‭ ection I: Multiple Choice‬

S
‭For questions 1-5, determine if the following statements are‬‭A) True‬‭or‬‭B) False.‬
‭1.‬ ‭The equilibrium constant increases if the concentration of one of the reactants is‬
‭increased.‬
‭2.‬ ‭At chemical equilibrium, K‬‭eq‬ ‭is always equal to 1.‬
‭3.‬ ‭An increase in pressure with no change in volume causes the reaction to shift right.‬
‭N‬‭2‭(‬ g) + 3 Br‬‭2‬‭(l) ⇌ 2 NBr‬‭3‬ ‭(s)‬
‭4.‬ ‭In an exothermic reaction, heating the reaction causes it to shift left.‬
‭5.‬ ‭The correct chemical name for ZnO is zinc II oxide.‬
‭6.‬ ‭For this unbalanced reaction, 59.78 g of Glucose is used. Calculate the percent yield if the‬
‭reaction goes to completion with an excess of Oxygen if 32.6 mL of water is recovered,‬
‭with no water present initially. Keep three significant figures for your answer.‬
‭C‬‭6‭H
‬ ‬‭12‬‭O‭6‬ ‬ ‭+ O‬‭2‬ ‭→ CO‬‭2‬ ‭+ H‬‭2‬‭O‬
‭a.‬ ‭90.9 %‬
‭b.‬ ‭91%‬
‭c.‬ ‭18.3%‬
‭d.‬ ‭0.18%‬
‭7.‬ ‭In which direction will this reaction proceed if there are 0.5M of N‬‭2‬‭, 3.0M of H‬‭2‭,‬ and‬
‭0.73M of NH‬‭3‬ ‭given that the Keq for this reaction‬‭is 2.‬
‭N‬‭2‬ ‭+ 3 H‬‭2‬ ‭↔ 2NH‬‭3‬
‭a.‬ ‭Towards the products‬
‭b.‬ ‭Towards the reactants‬
‭c.‬ ‭No shift, the system will remain at those concentrations in equilibrium.‬
‭d.‬ ‭Answer cannot be determined without additional information‬
‭8.‬ ‭Given this titration curve, what is Keq?‬

a‭ .‬ 1‭ * 10‬‭7‬
‭b.‬ ‭1 * 10‬‭-7‬
‭c.‬ ‭1 * 10‬‭-8‬
‭d.‬ ‭1 * 10‬‭8‬
 ‭9.‬ ‭What type is the following reaction?‬
‭NaI → Na‬‭+‬ ‭+ I‬‭-‬
‭a.‬ ‭Decomposition Reaction‬
‭b.‬ ‭Single Replacement Reaction‬
‭c.‬ ‭Double Replacement Reaction‬
‭d.‬ ‭Synthesis Reaction‬
‭10.‬‭What are the respective integer coefficients for the following chemical reaction.‬
‭C‬‭7‭H
‬ ‬‭6‬‭O‬‭2‬ ‭+ O‬‭2‬ ‭→ CO‬‭2‬ ‭+ H‬‭2‬‭O‬
‭A.‬ ‭1, 7.5, 7, 3‬
‭B.‬ ‭1, 7, 7, 3‬
‭C.‬ ‭4, 30, 14, 5‬
‭D.‬ ‭2, 15, 14, 6‬
‭11.‬‭What description below‬‭best‬‭fits the term of solubility?‬
‭a.‬ ‭The amount of solvent that can be dissolved in a given volume of solute‬
‭b.‬ ‭The ability for a substance to undergo a displacement reaction in a given solution‬
‭c.‬ ‭The amount of a solvent that is lost when a compound breaks apart‬
‭d.‬ ‭The ability for a substance to be dissolved in a given solvent‬
‭12.‬‭Determine the net ionic equation for the chemical reaction between magnesium‬
‭phosphate and water to produce magnesium chloride and phosphoric acid.‬
‭Mg‬‭3‬‭(PO‬‭4‭)‬ ‬‭2‬ ‭(s) + 6 HCl (aq) → 3 MgCl‬‭2‭(‬ aq) +2 H‬‭3‬‭PO‬‭4‬‭(aq)‬
‭a.‬ ‭Mg‬‭3‬‭(PO‬‭4‬‭)‭2‬ ‬ ‭(s) + 6 H‬‭+‭(‬ aq) → 3 Mg‬‭2+‬‭(aq) +2 H‬‭3‬‭PO‬‭4‭(‬ aq)‬
‭b.‬ ‭Mg‬‭3‬‭(PO‬‭4‬‭)‭2‬ ‬ ‭(s) + 6 H‬‭+‭(‬ aq) + 6 Cl‬‭-‬ ‭(aq) → 3 Mg‬‭2+‬‭(aq)‬‭+2 H‬‭3‭P ‬ O‬‭4‬‭(aq)‬
‭c.‬ ‭Mg‬‭3‬‭(PO‬‭4‬‭)‭2‬ ‬ ‭(s) + 6 H‬ ‭(aq) + 6 Cl‬ ‭(aq) → 3 Mg‬ ‭(aq)‬‭+ 6 H‬ ‭(aq) +2 PO‬‭4‭3‬ -‬‭(aq)‬
‭+‬ ‭-‬ ‭2+‬ ‭+‬

‭d.‬ ‭Mg‬‭3‬‭(PO‬‭4‬‭)‭2‬ ‬ ‭(s) → 3 Mg‬‭2+‬‭(aq) + 2 PO‬‭4‬‭3-‬‭(aq)‬

‭Using the reaction below, determine if the following scenarios would shift the chemical reaction‬
‭a) left, b) right or c) have no effect for questions 13-15.‬
‭NH‬‭4‬‭Cl (s) ⇌ NH‬‭3‬ ‭(g) + HCl (g)‬ ‭ΔH° = 176 KJ/mol‬
‭13.‬‭Increasing the volume‬
‭14.‬‭Removing NH‬‭3‬
‭15.‬‭Increasing the temperature‬
‭16.‬‭Bromothymol blue is an acid and base indicator with a pKa of 6.8. At around what pH‬
‭will bromothymol blue undergo a color change during an acid and base titration?‬
‭a.‬ ‭2‬
‭b.‬ ‭5‬
‭c.‬ ‭7‬
‭d.‬ ‭9‬
‭17.‬‭In which substance does phosphorus have the lowest oxidation state?‬
‭a.‬ ‭PF‬‭3‬
‭b.‬ ‭H‬‭3‬‭PO‬‭4‬
‭c.‬ ‭Ca‬‭3‬‭P‭2‬ ‬
‭d.‬ ‭PO‬‭4‭3‬ -‬
‭18.‬‭Given the following reaction, identify the reducing and oxidizing agent, respectively.‬
‭8 NH‬‭3‬‭(g) + 6 NO‬‭2‬ ‭→ 7 N‬‭2‬‭(g) + 12 H‬‭2‬‭O (l)‬
‭a.‬ ‭NH‬‭3‬ ‭; NO‬‭2‬
‭b.‬ ‭NO‬‭2‬ ‭; NH‬‭3‬
‭c.‬ ‭NH‬‭3‬ ‭; N‬‭2‬
‭d.‬ ‭NO‬‭2‬ ‭; N‬‭2‬
‭19.‬‭When carbon dioxide is bubbled through distilled water at 25 degrees Celsius, which of‬
‭the following is most likely to occur?‬
‭a.‬ ‭Solid carbon will precipitate‬
‭b.‬ ‭The water will boil‬
‭c.‬ ‭The pH of the solution will decrease‬
‭d.‬ ‭Methane gas will be produced‬
‭20.‬‭Which of the following statements is true?‬
‭a.‬ ‭K‬‭eq‬ ‭is independent of the starting concentration of‬‭the reactants and products‬
‭b.‬ ‭K‬‭eq‬ ‭only changes with temperature‬
‭c.‬ ‭K‬‭eq‬ ‭is dependent on the final concentration of the‬‭reactants and products‬
‭d.‬ ‭None of the above statement is true‬
‭21.‬‭Given the following equilibrium reaction, determine the equilibrium concentration of‬
‭PCl‬‭3‬ ‭if the initial concentration of PCl‬‭5‬ ‭is 1.00‬‭M and the Keq is 1.20.‬
‭PCl‬‭5‬‭(g) ⇌ PCl‬‭3‬‭(g) + Cl‬‭2‭(‬ g)‬
‭a.‬ ‭0.987 M‬
‭b.‬ ‭0.789 M‬
‭c.‬ ‭1.013 M‬
‭d.‬ ‭0.927 M‬
‭22.‬‭In a titration experiment, it was determined that a 80.0 mL sample of HNO‬‭3‬ ‭required 94.0‬
‭mL of 0.90 M NaOH to reach the equivalence point. Calculate the molarity of HNO‬‭3‬‭.‬
‭a.‬ ‭0.77 M‬
‭b.‬ ‭1.06 M‬
‭c.‬ ‭0.83 M‬
‭d.‬ ‭1.33 M‬
‭23.‬‭Which titration curve corresponds to an initial pH of 9.9 and an equivalence point at pH =‬
‭3.7?‬
‭a.‬ ‭A strong base to which a weak acid is added‬
‭b.‬ ‭A weak acid to which a weak base is added‬
‭c.‬ ‭A strong base to which a strong acid is added‬
‭d.‬ ‭A weak base to which a strong acid is added‬
‭24.‬‭Which of the following is a characteristic associated with base?‬
‭a.‬ ‭React with metal to produce hydrogen gas‬
‭b.‬ ‭Donate an unshared electron pair‬
‭c.‬ ‭It always contain an hydroxide ion‬
‭d.‬ ‭Formed by reacting a nonmetal oxide and water‬
‭25.‬‭A 1.3 M solution of the weak acid HCN has a pH of 4.56, what is its acid dissociation‬
‭constant?‬
‭a.‬ ‭2.75E-5‬
‭b.‬ ‭7.50E-10‬
‭c.‬ ‭5.83E-10‬
‭d.‬ ‭5.38E-5‬
‭26.‬‭If 48.6 grams of magnesium are placed in a container with 72 grams of oxygen gas, what‬
‭is the mass of MgO(s) produced?‬
‭Mg(s) + O‬‭2‬‭(g)→ MgO(s)‬
‭a.‬ ‭80.6 g‬
‭b.‬ ‭181.35 g‬
‭c.‬ ‭90.7 g‬
‭d.‬ ‭85.2 g‬

‭Consider the equilibrium reaction below for questions 27-28.‬

‭2 HX (g) ⇌ H‬‭2‬ ‭(g) + X‬‭2‬ ‭(g)‬

‭27.‬‭Suppose a 5.70 mol sample of HX is placed in a 1.00 L vessel at 481°C, and the reaction‬
‭reaches an equilibrium where HX decomposes to form 0.451 mol H‬‭2‬ ‭and 0.451 mol X‬‭2‬‭.‬
‭Determine the equilibrium constant for this reaction at the given temperature.‬
‭a.‬ ‭113‬
‭b.‬ ‭160‬
‭c.‬ ‭135‬
‭d.‬ ‭The answer cannot be determined without knowing the concentration of HX‬
 ‭28.‬‭Consider the reaction below. The initial concentration of HX gas is 0.75 M and the‬
‭equilibrium concentration of X gas is 0.300 M. What would be the equilibrium‬
‭concentration of HX gas?‬
‭a.‬ ‭0.85 M‬
‭b.‬ ‭0.30 M‬
‭c.‬ ‭0.15 M‬
‭d.‬ ‭0.75M‬

‭Use the following to answer questions 29-34.‬

‭ or the following reaction, write how each change will affect the indicated quantity, assuming a‬
F
‭container of fixed size unless specified otherwise. Write A (increase), B (decrease), or C (no‬
‭change). For a chemical added, write how it would respond AFTER the addition.‬

‭X‭2‬ ‬‭(g) + M‬‭2‬‭(g) ⇌ 2XM(g)‬ ‭ΔHº = -516.8 kJ/mol‬

2‭ 9.‬‭How would M‬‭2‬ ‭change if the pressure is increased and‬‭volume decreased?‬

‭30.‬‭How would M‬‭2‬‭change when some HBr is added?‬
‭31.‬‭How would X‬‭2‬ ‭change when some of it is removed?‬
‭32.‬‭How would the K value change when some X‬‭2‬ ‭was added?‬
‭33.‬‭How would the K value change when the temperature is increased?‬
‭34.‬‭How would XM change when some of it is removed?‬