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Quantum Number Assignment Class Xi

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402 views2 pages

Quantum Number Assignment Class Xi

Uploaded by

ada.studies20
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© © All Rights Reserved
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ASSIGNMENT-STRUCTURE OF ATOM

TOPIC-QUANTUM NUMBERS
CLASS-XI

Q1. Write the electronic configuration of elements with the atomic numbers-10, 38, 24, 44.

Q2. How many unpaired electrons are present in –


(i) P(Z=15)
(ii) Fe3+(Z=26)
(iii) S2-(Z=16).

Q3. Give two examples of positive and negative ions corresponding to the configuration-
1s22s22p6.

Q4. Which of the following does not exist. Give reason also.
7p, 2d, 3s5, 4f, 3 p3y

Q5. An atom has 2 electrons in K-shell, 8 electrons in L shell and 2 electrons in M shell. Give the
electronic configuration and find the following-
(a) Atomic number (b) Total number of Principal quantum numbers
(c) Total number of s-orbitals (d) Total number of p-electrons

Q6. Find the value of n and l for the following orbitals-


(a) 3s (b) 4p (c) 4f (d) 3d

Q7. Calculate all the 4 quantum numbers for 11th electron of Sodium.

Q8. Calculate all the 4 quantum numbers for 19th electron of Chromium(Z=24).

Q9. How many electrons in Zinc(Z=30) have n+l=4?

Q10. What is the sequence of energies of 4s, 4p, 4d, 4f orbitals in


(a) Hydrogen atom (b) Zinc atom

Q11. The 4f subshell of an atom contains 12 electrons. What is the maximum number of
electrons having same spin in it?

Q12. Which of the following set of quantum numbers has larger energy?
n=3, l=2, ml = +1 n=3, l=2, ml = -1

Q13. Calculate the number of total nodes in 3p orbitals.

Q14. Calculate the number of radial nodes in 3d orbital.

Q15. Calculate the total number of spherical nodes in 4s-orbital?

Q16. In which atom, the outermost electron can have following set of quantum numbers?
n=3, l=0, ml=0, ms= -1/2

Q17. Calculate the total number of electrons having ms= +1/2 in n=3.

Q18. Calculate the total number of orbitals in 3d orbital.

Q19. What does 4,d,6 represents in 4d6?


Q20. Which quantum number does not follow from the solution of Schrodinger Wave equation?

Q21. Draw the boundary surface diagram for 3dxy, 3dzx, 3 d z .


2

Q22. Calculate the number of angular nodes and radial nodes in 3p orbital.

Q23. Define-(a) Aufbau principle (b) Hund’s Rule of maximum multiplicity


(c) Pauli Exclusion principle (d) Degenerate orbitals

Q24. The energy of an orbital in a multielectron atom depends on-


(a) Principal Quantum number
(b) principal and Azimuthal quantum number
(c) principal, Azimuthal and magnetic quantum number
(d) Principal, Azimuthal and spin quantum number

Q25. Explain giving reason why the following set of quantum numbers is not possible?
(i) n=3, l=0, mL=0, ms=+1/2
(ii) n=3, l=3, mL=-3, ms= -1/2

Q26. The two electrons in 1s orbital of He have antiparallel spin. Why they do not have parallel
spin?

Q27. Exactly half-filled and completely filled configurations possess extra stability. Give two
reasons to justify your answer.

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