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2013

Uploaded by

bargujardhruv925
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© © All Rights Reserved
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No.

of Printed Pages : 8 CHE-04

BACHELOR OF SCIENCE (B.Sc.)


Term-End Examination
7.\J
December, 2013
CP7,
CHEMISTRY
CHE-04 : PHYSICAL CHEMISTRY
Time : 2 hours Maximum Marks : 50

Note : Attempt all the parts. Answer five questions from each
of the parts A, B, C and D.

PART - A
Attempt any five questions.
1. What is SI unit of Frequency ? 1

2. State Charle's law of gases.


1
3. Name the various intermolecular forces. 1

4. State third law of thermodynamics. 1

5. Write the names of two methods to study the fast 1


reactions.

6. Write the expressions of phase rule. 1

7. Name the photosensitizer in the photosynthesis 1


process.
PART - B
Attempt any five questions.
8. Among the alkanes, octane, nonane and decane 2
which is expected to have high viscosity and
why ?

CHE-04 1 P.T.O.
9. When a non volatile solute is added to a solvent,
the depression in freezing point is more than
elevation point. Explain.
10. Calculate the number of atoms in the unit cells of 2
body centre cubic lattice and face centre cubic
lattice.
11. What are indicators ? What are their uses ? 2
12. Derive the units of rate constants of first and
second order reactions.
13. For the following reaction 2
2S02(g) + O2(g) 2S03(g)
it is found that PS0,— 3.42 x 104 Pa,
PO, = 3.13 x 104Pa and PS03 = 3.58 x 104 Pa.
Calculate the value for the equilibrium constant
K T).

14. What are lyophilic and lyophobic sols ? 2


PART - C
Attempt any five questions.
15. Differentiate between extensive and intensive 3
variable. Give one example of each.
16. State Raoult's law. Give the characteristics of an 3
ideal solution. Give one example of ideal solution.
17. Explain the term electrophoresis. State two of its 3
applications.
18. Define molar conductance. At 298 K the resistance 3
of 2.00 x 10 -2M KCI is 195.96 1 and that of
2.50 x 10 -3M K2SO4 is 775.1911 The specific
conductance (K) of 2.00 x 10 -21\/1 KCl at 298 K is
0.2768 Sm .- 1. Calculate molar conductivity of
K2SO4 solution.

CHE-04 2
19. What is the difference between physiosorption 3
and chemisorption ?

20. State Nensart distribution law and give its any 3


two applications.

21. What are Potentiometric Titrations ? Name the 3


electrodes used to determine the pH of a solution.

PART - D
Attempt any five questions.
22. The first order rate constant for the decomposition 4
of N205 at 340K is 5.20 x10 -3 sec - I. Calculate
the time required for the conc. of N205 to fall to
(a) One half
(b) One fourth of its initial concentration

23. What is common ion effect ? Addition of NH4C1 4


to NH4OH results in the decrease of OH - ion
concentration. Explain.

24. State Hess's law of constant Heat Summation. 4


Calculate ArH° for the reaction
1
C (graphite) + 2 02(g) -->CO2(g) at 298 K using
the following thermo chemical equations.
C (graphite) + 02(g) - CO2(g) Ai.1-1°= - 393.5 kJ
1
CO (g) + 2 02(g) - CO2(g) Ar1-1°= -283.5 kJ

25. Derive the various Maxwell relations. 4

CHE-04 3 P.T.O.
dP
26. Draw the phase diagram of water. Calculate — 4
dT
for the three equilibrium processes using
Clapeyron equation.

27. Explain the Kohlrausch's law of independent 4


Migration of ions. The
A°mAgNO3 =1.334 x 10 -2 Sm2 MOi -1,
A°mKC1= 1.49 x 10 -2 SM2Mo1 -1
A'm KNO3 =1.450 x 10 -2 Sm2 M01-1. Find the
n'm AgC1 ?

28. Calculate the equilibrium constant at 298 K for 4


Al (s) A13+ (C1 ) cu2 + (c2 ) Cu (s) cell.
E Al3 _,_' Al= -1.66 V

ECu 2+ Cu = +0.34 V

CHE-04 4

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