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11 Chemistry Set 01 Solution - 250115 - 170027

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19 views23 pages

11 Chemistry Set 01 Solution - 250115 - 170027

Uploaded by

babaazlaancsc
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Q4.

(i) or

Emission Spectrum:-

A substance gets excited on heating at a very high temp. or by giving


energy and subsequently radiations are emitted. These radiations when
analysed with the help of spectroscope ,spectral lines are obtained.
Pattern of the lines are known as emission spectrum.

A substance may be excited by

Heating at higher temp.

Passing electric current at a very low pressure in a discharge tube filled


with gas.

By passing electric current into metallic filament.

Absorption Spectrum:-

When the white light of an incandescent substance is passed through


any other substance ,this substance absorbs the radiations of certain
wavelength from the white light .On analysing the transmitted light we
obtain a spectrum in which dark lines of specific wavelengths are
observed. These lines constitute the absorption spectrum. The
wavelength of the dark lines correspond to the wavelength of light
absorbed.
Line Spectrum of Hydrogen:-

Line spectrum of hydrogen is observed due to excitation or de-excitation of electron from one
stationary orbit to another stationary orbit.

Let e- make transition from n2 to n1 (n2> n1) in a H- like sample.

.
Energy of n2 stationary orbit En2 =

.
Energy of n1 stationary orbit En1 =
Energy of emitted photon = (∆ E )n →n1

= En2 – En1

(∆ E )n →n1 = 2.18 x 10-18 z2 ( - )J

= 2.18 x 10-18 z2 ( - )J

.
= z2 ( - )J

.
= 𝑣̅ = z2 ( - )J
.

Wave number , 𝑣̅ = λ = Rz2 ( - ) m-1

Where, R = Rydberg constant

= 1.09678 x 107 m-1

≈ 1.1 x 107 m-1

Spectral lines of Hydrogen Atom:-

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