Date: 09-09-2024 Batch: A1-A3

S TU DY C ENT R E REPEATERS 2025 - JEE ADVANCED EXAMINATION

Puliyannoor P.O., PA L A
Ph - 04822 206416, 206516, 206459 PHYSICS + CHEMISTRY + MATHEMATICS
www.brilliantpala.org

PHYSICS -Heat and thermodynamics

Section I - Straight objective type (4, -1)

1. A faulty thermometer has its fixed points marked as 5 and 95. When this thermometers reads 68 the
correct temperature in Celsius is
A) 68°C B) 70°C C) 66°C D) 72°
2. If ,  and  are co-efficidnets of linear, superficial and volume expansion respectively then

 1  2  3  
A)  B)   3 C)  D)   
 2  5
3. Two metal rods of same length have same temperature difference between their ends. Their thermal
conductivities are K1 and K2 and cross sections A1 and A2 respectively. What is the condition for the same
rates of flow of heat?
K1 A1 K1 A 2
A) K  A B) K  A C) K12 A 22  K 22 A12 D) K1A12  K 2 A 22
2 2 2 1

4. A lead bullet strikes a target with a velocity of 480 m/s. If the bullet falls dead, the rise in temperature
of bullet  C  0.03ca lg 1o C1  assuming that heat produced is equally shared between the bullet and
target is
A) 557°C B) 457°C C) 857°C D) 754°C

5. A wall is made up of two layers A and B. The thickness of the two layers is the same, but materials
are different. The thermal conductivity of A is double than that of B. In thermal equilibrium the
temperature difference between the two ends is 36 o C . Then the difference of temperature at the two
surfaces of A will be
A) 6 o C B) 12 o C C) 18 o C D) 24 o C
Section 2 - Multiple correct answer type (4, -1 Partial Mark +1)
Full marks : +4 - If only the bubble(s) corresponding to all the correct option (s)
is (are ) darkened. Partial Marks: + 1 - For darkening a bubble corresponding to each correct
option

6.
FT 24B/TP/PCM 2 STUDY CENTRE

7.

8. The figure shows the variation of specific heat capacity (s) of a solid as a function of temperature
(T). The temperature is increased continously from 0 to 500K at a constant rate. Ignoring any volume
change, the following statements is/are correct to a reasonable approximation.

A) The rate at which heat is absorbed in the range 0 – 100K varies linearly with temperature T.
B) Heat is absorbed in increasing the temperature from 0 – 100K is less than the heat required for
increasing the temperature from 400 – 500K
C) There is no change in rate of heat absorbtion in the range 400 – 500K
D) The rate of heat absorption increases in the range 200 – 300K
9. A clock with a metallic pendulum gains 6 seconds each day when the temperature is 20°C and loses
seconds when the temperature is 40°C. Then
80 o
A) the clock will keep correct time at temperature C
3

100 o
B) the clock will keep correct time at temperature C
3

C) the coefficient of linear expansion of metal is 1.2  105 per o C

D) the coefficient of linear expansion of metal is 2.1 105 per o C

FT 24B/TP/PCM 3 STUDY CENTRE

10. Two bodies A and B have thermal emissivities of 0.81 respectively. The outer surface areas of the
two bodies are the same. The two bodies radiate energy at the same rate. The wavelength  B ,
corresponding to the maximum spectral radiancy in the radiation from B, is shifted from the wave-
length corresponding to the maximum spectral radiancy in the radiation from A by 1.00 m . If the
temperature of A is 5802 K,
A) The temperature of B is 1934 K B)  B  1.5 m
C) The temperature of B is 11604 K D) The temperature of B is 2901 K
Section III - Numerical answer type (4, -1)
The answer to each question is a NUMERICAL VALUE. Each questions carries +4 marks for
correct answer and -1 marks for all other cases. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to the second decimal place; eg. 6.25, 7.00,
30.27, 127.30)
11. Two liquids A and B are at 60OC and 20OC respectively. If their masses are in the ratio 4 : 5 and
their sp. heats in the ratio 3 : 4. The resulting temp. of the mixture when the liquids are mixed is
:[Answer should be in oC]
12. A beaker contains 200 g of water. The heat capacity of beaker is equal to that of 20 g of water. The
initial temperature of water in the beaker is 200C. if 440 g of hot water at 920C is poured in, the final
temperature neglecting radiation loss will be: (in oC)

13.

(in cm)

14.

15.
FT 24B /TP/PCM 4 STUDY CENTRE

CHEMISTRY - Hydrocarbon
Section I - Straight objective type (4, -1)
16. Consider the following reaction

+ Br 
 X + HBr
D

Identify the structure of the major product X.

H H H

A) B) C) D)
D
D D

17. Liquid hydrocarbon can be converted to a mixutre of gaseous hydrocarbons by :

A) oxidation B) cracking
C) distillation under reduced pressure D) hydrolysis
18. The major product of the following reaction is

Cl      

Na / Ether Br2 /hv Alc.KOH
Br

A) B) C) D)

19. CH 3CH  CH 2 

BD3 /THF
H O /OH 
 X . Identify product X is
2 2

A) CH3CHCH2D B) CH3CHCH2OH C) CH3CHCH3 D) CH2D CH CH3

OH D OD OH

20. The compound  CH3 2 CH  CHCl  CH 3 reacts with alcoholic KOH to give the following alkene

A)  CH3 2 CH  CH  CH 2 B) CH 3  CH  C  CH 2

C) CH 3  CH 2  CH  CHCH 3 D)  CH 3  2 C  CH  CH3

Section 2 - Multiple correct answer type (4, -1 Partial Mark +1)

Full marks : +4 - If only the bubble(s) corresponding to all the correct option (s)
is (are ) darkened. Partial Marks: + 1 - For darkening a bubble corresponding to each correct
option
21.

22.
FT 24B /TP/PCM 5 STUDY CENTRE

CH2
23. H , H2 o
  product; Product (s) is/are:

CH3
CH3 HOCH2

A) B) C) D)
OH OH CH3
OH
24. Which of the following does not give alkane
A) Reaction of CH3I with Na in ether
B) Reaction of sodium acetate with sodalime
C) Electrolysis of concentrated sodium acetate solution
D) Reaction of ethyl chloride with alco. KOH

25.

Section III - Numerical answer type (4, -1)

The answer to each question is a NUMERICAL VALUE. Each questions carries +4 marks for
correct answer and -1 marks for all other cases. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to the second decimal place; eg. 6.25, 7.00,
30.27, 127.30)

26. In the molecule

x = no. of 1o carbon atoms

y = no. of 2o carbon atoms
z = no. of 3o carbon atoms
m = no. of 4o carbon atoms
Give the value of x + y + z – m
27. How many sp3 hybridised carbon atoms are there in one molecule of the major product (B) in the
sequence of reactions given below

CH 3  C  CH  CH 2 CH 3 (I) B H
|  2 6
[A] 
dilH 2SO 4
 [B]
(II) H 2 O2 ,OH 
CH(CH 3 ) 2 (major product )
FT 24B /TP/PCM 6 STUDY CENTRE

28.

29.

30.

MATHEMATICS- Limits of Real functions

Section I - Straight objective type (4, -1)

1
e 1
x

31. xLt 1

0
e 1
x

A) 1 B) –1 C) 0 D) Does not exist

a cot x  a cos x
32. Lt 
x
 cot x  cos x
2

A) log a B) log a C) –log a D) a

33. a1 = 1 an  n  an 1  1 n  2,3, 4...

 1  1  1 
Pn   1   1   ....  1   . The Lt Pn 
 a1   a2   an  n 

A) e2 B) e C) e D) e–1
FT 24B /TP/PCM 7 STUDY CENTRE

 n! 
34. n 
Lt 

  mn 
n


e 1
A) em B) em C) D)
m em
1
 ax  bx  cx  x
35. Lt   
x 0
 3 
A) Arithmetic mean of a,b,c B) Geometric mean of a,b,c
C) Harmonic mean of a,b,c D) None
Section 2 - Multiple correct answer type (4, -1 Partial Mark +1)
Full marks : +4 - If only the bubble(s) corresponding to all the correct option (s)
is (are ) darkened. Partial Marks: + 1 - For darkening a bubble corresponding to each correct
option

36.

37.

38.

39.

40.
FT 24B /TP/PCM 8 STUDY CENTRE

Section III - Numerical answer type (4, -1)

The answer to each question is a NUMERICAL VALUE. Each questions carries +4 marks for
correct answer and -1 marks for all other cases. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to the second decimal place; eg. 6.25, 7.00,
30.27, 127.30)

 P( x) 
41. f(x) is a polynomial of degree 4 having f / (1)  0, f / (2)  0 and xLt  1  2   2 . Then f(2)=
0
 x 

42.

43. The graph of a real values function is given below whose domain is (–1,4]

The number values of x where limits do not exist is

44.

45.
 09- 09- 2024 Batch: A1 - A3

STUDY CENTRE REPEATERS JEE ADVANCED EXAMINATION

Pu liyannoo r P.O., P A L A
Ph - 04822 206416, 206516, 206459
www.brilliantpala.org P + C + M - Key with Hints

PHYSICS - Heat and thermodynamics

1. B

2. B

3. B ;

V2
4. B T 
4JC

Q Q K S A( 1   2 ) 2 KA (1   )

5. B Suppose thickness of each wall is x then     Þ 
 t combinatio n  t  A 2x x

2  2K  K 4
 K S  (2 K  K )  3 K and (1   2 )  36 

A B

2K K

1 x  x 2

4
KA  36
Þ 3 2 KA(1   )

2x x
Hence temperature difference across wall A is
( 1   )  12 o C

6. A,C
FT 24B/TP/PCM 2 STUDY CENTRE

7. A,D

8. A, B, C, D
dQ
Q = area under graph s
dt
FT 24B/TP/PCM 3 STUDY CENTRE

9. A, D

1  80 
b   a    20   86400
2  3 

Which gives   2.1 105 per C

Thus the correct choices are A and D
10. A, B
FT 24B/TP/PCM 4 STUDY CENTRE

11. 35 m1 x c1x (60 - T) = m2 x c2 x (T - 20);

m1 4 c1 3 60  T m2 c 2 5 x 4
 ;  ;  x 
m2 5 c 2 4 T  20 m1 c1 4 x 3

60  T 5
 ; 180 - 3T = 5 T- 100; 8 T = 280; T = 350C
T  20 3
12. 68 Heat gained by cold water + beaker = Heat lost by hot water, m x c for beaker is equal to
heat capacity for 20 g water.
ie. (200 x 1 + 20) [ – 20] = 440 [92 – ]
3  = 204,  = 68o

13. 10

14. 69

15. 3

CHEMISTRY - Hydrocarbon
16. B Abstraction of 3H by Br gives (b)
17. B During cracking higher hydrocarbons (liquid) are converted to lower gaseous hydrocarbon.

Cl 

Na / Ether
18. B Br

Br

Br2 , hv
 
alc.KOH

FT 24B/TP/PCM 5 STUDY CENTRE

BD3/THF H2O2/OH-
19. B CH3CH CH2 (CH3CHCH2)3B CH3CHCH2OH

D D
As hydroboration follows anti-Markovnikov’s addition.
20. D Follow Saytzeff’s rule for elimination
21. ABD
22. AB

23. B,C

24. D

25. C

26. 14

M=1

27. 6
FT 24B/TP/PCM 6 STUDY CENTRE

28. 1
29. 5
30. 4

MATHEMATICS- Limits of Real functions

31. D
32. A
33. C
34. D
35. B
36. A,B,D
37. B,C
38. A,B
39. B,D
40. A,B,C
41. 0
42. 0
43. 2
44. 4
45. 128