCII Command to View Conductivity Reference Temperature

Function Command Response Explanation
Get Reference GCRTEMP A number between 0 and 100 Data reported in °C

ASCII Command to Set Conductivity Reference Temperature

Function Command Explanation
Set Reference SCRTEMP X Where X is a number between 0 and 100. Units are in °C
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.3.2.8 CONDUCTIVITY TEMPERATURE COMPENSATION SLOPE

Select COMPENSATION SLOPE from the configuration menu to view or change the compensation slope for conductivity
measurements.
The default compensation slope is 2.00%/°C. The system will accept any number from 0 to 9.9 with up to two decimal places.
The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK.
To abort the change, click CANCEL.
The reference can be changed to any temperature between 0°C to 100°C with one-tenth degree resolution. Edit the reference
temperature by typing a new value in the edit box and clicking OK.

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 ASCII Command to View Conductivity Slope and Reference Temperature
Function Command Response Explanation
Get Slope GCCSLOPE A number between 0 and 9.9 Data reported in %/°C
Get Reference GCRTEMP A number between 0 and 100 Data reported in °C

ASCII Command to Set Conductivity Slope and Reference Temperature

Function Command Explanation
Set Slope SCCSLOPE X Where X is a number between 0 and 9.9. Units are in %/°C
Set Reference SCRTEMP X Where X is a number between 0 and 100. Units are in °C
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.3.2.9 TEN POINT CONCENTRATION TABLE ENTRIES

Select CONCENTRATION TABLE from the configuration menu to view or change any or all of the points in the table.
When selecting the ten-point concentration table, there will be an automatic update of each of the 10 points before any editing
or scrolling of the table can occur. This scan takes about 10 seconds.
The concentration table coordinates must be monotonic. Conductivity must increase with each point. Concentration can either
increase or decrease with each point. The table must start at POINT 1 and continue incrementally from there. Unused points
(except POINT 1) have zero, zero coordinates.
Current entries can be viewed by scrolling up and down on the “Number” window.
Table entries for specific chemicals are available from Thermo Fisher Scientific Customer Service on request.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 56

 The default concentration table is set up as shown in Table 1. The numbers can be viewed by scrolling the up/down arrows.

Table 1: 10 Point Conductivity Vs. Concentration Table

Conductivity Concentration
Point
(µS/cm) %
1 0 0
2 20,000 99.99
3 0 0
4 0 0
5 0 0
6 0 0
7 0 0
8 0 0
9 0 0
10 0 0

The following example shows how to change and add data points to the table. In this case, POINT 2 is changed and
POINTS 3 and 4 are added.
To change point 2 from 20,000 μS/cm at 99.99%, to 20,000µS/cm at 50%, scroll to point 2 and place the cursor in the
concentration coordinate window.

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 Delete the 99.99 in the concentration coordinate and replace it with 50. Note that the STORE and REVERT buttons are now
active. If the point is what is intended, click the STORE button to save the point to temporary memory. Clicking REVERT will
restore the point to what it was before editing was initiated.

Scroll to point 3 and replace the zero coordinates with 50,000µS/cm at 70% concentration. Then click on the STORE button
to save point 3 to temporary memory.

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 Scroll to point 4 and replace the zero coordinates with 100,000µS/cm at 97% concentration. Then click on the STORE button
to save point 4 to temporary memory.

Data for points 5 through 10 should be zero. Data stored in temporary memory can now be permanently stored using
the ACTIVATE STORED TABLE button.

If any error messages are shown, review the data points to be sure they are monotonic, that conductivity increases from
point 1 and that concentration increases or decreases from point 1.
Once the table has been activated, use the EXIT button and return to the main measure menu.
Table entries for specific chemicals are available from Thermo Fisher Scientific Customer Service on request.
The table entries made in this example are shown in Table 2.

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 Table 2: Concentration Vs Conductivity after Editing

Conductivity Concentration
Point
(µS/cm) %
1 0 0
2 20,000 50
3 50,000 70
4 100,000 97
5 0 0
6 0 0
7 0 0
8 0 0
9 0 0
10 0 0

When the units of measure are set to “%” the conversion from conductivity to concentration will make use of the entered table
and will present the readings as shown.

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Inside the DataStick there are two concentration tables; the scratch table and the working table. The scratch table is used to store
the points written with the SUPNT command. If the points in the scratch table are valid, they are copied to the working table when the
SUTBL command is used. The points in the working table are used to convert the measured conductivity value into a concentration value.
The points in the scratch table can be read using the GSPNT command. The GSPNT command is available in DataStick firmware version
D3.21 or later. The DataStick firmware version can be obtained using the GCVSN command.
The points in the working table can be read using the GUPNT command. A point read from the working table using the GUPNT command
is automatically written to the scratch table. This helps to insure that the scratch table is always known and valid.

Scratch Table Working Table

Cond Conc Cond Conc
0 0 0 0 0 0
1 20000 99.99 1 20000 99.99
2 0 0 2 0 0
3 0 0 SUTBL 3 0 0
(if scratch table Conductivity
4 0 0 is valid) 4 0 0 scaling
5 0 0 5 0 0
6 0 0 6 0 0
7 0 0 7 0 0
8 0 0 8 0 0
9 0 0 9 0 0

SUPNT GUPNT
GSPNT

User

Figure 9. The inner workings of the User-Entered Concentration Table.

For the scratch table to be considered valid, the following must be true:
1. All successive conductivity point values must be monotonic and increasing and be within the bounds of 0 to 2,000,000.0
µS/cm.
2. The concentration values must be monotonic and either increasing or decreasing and be within the bounds of 0 to 99.99%.
3. If fewer than ten points are entered, then the scratch table must be terminated with a last point containing zero values.
Provided the above criteria are met, the points in the scratch table are transferred to the working table when the SUTBL command is used;
otherwise the current working table is retained.

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 ASCII Command to View Concentration Table Entries
Function Command Response Explanation
Get Point from
GUPNT X Conductivity, Concentration X is a point from 0 to 9
working table
Get point from
GSPNT X Conductivity, Concentration X is a point from 0 to 9
scratch table

ASCII Command to Set a Concentration Table Entry

Function Command Explanation
X=point number. Y=conductivity in μS/cm, Z=concentration in %
Set Point in This function will put individual points in “temporary memory”. Entries
SUPNT X Y Z
scratch table will not become active until the full table is set with the SUTBL
command.
Activates new point entries.
Set Table SUTBL Will return ERROR if stored points for new table are not valid.
Will return OK if the new table is accepted.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted.

4.3.3 Contacting Conductivity Calibration

When a contacting conductivity sensor is connected to the DataStick, calibration choices specific to contacting conductivity are
automatically available. After a calibration, the sensor-head can be moved to another DataStick and measurement accuracy will
be maintained.
Sensors are calibrated at the factory. When field calibrations are necessary the ZERO calibration can be made when the sensor
is dry and out of the process. 1-POINT SAMPLE calibration can be done when the sensor is in process liquid.

4.3.3.1 ZERO CALIBRATION

Select ZERO from the calibration menu to begin the contacting conductivity zero calibration.
A zero calibration is applied to a sensor placed in dry air. The calibration establishes the zero for the measurement system
and will require more than 1 minute to complete. Please be patient.
Suspend the sensor in dry air, away from surfaces. Be sure that the sensor body is dry by wiping it clean with a dry rag.
For best results, wait for the sensor reading to reach a steady state.
Initiate the zero calibration by clicking the CALIBRATE button.

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 Once the calibration has been initiated it will take approximately 1 to 2 minutes. During this period, the abort sequence can
be initiated as shown with the active Abort button.

When the point has been successfully calibrated, measured values will be based on the new zero. The rate of change in reading
from the old measured value to the new will be dependent on the sensor filter value that is entered in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

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 ASCII Command to Initiate a Zero Calibration
Function Command Explanation
Zero Calibration CALSZERO Initiates a zero calibration of toroidal sensor
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is progressing. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.3.3.2 ONE-POINT SAMPLE CALIBRATION

Select 1-POINT SAMPLE from the calibration menu to begin a contacting conductivity span calibration.
When the 1-point sample method is chosen, the status box will prompt the user to enter the desired calibration value.
This calibration should be initiated when the sensor is in a liquid that is at the high end of the expected measuring range.
Stable temperature and sensor readings will also help to establish an accurate calibration.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor and
temperature values are stable and near expected values, click the CALIBRATE button to initiate the calibration or click EXIT
to return to the main measure screen.

Once the calibration has been initiated it will take between 30 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active ABORT button.

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 .

When the point has been successfully calibrated, measured values will be based on the new calibration. The rate of change
in reading from the old measured value to the new will be dependent on the sensor filter value that is entered in the configuration
menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to initiate a 1-Point Sample Calibration

Function Command Explanation
1-Point Sample CALS1PS Initiates a 1-point calibration
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.3.4 Contacting Conductivity Maintenance

Contacting conductivity cells must be kept clean to maintain accuracy. Even a thin film of oil or mineral deposits on the electrodes
can cause significant loss of span.

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 Note: Cleaning can be process-specific.
Some users will have to develop a procedure that works best for them.

Many types of deposits can be removed by wiping the electrodes with a cloth, brush, or paper towel and then rinsing with clean water.
Additional deposits may be removed by soaking in water and detergent. In general, never use a cleaner that contains a skin softener
such as aloe or lanolin. These can coat the electrode. Powdered Alconox™ and Dawn™ are known to work well.
Stubborn mineral deposits may be removed by soaking in dilute hydrochloric acid (about 0.1 M to 1.0 M). HCl will in time, attack both
316 stainless steel and titanium, so the cell should be soaked no longer than required. Rinse the cell to remove the acid.
Oily deposits may be removed with a solvent such as alcohol or acetone. Assure that the sensor body in compatible with the solvent.
A mild alkaline cleaner such as Alconox Solujet™ may also work.
Rinse or soak the cell in clean water before returning to service.

Caution: Ensure that a dangerous chemical reaction will not occur between process deposits and the
cleaning solution, such as compounds of cyanide, and the hydrochloric acid. Cyanide is often used in
electroplating and in gold refining. If in doubt check with a chemist.

Caution: When using dangerous chemicals such as hydrochloric acid or chlorine bleach, use all
appropriate safety precautions, especially eye protection.

4.4 Toroidal Conductivity

The toroidal conductivity sensor head has a number of physical features that should be noted. The connector is keyed. The key provides
protection for the pins during installation. To insure that pins remain free of moisture and dirt, a rubber boot is supplied with replacement
sensor heads and should be kept in place when the sensor is being transferred or placed in storage. In very humid or dirty environments,
we also recommend applying some electrical grease to the connector pins.
Keep the O-Ring and the shaft of the sensor free of dirt. Be sure the DataStick cavity is also free of dirt and moisture prior to insertion.

Connector Key Retaining Ring

Locks the sensor head
into the DataStick body
Gold Pins

Encapsulated
Product Number/ O-Ring
Serial Number Water tight seal

4.4.1 Toroidal Conductivity Overview

When an ORP sensor head is installed in the DataStick, AquaComm™ will automatically display millivolts, temperature, sensor type
and DataStick serial number. Pull-down menus will also automatically provide calibration, configuration and diagnostic choices for
toroidal conductivity.

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 Factory default configurations for an Toroidal sensor heads are:
• Units of measure: µS/cm (options include %, ppm and MΩ·cm)
• Units for temperature: °C (options include °F)
• Sensor Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Temperature Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Reference Temperature: 25°C (options include 0°C to 100°C)
• Compensation Slope: 2% / °C (options include 0 to 9.9 %/°C)
• Concentration Table (10 Points Capability): Point 1 is (0 µS/cm, 0%), Point 2 is (20,000 µS/cm, 99.99%)
When configuration information is changed in a DataStick, the information remains with the DataStick. If a new sensor head
is installed, the configuration will remain as programmed by the user. It will not revert to default values.
Calibration options for the toroidal conductivity sensor are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
• Zero: Sets the zero point for the sensor in dry air. Be sure the sensor is clean before doing this one.
Calibration options for temperature are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
4.4.2 Configuration of Toroidal Sensors
The AquaComm™ CONFIGURE functions can be accessed from a pull-down menu that automatically changes based on the sensor
type connected to the DataStick. When a toroidal sensor is connected, settings for data filters, units of measure, reference temperature,
temperature compensation and a 10-point concentration table can be viewed or changed.

4.4.2.1 SENSOR FILTER

Select SENSOR FILTER from the Configuration pull-down menu to view or change the sensor filter constant.

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 The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the sensor filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely
unfiltered reading.
4.4.2.2 TEMPERATURE FILTER

Select TEMPERATURE FILTER from the Configuration pull-down menu to view or change the temperature filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the temperature filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely unfiltered
reading.

Although temperature and sensor filter constants are independently controlled the best results are
generally achieved when both filters are set to the same constant.

The toroidal sensor head has significant mass and although the temperature element is located as close to the process as
possible, temperature readings can take up to 40 minutes to reach steady state when exposed to extreme temperature changes.
This is important to note when calibrating the sensor.

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 ASCII Commands to View Sensor and Temperature Filter Settings
Function Command Response Explanation
Get Sensor Filter GSFIL A number between 0 and 100. Number of seconds.
Get Temp Filter GTFIL A number between 0 and 100. Number of seconds.

ASCII Commands to Set Sensor and Temperature Filter Settings

Function Command Explanation
Set Sensor Filter SSFIL X Where X is a number between 0 and 100. Units are in seconds.
Set Temp Filter STFIL X Where X is a number between 0 and 100. Units are in seconds.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.4.2.3 SENSOR UNITS

Select SENSOR UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the sensor units window are active. To change units or to review options, scroll the selection list. Click on
the desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort
the change, click CANCEL.
For toroidal conductivity sensors, conductivity measurements can be set to conductivity in μS/cm, concentration in %, total
dissolved solids in ppm and resistivity in MΩ·cm.
Default units of measure are µS/cm.
Concentration measurements are converted from the data points entered in a 10-point concentration table that can be viewed
and edited from the Configuration pull-down menu.

ASCII Commands to View Sensor units

Function Command Response Explanation
View Sensor Units GSUNITS 0 Data reported in µS/cm units
1 Data reported in % concentration
2 Data reported in ppm (total dissolved solids)
3 Data reported in MΩ·cm units

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 ASCII Commands to Set Sensor units
Function Command Explanation
Set to µS/cm SSUNITS 0 Sensor data will be reported in µS/cm units
Set to % SSUNITS 1 Sensor data will be reported in % units
Set to ppm SSUNITS 2 Sensor data will be reported in ppm units
Set to MΩ·cm SSUNITS 3 Sensor data will be reported in MΩ·cm units
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.4.2.4 TEMPERATURE UNITS

Select TEMPERATURE UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the temperature units window are active. To change units or to review options, scroll the selection list. Click on
the desired units of measure to place the new choice in the sensor units window. To accept the change, click OK. To abort the
change, click CANCEL.
Temperature can be displayed in °C or °F. Default units are °C.

ASCII Commands to View Temperature units

Function Command Response Explanation
View Temperature Units GTUNITS 0 Data reported in °C
1 Data reported in °F

ASCII Commands to Set Temperature units

Function Command Explanation
Set °C STUNITS 0 Sensor data will be reported in °C
Set °F STUNITS 1 Sensor data will be reported in °F
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

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4.4.2.5 CONDUCTIVITY TEMPERATURE COMPENSATION TYPE

The commands in this section are available in DataStick firmware D3.32 or later. The DataStick firmware version can be obtained using
the GCVSN command.
ASCII Command to View Conductivity Temperature Compensation Type
Function Command Response Explanation
The type of temperature compensation used
0
is Linear (default)
View conductivity
temperature GCTCTYPE The type of temperature compensation used
1
compensation type is Natural Water
The type of temperature compensation used
2
is None

ASCII Commands to Set Conductivity Temperature Compensation Type

Function Command Explanation
Set conductivity
The type of temperature compensation used will be Linear and
temperature
SCTCTYPE 0 it will be based on the reference temperature and slope set with
compensation type
the SCRTEMP and SCCSLOPE commands, respectively
to Linear
Set conductivity
temperature The type of temperature compensation used will
SCTCTYPE 1
compensation type be Natural Water
to Natural Water
Set conductivity
temperature
SCTCTYPE 2 The type of temperature compensation used will be None
compensation type
to None
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted.
4.4.2.6 CONDUCTIVITY REFERENCE TEMPERATURE

Select REFERENCE TEMPERATURE from the Configuration pull-down menu to view or change the conductivity
reference temperature.
The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK.
To abort the change, click CANCEL.
The default reference temperature for conductivity is 25°C. The system will accept any number between 0 and 100
with up to one decimal place.
Edit the reference temperature by typing a new value in the edit box and clicking OK.

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 ASCII Command to View Conductivity Reference Temperature
Function Command Response Explanation
Get Reference GCRTEMP A number between 0 and 100 Data reported in °C

ASCII Command to Set Conductivity Reference Temperature

Function Command Explanation
Set Reference SCRTEMP X Where X is a number between 0 and 100. Units are in °C
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.4.2.7 CONDUCTIVITY TEMPERATURE COMPENSATION SLOPE

Select COMPENSATION SLOPE from the configuration menu to view or change the compensation slope for conductivity
measurements.
The default compensation slope is 2.00%/°C. The system will accept any number from 0 to 9.9 with up to two decimal places.
The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK. To abort
the change, click CANCEL.
The reference can be changed to any temperature between 0°C to 100°C with one-tenth degree resolution. Edit the reference
temperature by typing a new value in the edit box and clicking OK.

ASCII Command to View Conductivity Slope and Reference Temperature

Function Command Response Explanation
Get Slope GCCSLOPE A number between 0 and 9.9 Data reported in %/°C
Get Reference GCRTEMP A number between 0 and 100 Data reported in °C

ASCII Command to Set Conductivity Slope and Reference Temperature

Function Command Explanation
Set Slope SCCSLOPE X Where X is a number between 0 and 9.9. Units are in %/°C
Set Reference SCRTEMP X Where X is a number between 0 and 100. Units are in °C
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

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4.4.2.8 TEN POINT CONCENTRATION TABLE ENTRIES

Select CONCENTRATION TABLE from the configuration menu to view or change any or all of the points in the table.
When selecting the ten-point concentration table, there will be an automatic update of each of the 10 points before any editing
or scrolling of the table can occur. This scan takes about 10 seconds.
The concentration table coordinates must be monotonic. Conductivity must increase with each point. Concentration can either
increase or decrease with each point. The table must start at POINT 1 and continue incrementally from there. Unused points
(except POINT 1) have zero, zero coordinates.
Current entries can be viewed by scrolling up and down on the “Number” window.
Table entries for specific chemicals are available from Thermo Fisher Scientific Customer Service on request.

The default concentration table is set up as shown in Table 1. The numbers can be viewed by scrolling the up/down arrows.

Table 3: 10 Point Conductivity Vs. Concentration Table

Point Conductivity Concentration

(µS/cm) %
1 0 0
2 20,000 99.99
3 0 0
4 0 0
5 0 0
6 0 0
7 0 0
8 0 0
9 0 0
10 0 0

The following example shows how to change and add data points to the table. In this case, POINT 2 is changed
and POINTS 3 and 4 are added.

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 To change point 2 from 20,000 µS/cm at 99.99%, to 20,000 µS/cm at 50%, scroll to point 2 and place the cursor
in the concentration coordinate window.

Delete the 99.9 in the concentration coordinate and replace it with 50. Note that the STORE and REVERT buttons
are now active. If the point is what is intended, click the STORE button to save the point to temporary memory.
Clicking REVERT will restore the point to what it was before editing was initiated.

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 Scroll to point 3 and replace the zero coordinates with 50,000 μS/cm at 70% concentration. Then click on the STORE button
to save point 3 to temporary memory.

Scroll to point 4 and replace the zero coordinates with 100,000 μS/cm at 97% concentration. Then click on the STORE button
to save point 4 to temporary memory.

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 Data for points 5 through 10 should be zero. Data stored in temporary memory can now be permanently stored using
the ACTIVATE STORED TABLE button.

If any error messages are shown, review the data points to be sure they are monotonic, that conductivity increases
from point 1 and that concentration increases or decreases from point 1.
Once the table has been activated, use the EXIT button and return to the main measure menu.
Table entries for specific chemicals are available from Thermo Fisher Scientific Customer Service on request.
The table entries made in this example are shown in Table 2.
Table 4: Concentration Vs Conductivity after Editing
Point Conductivity (µS/cm) Concentration %
1 0 0
2 20,000 50
3 50,000 70
4 100,000 97
5 0 0
6 0 0
7 0 0
8 0 0
9 0 0
10 0 0
When the units of measure are set to “%” the conversion from conductivity to concentration will make use of the entered
table and will present the readings as shown.

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Inside the DataStick there are two concentration tables; the scratch table and the working table. The scratch table is used to store
the points written with the SUPNT command. If the points in the scratch table are valid, they are copied to the working table when the
SUTBL command is used. The points in the working table are used to convert the measured conductivity value into a concentration value.
The points in the scratch table can be read using the GSPNT command. The GSPNT command is available in DataStick firmware version
D3.21 or later. The DataStick firmware version can be obtained using the GCVSN command.
The points in the working table can be read using the GUPNT command. A point read from the working table using the GUPNT command
is automatically written to the scratch table. This helps to insure that the scratch table is always known and valid.

Scratch Table Working Table

Cond Conc Cond Conc
0 0 0 0 0 0
1 20000 99.99 1 20000 99.99
2 0 0 2 0 0
3 0 0 SUTBL 3 0 0
(if scratch table Conductivity
4 0 0 is valid) 4 0 0 scaling
5 0 0 5 0 0
6 0 0 6 0 0
7 0 0 7 0 0
8 0 0 8 0 0
9 0 0 9 0 0

SUPNT GUPNT
GSPNT

User

Figure 10. The inner workings of the User-Entered Concentration Table.

For the scratch table to be considered valid, the following must be true:
1. All successive conductivity point values must be monotonic and increasing and be within the bounds of 0 to 2,000,000.0
µS/cm.
2. The concentration values must be monotonic and either increasing or decreasing and be within the bounds of 0 to 99.99%.
3. If fewer than ten points are entered, then the scratch table must be terminated with a last point containing zero values.
Provided the above criteria are met, the points in the scratch table are transferred to the working table when the SUTBL command is used;
otherwise the current working table is retained.

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 ASCII Command to View Concentration Table Entries
Function Command Response Explanation
Get Point from
GUPNT X Conductivity, Concentration X is a point from 0 to 9
working table
Get point from
GSPNT X Conductivity, Concentration X is a point from 0 to 9
scratch table

ASCII Command to Set a Concentration Table Entry

Function Command Explanation
X=point number. Y=conductivity in μS/cm, Z=concentration in %
Set Point in This function will put individual points in “temporary memory”. Entries
SUPNT X Y Z
scratch table will not become active until the full table is set with the SUTBL
command.
Activates new point entries.
Set Table SUTBL Will return ERROR if stored points for new table are not valid.
Will return OK if the new table is accepted.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.4.3 Toroidal Conductivity Calibration

When a toroidal sensor is connected to the DataStick, calibration choices specific to toroidal conductivity are automatically available.
After a calibration, the sensor-head can be moved to another DataStick and measurement accuracy will be maintained.
Sensors are calibrated at the factory. When field calibrations are necessary the ZERO calibration can be made when the sensor
is dry and out of the process. 1-POINT SAMPLE calibration can be done when the sensor is in process liquid.

4.4.3.1 ZERO CALIBRATION

Select ZERO from the calibration menu to begin the toroidal conductivity zero calibration.
A zero calibration is applied to a sensor placed in dry air. The calibration establishes the zero for the measurement system
and will require more than 1 minute to complete. Please be patient.
Suspend the sensor in dry air, away from surfaces. Be sure that the sensor body is dry by wiping it clean with a dry rag.
For best results, wait for the sensor reading to reach a steady state. If the sensor is being calibrated for the first time,
the reading may be as high as 100 μS/cm. In most situations however, the sensor will already have a zero calibration
stored in it, which may require some periodic adjustment.

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 Initiate the zero calibration by clicking the CALIBRATE button.

Once the calibration has been initiated it will take approximately 1 to 2 minutes. During this period, the abort sequence
can be initiated as shown with the active Abort button.

When the point has been successfully calibrated, measured values will be based on the new zero. The rate of change in reading
from the old measured value to the new will be dependent on the sensor filter value that is entered in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

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 ASCII Command to Initiate a Toroidal Zero Calibration
Function Command Explanation
Zero Calibration CALSZERO Initiates a zero calibration of toroidal sensor
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is progressing. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.4.3.2 ONE-POINT SAMPLE CALIBRATION

Select 1-POINT SAMPLE from the calibration menu to begin a toroidal conductivity span calibration.
When the 1-point sample method is chosen, the status box will prompt the user to enter the desired calibration value.
This calibration should be initiated when the sensor is in a liquid that is at the high end of the expected measuring range.
Stable temperature and sensor readings will also help to establish an accurate calibration.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor
and temperature values are stable and near expected values, click the CALIBRATE button to initiate the calibration
or click EXIT to return to the main measure screen.

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 Once the calibration has been initiated it will take between 30 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active ABORT button.

When the point has been successfully calibrated, measured values will be based on the new calibration. The rate
of change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered
in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to Initiate a Toroidal 1-Point Sample Calibration

Function Command Explanation
1-Point Sample CALS1PS Initiates a 1-point calibration of toroidal sensor
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).
4.4.4 Toroidal Conductivity Maintenance
Unlike contacting conductivity where the electrodes must be kept clean of oil and other deposits, toroidal cells are not bothered by thin
coatings. In some processes however, surface deposits may become thick enough to cause a change in cell constant by constricting the
electric field around the cell. They must then be removed. All things being equal, deposits in the center bore are more important to remove
than those on the outer part of the body.
Use an appropriate chemical to remove the deposits on the cell and/or scrape the deposits off.

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 Note: Although toroidal conductivity cells are exceptionally robust, they can be damaged by physical
abuse, such as being struck against a hard surface.

4.5 Dissolved Oxygen (PPM and PPB) and Ozone

The Dissolved Oxygen and Ozone sensor heads have a number of physical features that should be noted. The connector is keyed.
The key provides protection for the pins during installation. To insure that pins remain free of moisture and dirt, a rubber boot is supplied
with replacement sensor heads and should be kept in place when the sensor is being transferred or placed in storage. In very humid or
dirty environments, we also recommend applying some electrical grease to the connector pins.
Keep the O-Ring and the shaft of the sensor free of dirt. Be sure the DataStick cavity is also free of dirt and moisture prior to insertion.

Connector Key O-Ring

Water tight seal
Gold Pins

Encapsulated
Product Number/
Serial Number

Retaining Ring
Locks the sensor head
into the DataStick body
Replaceable Membrane
Cap

4.5.1 Dissolved Oxygen / Ozone Interface Overview

When an Dissolved Oxygen / Ozone sensor heads are installed in the DataStick, AquaComm™ will automatically display ppm,
temperature, sensor type and DataStick serial number. Pull-down menus will also automatically provide calibration, configuration
and diagnostic choices.

Factory default configurations for a dissolved oxygen or ozone sensor head are:
• Units of measure: ppm ) (options include % and ppb)
• Units for temperature: °C (options include °F)
• Sensor Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Temperature Filter: 1 Second (options include 0 to 100 seconds in 1 second increments)
• Salinity: 0 mS/cm (options from 0 to 999.9 mS/cm)
• Atmospheric Pressure: 760 mmHg (options from 539.2 to 792.4 mmHg)

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 When configuration information is changed in a DataStick, the information remains with the DataStick. If a new sensor head
is installed, the configuration will remain as programmed by the user. It will not revert to default values.
Calibration options Dissolved Oxygen and Ozone sensors are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.
• Air Calibration: Measures the oxygen in air, compensated by the configured atmospheric pressure setting.
Calibration options for temperature are:
• 1-point Sample Calibration: Desired reading is entered for one sample to adjust measurement offset.

4.5.2 Configuration of Dissolved Oxygen and Ozone Sensor Heads

The AquaComm™ CONFIGURE functions can be accessed from a pull-down menu that automatically changes based on the sensor
type connected to the DataStick. When a dissolved oxygen sensor is connected, settings for data filters, units of measure, atmospheric
pressure, salinity, and temperature compensation can be viewed or changed.

4.5.2.1 SENSOR FILTER

Select SENSOR FILTER from the Configuration pull-down menu to view or change the sensor filter constant.
The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the sensor filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely
unfiltered reading.

4.5.2.2 TEMPERATURE FILTER

Select TEMPERATURE FILTER from the Configuration pull-down menu to view or change the temperature filter constant.

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 The filter setting can be changed by selecting the edit box and typing in the desired constant. To accept the change, click OK.
To abort the change, click CANCEL.

If the temperature filter is set to 5 seconds, it will take 5 seconds to reach 90% of the final value when the reading changes.
Measurements are averaged to reduce periodic variations.
The default filter setting is 1 second and the maximum filter is 100 seconds. Use zero seconds for a completely unfiltered
reading.

Although temperature and sensor filter constants are independently controlled the best results
are generally achieved when both filters are set to the same constant.

ASCII Commands to View Sensor and Temperature Filter Settings

Function Command Response Explanation
Get Sensor Filter GSFIL A number between 0 and 100. Number of seconds.
Get Temp Filter GTFIL A number between 0 and 100. Number of seconds.

ASCII Commands to Set Sensor and Temperature Filter Settings

Function Command Explanation
Set Sensor Filter SSFIL X Where X is a number between 0 and 100. Units are in seconds.
Set Temp Filter STFIL X Where X is a number between 0 and 100. Units are in seconds.
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.5.2.3 SENSOR UNITS

Select SENSOR UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the sensor units window are active. To change units or to review options, scroll the selection list.
Click on the desired units of measure to place the new choice in the sensor units window. To accept the change, click OK.
To abort the change, click CANCEL.
For dissolved oxygen sensors, units of measure can be set to ppm or %. For special DO sensors, ppb units can also be selected.
Consult the factory for details.

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 Default units of measure are ppm.

ASCII Commands to View Sensor units

Function Command Response Explanation
View Sensor Units GSUNITS 0 Data reported in ppm units
1 Data reported in % concentration

ASCII Commands to Set Sensor units

Function Command Explanation
Set to ppm SSUNITS 0 Sensor data will be reported in ppm units
Set to % SSUNITS 1 Sensor data will be reported in % concentration
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.5.2.4 TEMPERATURE UNITS

Select TEMPERATURE UNITS from the Configuration pull-down menu to view or change units of measure.
Units shown in the temperature units window are active. To change units or to review options, scroll the selection list.
Click on the desired units of measure to place the new choice in the sensor units window. To accept the change, click OK.
To abort the change, click CANCEL.
Temperature can be displayed in °C or °F. Default units are °C.

ASCII Commands to View Temperature units

Function Command Response Explanation
View Temperature Units GTUNITS 0 Data reported in °C
1 Data reported in °F

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 ASCII Commands to Set Temperature units
Function Command Explanation
Set °C STUNITS 0 Sensor data will be reported in °C
Set °F STUNITS 1 Sensor data will be reported in °F
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.5.2.5 ATMOSPHERIC PRESSURE SETTING FOR AIR CALIBRATION

Select PRESSURE from the Configuration pull-down menu to view or change the setting of atmospheric pressure used
during an air calibration.
Edit the pressure setting by typing a new value in the edit box. To accept the change, click OK. To abort the change,
click CANCEL.
The system will accept any number between 539.2 and 792.4 with up to one decimal place.

The default PRESSURE setting for dissolved oxygen and ozone measurements is 760mm•Hg.

ASCII Command to View Conductivity Reference Temperature

Function Command Response Explanation
Get Pressure GPRESS A number between 539.2 and 792.4 Data reported in mm•Hg

ASCII Command to Set Conductivity Reference Temperature

Function Command Explanation
Set Pressure SPRESS X Where X is a number between 539.2 and 792.4. Units are in mm•Hg
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.5.2.6 SALINITY SETTING

Select SALINITY from the configuration menu to view or change the salinity compensation for dissolved oxygen measurements.
The default compensation slope is 0 mS/cm. The system will accept any number from 0 to 999.9 with up to one decimal place.

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 The setting can be changed by selecting the edit box and typing the desired number. To accept the change, click OK.
To abort the change, click CANCEL.

ASCII Command to View Conductivity Slope and Reference Temperature

Function Command Response Explanation
Get Salinity GSALT A number between 0 and 999.9 Data reported in mS/cm

ASCII Command to Set Conductivity Slope and Reference Temperature

Function Command Explanation
Set Salinity SSALT X Where X is a number between 0 and 999.9. Units are in mS/cm
All Set Commands will respond with “OK” if accepted and “ERROR” if not accepted

4.5.3 Dissolved Oxygen Calibration

When a DO sensor is connected to the DataStick, calibration choices specific to DO are automatically available. After a calibration,
the sensor head can be moved to another DataStick and measurement accuracy will be maintained.

Sensors are calibrated at the factory. When field calibrations are necessary, Air and 1-point sample calibrations are available.
For DO sensors that have not been active for several hours, it may take up to 1 hour before the reading becomes stable and accurate.

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4.5.3.1 ONE-POINT SAMPLE CALIBRATION

Select 1-POINT SAMPLE from the calibration menu to begin a dissolved oxygen span calibration.
When the 1-point sample method is chosen, the status box will prompt the user to enter the desired calibration value.
This calibration should be initiated when the sensor is in a liquid that is at the high end of the expected measuring range.
Stable temperature and sensor readings will also help to establish an accurate calibration.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed sensor and
temperature values are stable and near expected values, click the CALIBRATE button to initiate the calibration or click EXIT
to return to the main measure screen.

Once the calibration has been initiated it will take between 30 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active ABORT button.

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 When the point has been successfully calibrated, measured values will be based on the new calibration. The rate
of change in reading from the old measured value to the new will be dependent on the sensor filter value that is entered
in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to initiate a 1-Point Sample Calibration

Function Command Explanation
1-Point Sample CALS1PS Initiates a 1-point calibration
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

4.5.3.2 AIR CALIBRATION

Select AIR from the calibration menu to begin a dissolved oxygen air calibration.
Hold the sensor in the air and wait for temperature and sensor readings to stabilize. Do not allow the sensor membrane
to dry out.

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 Press the CALIBRATE button to initiate the calibration or click EXIT to return to the main measure screen.

Once the calibration has been initiated it will take between 30 seconds and 2 minutes depending on sensor and temperature
measurement stability. During this period, the abort sequence can be initiated as shown with the active ABORT button.

When the point has been successfully calibrated, measured values will be based on the new calibration. The reading will be
in the range of 8 ppm to 10 ppm depending on the atmospheric pressure setting. Consult dissolved oxygen tables for more
specific information on expected readings after an AIR calibration.
Exiting the calibration menu will return the user to the measure screen.

ASCII Command to Initiate an Air Calibration

Function Command Explanation
1-Point Sample CALSAIR Initiates an AIR calibration for DO or Ozone sensors
All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1,
the calibration is in process. When the last number returned is a 2, the calibration has been successful. Any other number
indicates a specific failure mode (see appendix).

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4.5.4 Zero Calibration

This calibration should not be initiated without a reliable zero reference.

Place the sensor in a solution from which all dissolved oxygen has been removed.
ASCII Command to Initiate a Zero Calibration
Function Command Explanation
Zero calibration CALSZERO Initiates a zero calibration for the DO sensor

4.5.4 Dissolved Oxygen Maintenance

Care must be taken when cleaning a DO sensor. The membrane is only a few thousands of an inch thick and can be punctured
or stretched by excessive pressure.
• Rinse off as much material as possible with a spray of warm, clean water. Soaking in water and detergent may loosen
additional material. Use a cleaner that does not contain oily hand softeners such as aloe or lanolin. Powdered Alconox™
and Dawn™ work well.

• Clean off left over material by wiping with a soft cloth or paper towel and clean water. A bristle brush is not recommended.

• If the membrane is worn or punctured, replace the membrane cartridge as shown in the following figure.

4.6 Turbidity
When a Turbidity system is installed, the DataStick automatically sends measurement information in NTU. Temperature is also provided.
All ASCII commands for measurement, calibration, configuration and diagnostics shown in Appendix 7 apply. For Drinking Water Turbidity
Systems, an AV38 local interface is provided. Refer to the AquaClear™ Low-Range Turbidimeter User Guide (258483-001) for details.

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 4.6.1 Drinking Water Turbidity
Mounting Plate
4 screws are needed
to mount the turbidity system

AV38 Local Display

This ¼ DIN NEMA 4X display is used
for local display, calibration, configuration
and diagnostics.

DataStick with Optical Detector

This can be connected through an AV38
Local Display or it can be cabled directly
to a computer network.
Sample Chamber and Plumbing
Terminal Block This sample chamber is used to remove
This box is used for wiring power, current loops, bubbles and prepare the sample for
relays, light source and host communications. measurement. It has a lid with a white
light source.

4.6.2 Wide-Range Turbidity Measurement System

Refer to the Wide-Range Turbidity Measurement System User Guide (258485-001) for details.

DataStick Communications
Any DataStick communications adapter can
be connected directly to the wide-range turbidity
system for direct computer communications.

Optical Head
The Wide-Range Turbidity system can
measure to 4000 NTU with a sophisticated
series of light sources and detectors.

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4.7 Temperature Calibration
All DataStick sensor heads (transducers) measure temperature the same way and share a common calibration process.

Select TEMPERATURE from the calibration menu to begin a temperature calibration. The status box will prompt the user to enter
the desired calibration value.

Once the desired value for calibration is entered, the CALIBRATE button becomes active. Once the displayed temperature value is stable
and near expected values, click the CALIBRATE button to initiate the calibration or click EXIT to return to the main measure screen.

Once the calibration has been initiated it will take about 30 seconds depending on temperature measurement stability. During this period,
the abort sequence can be initiated as shown with the active Abort button.

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When the point has been successfully calibrated, measured values will be based on the new calibration. The change in reading
from the old measured value to the new will be dependent on the temperature filter value that is entered in the configuration menu.

Exiting the calibration menu will return the user to the measure screen.

ASCII Command to initiate a 1-Point Temperature Calibration

Function Command Explanation
Temperature CALST1PS Initiates a 1-point calibration of temperature
Calibration

All Calibration Commands will respond with “OK” if accepted and “ERROR” if not accepted
The status of the calibration can be reviewed with the CALSTATUS command. When the last number returned is a 1, the calibration
is in process. When the last number returned is a 2, the calibration has been successful. Any other number indicates a specific failure
mode (see appendix).

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5 Diagnostics and Troubleshooting
5.1 Diagnostics
As long as the DataStick system is communicating with the host computer or PLC, a single command can be sent to obtain all operational
information. Through AquaComm™ the command is initiated through the DIAGNOSE pull down menu.

Select STATUS and all information will be detailed in the following report.

In this example specific information can link the specific DataStick to calibration and test information at the factory. Whenever there
are issues in the field, this information can make it much easier for Thermo Fisher Scientific to assist in troubleshooting.
In this example we know that the sensor type has been properly detected and that configuration and calibration memory are valid.
Most importantly, the run status of the DataStick is okay.
Refer to the Programming Guide for specific diagnostic commands and responses.

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5.2 Troubleshooting

Start

1. Check power is properly applied.

No 2. Check communications wires are properly connected.
Communications 3. Check baud rate, parity and station number.
OK 4. Check that the Comms Adapter is properly connected.

Fault not found: Replace DataStick or Comms Adapter.

Yes

1. Check that the sensor head is properly connected.

No 2. Cycle power.
Detected Sensor 3. Reset DataStick memory.
Type OK 4. Remove sensor head and inspect internal connectors (clean & dry).

Fault not found: Replace Sensor Head.

If problem persists, replace DataStick.
Yes

1. Cycle power.
No 2. Reset DataStick memory.
Detected Memory
OK
Fault not found: If failure is Sensor Memory, replace Sensor Head.
If failure is in Configuration or Calibration Memory, replace DataStick.
Yes

1. Check integrity of sensor electrodes, membranes and junctions.

No 2. Check sensor configuration to be sure appropriate parameters are
Sensor Calibration
OK properly set. These include: buffer type, pressure, salinity, temperature,
reference temperature, and reference slope.
3. Check that the temperature reading is correct.
If it reads full-scale then the temperature element is open circuit.
Yes
4. Check that sensor and temperature readings are stable in the
calibration solution. If not, wait for the sensor to reach equilibrium.
5. Check that the calibration solutions are correct.

Fault not found: Refurbish or replace the sensor head.

No
Measurement OK
1. Check sensor configuration to be sure appropriate parameters
are properly set. These include: buffer type, pressure, salinity,
temperature, reference temperature, and reference slope.
Yes 2. Check that the temperature reading is correct.
If it reads full-scale then the temperature element is open circuit.
3. Check that the calibration solutions are correct.
End
Fault not found: Refurbish or replace the sensor head.

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5.2.1 pH Sensor Head inspection

If the glass electrode is broken replace the sensor head.

If the salt bridge junctions have dried out soak the sensor head in salt bridge storage solution for several hours, or replace it and fill
the reference chamber with new reference solution.

Note: Any new sensor that has been in storage for more than a few days should be soaked in tap water
or a solution of known pH for at least 30 minutes before reviewing the span and offset performance.

Note: The electrodes of any pH sensor in storage must be kept moist at all times. Protective caps should
be filled with Thermo Scientific AquaSensors storage solution for best performance. The protective cap
should be placed securely over the sensor head.

If the sensor passes the visual inspection, there are three basic measurement tests that can verify normal operation. The temperature
measurement can be verified with an independent thermometer. Temperature comparisons should be done in liquid as it takes the sensor
much longer to reach steady state in air. The pH offset can be verified in 7 pH buffer. If the reading is more that 0.5 pH units off in 7 pH
buffer, then the sensor needs to be refurbished. The sensor should be stirred if the test is done in a beaker or at least the sensor head
should be swirled around for 10 seconds to make sure the solution gets through the reference junction. The pH span can be verified in a
sample solution that is more that 3 pH units away from 7 pH. Generally 4 pH buffer and 10 pH buffer work well. If the reading is more than
1 pH unit off then the sensor needs to be refurbished or replaced.
Make sure the correct configuration settings have been made:
• Correct Buffer Standards selected for buffer calibrations
• Temperature should read within 2 degrees centigrade of the expected value

5.2.2 ORP Sensor Head inspection

If the glass around the platinum electrode is broken replace the sensor head.
If the salt bridge junctions have dried out soak the sensor head in salt bridge storage solution for several hours, or replace it and fill
the reference chamber with new reference solution.

Note: Any new sensor that has been in storage for more than a few days should be soaked in tap water or
Thermo Scientific AquaSensors ORP Storage Solution for at least 30 minutes before reviewing the offset
performance.

Note: The salt bridge of any ORP sensor in storage must be kept moist at all times. Protective caps should
be filled with Thermo Scientific AquaSensors Storage Solution for best performance. The protective cap
should be placed securely over the sensor head.

If the sensor passes the general inspection, there are two basic tests that can verify normal operation. If the sensor passes the visual
inspection, there are two basic measurement tests that can verify normal operation. The temperature measurement can be verified with
an independent thermometer. Temperature comparisons should be done in liquid as it takes the sensor much longer to reach steady state
in air. The ORP measurement should be tested with a solution that is at least +200 mV. If the reading is more than 100 mV off then the
sensor needs to be refurbished or replaced.

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5.2.3 Dissolved Oxygen and Ozone Sensor Head inspection
Dissolved Oxygen and Ozone sensors may take up to 30 minutes to reach correct measurement values once power is applied. The less
oxygen in the electrolyte filling solution the better. Never vigorously stir or shake filling solution when replacing a cartridge. When power
is first applied to a DO or Ozone sensor, the reading will show saturation and then slowly decrease to the correct value.
Make sure there are no large bubbles (over 2 mm) under the membrane and that the membrane is stretched tightly over the center (gold)
electrode. Make sure the membrane cap is screwed down completely.
Make sure the correct configuration settings have been made:
• Pressure is normally set to 760 mmHg.
• Salinity is normally set to 0 mS/cm
• Temperature should read within 2 °C of the expected value

If the sensor has been given sufficient time after power is applied to reach the proper reading, several things can happen:
• If the sensor reads zero all the time: Replace the electrolyte and membrane cartridge.
• If the sensor reads near full scale and does not come down, give it additional time. If the electrolyte was shaken
vigorously prior to filling, additional time may be needed.

When the sensor head is placed in storage, keep the membrane moist with a wetted sensor cap.

5.2.4 Contacting Conductivity Sensor Head inspection

The best way to determine if a contacting conductivity sensor head requires cleaning is to connect a 1000 ohm resistor between the inner
and outer electrode in a dry environment and divide it by the current cell constant are reported in the AquaComm™ configuration menu.
If the measured reading is within 5% of the calculated reading, then the DataStick should be computing correctly. In liquid, if the
measurement reading is too far off for a valid calibration, then the electrodes must be cleaned and be free of oils.
It is also possible that the sensor will read correctly in solutions of a specific conductivity but not at others. This can be determined by
increasing the resistance between the electrodes from 100 ohms in 200 ohms steps to 5000 ohms in a dry environment. If the reading
either oscillates or displays a reading that is wildly off, there is a specific measurement range that has failed. This is most likely a problem
in the DataStick and not necessarily in the sensor head.
Make sure the correct configuration settings have been made:
• Reference temperature is normally set to 25 °C
• Reference slope is normally set to 2 % / °C
• Temperature should read within 0.5 °C of the expected value

When the sensor head is placed in storage, cap the metal electrodes to keep them clean and dry.

5.2.5 Toroidal Conductivity Sensor Head inspection

A toroidal conductivity sensor measures within 1 µS/cm from 1 μS/cm to 5 S/cm. It is possible that the sensor will read correctly in
solutions of a specific conductivity but not in others. This can be determined by increasing the resistance of a wire that is looped through
the center hole of the sensor. If the reading oscillates or displays a reading that is wildly off with a given resistance, there is a specific
measurement range that has failed. This is most likely a problem in the DataStick and not necessarily in the sensor.
Make sure the correct configuration settings have been made:
• Reference temperature is normally set to 25 °C
• Reference slope is normally set to 2 % / °C
• If measuring in %, make sure the concentration table entries make sense.
• Temperature should read within 0.5 °C of the expected value
When the sensor head is placed in storage, cap the metal electrodes to keep them clean and dry.

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6 Programming Guide - Commands and Responses
These commands can be used to program any host computer. If programming is not desirable, Thermo Fisher Scientific offers a
communications software package that can be used with most PC, PLD and PLC systems. The following ASCII text strings can be used
to exercise functions and features of the DataStick measurement system. If an RS-232 ASCII communications adapter is installed, any
terminal program can be used to communicate with the DataStick by typing commands and reading the replies.
The DataStick responds to commands from a host computer system except when a CALL command has been initiated to request periodic
data. These include CALL, CSNSR and CTEMP commands. The ESC key halts all CALL commands. Commands that are recognized and
accepted return an “OK”. Commands that are not return accepted return an “ERROR”.
The form of any command is:
KEYWORD P0 P1 P2….Pn [CR]; where the KEYWORD is the command identifier, the space character is the parameter separator,
Pn is a command parameter, and [CR] is carriage return, the command terminator. All commands are sent in an ASCII format.
Communication setups vary depending on the protocol chosen.
• RS-232 ASCII: 9600 Baud, 8 data bits, no parity, 1 stop bit.
• RS-232 DF1: Selectable baud rate and parity using a Thermo Scientific AquaSensors software utility.
• RS-485 MODBUS: Station address, baud rate, parity are selectable using a Thermo Scientific AquaSensors
software utility.
• Ethernet, USB, DeviceNet, Profibus do not require communications setup.

Commands and responses are organized in the following tables:

Table 5: Data Reporting
Table 6: Changing Measurement and Configuration Settings
Table 7: View Configuration Settings
Table 8: Calibration Commands
Table 9: Diagnostic and Systems Information
Table 10: Simulated Temperature Control

Please note that commands are common for each sensor type but that response codes may vary depending on the sensor connected.
A 1-point sample calibration command will be the same for dissolved oxygen as it is for toroidal conductivity. This simplifies ladder logic
coding for applications that presume the possibility of changes in sensor type.
Table 5: Data Reporting

Get Measurement Using the Command And view response

Comments
Data for … Text… from the DataStick…
Obtains current sensor data at a rate defined
Number with decimal in selected by the host computer (Polled).
Sensor GSNSR units of measure. Units of measure are configured using the
(Main Parameter) SSUNITS command.
Obtains current temperature data at a rate
Number with decimal in selected defined by the host computer (Polled).
Temperature GTEMP units of measure. Units of measure are configured using the
STUNITS command.
Obtains current sensor and temperature data
Sensor and temperature readings every X seconds. Example: CALL 5 would
Main parameter and
every X seconds in selected units return new values for the main parameter
temperature CALL X of measure. and temperature every five seconds. Reporting
is halted with the ESC key.

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 Table 6: Change Measurement Configuration Settings

Change Configuration Using the

Where X is a number meaning… Comments
Settings for… Command Text…
PH: Typing “SSUNITS 3”when a toroidal
0 = pH units conductivity sensor head is installed
1 = mV units will set measurement units to MΩ•cm.
ORP:
0 = mV
Sensor Conductivity: As different sensor heads are added to
Units of Measure SSUNITS X 0 = µS/cm the family of DataStick measurements
1=% this list will be expanded.
2 = TDS
3 = MΩ•cm
DO/Ozone:
0 = ppm
Default is always zero (X = 0).
1=%
Typing “STUNITS 0” will set
Temperature STUNITS X 0 = ˚C temperature units to ˚C.
Units of Measure 1 = ˚F Default is always zero (X = 0).
Filter time constant from 0 to 100 seconds. The sensor process variable will reach
Sensor Data Filter SSFIL X
X = 0 to X = 100. 90% of the final value in “X” seconds.
Filter time constant from 0 to 100 seconds. The temperature variable will reach 90%
Integers only. of the final value in “X” seconds. Caution:
Temperature Data Filter STFIL X It is advised to keep the temperature
X = 0 to X = 100. and process filter constants equal.
pH buffer calibration: the current
Buffer type set for auto recognition during reading will be changed to the closest
Buffer Set buffer calibration. value in the buffer set selected.
SPHBUF X
for pH calibration
0 = 4, 7, 10 pH Buffers DIN Buffer Standards are: 1.09, 4.65,
1 = DIN Buffer Standards 6.79, 9.23 and 12.75 pH

Salinity is set from 0 to 999.9 mS/cm. Set up the average salinity for
Salinity for Dissolved
SSALT X compensation of dissolved oxygen
Oxygen Compensation X = 0 to X = 999.9 mS/cm measurement.
Pressure for Dissolved Pressure is set from 539.2 to 792.4 mmHg Set up the average pressure for
SPRESS X
Oxygen Compensation X = 539.2 mmHg to X = 792.4 mmHg compensation of measurement.
Conductivity Reference Conductivity reference temperature is set
SCRTEMP X Default value is 25˚C.
Temperature from 0˚C to 100˚C. X = 0˚C to X = 100˚C
Conductivity Conductivity slope is set from:
SCCSLOPE X Default is 2.0%/˚C
Compensation Slope X = 0 to X = 9.9% / ˚C
Points in the table where:
X is the table entry (X = 0 through 9) This table is designed to convert
Customized conductivity measurements to
Y is the Conductivity value in µS/cm.
Concentration Table SUPNT X Y Z concentration. Currently uses a built-in
Z is the Concentration value in %.
Natural Water table for temperature
Conductivity Range: 0 to 2,000,000.0 compensation. Up to 10 points.
Concentration Range: 0 to 99.99%
Customized When edits to all points are complete use Entries must be monotonic
SUTBL
Concentration Table SUTBL to activate the new table with increasing conductivities.

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Table 7: View Configuration Settings

View Configuration Using the Where the DataStick replies with a number
Comments
Settings for… Command Text… that means…
PH:
0 = pH units
1 = mV units
ORP:
Sensor 0 = mV As different sensor heads are added to
Conductivity: the family of DataStick measurements
Units of Measure GSUNITS 0 = µS/cm this list will be expanded.
1=%
2 = TDS
3 = MΩ•cm
DO/Ozone:
0 = ppm
1=%
Temperature Units 0 = ˚C
GTUNITS
of Measure 1 = ˚F
Filter time constant from 0 to 100 seconds. The sensor process variable will reach
Sensor Data Filter GSFIL
Integers only. 90% of the final value in “X” seconds.
The temperature variable will reach
Filter time constant from 0 to 100 seconds. 90% of the final value in “X” seconds.
Temperature Data Integers only.
GTFIL Caution: It is advised to keep the
Filter
temperature and process filter
constants equal.
pH buffer calibration: the current
Buffer type set for auto recognition during reading will be changed to the closest
Buffer Set for pH buffer calibration. value in the buffer set selected.
GPHBUF
Calibration
0 = 4,7, 10 pH Buffer DIN Buffer Standards are:
1 = DIN Buffer Type 1.09, 4.65, 6.79, 9.23 and 12.75 pH
Salinity for Salinity setting between: Average salinity for compensation
Dissolved Oxygen GSALT
0 and 999.9 mS/cm of dissolved oxygen measurement.
Compensation
Pressure for Pressure setting between: Average pressure for compensation
Dissolved Oxygen GPRESS
539.2 to 792.4 mmHg of dissolved oxygen measurement.
Compensation

Conductivity Conductivity reference temperature is set

Reference GCRTEMP from: Default value is 25˚C
Temperature 0˚C to 100˚C
Conductivity Conductivity slope is set from:
Compensation GCCSLOPE Default is 2.0%/˚C
Slope 0 to 9.9%/˚C

X is the table entry (X = 0 through 9).

Customized This table is designed to convert
Concentration GUPNT X The values returned are: conductivity measurements to
Table Conductivity in µS/cm concentration. Up to 10 points.
Concentration in %

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 View Configuration Using the Where the DataStick replies with a number
Comments
Settings for… Command Text… that means…
Customized GSPNT X X is the table entry (X = 0 through 9). This table is designed to convert
Concentration conductivity measurements to
The values returned are:
Table concentration. Up to 10 points.
Conductivity in µS/cm
Concentration in %

Table 8: Calibration Commands

Calibration Using the Command

Parameter Comments
Method… Text…
Auto buffer recognition. Just initiate the command
pH 1-point pH Buffer CALS1PB
and the system will adjust offset.
Auto buffer recognition.
CALS2PB X CALS2PB 0 stores calibration data from the first
buffer solution.
2-point pH Buffer CALS2PB 1 stores calibration data for the second
Where:
buffer solution.
X = 0 is the first point
X = 1 is the second point Readings do not change until the second point
has been accepted.

CALS1PS X Sample calibration changes the current value

1-point pH Sample to a desired value.
Where:
X = Desired number in pH Example: CALS1PS 7.5
Put the sensor in the first sample solution and adjust
the first point to the desired reading:
CALS2PS X Y Example: CALS2PS 0 7.5
Put the sensor in the second sample solution and
2-point pH Sample
Where: adjust the second point to the desired reading:
X = Point 0 or 1 Example: CALS2PS 1 4.12
Y = Desired Value in pH
Readings do not change until the second point
has been accepted.
Sample calibration changes the current value to
CALS1PS X a desired value. If the reading is currently +235 mV
ORP 1-point ORP Sample and the desired value is +300mV, then:
Where:
X = Desired number in mV CALS1PS 300
Make a user guide adjustment to the actual
cell constant. This will change the calibration.
SCELL X
Contacting Adjust Example: SCELL 1.0045
Conductivity Cell Constant Where:
X = Desired cell constant This will change the cell constant and change
the measurement.

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 Calibration Using the Command
Parameter Comments
Method… Text…
Enter desired value and initiate calibration.
CALS1PS X
1-point Contacting
Example: CALS1PS 1250
Conductivity Sample Where:
X = Desired number in µS/cm Will change the current reading to 1250 µS/cm

Contacting Establish the sensor zero. With sensor in dry air,

CALSZERO
Conductivity ZERO initiate this calibration.

Toroidal CALS1PS X Enter desired value and initiate calibration.

Conductivity 1-point Sample This will take time with many ranges to calibrate.
X = Desired number in µS/cm
Establish the sensor zero. With sensor in dry air,
ZERO CALSZERO
initiate this calibration.
Put the sensor in air and initiate this calibration.
Dissolved AIR Calibration for The final reading should be the amount of oxygen
CALSAIR
Oxygen Dissolved Oxygen in air - approximately 8 to 9 ppm depending on
temperature, pressure and salinity.
1-point CALS1PS X
Dissolved Oxygen Enter desired value and initiate calibration.
Sample X = Desired number in ppm

ZERO for Establish the sensor zero for ppb measurements.

CALSZERO This calibration should not be initiated without a
Dissolved Oxygen reliable zero reference.
1-point CALT1PS X
Temperature Temperature Enter desired value and initiate calibration.
Sample X = Desired number in ˚C

Once a calibration sequence has been initiated, this

Check
All CALSTATUS command will return detailed status. See below for
Calibration Status
details of the response codes.
Sending this command with stop any calibration
Abort Calibration CALABORT sequence currently in process and return the system
to its original state.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 103

Calibration Status (CALSTATUS) Response Codes:

Reply is of the form: XYZ

Where:
X Y Z

0= No Sensor Calibration 0 = No Sensor Calibration 0 = No Sensor Calibration

1= pH Sensor 1 = 1pt Buffer 1 = Cal In Progress
2= ORP Sensor 2 = 2pt Buffer, 1st point 2 = Cal OK
3= DO Sensor 3 = 2pt Buffer, 2nd point 3 = Fail – Not Stable
4= Contacting Conductivity Sensor 4 = 1pt Sample 4 = Fail – Buffer not found
5= Toroidal Conductivity Sensor 5 = 2pt Sample 1st point 5 = Fail – 1st Buffer not found
6= Ozone Sensor 6 = 2pt Sample 2nd point 6 = Fail – 2nd Buffer not found
7= Turbidity Sensor 7 = Air Calibration 7 = Fail – Value too low
8 = Zero Calibration 8 = Fail – Value too high
10 = Temperature Calibration 9 = Fail – Slope too low
10 = Fail – Slope too high
11 = Fail – Offset too low
12 = Fail – Offset too high
13 = Fail – Points too close
14 = General Cal Fail

Calibration Procedure

The DataStick system can perform many different calibration types, e.g., air, 1-point buffer, 2-point sample, etc.
Aside from the calibration command used, the procedure is the same for all of them. Below is a description of that procedure.
1. Observe the calibration status by monitoring the Z field in the response from the CALSTATUS command (see above).
Prior to using the calibration command, the value will be 0 (no sensor calibration).
2. Prepare the DataStick for calibration and allow the measured readings to stabilize.
3. Issue the appropriate calibration command, e.g., CALS1PS to do a 1-point sample calibration.
4. Monitor the Z field and observe the change from 0 to 1 indicating that the calibration is in progress.
5. Continue monitoring the Z field. When it changes from 1 to 2 (Cal OK), the calibration procedure is complete and has been
successful. If it changes from 1 to 3 or greater, then the procedure is complete but has failed. For example, if it changes
from 1 to 7 (Fail – Value too low), it indicates that the measured value is too close to zero for a calibration to take place.
Take corrective action and repeat the procedure.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 104

 Table 9: Diagnostics and System Information

Using the Where the DataStick replies with a number

Get… Comments
Command Text… that means…
First Number (Sensor Status):
0 = Sensor memory not functional
1 = Sensor memory not valid
2 = Sensor memory valid
Second Number (User Configuration Status):
1 = Configuration initialized
2 = Configuration valid
3 = Configuration valid and new sensor
System Status GSTATUS Tests system ID, calibration memory
4 = Configuration valid but new version
Third Number (DataStick Cal Status): and runtime status.
1 = DataStick calibration initialized
2 = DataStick calibration valid
3 = DataStick calibration valid but new
version
Fourth Number (Run Status):
0 = System error
1 = Sensor installation required
2 = System OK
CSNSR X Get sensor in millivolts, ADC counts, and value More detailed measurement
in user set units every X seconds. information can help diagnose
Raw Sensor Data Where:
system integrity. Readings will
X = frequency in
be reported every X seconds.
seconds
CTEMP X More detailed measurement
Get temperature in millivolts, ADC counts, and
Raw Temperature Where: value in user set units every X seconds. information can help diagnose
Data X = frequency in system integrity. Readings will
seconds be reported every X seconds.

0 = No Sensor Connected
1 = pH
2 = ORP Confirmation that the correct
Check Sensor 3 = DO
GSTYPE sensor type is connected
Type 4 = Contacting Conductivity or configured properly.
5 = Toroidal Conductivity
6 = Ozone
7 = Turbidity
PH:
0 = Differential
1 = Combination
ORP:
0 = Differential Confirmation that the correct
Check Sensor
GSCAT 1 = Combination sensor category is connected
Sub-Type
Conductivity: or configured properly.
0 = 0.1 Cell (Nominal)
1 = 1.0 Cell (Nominal)
2 = 10.0 Cell (Nominal)

Current For contacting conductivity: 0,1, 2. Get information on the exact

conductivity GSRNGE hardware settings being used
gain ranges For toroidal conductivity: 0, 1, 2, 3, 4, 5, 6, 7. to condition the sensor data.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 105

 Using the Where the DataStick replies with a number
Get… Comments
Command Text… that means…
The unique sensor serial number
is printed on the side of the sensor
Sensor Head
GSSNO Returns the sensor head serial number. head. It can also be retrieved
Serial Number
electronically and can be used to
trace history.
The unique DataStick serial number
is printed inside the comms adapter
DataStick Serial
GMSNO Get the DataStick Serial Number. end of the tube body. It can also be
Number
retrieved electronically and can be
used to trace history.
Code, otherwise known as firmware
Code Version can be upgraded in the field. The
GCVSN Get the Code Version.
Number version being used is retrieved with
this command.

GCALS X Displays both calibration points

pH Calibration Returns the calibration point in pH equivalent
in terms of pH = mV at a specific
Values Where X = 0 or 1 millivolts at a specific temperature at point 0 or 1.
temperature.
Returns the sensor slope based on the most-
Sensor Slope GSSLOPE
recent calibration in mV/pH.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 106

7 Free Chlorine Concentration Calculation
This section explains how the free chlorine concentration of a solution can be calculated from the measurements provided by
a Chlorine and a pH DataStick. It also explains how the hypochlorous acid concentration can be calculated from an independent free
chlorine concentration measurement for use during DataStick calibration. Included are some guidelines for the PLC programmer.

Square brackets [ ] are used to indicate concentration.

7.1 Measurement
Free chlorine is composed of hypochlorous acid, HOCl, and hypochlorite ion, OCl–. The free chlorine concentration is the sum of the
[ ]
hypochlorous acid concentration HOCl and the hypochlorite ion concentration OCl [ −
].
[HOCl ] + [OCl − ] (1)

pH is the negative of the decimal logarithm of the hydrogen ion concentration.

pH = − log10 H + [ ] (2)

Or

[H ] = 10
+ − pH
(3)

According to the Handbook of Chlorination and Alternative Disinfectants, Fourth Edition, 1998, equation (4) relates the free chlorine
concentration in ppm to the hypochlorous acid concentration in ppm, the pH, and the temperature in °C.

⎧ 0.056714 × 10−8 × T + 1.476 × 10−8 ⎫

[ ]
[HOCl ] + OCl = [HOCl ]× ⎨1 +
−

H+
⎬
[ ] (4)
⎩ ⎭
[ ]
The Chlorine DataStick measures the hypochlorous acid concentration HOCl and the temperature T of the solution. The pH
DataStick measures the pH of the solution. With these measurements equation (4) can be used to calculate the free chlorine
concentration of the solution.
For example, if the hypochlorous acid concentration is 4.99 ppm and the temperature is 27 °C as measured by the Chlorine
DataStick, and the pH is 7 as measured by the pH DataStick, then the free chlorine concentration in ppm will be

⎧ × 27 + 1.476 × 10−8 ⎫
[HOCl ] + [OCl − ] = 4.99 × ⎨1 + 0.056714 × 10
−8

⎬ = 6.49
⎩ 10− 7 ⎭
7.2 Calibration
[ ]
The Chlorine DataStick requires a hypochlorous acid concentration HOCl value when it is calibrated. If the user has a free
chlorine concentration value obtained from a colorimeter, for example, then the calculation done in equation (4) must be reversed.

[HOCl ] = [HOCl ] + [OCl − ] (5)

0.056714 × 10−8 × T + 1.476 × 10−8
1+
H+ [ ]

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 107

 For example, if the free chlorine concentration is 0.88 ppm as measured by the colorimeter, the temperature is 25 °C as measured by
the Chlorine DataStick, and the pH is 6.73 as measured by the pH DataStick, then the hypochlorous acid concentration value in ppm
that must be written to the Chlorine DataStick will be
0.88
[HOCl ] = = 0.76
0.056714 × 10−8 × 25 + 1.476 × 10−8
1+
10− 6.73
7.3 PLC Programming Guidelines
This section provides some guidelines for the PLC programmer.
Assume that the following floating-point registers are allocated within the PLC:
Register Variable
F8:1
[HOCl ] as read from the Chlorine DataStick
F8:2 T as read from the Chlorine DataStick
F8:3 pH as read from the pH DataStick
F8:4
[HOCl ] + [OCl − ] for displaying to the user
F8:5
[HOCl ] + [OCl − ] entered by user at calibration time
F8:6 [HOCl ] to be written to the Chlorine DataStick at calibration time
The PLC reads [HOCl ] and T from the Chlorine DataStick and stores the values in F8:1 and F8:2, respectively, and it reads
pH from the pH DataStick and stores the value in F8:3.
7.3.1 Measurement
The PLC calculates [HOCl] + [OCl−] and stores the value in F8:4 using equation (4):

⎧ −8
× (F 8 : 2 ) + 1.476 × 10−8 ⎫
(F 8 : 4) = (F 8 :1) × ⎨1 + 0.056714 × 10 ⎬ (6)
⎩ 10− ( F 8:3 ) ⎭
The free chlorine concentration value in F8:4 can then be displayed to the user.

7.3.2 Calibration
[
At calibration time, the user enters a free chlorine value that the PLC stores in F8:5. The PLC then calculates HOCl using ]
equation (5) and stores the value in F8:6:

(F 8 : 6 ) = (F 8 : 5) (7)
0.056714 × 10 × (F 8 : 2 ) + 1.476 × 10−8
−8
1+
10− ( F 8:3 )
The hypochlorous acid concentration value in F8:6 can then be written to the Chlorine DataStick to calibrate it.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 108

8 Compliance Information

Declaration of Conformity
Thermo Fisher Scientific certifies this product was tested thoroughly, inspected, and found to meet its published specifications
when it was shipped from the factory.

The DataStick is a DC powered measurement system with many sensing and communications options. Representative
combinations of the product have been tested and are certified as indicated to the following instrumentation standards:

Product Safety: Certified by Thermo Fisher Scientific LLC to EN 61010-1

Immunity: The equipment was tested to the Industrial level of performance in accordance with EN 61326, which includes
test criteria for electromagnetic compatibility for electrical equipment for measurement control and laboratory use per
89/336/EEC EMC. Supporting test records were written and certified by Thermo Fisher Scientific LLC.

Test Standards include:

IEC 1000-4-2:1995 (EN61000-4-2:1995) Electrostatic Discharge Immunity Criteria B
IEC1000-4-3: 1995 (EN61000-4-3:1996) Radiated RF Electromagnetic Field Immunity Criteria A
IEC1000-4-4: 1995 (EN61000-4-4: 1995) Electrical Fast Transient/Burst Criteria B
IEC1000-4-5: 1995 (EN61000-4-5: 1995) Surge Criteria B
IEC1000-4-6: 1996 (EN61000-4-6: 1996) Conducted Disturbances Induced by RF fields Criteria A

Emissions: The equipment was tested to for radio frequency emissions in accordance with EN 61326:1998, which
includes test criteria for electromagnetic emissions limits for electrical equipment for measurement, control and laboratory
use. Supporting test records were written and certified by Thermo Fisher Scientific LLC.
Test Standards include:
EN55011 (CISPER 11) Conducted emissions from 150 kHz to 30 MHz Class B.
EN55011 (CISPER 11) Radiated emissions from 30 MHz to 1 GHz Class B.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 109

9 Limited Warranty

DataStick WARRANTY/REPLACEMENT PLAN

Thermo Fisher Scientific warrants its DataStick against material and workmanship defect for a period of one year from the
date of shipment.

In the event that a defect is discovered during the warranty period, Thermo Fisher Scientific agrees, at its option, to repair or
replace the defective product. Any product repaired or replaced under this warranty will be warranted only for the remainder
of the original product warranty period.

This warranty does not apply to consumable products associated with this product including, but not limited to, chemical
reagents and salt bridges.

Products may not be returned without authorization from Thermo Fisher Scientific. To obtain authorization, please call
Thermo Fisher Scientific for a return material authorization number.

Limitations:
This warranty does not cover:
1. Damage caused by misuse, neglect (lack of appropriate maintenance), alteration, accident or improper application
or installation.
2. Damage caused by any repair or attempted repair not authorized by Thermo Fisher Scientific.
3. Any product not used in accordance with the instructions furnished by Thermo Fisher Scientific.
4. Damage caused by acts of God, natural disaster, acts of war (declared or undeclared), acts of terrorism,
work actions, or acts of any governmental jurisdiction.
5. Freight charges to return merchandise to Thermo Fisher Scientific.
6. Travel fees associated with on-site warranty repair.

This warranty is the sole expressed warranty made by Thermo Fisher Scientific in connection with its products. All other
warranties, whether expressed or implied, including without limitation, the warranties of merchantability and fitness for
a particular purpose, are expressly disclaimed.

The liability of Thermo Fisher Scientific shall be limited to the cost of the item giving rise to the claim. In no event shall
Thermo Fisher Scientific be liable for incidental or consequential damages.

This warranty is the sole and complete warranty for Thermo Fisher Scientific. No person is authorized to make any warranties
or representations on behalf of Thermo Fisher Scientific.

Thermo Fisher Scientific reserves the right to change or modify this warranty at any time.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 110

10 Terms and Conditions

Terms and Conditions of Sale

The following terms and conditions will be presumed acceptable unless changes are made in writing and accepted
by both parties in a reasonable amount of time.

Any standard or boilerplate terms and conditions supplied with a written purchase order will not be applicable unless
accepted in writing by both parties.

Quotations: All quotations shall be in writing. Written quotations shall be valid for 30 days from the date issued.
Verbal quotations or price lists are not valid.

Pricing: All pricing is in US Dollars. Thermo Fisher Scientific reserves the right to change pricing without notice.

Terms: Payment terms are net 30 days from the date of invoice with approved credit. Thermo Fisher Scientific reserves
the right to deny credit or revoke previously extended credit. Past due accounts are subject to interest charges. Other
acceptable payment terms are cash, certified check, money order, credit card or letter of credit confirmed by any United
States of America bank. Other payment terms are not valid unless accepted in writing.

Sales taxes shall be included on the invoice unless a valid tax exemption certificate is supplied.

Return Material Authorization: Contact Thermo Fisher Scientific Customer Service for a Return Material Authorization
(RMA) number. Items returned without an RMA number will be rejected.

All returned merchandise must be in unused, resalable condition, and must not be contaminated with hazardous materials.

Cancelled orders must be returned within 30 days of the date on the invoice and shall be subject to expenses incurred
that may include, but are not limited to, inspection and restocking fees. Items returned within 60 days shall be subject
to a restocking charge that is equal to 15% of the purchase price. Items returned after more than 60 days shall be subject
to a restocking charge equal to 25% of the purchase price. Thermo Fisher Scientific reserves the right to reject any return
that is not under warranty after 60 days. Non-stock items are normally not returnable.

Transportation: Orders are shipped FOB Thermo Fisher Scientific, or factory, by the most efficient means available.
Appropriate charges, such as freight and insurance will be added to invoices. All shipments will be insured. Goods damaged
in shipment must be reported by the recipient to the freight carrier for claims.

Thermo Scientific AquaSensors™ DataStick™ Measurement System User Guide 111

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