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Model answer lesson 2 Chapter 3 copy

Chemistry 3rd sec

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5 views

Model answer lesson 2 Chapter 3 copy

Chemistry 3rd sec

Uploaded by

mo7farid1332007
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Model answer lesson 2 chapter 3

Question Answer Question Answer


1 A 33 D
2 D 34 D
3 A 35 C
4 A 36 B
5 C 37 D
6 A 38 A
7 B 39 A
8 B 40 A
9 A 41 C
10 A 42 A
11 B 43 B
12 B 44 B
13 B 45 D
14 B 46 Bsteps↓
15 A 47 B steps↓
16 A 48 C steps↓
17 C 49 D steps↓
18 C 50 B steps↓
19 B 51 D steps↓
20 B 52 B steps↓
21 C 53 a) a steps↓
b) B
22 D 54 B steps↓
23 A 55 D steps↓
24 A 56 D steps↓
25 C 57 A steps↓
26 B 58 C steps↓
27 D 59 C steps↓
28 B 60 Essay questions↓
29 A 61 D steps↓
30 A 62 C steps↓
31 B 63 Essay questions↓
32 B 64

Essay questions
60)
𝐾1
Kc = 𝐾2
500
= 0.2
= 2500

63)
• Letter (X) represents experiment (1) and letter (Y) represents
experiment (2) because in experiment (1), we used powder calcium
carbonate which increases the surface area of the reactants exposed
to the reaction therefore, the rate of chemical reaction increases
(higher rate than experiment 2).
• Letter (Z) can’t represent any of these experiments because :
- It doesn’t represent experiment (1) because experiment (1) is faster
than experiment (2) and from the graph, Curve (Z) has the lowest
rate of evolution of CO2 gas.
- It doesn’t represent experiment (2) because the amount of evolved
gas represented by curve (Z) is less than the amount of evolved gas
of both curve (X) and (Y) so, this isn’t accurate according to the
given regarding volume of HCl and mass of calcium carbonate.
64)
(a) Physical factor: Crushing the cube of substance (Y) to increase the
surface area of reactants exposed to the reaction and so, rate of chemical
reaction increases.
Or
Increasing temperature which makes the kinetic energy of molecules
increases, Activated molecules increase, the chance of collision between
reacting molecules increase, breaking bonds increase, the rate of reaction
increase.

(B) Chemical factor: Increasing the concentration of acid (X) to increase


the number of reacting molecules so the chance of collision increase,
breaking bonds increase, rate of the chemical reaction increases.
Or
Addition of a catalyst which decrease the activation energy of the reaction,
so it increases the number of activated molecules which increase the chance
of collision between the reacting molecules which leads to an increase in the
rate of the chemical reaction.
Steps
46)
[product] [NO2]2
Kc1= [reactants]= [N2O4]
[product] [N2O4]
Kc2= [reactants]= [NO2]2

Kc1 x Kc2 = 1

47)
2NO + O2 ⇄ 2NO2
[product] [NO2]2 [0.18]2
Kc= [reactants]= [NO]2[O2] = [0.52]2[0.24] = 0.499 ≈0.5

48)
PCl5⇄PCl3+Cl2
number of moles
Concentration = volume(L)
0.008
Conc PCl5= = 8x10−4M
10
0.0114
Conc PCl3= = 1.4x10−3 M
10
0.0114
Conc Cl2 = = 1.4x10−3 M
10
[Cl2][PCl3] [1.4x10−3][1.4x10−3 ]
Kc = = = 1.6245x10-3≈ 1.6245x10-3
[PCl5] [8x10−4 ]

49)
CH4 + H2O(l) ⇄ CO + 3H2
[product] [H2]3[CO] [0.04]3 [0.08]
Kc= [reactants] = = =4.266667 X 10-6 ≈4.267 X 10-6
[CH4] [1.2]

“Liquid water ➔ OUT”

50)
AgCl(s) +2NH3 ⇄[Ag(NH3)2] + +Cl-
[product] [Ag(NH3)2][Cl−] [5x10−3 ][5x10−3]
Kc= = = = 0.25
[reactants] [NH3]2 [10x10−3 ]2

“AgCl is solid ➔ OUT”


51)
𝑛𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
Concentration = 𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑟𝑒𝑠
0.6
[HA] = = 0.3M
2
0.7
[BOH] = = 0.35M
2
1
[BA] = 2 = 0.5M
“Liquid water is OUT from Kc calculation”
[product] [𝐵𝐴] 0.5
Kc= [reactants] = [𝐻𝐴][𝐵𝑂𝐻]
= = 4.76
0.3 𝑥 0.35

52)
I2(g) +H2(g) ⇄ 2HI(g)
[product] [HI]2
Kc = =
[reactants] [I2]x [H2]
There are 2 different methods :

Note :
𝑛𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
We said that [H2] = [I2] as concentration = 𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑟𝑒𝑠
And since they have the same number of moles (same balance) and have
the same volume as they’re found in the same container ➔ They have equal
concentrations.
53)
a)
N2O4+heat ⇄ 2NO2
From graph we can detect that :
• Concentration of NO2 at t1 = 0.65M
• Concentration N2O4 at t1 = 0.6M
[product] [NO2]2 [0.65]2
Kc= [reactants] = [N2O4] = = 0.704 ≈ 0.7
[0.6]

54)
As shown in the graph :
[A] = 0.1M
[B] = 0.3M
[C] = 0.2M

[𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑠]
Kc = [𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠]
[𝐶]² [0.2]²
=[𝐴].[𝐵]³ = [0.1].[0.3]³

= 14.81

55)
2SO2 + O2 ⇄ 2SO3
There are 2 different methods :
56)
PCl3 + Cl2 ⇄ PCl5
[product]
Kc = [reactants]
[PCl5]
Kc= [Cl2][PCl3]
[PCl5]
15.57= [0.3][0.84]

PCl5 = 3.923 M

57)
2SO2 + O2 ⇄ 2SO3
There are 2 different methods: -

no of moles
[O2] = volume(L)

No of moles = [O2] x Volume


No of moles =0.028 x 2=0.056 moles

58)
N2(g) + 3H2(g) ⇌ 2NH3(g)
[product] [𝑁𝐻₃]²
Kc= [reactants] = [𝑁₂][𝐻₂]³
(0.4)²
200 = (0.2)³𝑥
[𝑁₂]

[N2] x (0.2)3 x 200 = (0.4)2


(0.4)²
[N2] = (0.2)3𝑥 200 = 0.1 M
𝑛𝑜.𝑜𝑓 𝑚𝑜𝑙𝑒𝑠
Concentration = 𝑉𝑜𝑙𝑢𝑚𝑒 𝑖𝑛 𝑙𝑖𝑡𝑟𝑒𝑠
0.2
0.1 = 𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑐𝑜𝑛𝑡𝑎𝑖𝑛𝑒𝑟 𝑖𝑛 𝑙𝑖𝑡𝑟𝑒𝑠

Volume of container = 2L
59)
2SO2 +O2 ⇄ 2SO3
Reversed equation ➔ 2SO3 ⇄ 2SO2 +O2
Kc reversible = 1/Kc = 1/102 = 0.01

61)
2A ⇄ 3B +C
[product] [B]3 [c] [0,4]3 [1.8]
Kc = [reactants]= [A]2
= [0.6]2
= 0.32

Kc < 1
Kc<1 ➔ backward is predominant ➔ reactant conc. > product conc.

62)
[product] [𝐻𝐼]² (5𝑥10¯3 )²
Kc= [reactants] = [𝐻₂][𝐼₂]
= (1𝑥10¯³)(1.5𝑥10¯3) = 16.667

Calculated Kc not equal Given Kc ➔ Reaction is not at equilibrium


Calculated Kc < Given Kc ➔ Reaction should shift to the forward direction
(right) to reach equilibrium.

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