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34 views

solutions

Uploaded by

Atanu Sarkar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Name: ______________________________ Total Marks: 30 Time: 1 hr 45 min

1. One litre of water at NTP dissolves 0.08 g of nitrogen. Calculate the amount of [2]
nitrogen that can be dissolved in four litres of water at 273k and at a pressure of
1520 mm hg.

2. State Raoult’s law for a solution containing volatile components. What is the [2]
similarity between Raoult’s law and Henry’s law?

3. An aqueous solution containing 20% by weight of liquid ‘A’ (Mol. Wt. = 140) [2]
has vapour pressure of 160 mm at 570c. find the vapour pressure of pure A, if
that of water in 150 mm at this temperature.

4. A 4% solution w/W of sucrose (M = 342 g mol-1) in water has a freezing point [2]
of 271.5K. Calculate the freezing point of 5% glucose (M = 180 g mol-1) in
water. (Given: Freezing point of pure water = 273.15K)

5. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in [3]


freezing point of 1.62K. calculate the Van’t Hoff factor and predict the nature
of solute (associated or dissociated).
(given: molar mass of benzoic acid = 122 g mol-1, Kf for benzene = 4.9 K kg mol-1)

6. 0.1M NaCl, 0.1M Sucrose, 0.1M CaCl2, 0.1M Ca3(PO4)2 [2]


Which of the above has the highest boiling point at 1 Atm. Pressure and why?

7. Write two differences between ideal solutions and non-ideal solutions [2]

8. State the factors affecting the vapour pressure of a liquid [2]

9. Give reasons [2]


a. An increase in temperature is observed on mixing chloroform and
acetone
b. Aquatic animals are more comfortable in cold water than in warm water
10. The vapour pressures of ethanol and methanol are 44.5 mm Hg and 88.7 mm [3]
Hg respectively. An ideal solution is formed at the same temperature by mixing
60g of ethanol and 40 gm of methanol. Calculate the total vapour pressure of
the solution and the mole fraction of methanol in the vapour

11. Calculate the freezing point of a solution containing 60g of glucose (Molar [2]
mass = 180 g mol-1) in 250 g of water (Kf of water = 1.86 K Kg mol-1)

12. Define the following terms [2]


a. Abnormal Molar mass
b. Van’t Hoff factor (i)

13. Measurement of osmotic pressure method is preferred for the determination of [2]
molar masses of macromolecules such as protein and polymers. Justify.

14. 45 g of ethylene glycol (C2H4O2) is mixed with 600 g of water. Calculate [2]
a. The freezing point depression
b. The freezing point of the solution

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