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CHM135 Equation Sheet (1)

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2 views

CHM135 Equation Sheet (1)

-

Uploaded by

saba.mrd1385
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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𝐸 = ℎ𝜈 𝑐 = 𝜆𝜈 𝑃𝑉 = 𝑛𝑅𝑇

"#.%&×%(!"# ) % %
𝐸! = !$
∆𝐸 = −2.18 × 10"%& 𝐽 6! $ − ! $ 7
% &

888* = +,-
𝐸 𝑢/01 = :
+,-
𝑆𝑜𝑙𝑢𝑏𝑖𝑙𝑖𝑡𝑦 = 𝑘! 𝑃"#$ 𝑃3 = 𝑋3 𝑃34
#. ' 2

6()* %
𝛱 = 𝑖𝑀𝑅𝑇 Δ𝑆151 = -
𝑆 = 𝑘 ln 𝑊 𝐸7 = # 𝑚𝑢#

𝛥𝐻 = 𝛥𝐸 + 𝑃𝛥𝑉 𝛥𝐺 = 𝛥𝐻 − 𝑇𝛥𝑆 𝛥𝐺 = −𝑛𝐹𝐸89::

𝛥𝐺 = 𝛥𝐺 4 + 𝑅𝑇 𝑙𝑛 𝑄 𝑞8;: = 𝐶8;: 𝛥𝑇 𝑞 = 𝑐 × 𝑚𝑎𝑠𝑠 × Δ𝑇

"<±√<$ "?;8
Δ𝐸 = 𝑞 + 𝑤 𝑤 = −𝑃Δ𝑉 For: 𝑎𝑥 # + 𝑏𝑥 + 𝑐 = 0 , 𝑥 = #;

[𝐴 ]@ 1 1
[𝐴]@ = −𝑘𝑡 + [𝐴]( ln ] ^ = −𝑘𝑡 = 𝑘𝑡 +
[ 𝐴 ]( [𝐴 ]@ [𝐴](

𝐸; 𝑘# 𝐸; 1 1
𝑙𝑛 𝑘 = 𝑙𝑛 𝐴 − ln 6 7 = 6− 7 6 − 7 𝐾A = 𝐾8 (𝑅𝑇)B!
𝑅𝑇 𝑘% 𝑅 𝑇# 𝑇%

[𝐴" ] 4
𝑅𝑇
𝑝𝐻 = 𝑝𝐾; + 𝑙𝑜𝑔 ] ^ 𝐸89:: = 𝐸89:: − 𝑙𝑛 𝑄
[𝐻𝐴] 𝑛𝐹

Constants Conversion factors


Avogadro’s number NA = 6.022 x 1023 mol-1 1 amu = 1.6605402 x 10-27 kg
Mass of an electron me = 9.109 x 10-31 kg 1 atmosphere (atm) = 1.01325 x 105 Pa
= 760.0 mm Hg (torr)
= 1.01325 bar
Boltzmann’s constant k = 1.380658 x 10-23 J K-1 1 eV/particle = 96.485 kJ mol-1 = 23.061 kcal mol-1
Zero point 0 °C = 273.15 K 1 calorie (cal) = 4.184 joules (J)
Gas constant R = 8.314 J mol-1K-1 1 m = 10 dm = 100 cm = 103 mm = 106 μm = 109 nm = 1012 pm
R = 0.08206 L atm mol-1K-1 1 L atm = 101.325 J = 24.217 cal
Planck’s constant h = 6.626 x 10-34 J s 1 J = 1 kgm2s-2
Speed of light c = 3.00x108 m s-1 1 V = 1 J C-1
Faraday’s constant F = 9.650 x 104 C mol-1 1 A = 1 C s-1
Ion-product constant
Kw = 1 x 10-14
of water (at 25 °C)

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