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Basic Chemistry -2018

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4 views3 pages

Basic Chemistry -2018

Uploaded by

Dibyendu Roy
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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103(S)

December 2018

BASIC Cl+EM.STRY

Time Allowed: 3 Hours Full Mccks: 70

Answer to Question No.1 is compulsory and to be answered first.


This answer is to be made in separate loose script(s) provided for the purpose.
Maximum time allowed is 45 minutes, after which the loose answer scripts will be collected and
fresh answer scripts for answering the remaining part of the question will be provided.
On early submission of answer scripts of Question No.1,
a student will get the remaining script earlier.
Answer any five questions' from Group-A, 8 & C, taking at least one from eacli group.

1. Choose the correct answer from the given alternatives (any twenty): 20xl

i) Secondary standard solution is prepared from - (a) NaoH, a) Oxalic Acid, (c) K2Cr207
(d) Na2C03 anhydrous.

ii) Which quantum indicates shell number? -(a) azimuthal, a) spin, (c) magnetic, (d) principal.

iii) Sp hybridization is known in -(a) BCL3, (b) Cec12, (c) CH4, (d) NH3.

iv) Fomula ofcALGON is -(a) Na6(P03)6, (I)) Na2HP04, (C) Na3P04, (d) Na2HP03.

v) Fe can be replaced from Fes04 solution using -(a) Cu, (b) Pb, (c) Al, (d) Ag.

vi) Electrolyte for traditional DRY CELL is -(a) H2S04, (b) Mn02, NH4Cl, H20, (c) Nacl, Mn0
(d) NH4C1, Nacl.

vii) Which can actboth as oxidant andreductant? -(a) KMn04, (b) S02, (C) K2Cr207, (d) H2S04.

viii) Number of coordinate bond in 03 molecule is -(a) 0, (b) 3, (c) 2, (d) 1.

ix) Buffer solution is -(a) NH4N03+KN03, (b) HC1+Nac1, (c) NH4N03+NH40H, (d) Nac1+HN03.

x) In ice, arrangement.9f H20 molecules is -(a) tetrahedral, a) linear, (c) triangular, (d) squar
plamer.
`-~`
xi) 46gmNa is how much gin equivalent? -(a) 1, (b) 2, (c) 3, (d) 4.

xii) Acid salt-is=(a)KIIS04, (b)Na2S03, (c)K3P04, (d)KN03.

xiii) Variable valency is shownby-(a) O, (b)N, (c) C1, (d) F.

xiv) De Broglie equation forwave nature of electron is -(a) v ==^, a) ^X h xm = 1, (c) h

(d) A -

xv) TheeffectivenumberofNa+andc1-ionsisunitcellis-(a) 3, a)4, (c) 3, (d) 1.

xvi) To deposit o.04 equivalent zn through electrolysis ofzns04, electricity required is -(a) 0.02 F,
(b) 0.04 F, (c) 0.06 F, (d) 0.03 F.

xvii) Ore of copper is -(a) CuFes2, (b) CuS04, (C) CuC12, (d) CuC03.

xviii) Catalyst used to convert NO from NH3 is - (a) Mo, ® P+dust, (c) Pt-gauze, (d) Pd.
xix) Correct electronic configuration if 24Cr is -(a) 4s[3d5, (b) 4s23d4, (c) 4s24p33d[, (d) 4s24p4.

xx) `Spiegel' contains -(a) Fe, Mo, C, a) Fe, Si, Mn, (c) Fe, C, Pt, (d) Fe, C, Man.

xxi) Permutit used to remove hardness of water is sodium salt ofanion forme.d by -(a) B, A1, O, (b) A1,
Si, 0, (c) S, 0, Al, (d) 8, S, 0.

xxii) Unsaturation of carbon-carbon is detected by - (a) K2Cr207, (b) H2S04, (c) NaN02,
(d) Br2+CC14.

Group-A

a) Show the bonding in N20, Cao, H2S04.


b) Ethyl alcohol is water soluble but dimethyl ether doesn't -why?
c) Explain `6' bond and `H' bond taking the exapple of ethylene.
d) What is Aufoan principle? 3+2+3+2

a) Explain with diagram of chemical bonding why diamond is extremely hard and non-conductor of
electricity but graphite is good electrical conductor and acts as lubricant.
b) Write Bohr's theory of electrons in his atomic model.
c) What happens in solubility of Agcl due to addition of AgN03 solution to the precipitated Agc1?`J
Explain.
d) Which is more stable and why? Fe+2 and Fe+3 3+3+2+2

a) How much volume of c02 is produced at NTP on reaction between o.25g cac03 with excess
dilute HC1?
b) Calculate the number of atoms in o.034gm NH3.
c) What is meant by buffer solution? Give example of one acid and one basic buffer solution. 3+3+4

Group-B

a) State Faraday's laws of electrolysis.


b) Write the electrodes, electrolyte and reactions in lead storage cell.
c) Mention the products during electrolysis of cus04 solution using -(i) Pt electrodes, and (ii) Cu
electrodes. 3+4+3

a) How can you prepare 350ml 0.2N Hcl from l2N Hcl?

:} S:i::]caeteb;h±eo:=:feaati°onnnmT:£:rd:f `S' [n H2S03 and `Cr' in K2Cro4.


i) NO;+Znizn+2 +NO+H20
ii) Cl-+ Cr2072 i cr+3 + C12 + H20 3+3+4¥
a) What are meant by exothermic and endothermic reactions?_ Give example. -
b) How is sulphuric acid manufactured by CONTACT process? Write the physic-chemical principles
only.
c) Explain the nature of aqueous sodium oxalate. 4+4+2

Group-C

a) Write the IupAc name:

CH3

i) CH3-C-CH3
I

CH3

ii) CH2 = CH-CH2-CH20H


iii) CH3 0 CH2CH3

b) Write the products :

i)03
i) L CH2=CH2
ii) Zn + H20

11) CH=CH#

c) flow is rectified spirit prepared from starch?


d) Deflne `homologous series'. 3+2+3+2

a) How is copper extracted from `Copper Matte'?


b) What are the ingredients required to extract aluminium from pure A1203?
c) Mention the raw materials to get iron from roasted ore.
d) Write the composition and use of alloy -(i) Nichrome, (ii) Bell Metal. 2+2+2+(2+2)

10 a) llitre of a sample of hard water contains o.0111gm cac12 and o.0120gm Mgs04. Calculate the
amount of hardness in ppm unit.
b) Mention two reactions of hard water using cation exchange resin and two reactions using anion
exchange resin. Write the conclusion after resin heated water.
c) What is meant by hardness of water?
d) Why hard water cannot be used for boiler? 3+3+2+2

ty

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