1.

The solubility of a gas in water depends on

(a) Nature of the gas (b) Temperature
H SO
(c) Pressure of the gas (d) All of the above 9. Dilute one litre 1 molar 2 4 solution by 5 litre
water, the normality of that solution is
(a) 0 . 2 N (b) 5N
D2 O
2. Which of the following is not correct for
(c) 10 N (d) 0.33 N
H2O
(a) Boiling point is higher than
D2 O H2O
(b) reacts slowly than 10. If 5.85 gms of NaCl are dissolved in 90 gms of water,
H2O o
the mole fraction of NaCl is
(c) Viscosity is higher than at 25
(a) 0.1 (b) 0.2
H2O
(d) Solubility of NaCl in it is more than (c) 0.3 (d) 0.01
(e) 0.0196
3. The statement “ The mass of a gas dissolved in a
given mass of a solvent at any temperature is
proportional to the pressure of the gas above the 11. The molarity of 0.006 mole of
NaCl in 100 ml solution
solvent” is is
(a) Dalton’s Law of Partial Pressures (a) 0.6 (b) 0.06
(b) Law of Mass Action (c) 0.006 (d) 0.066
(c) Henry’s Law (e) None of these
(d) None of these
H SO
12. 9 . 8 g of 2 4 is present in 2 litres of a solution. The
4. Which is correct about Henry’s law molarity of the solution is
(a) The gas in contact with the liquid should behave (a) 0 . 1 M (b) 0 . 05 M
as an ideal gas
(c) 0 . 2 M (d) 0 . 01 M
(b) There should not be any chemical interaction
between the gas and liquid
(c) The pressure applied should be high 13. What will be the molarity of a solution containing 5g
(d) All of these
of sodium hydroxide in 250 ml solution
(a) 0.5 (b) 1.0
5. The statement “If 0.003 moles of a gas are dissolved (c) 2.0 (d) 0.1
in 900 g of water under a pressure of 1 atmosphere,
0.006 moles will be dissolved under a pressure of 2
atmospheres”, illustrates 14. The normality of 0 . 3 M phosphorus acid
( H 3 PO 3 ) is
(a) Dalton’s law of partial pressure (a) 0.1 (b) 0.9
(b) Graham’s law (c) 0.3 (d) 0.6
(c) Raoult’s law
(d) Henry’s law
15. Which of the following has maximum number of
molecules
6. The solution of sugar in water contains O2 NO 2
(a) 16 gm of (b) 16 gm of
(a) Free atoms (b) Free ions
N2 H2
(c) Free molecules (d) Free atom and (c) 7 gm of (d) 2 gm of
molecules
16. Molarity is expressed as
(a) Gram/litre (b) Moles/litre
7. 25 ml of are mixed with 75 ml of
3 . 0 M HNO 3
(c) Litre/mole (d) Moles/1000 gms
4 .0 M HNO 3
. If the volumes are additive, the molarity
of the final mixture would be
17. 20 ml of HCl solution requires 19.85 ml of 0.01 M NaOH
(a) 3.25 M (b) 4 .0 M
solution for complete neutralization. The molarity of
(c) 3.75 M (d) 3 .50 M HCl solution is
(a) 0.0099 (b) 0.099
(c) 0.99 (d) 9.9
Na CO
8. The amount of anhydrous 2 3 present in 250 ml
of 0.25 M solution is
3
(a) 6.225 g (b) 66.25 g 18. How much of NaOH is required to neutralise 1500 cm
(c) 6.0 g (d) 6.625 g of 0.1 N HCl (At. wt. of Na =23)
(a) 4 g (b) 6 g
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 (c) 40 g (d) 60 g

29. The volumes of 4 N HCl and 10 N HCl required to

19. If 5.85 g of NaCl (molecular weight 58.5) is dissolved in
water and the solution is made up to 0.5 litre, the make 1 litre of 6 N HCl are
molarity of the solution will be (a) 0.75 litre of 10 N HCl and 0.25 litre of 4 N HCl
(a) 0.2 (b) 0.4 (b) 0.25 litre of 4 N HCl and 0.75 litre of 10 N HCl
(c) 1.0 (d) 0.1
(c) 0.67 litre of 4 N HCl and 0.33 litre of 10 N HCl
(d) 0.80 litre of 4 N HCl and 0.20 litre of 10 N HCl
20. A mixture has 18g water and 414g ethanol. The mole (e) 0.50 litre of 4 N HCl and 0.50 litre of 10 N HCl
fraction of water in mixture is (assume ideal behaviour
of the mixture)
(a) 0.1 (b) 0.4 H SO 4
30. Which statement is true for solution of 0.020 M 2
(c) 0.7 (d) 0.9
(a) 2 litre of the solution contains 0.020 mole of
SO2−
4
21. The number of molecules in 4.25 g of ammonia is
approximately (b) 2 litre of the solution contains 0.080 mole of
23 23
(a) 0 . 5×10 (b) 1 .5×10 H 3 O+
23 23
(c) 3 .5×10 (d) 2 .5×10 H 3 O+
(c) 1 litre of the solution contains 0.020 mole
(d) None of these
22. The largest number of molecules is in
25 g CO 2 46 g C 2 H 5 OH
(a) of (b) of 31. 10 litre solution of urea contains 240g urea. The active
H2O N 2 O5 mass of urea will be
(c) 36 g of (d) 54 g of (a) 0.04 (b) 0.02
(c) 0.4 (d) 0.2
23. If 1 M and 2.5 litre NaOH solution is mixed with
another 0.5 M and 3 litre NaOH solution, then molarity
of the resultant solution will be H 2 SO 4
32. 5 ml of NHCl, 20 ml of N/2 and 30 ml of N/3
(a) 1.0 M (b) 0.73 M HNO3 are mixed together and volume made to one litre.
(c) 0.80 M (d) 0.50 M The normally of the resulting solution is
N N
24. When a solute is present in trace quantities the (a) 5 (b) 10
following expression is used N N
(a) Gram per million (b) Milligram percent (c) 20 (d) 40
(c) Microgram percent (d) Parts per million

2 K Cr O
2 7 (eq. wt. 49.04) required to
25. When the concentration is expressed as the number of 33. The amount of
moles of a solute per litre of solution it known as prepare 100 ml of its 0.05 N solution is
(a) Normality (b) Molarity (a) 2.9424 g (b) 0.4904 g
(c) Mole fraction (d) Mass percentage (c) 1.4712 g (d) 0.2452 g

34. With increase of temperature, which of these changes

(a) Molality
H 2 SO 4
26. The normality of 2.3 M solution is (b) Weight fraction of solute
(a) 2.3 N (b) 4.6 N
(c) Fraction of solute present in water
(c) 0.46 N (d) 0.23 N
(d) Mole fraction

27. The molarity of a solution made by mixing 50ml of

35. 25ml of a solution of barium hydroxide on titration
H SO4 with a 0.1molar solution of hydrochloric acid gave a
conc. 2 (36N) with 50 ml of water is
(a) 36 M (b) 18 M litre value of 35 ml. The molarity of barium hydroxide
(c) 9 M (d) 6 M solution was
(a) 0.07 (b) 0.14
(c) 0.28 (d) 0.35
(C 12 H 22 O11 )
28. 171 g of cane sugar is dissolved in 1 litre
of water. The molarity of the solution is 36. 2.0 molar solution is obtained , when 0.5 mole solute
(a) 2.0 M (b) 1.0 M is dissolved in
(c) 0.5 M (d) 0.25 M (a) 250 ml solvent (b) 250 g solvent
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 (c) 250 ml solution (d) 1000 ml solvent (c) 1 (d) 0.75

37. How many gram of HCl will be present in 150 ml of its

46. The normality of a solution of sodium hydroxide 100
0.52 M solution ml of which contains 4 grams of NaOH is
(a) 2.84 gm (b) 5.70 gm (a) 0.1 (b) 40
(c) 8.50 gm (d) 3.65 gm (c) 1.0 (d) 0.4

38. The number of moles present in 2 litre of 0.5 M NaOH

47. Two solutions of a substance (non electrolyte) are
mixed in the following manner 480 ml of 1.5M first
is
solution + 520 mL of 1.2M second solution. What is
(a) 0.5 (b) 0.1
the molarity of the final mixture
(c) 1 (d) 2
(a) 1.20 M (b) 1.50 M
(c) 1.344 M (d) 2.70 M
39. 36g water and 828g ethyl alcohol form an ideal
solution. The mole fraction of water in it, is
(a) 1.0 (b) 0.7 48. The normal amount of glucose in 100 ml of blood (8–12
(c) 0.4 (d) 0.1 hours after a meal) is

(a) 8 mg (b) 80 mg
40. What will be the normality of a solution containing 4.9
(c) 200 mg (d) 800 mg
H 3 PO 4
g. dissolved in 500 ml water
(a) 0.3 (b) 1.0
(c) 3.0 (d) 0.1
49. Molar solution means 1 mole of solute present in
(a) 1000g of solvent (b) 1 litre of solvent
(c) 1 litre of solution (d) 1000g of solution
41. 3.0 molal NaOH solution has a density of 1.110 g/ml.
The molarity of the solution is
(a) 3.0504 (b) 3.64 50. What will be the molality of a solution having 18 g of
(c) 3.05 (d) 2.9732
glucose (mol. wt. = 180) dissolved in 500 g of water

(a) 1m (b) 0.5 m

42. Which of the following modes of expressing
concentration is independent of temperature
(c) 0.2 m (d) 2m
(a) Molarity (b) Molality
(c) Formality (d) Normality
2 Al (SO ) {d=1 .253 gm/ml}
4 3
51. A solution of contain 22%
43. The molality of a solution is salt by weight. The molarity, normality and molality of
the solution is
(a) Number of moles of solute per 1000 ml of the (a) 0.805 M, 4.83 N, 0.825 M
solvent (b) 0.825 M, 48.3 N, 0.805 M
(b) Number of moles of solute per 1000 gm of the (c) 4.83 M, 4.83 N, 4.83 M
solvent (d) None

(c) Number of moles of solute per 1000 ml of the

solution 52. Which of the following should be done in order to
(d) Number of gram equivalents of solute per prepare 0.40 M NaCl starting with 100 ml of
1000 ml of the solution
0.30M NaCl (mol.wt. of NaCl=58. 5 )
(a) Add 0.585 g NaCl (b) Add 20 ml water
44. The number of molecules in 16 gm of methane is 0.010ml NaCl
23 23
(c) Add (d) Evaporate 10 ml water
(a) 3 . 0×10 (b) 6 . 02×10
16 16 53. Which of the following solutions has the highest
×10 23 ×10 23
(c) 6 .02 (d) 3. 0 normality
(a) 8 gm of KOH / litre (b) N phosphoric acid
0 . 5 M H 2 SO4
45. The number of moles of a solute in its solution is 20 (c) 6 gm of NaOH / 100 ml (d)
and total number of moles are 80. The mole fraction of
solute is
(a) 2.5 (b) 0.25
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
54. What volume of 0.8 M solution contains 0.1 mole of 62. Mole fraction
( X ) of any solution is equal to
the solute No . of moles of solute
(a) 100 ml (b) 125 ml (a) Volume of solution in litre

500 ml 62.5 ml No . of gram equivalent of solute

(c) (d)
(b) Volume of solution in litre
No . of moles of solute
55. Hydrochloric acid A and B have
solution
0 . 5 N 0 . 1 N (c) Mass of solvent in kg
concentration of and respectively. The
A B No . of moles of any constituent
volumes of solutions and required to make
2 litres of 0 . 2 N HCl are (d) Total no . of moles of all constituents

(a) 0.5 l of A+1.5 l of B W B gm solute (molecular mass M B ) dissolves in

63. When
(b) 1.5 l of A+0 . 5 l of B W A gm solvent. The molality M of the solution is
(c) 1.0 l of A+1.0 l of B WB MB WB 1000
× ×
(d) 0.75 l of A+1 . 25l of B (a) W A 1000 (b) M B WA
W A 1000 W A ×M B
×
H 2 SO4 (c) W B MB (d) W B ×1000
56. Conc. has a density of 1.98 gm/ml and is 98%
H 2 SO 4
by weight. Its normality is
(a) 2 N (b) 19.8 N 64. Normality ( N ) of a solution is equal to
(c) 39.6 N (d) 98 N No . of moles of solute
(a) Volume of solution in litre
57. The mole fraction of the solute in one molal No . of gram equivalent of solute
aqueous solution is (b) Volume of solution in litre
(a) 0.027 (b) 0.036 No . of moles of solute
(c) 0.018 (d) 0.009
(c) Mass of solvent in kg
(d) None of these
N
58. With 63 gm of oxalic acid how many litres of 10
65. The volume strength of
1 .5 N H 2 O2 solution is
solution can be prepared
(a) 100 litre (b) 10 litre (a) 4.8 (b) 5.2
(c) 1 litre (d) 1000 litre (c) 8.8 (d) 8.4

0 . 2 N H 2 SO4 H SO4 is present in

66. How many gm of 2 0 . 25 gm mole of
59. Molarity of is
(a) 0.2 (b) 0.4 H 2 SO4
(c) 0.6 (d) 0.1 (a) 24.5 (b) 2.45
(c) 0.25 (d) 0.245
60. 10.6 grams of a substance of molecular weight 106 was
dissolved in 100 ml . 10 ml of this solution was pipetted 67. 20 g of hydrogen is present in 5 litre vessel. The molar
concentration of hydrogen is
out into a 1000 ml flask and made up to the mark with
(a) 4 (b) 1
distilled water. The molarity of the resulting solution is
(c) 3 (d) 2
(a) 1.0 M
−2
(b) 10 M
−3 −4
(c) 10 M (d) 10 M 68. To prepare a solution of concentration of 0.03
g/ml of
AgNO
3 , what amount of AgNO
3 should be
61. The mole fraction of water in 20% aqueous solution of added in 60 ml of solution
H 2 O2 is (a) 1.8 (b) 0.8
77 68 (c) 0.18 (d) None of these
(a) 68 (b) 77
69. How many grams of dibasic acid (mol. wt. 200) should
20 80
be present in 100 ml of its aqueous solution to give
(c) 80 (d) 20 decinormal strength
(a) 1g (b) 2g

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 (c) 10 g (d) 20 g
78. 1.0 gm of pure calcium carbonate was found to require
3 50 ml of dilute HCl for complete reaction. The strength
70. The weight of pure NaOH required to prepare 250 cm
of the HCl solution is given by
of 0 . 1 N solution is (a) 4 N (b) 2 N
(a) 4g (b) 1g (c) 0.4 N (d) 0.2 N
(c) 2g (d) 10 g
79. Molecular weight of glucose is 180. A solution of
glucose which contains 18 gms per litre is
71. If 20 ml of 0.4 N NaOH solution completely neutralises (a) 2 molal (b) 1 molal
40 ml of a dibasic acid. The molarity of the acid (c) 0.1 molal (d) 18 molal
solution is
(a) 0 . 1 M (b) 0 . 2 M
H SO
(c) 0 . 3 M (d) 0 . 4 M 80. 0.5 M of 2 4 is diluted from 1 litre to 10 litre,

normality of resulting solution is

(a) 1 N (b) 0.1 N
72. Which of the following concentration factor is affected
(c) 10 N (d) 11 N
by change in temperature
(a) Molarity (b) Molality
(c) Mole fraction (d) Weight fraction
81. If one mole of a substance is present in 1 kg of solvent,
then
73. The distribution law is applied for the distribution of (a) It shows molar concentration
basic acid between (b) It shows molal concentration
(a) Water and ethyl alcohol (c) It shows normality
(b) Water and amyl alcohol
(d) It shows strength gm/gm
(c) Water and sulphuric acid
(d) Water and liquor ammonia
H SO4
82. The molality of 90% 2 solution is
74. Which is heaviest [density=1.8 gm/ml]
(a) 25 gm of mercury (a) 1.8 (b) 48.4
(b) 2 moles of water (c) 9.18 (d) 94.6
(c) 2 moles of carbon dioxide
(d) 4 gm atoms of oxygen 3
83. The volume of water to be added to 100 cm of 0.5 N
H 2 SO4
to get decinormal concentration is
Na2 CO 3 3 3
75. The molarity of a solution of having (a) 400 cm (b) 500 cm
10 . 6 g /500 ml of solution is 3 3
(c) 450 cm (d) 100 cm
(a) 0 . 2 M (b) 2 M
(c) 20 M (d) 0 . 02 M 84. If 25 ml of 0.25 M NaCl solution is diluted with water to
a volume of 500ml the new concentration of the
solution is
H2 S +
76. On passing gas through a solution of Cu and (a) 0.167 M (b) 0.0125 M
Zn+2 ions, CuS is precipitated first because (c) 0.833 M (d) 0.0167 M
(a) Solubility product of CuS is equal to the ionic
product of ZnS 85. 10 grams of a solute is dissolved in 90 grams of a
(b) Solubility product of CuS is equal to the solubility solvent. Its mass percent in solution is
product of ZnS (a) 0.01 (b) 11.1
(c) Solubility product of CuS is lower than the (c) 10 (d) 9
solubility product of ZnS
(d) Solubility product of CuS is greater than the 86. What is the molality of a solution which contains 18 g
solubility product of ZnS (C 6 H 12 O6 )
of glucose in 250 g of water
(a) 4.0 m (b) 0.4 m
77. The number of moles of solute per kg of a solvent is (c) 4.2 m (d) 0.8 m
called its
(a) Molarity (b) Normality
(c) Molar fraction (d) Molality

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 H 2 SO4 (a) 0.02 M (b) 0.01 M
87. Calculate the molality of 1 litre solution of 93%
(weight/volume). The density of the solution is 1.84 (c) 0.001 M (d) 0.1 M
g /ml N A =6 . 02×1023 mol−1 )
(a) 10.43 (b) 20.36 (Avogadro constant,
(c) 12.05 (d) 14.05
SO 2 Cl 2
97. The number of moles of in 13 .5 gm is
HNO 3 (a) 0.1 (b) 0.2
88. Volume of water needed to mix with 10 ml 10N
HNO 3 (c) 0.3 (d) 0.4
to get 0.1 N
(a) 1000 ml (b) 990 ml
(c) 1010 ml (d) 10 ml H 2 C 2 O4 . 2 H 2 O
98. The weight of required to prepare
500 ml of 0 . 2 N solution is
89. The sum of the mole fraction of the components of a 126 g 12 .6 g
solution is (a) (b)
(a) 0 (b) 1 (c) 63 g (d) 6.3g
(c) 2 (d) 4

90. Increasing the temperature of an aqueous solution will 99. In a solution of

7.8 gm benzene 6 6 and 46.0 gm C H
cause (C 6 H 5 CH 3 )
toluene , the mole fraction of benzene in
(a) Decrease in molality this solution is
(b) Decrease in molarity
(a) 1/ 6 (b) 1/ 5
(c) Decrease in mole fraction
(d) Decrease in % w/w (c) 1/ 2 (d) 1/ 3

CaCO 3 2 , 2 5 25 %H O 25 %C H OH
91. 1000 gms aqueous solution of contains 10 gms 100. A solution contains and
of carbonate. Concentration of the solution is 50 % CH 3 COOH H2O
by mass. The mole fraction of
(a) 10 ppm (b) 100 ppm would be
(c) 1000 ppm (d) 10000 ppm (a) 0.25 (b) 2.5
(c) 0.503 (d) 5.03
92. 3.65 gms of HCl is dissolved in 16.2 gms of water. The
mole fraction of HCl in the resulting solution is
H SO
(a) 0.4 (b) 0.3 101. A 5 molar solution of 2 4 is diluted from 1

(c) 0.2 (d) 0.1 litre to 10 litres. What is the normality of the solution
(a) 0.25 N (b) 1 N
(c) 2 N (d) 7 N
93. An aqueous solution of glucose is 10% in strength. The
volume in which 1 gm mole of it is dissolved will be
(a) 18 litre (b) 9 litre 102. Molarity of a solution containing 1g NaOH in
(c) 0.9 litre (d) 1.8 litre 250ml of solution is
(a) 0 . 1 M (b) 1 M
94. The concentration of an aqueous solution of
0 . 01 M CH 3 OH (c) 0.01 M (d) 0.001 M
solution is very nearly equal to which of
the following
0 . 01 % CH 3 OH 0 . 01 m CH 3 OH 103. What is molarity of a solution of HCl which
(a) (b)
contains 49% by weight of solute and whose specific
x CH OH =0 . 01 0 . 01 N CH 3 OH gravity is 1.41
(c) 3 (d)
(a) 15.25 (b) 16.75
(c) 18.92 (d) 20.08
95. When 1 .80 gm glucose dissolve in 90 gm of
H2O
, the
mole fraction of glucose is H 2 SO3
104. NaClO solution reacts with as,
(a) 0.00399 (b) 0.00199
NaClO+ H 2 SO 3 → NaCl+ H 2 SO 4
(c) 0.0199 (d) 0.998 . A solution of NaClO
used in the above reaction contained 15g of NaClO
20 per litre. The normality of the solution would be
96. 6 . 02×10 molecules of urea are present in 100 ml of (a) 0.8 (b) 0.6
its solution. The concentration of urea solution is
(c) 0.2 (d) 0.33

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 No . of moles of any constituent
105.
24
A solution contains 1 .2046×10 hydrochloric acid (d) Total no . of moles of all constituents
3
molecules in one dm of the solution. The strength of
the solution is
114. If 5 . 0 gm of
BaCl 2
is present in 106 gm solution,
(a) 6 N (b) 2 N
the concentration is
(c) 4 N (d) 8 N (a) 1 ppm (b) 5 ppm
(c) 50 ppm (d) 1000 ppm
1
N
106. 10 N and 10 solution is called 115. 1 Molar solution contains
(a) Decinormal and decanormal solution (a) 1000g of solute (b) 1000g of solvent
(b) Normal and decinormal solution (c) 1 litre of solvent (d) 1 litre of solution
(c) Normal and decanormal solution
(d) Decanormal and decinormal solution 116. To neutralise completely 20 mL of 0.1 M aqueous
3 3 ( H PO ),
solution of phosphorous acid the volume of
7 . 1 gm Na 2 SO4 0.1 M aqueous KOH solution required is
107. When (molecular mass 142) (a) 40 mL (b) 20 mL
100 ml H 2 O
dissolves in , the molarity of the solution is (c) 10 mL (d) 60 mL
(a) 2.0 M (b) 1.0 M
(c) 0.5 M (d) 0.05 M
117. On dissolving 1 mole of each of the following
acids in 1 litre water, the acid which does not give a
108. Molarity of 4% NaOH solution is solution of strength 1 N is
(a) 0 . 1 M (b) 0 . 5 M (a) HCl (b) Perchloric acid
(c) 0 . 01 M (d) 1 .0 M HNO 3
(c) (d) Phosphoric acid

180 gm H 2 O
109. When 6 gm urea dissolve in . The mole 118. How many grams of NaOH will be required to
fraction of urea is neutralize 12.2 grams of benzoic acid
10 10 .1 40 gms 4 gms
(a) (b)
(a) 10 .1 (b) 10
(c) 16 gms (d) 12.2 gms
10 .1 0. 1
(c) 0. 1 (d) 10 .1
H SO
10 ml of conc. 2 4 (18 molar) is diluted to 1
119.
110. The normality of 10% (weight/volume) acetic acid litre. The approximate strength of dilute acid could be
is (a) 0.18 N (b) 0.09 N
(a) 1 N (b) 10 N (c) 0.36 N (d) 1800 N
(c) 1.7 N (d) 0.83 N
120. The normality of 10 lit. volume hydrogen peroxide is
111. Unit of mole fraction is (a) 0.176 (b) 3.52
(a) Moles/litre (b) Moles/litre2 (c) 1.78 (d) 0.88
(c) Moles–litre (d) Dimensionless

112. Normality of 2 M sulphuric acid is 121. Essential quantity of ammonium sulphate taken
for preparation of 1 molar solution in 2 litres is
(a) 2 N (b) 4 N
(a) 132 gm (b) 264 gm
(c) N / 2 (d) N / 4
(c) 198 gm (d) 212 gm
113. Molar concentration ( M ) of any solution =
No . of moles of solute H O2
122. In a mixture of 1 gm 2 and 8 gm , the mole
(a) Volume of solution in litre fraction of hydrogen is
No . of gram equivalent of solute (a) 0.667 (b) 0.5
(c) 0.33 (d) None of these
(b) Volume of solution in litre
No . of moles of solute
(c) Mass of solvent in kg
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
123. A solution of
CaCl 2
is 0.5 mol/litre , then the
132. Molarity of a solution prepared by dissolving 75.5
g of pure KOH in 540 ml solution is
moles of chloride ion in 500 ml will be (a) 3.05 M (b) 1.35 M
(a) 0.25 (b) 0.50 (c) 2.50 M (d) 4.50 M
(c) 0.75 (d) 1.00

133. Which one of the following is an extensive

H 2 SO4 property
124. What is the molarity of solution, that has
o
(a) Molar volume (b) Molarity
a density 1.84 gm/cc at 35 C and contains solute 98% (c) Number of moles (d) Mole fraction
by weight
(a] 4.18 M (b) 8.14 M
(c) 18.4 M (d) 18 M BaCl 2
134. Addition of conc. HCl to saturated solution
BaCl 2
precipitates ; because
FeCl 3 (a) It follows from Le Chatelier’s principle
125. A certain aqueous solution of (formula
(b) Of common-ion effect
mass =162) has a density of 1.1 g/ml and contains ++ −
20 . 0 % FeCl 3 (c) Ionic product ( Ba ),(Cl ) remains constant in a
. Molar concentration of this solution is
(a) 0.028 (b) 0.163 saturated solution
(c) 1.27 (d) 1.47 (d) At constant temperature, the product ( Ba2+ ),
(Cl− )2 remains constant in a saturated solution
CaCl 2
126. If 0.50 mol of is mixed with 0.20 mol of
Na3 PO 4 Ca3 ( PO 4 )2 135.
, the maximum number of moles of How much water is needed to dilute 10 ml of 10
which can be formed, is N hydrochloric acid to make it exactly decinormal (0.1
(a) 0.70 (b) 0.50 N)
(c) 0.20 (d) 0.10 (a) 990 ml (b) 1000 ml
(c) 1010 ml (d) 100 ml

127. An X molal solution of a compound in benzene

has mole fraction of solute equal to 0.2. The value of 136. H SO4
The formula weight of 2 is 98. The weight of
X is
the acid in 400 ml of 0 . 1 M solution is
(a) 14 (b) 3.2
(a) 2.45 g (b) 3.92 g
(c) 4 (d) 2
(c) 4 .90 g (d) 9.8 g
128. Molecular weight of urea is 60. A solution of urea
containing 6 g urea in one litre is 137. The molarity of pure water is
(a) 1 molar (b) 1.5 molar (a) 55.6 (b) 5.56
(c) 0.1 molar (d) 0.01 molar (c) 100 (d) 18

129. The molar solution of sulphuric acid is equal to 0 . 2 N Na 2 CO 3

138. The molarity of a solution will be
(a) N solution (b) 2 N solution (a) 0.05 M (b) 0.2 M
(c) N / 2 solution (d) 3 N solution (c) 0.1 M (d) 0.4 M

130. The weight of sodium carbonate required to 139. How many moles of water are present in 180 g
prepare 500 ml of a semi- normal solution is of water
(a) 13.25 g (b) 26.5 g (a) 1 mole (b) 18 mole
(c) 53 g (d) 6.125 g (c) 10 mole (d) 100 mole

200 ml of a solution contains 5.85 g dissolved CO 2 N

If we take 44 g of and 14 g of 2 what will
131.
140.
sodium chloride. The concentration of the solution will
CO 2
be ( Na=23; Cl=35.5)
be mole fraction of in the mixture
(a) 1/5 (b) 1/3
(a) 1 molar (b) 2 molar
(c) 0.5 molar (d) 0.25 molar (c) 2/3 (d) 1/4

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

141. What is the volume of 0.1 N HCl required to react
150. A solution contains 1 mole of water and 4 mole of
ethanol. The mole fraction of water and ethanol will be
completely with 1 .0 g of pure calcium carbonate (a) 0.2 water + 0.8 ethanol
(Ca=40 , C=12 and O=16 ) (b) 0.4 water + 0.6 ethanol
3 3 (c) 0.6 water + 0.8 ethanol
(a) 150 cm (b) 250 cm
(d) 0.8 water + 0.2 ethanol
(c) 200 cm 3 (d) 100 cm 3
151. The magnitude of colligative properties in all
3 colloidal dispersions is ….than solution
142. The amount of NaOH in gms in 250 cm of a (a) Lower (b) Higher
0.100 M NaOH solution would be (c) Both (d) None
(a) 4 gm (b) 2 gm
(c) 1 gm (d) 2.5 gm
152. Equimolar solutions in the same solvent have
(a) Same boiling point but different freezing point
143. 4.0 gm of NaOH are contained in one decilitre of
(b) Same freezing point but different boiling point
solution. Its molarity would be
(a) 4 M (b) 2 M (c) Same boiling and same freezing points
(c) 1 M (d) 1.5 M (d) Different boiling and different freezing points

144. When 90 gm of water is mixed with 300 gm of 153. Which of the following is a colligative property
acetic acid. The total number of moles will be (a) Osmotic pressure (b) Boiling point
(a) 5 (b) 10 (c) Vapour pressure (d) Freezing point
(c) 15 (d) 20
154. The colligative properties of a solution depend on
145. A molal solution is one that contains one mole of (a) Nature of solute particles present in it
a solute in (b) Nature of solvent used
(a) 1000 gm of the solvent (c) Number of solute particles present in it
(b) One litre of the solvent (d) Number of moles of solvent only
(c) One litre of the solution
(d) 22.4 litres of the solution
155. Which of the following is not a colligative
property
146. What weight of ferrous ammonium sulphate is (a) Osmotic pressure
needed to prepare 100 ml of 0.1 normal solution (mol. (b) Elevation in B.P.
wt. 392) (c) Vapour pressure
(a) 39.2 gm (b) 3.92 gm
(d) Depression in freezing point
(c) 1.96 gm (d) 19.6 gm

156. Which of the following is not a colligative

(C 6 H 12 O6 ) property
147. If 18 gm of glucose is present in 1000
(a) Optical activity
gm of an aqueous solution of glucose, it is said to be
(a) 1 molal (b) 1.1 molal (b) Elevation in boiling point

(c) 0.5 molal (d) 0.1 molal (c) Osmotic pressure

(d) Lowering of vapour pressure

148. The number of moles of KCl in 1000 ml of 3 157. Colligative properties of a solution depends upon
molar solution is (a) Nature of both solvent and solute
(a) 1 (b) 2
(b) The relative number of solute and solvent
(c) 3 (d) 1.5 particles
(c) Nature of solute only
149. The unit of molality is (d) Nature of solvent only
(a) Mole per litre (b) Mole per kilogram
(c) Per mole per litre (d) Mole litre 158. Which of the following is a colligative property
(a) Surface tension (b) Viscosity
(c) Osmotic pressure (d) Optical rotation
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 167. Vapour pressure of a solution is
(a) Directly proportional to the mole fraction of the
159. Which is not a colligative property
(a) Refractive index solvent

(b) Lowering of vapour pressure (b) Inversely proportional to the mole fraction of the
solute
(c) Depression of freezing point
(c) Inversely proportional to the mole fraction of the
(d) Elevation of boiling point
solvent
(d) Directly proportional to the mole fraction of the
160. Colligative properties are used for the solute
determination of
(a) Molar Mass
(b) Equivalent weight 168. When a substance is dissolved in a solvent the
vapour pressure of the solvent is decreased. This
(c) Arrangement of molecules results in
(d) Melting point and boiling point (a) An increase in the b.p. of the solution
(d) Both (a) and (b) (b) A decrease in the b.p. of the solvent
(c) The solution having a higher freezing point than
161. What does not change on changing temperature the solvent
(a) Mole fraction (b) Normality (d) The solution having a lower osmotic pressure
(c) Molality (d) None of these than the solvent

CCl 4 o o
If P and P are the vapour pressure of a solvent
162. Vapour pressure of at 25 C is 143 mm of 169.
Hg 0.5 gm N N
of a non-volatile solute (mol. wt. = 65) is and its solution respectively and 1 and 2 are the

100 ml CCl 4 mole fractions of the solvent and solute respectively,

dissolved in . Find the vapour pressure of then correct relation is
CCl 4 =1. 58 g/cm 2 P=P o N 1 P=P o N 2
the solution (Density of ) (a) (b)
(a) 141.43 mm (b) 94.39 mm Po =P N 2 P=P o (N 1 / N 2 )
(c) (d)
(c) 199.34 mm (d) 143.99 mm
170. An aqueous solution of methanol in water has
vapour pressure
163. For a solution of volatile liquids the partial vapour
pressure of each component in solution is directly (a) Equal to that of water
proportional to (b) Equal to that of methanol
(a) Molarity (b) Mole fraction (c) More than that of water
(c) Molality (d) Normality (d) Less than that of water

164. “The relative lowering of the vapour pressure is 171. The pressure under which liquid and vapour can
equal to the mole fraction of the solute.” This law is coexist at equilibrium is called the
called (a) Limiting vapour pressure
(a) Henry's law (b) Raoult's law
(b) Real vapour pressure
(c) Ostwald's law (d) Arrhenius's law (c) Normal vapour pressure
(d) Saturated vapour pressure
165. The relative lowering of vapour pressure
produced by dissolving 71.5 g of a substance in 1000
g of water is 0.00713. The molecular weight of the
substance will be 172. Which solution will show the maximum vapour
(a) 18.0 (b) 342 pressure at 300 K
(c) 60 (d) 180 C 12 H 22 O11 CH 3 COOH
(a) 1 M (b) 1 M
NaCl
(c) 1 M 2 (d) 1 M NaCl
166. When mercuric iodide is added to the aqueous
solution of potassium iodide, the
(a) Freezing point is raised 173. The relative lowering of the vapour pressure is
(b) Freezing point is lowered equal to the ratio between the number of
(a) Solute moleules and solvent molecules
(c) Freezing point does not change
(b) Solute molecules and the total molecules in the
(d) Boiling point does not change
solution

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 (c) Solvent molecules and the total molecules in the (c) Kerosene (d) Rectified spirit
solution
(d) Solvent molecules and the total number of ions 181. According to Raoult's law the relative lowering of
of the solute vapour pressure of a solution of volatile substance is
equal to
(a) Mole fraction of the solvent
3
174. 5 cm of acetone is added to 100 cm of water, the
3
(b) Mole fraction of the solute
vapour pressure of water over the solution (c) Weight percentage of a solute
(a) It will be equal to the vapour pressure of pure (d) Weight percentage of a solvent
water
(b) It will be less than the vapour pressure of pure
182. When a substance is dissolved in a solvent, the
water
vapour pressure of the solvent is decreased. This
(c) It will be greater than the vapour pressure of results in
pure water (a) An increase in the boiling point of the solution
(d) It will be very large (b) A decrease in the boiling point of solvent
(c) The solution having a higher freezing point than
175. At 300 K, when a solute is added to a solvent its the solvent
vapour pressure over the mercury reduces from 50 (d) The solution having a lower osmotic pressure
mm to 45 mm. The value of mole fraction of solute will than the solvent
be
(a) 0.005 (b) 0.010
(c) 0.100 (d) 0.900 183. The vapour pressure of a liquid depends on
(a) Temperature but not on volume
(b) Volume but not on temperature
176. A solution has a 1 : 4 mole ratio of pentane to
hexane. The vapour pressure of the pure hydrocarbons (c) Temperature and volume
at 20°C are 440 mmHg for pentane and 120 mmHg for (d) Neither on temperature nor on volume
hexane. The mole fraction of pentane in the vapour
phase would be
(a) 0.549 (b) 0.200 184. Which one of the statements given below
(c) 0.786 (d) 0.478 concerning properties of solutions, describes a colligative
effect
(a) Boiling point of pure water decreases by the
177. Benzene and toluene form nearly ideal solutions. addition of ethanol
At 20°C, the vapour pressure of benzene is 75 torr and (b) Vapour pressure of pure water decreases by the
that of toluene is 22 torr. The parial vapour pressure of
addition of nitric acid
benzene at 20°C for a solution containing 78g of
benzene and 46g of toluene in torr is (c) Vapour pressure of pure benzene decreases by
(a) 50 (b) 25 the addition of naphthalene
(c) 37.5 (d) 53.5 (d) Boiling point of pure benzene increases by the
addition
of toluene
178. The vapour pressure lowering caused by the
addition of 100 g of sucrose(molecular mass = 342) to
1000 g of water if the vapour pressure of pure water 185. The atmospheric pressure is sum of the
o
at 25 C is 23.8 mm Hg (a) Pressure of the biomolecules
(a) 1.25 mm Hg (b) 0.125 mm Hg (b) Vapour pressure of atmospheric constituents
(c) 1.15 mm Hg (d) 00.12 mm Hg (c) Vapour pressure of chemicals and vapour
pressure of volatiles
179. Which of the following is incorrect (d) Pressure created on to atmospheric molecules
(a) Relative lowering of vapour pressure is
independent 186. The vapour pressure of pure liquid A is 0.80 atm.
(b) The vapour pressure is a colligative property On mixing a non-volatile B to A, its vapour pressure
(c) Vapour pressure of a solution is lower than the becomes 0.6 atm. The mole fraction of B in the
solution is
vapour pressure of the solvent
(a) 0.150 (b) 0.25
(d) The relative lowering of vapour pressure is
(c) 0.50 (d) 0.75
directly propertional to the original pressure

187. Lowering of vapour pressure is highest for

180. Among the following substances the lowest
vapour pressure is exerted by (a) Urea (b) 0 . 1 M glucose
(a) Water (b) Mercury
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 0 . 1 M MgSO 4 0 . 1 M BaCl 2 (a) HI (b) HBr
(c) (d)
(c) HCl (d) HF

188. An aqueous solution of glucose was prepared by

dissolving 18 g of glucose in 90 g of water. The 195. When a non-volatile solute is dissolved in a
relative lowering in vapour pressure is solvent, the relative lowering of vapour pressure is
(a) 0.02 (b) 1 equal to
(a) Mole fraction of solute
(c) 20 (d) 180
(b) Mole fraction of solvent
(c) Concentration of the solute in grams per litre
189. “Relative lowering in vapour pressure of solution
containing non-volatile solute is directly proportional (d) Concentration of the solute in grams 100 ml
to mole fraction of solute”. Above statement is
(a) Henry law (b) Dulong and Petit law
196. 60 gm of Urea (Mol. wt 60) was dissolved in 9.9
(c) Raoult's law (d) Le-Chatelier's principle moles, of water. If the vapour pressure of pure water is
Po , the vapour pressure of solution is
190. An ideal solution was obtained by mixing Po Po
methanol and ethanol. If the partial vapour pressure of (a) 0.10 (b) 1.10
2.619 kPa 4 .556 kPa (c) 0.90
Po (d) 0.99
Po
methanol and ethanol are and
respectively, the composition of the vapour (in terms
of mole fraction) will be o
(a) 0.635 methanol, 0.365 ethanol 197. The vapour pressure of water at 20 C is 17.54
(b) 0.365 methanol, 0.635 ethanol mm. When 20g of a non-ionic, substance is dissolved
in 100g of water, the vapour pressure is lowered by
(c) 0.574 methanol, 0.326 ethanol 0.30 mm. What is the molecular weight of the
(d) 0.173 methanol, 0.827 ethanol substances
(a) 210.2 (b) 206.88
(c) 215.2 (d) 200.8
191. The vapour pressure of two liquids P and Q are
80 and 600 torr, respectively. The total vapour
pressure of solution obtained by mixing 3 mole of P 198. In an experiment, 1 g of a non-volatile solute was
and 2 mole of Q would be dissolved in 100 g of acetone (mol. mass = 58) at
(a) 140 torr (b) 20 torr 298K. The vapour pressure of the solution was found
(c) 68 torr (d) 72 torr to be 192.5 mm Hg. The molecular weight of the
solute is (vapour pressure of acetone = 195 mm Hg)
(a) 25.24 (b) 35.24
192. The vapour pressure of benzene at a certain
(c) 45.24 (d) 55.24
temperature is
640 mm of Hg . A non-volatile and non-
electrolyte solid weighing 2 .175 g is added to 39 . 08 g CH 3 OH
of benzene. The vapour pressure of the solution is 199. How many grams of should be added to
600 mm of Hg . What is the molecular weight of solid water to prepare 150 ml solution of
2 M CH 3 OH
substance (a) 9.6 (b) 2.4
(a) 49.50 (b) 59.6 3 3
(c) 9 . 6×10 (d) 2 . 4×10
(c) 69.5 (d) 79.8

200. The vapour pressure of a solvent decreased by

193. Which one of the following is the expression of
Raoult's law 10 mm of mercury, when a non-volatile solute was
p− p s ps− p added to the solvent. The mole fraction of the solute in
n N
= = the solution is 0.2. What should be the mole fraction of
(a) p n+ N (b) p N +n the solvent, if decrease in the vapour pressure is to be
p− p s N ps− p N −n 20 mm of mercury
= =
ps N −n ps N (a) 0.8 (b) 0.6
(c) (d)
(c) 0.4 (d) 0.2
p= vapour pressure of pure solvent
p s=
vapour pressure of the solution 201. For a dilute solution, Raoult's law states that
n= number of moles of the solute (a) The lowering of vapour pressure is equal to mole
N= number of moles of the solvent fraction of solute
(b) The relative lowering of vapour pressure is equal
to mole fraction of solute
194. Which has maximum vapour pressure
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 (c) The relative lowering of vapour pressure is CCl 4 + SiCl 4 H 2 O+C 4 H 9 OH
(a) (b)
proportional to the amount of solute in solution
(d) The vapour pressure of the solution is equal to C 2 H 5 Br +C 2 H 5 I C 6 H 14 +C 7 H 16
(c) (d)
the mole fraction of solvent

210. An ideal solution is that which

202. The vapour pressure of a solvent A is 0.80 atm (a) Shows positive deviation from Raoult's law
When a non-volatile substance B is added to this
solvent its vapour pressure drops to 0.6 atm. What is (b) Shows negative deviation from Raoult's law
mole fraction of B in solution (c) Has no connection with Raoult's law
(a) 0.25 (b) 0.50 (d) Obeys Raoult's law
(c) 0.75 (d) 0.90

211. Which one of the following mixtures can be

203. Determination of correct molecular mass from separated into pure components by fractional
Raoult's law is applicable to distillation
(a) An electrolyte in solution (a) Benzene – toluene (b) Water – ethyl alcohol
(b) A non-electrolyte in a dilute solution (c) Water – nitric acid (d) Water – hydrochloric
(c) A non-electrolyte in a concentrated solution acid
(d) An electrolyte in a liquid solvent

212. All form ideal solutions except

P0A : P0B=1 : 2 C 2 H 5 Br C2 H5 I C 6 H 5 Cl C 6 H 5 Br
204. If two substances A and B have and (a) and (b) and
have mole fraction in solution 1 : 2 then mole fraction
C6 H6 C 6 H 5 CH 3 C2 H5 I C 2 H 5 OH
of A in vapours (c) and (d) and
(a) 0.33 (b) 0.25
(c) 0.52 (d) 0.2 213. Which property is shown by an ideal solution
ΔH mix =0
(a) It follows Raoult's law(b)
205. A dry air is passed through the solution,
containing the 10 gm of solute and 90 gm of water ΔV mix =0
(c) (d) All of these
and then it pass through pure water. There is the
depression in weight of solution wt by 2.5 gm and in
weight of pure solvent by 0.05 gm. Calculate the 214. When two liquid A and B are mixed then their
molecular weight of solute boiling points becomes greater than both of them.
(a) 50 (b) 180 What is the nature of this solution
(c) 100 (d) 25 (a) Ideal solution
(b) Positive deviation with non ideal solution
(c) Negative deviation with non ideal solution
(d) Normal solution
206. Which of the following liquid pairs shows a
positive deviation from Raoult's law
(a) Water-nitric acid (b) Benzene-methanol 215. In mixture A and B components show –ve
(c) Water-hydrochloric acid (d)Acetone-chloroform deviation as
ΔV mix >0
(a)
207. Which one of the following is non-ideal solution ΔHmix <0
(b)
(a) Benzene + toluene (c) A-B interaction is weaker than A-A and B-B
(b) n -hexane + n -heptane interaction
(c) Ethyl bromide + ethyl iodide (d) A-B interaction is strong than A-A and B-B
CCl 4 +CHCl 3 interaction
(d)

216. In which case Raoult's law is not applicable

208. A non ideal solution was prepared by mixing 30 ml
(a) 1 M NaCl (b) 1 M urea
chloroform and 50 ml acetone. The volume of mixture
will be (c) 1 M glucose (d) 1 M sucrose
(a) > 80 ml (b) < 80 ml
(c) = 80 ml (d)  80 ml 217. A solution that obeys Raoult's law is
(a) Normal (b) Molar
(c) Ideal (d) Saturated
209. Which pair from the following will not form an
ideal solution
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
218. An example of near ideal solution is (c) Positive deviation from Raoult's law
(a) n -heptane and n -hexane (d) Practically no deviation from Raoult's law
CH 3 COOH +C 5 H 5 N
(b)
226. The solution which shows negative or positive
(c)
CHCl 3 +(C 2 H 5 )2 O deviation by Raoult's law, is called
H 2 O+ HNO 3 (a) Ideal solution (b) Real solution
(d)
(c) Non-ideal solution (d) Colloidal solution

219. A mixture of liquid showing positive deviation in

227. Which of the following does not show positive
Raoult's law is
deviation from Raoult’s law
(a)
(CH 3 )2 CO+C2 H 5 OH (b) (CH 3 )2 CO +CHCl 3 (a) Benzene-Chloroform
(C 2 H 5 )2 O+CHCl 3 (CH 3 )2 CO+C6 H 5 NH 2 (b) Benzene-Acetone
(c) (d)
(c) Benzene-Ethanol
(d) Benzene-Carbon tetrachloride
220. All form ideal solution except
C 2 H 5 Br C2 H5 I C 2 H 5 Cl C 6 H 5 Br
(a) and (b) and 228. Which of the following mixture shows positive
C6 H6 C 6 H 5 CH 3 C2 H5 I C 2 H 5 OH deviation by ideal behaviour
(c) and (d) and CHCl 3 +(CH 3 )2 CO C 6 H 6 +C6 H 5 CH 3
(a) (b)
H O+ HCl CCl +CHCl
221. Formation of a solution from two components can (c) 2 (d) 4 3
be considered as
(i) Pure solvent  separated solvent molecules H1
229. Which property is not found in ideal solution
(ii) Pure solute  separated solute molecules H2
P ≠PoA× X A
(a) A (b)
ΔH mix ≠0
(iii) Separated solvent and solute molecules 
solution H3 ΔV mix ≠0
(c) (d) All of these
Solution so formed will be ideal if
ΔH soln= ΔH 3 −ΔH 1 −ΔH 2
(a) 230. Which of the following is not correct for ideal
ΔH soln= ΔH 1 + ΔH 2 + ΔH 3 solution
(b) ΔS mix =0 ΔH mix =0
(a) (b)
ΔH soln= ΔH 1 + ΔH 2 −ΔH 3
(c) ΔV mix =0
(c) It obeys Raoult's law (d)
ΔH soln= ΔH 1 −ΔH 2− ΔH 3
(d)
231. Which of the following does not show negative
222. Identify the mixture that shows positive deviation deviation from Raoult’s law
from Raoult’s law (a) Acetone-Chloroform (b) Acetone-Benzene

(a)
CHCl 3 +(CH 3 )2 CO (b)
(CH 3 )2 CO +C6 H 5 NH 2 (c) Chloroform-Ether (d) Chloroform-Benzene

CHCl 3 +C 6 H 6 (CH 3 )2 CO +CS2

(c) (d) 232. A mixture of benzene and toluene forms
(a) An ideal solution (b) Non-ideal solution
223. When acetone is added to chloroform, then (c) Suspension (d) Emulsion
hydrogen bond is formed between them.These liquids
show
233. Which of the following is an ideal solution
(a) Positive deviation from Raoult's law
(a) Water + ethanol
(b) Negative deviation from Raoult's law
(b) Chloroform + carbon tetrachloride
(c) No deviation from Raoult's law
(c) Benzene + toluene
(d) Volume is slightly increased
(d) Water + hydrochloric acid

224. Which of the following is true when components

234. When ethanol mixes in cyclohexane;
forming an ideal solution are mixed
cyclohexane reduces the intermolecular forces
ΔH m=ΔV m=0 ΔH m > ΔV m between ethanol molecule. In this, liquid pair shows
(a) (b)
(a) Positive deviation by Raoult's law
ΔH m < ΔV m ΔH m=ΔV m=1
(c) (d) (b) Negative deviation by Raoult's law
(c) No deviation by Raoult's law
225. The liquid pair benzene-toluene shows (d) Decrease in volume
(a) Irregular deviation from Raoult's law
(b) Negative deviation from Raoult's law 235. Liquids A and B form an ideal solution
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 (a) The enthalpy of mixing is zero (c) 5.7 (d) 19
(b) The entropy of mixing is zero
(c) The free energy of mixing is zero
243. Osmotic pressure is 0.0821 atm at temperature
(d) The free energy as well as the entropy of mixing
are each zero of
300 K . Find concentration in mole/litre
(a) 0.033 (b) 0.066
−2
o (c) 0 . 33×10
The azeotropic mixture of water (b . p .100 C ) and
(d) 3
236.
HCl (b. p. 85o C ) o
boils at 108 .5 C . When this mixture is
244. Osmotic pressure of a solution containing 0.1 mole of
distilled it is possible to obtain
solute per litre at 273 K is (in atm)
(a) Pure HCl
0 .1
(b) Pure water ×0 . 08205×273
(a) 1 (b) 0 . 1×1×0 . 08205×273
(c) Pure water as well as pure HCl
1 0 .1 273
HCl H2O ×0 . 08205×273 ×
(d) Neither nor in their pure states (c) 0 .1 (d) 1 0 .08205

237. An azeotropic solution of two liquids has boiling 245. A solution contains non-volatile solute of
point lower than either when it
Mp
(a) Shows a negative deviation from Raoult's law molecular mass . Which of the following can be
(b) Shows no deviation from Raoult's law used to calculate molecular mass of the solute in
terms of osmotic pressure (m = Mass of solute, V =
(c) Shows positive deviation from Raoult's law Volume of solution and  = Osmotic pressure)
(d) Is saturated

238. A liquid mixture boils without changing (a)

Mp=( mπ ) VRT (b)
Mp= ( Vm ) RTπ
constituent is called
Mp=( ) Mp=( ) π RT
(a) Stable structure complex m π m
(b) Binary liquid mixture
V RT V
(c) (d)
(c) Zeotropic liquid mixture
(d) Azeotropic liquid mixture 246. The osmotic pressure of a 5% (wt/vol) solution of
o
cane sugar at 150 C is
239. Azeotropic mixture are (a) 2.45 atm (b) 5.078 atm
(a) Constant temperature boiling mixtures (c) 3.4 atm (d) 4 atm
(b) Those which boils at different temperatures
(c) Mixture of two solids
247. The relationship between osmotic pressure at
(d) None of the above
273 K when 10 g glucose
( P1 ), 10 g
urea
( P2 )
and 10 g
( P3 )
240. A mixture of two completely miscible non-ideal sucrose are dissolved in 250 ml of water is
liquids which distil as such without change in its P1 > P 2 > P3 P3 > P 1 > P2
composition at a constant temperature as though it (a) (b)
were a pure liquid. This mixture is known as P2 > P 1 > P3 P2 > P 3 > P1
(a) Binary liquid mixture (b) Azeotropic mixture (c) (d)
(c) Eutectic mixture (d)Ideal mixture
248. In osmosis
(a) Solvent molecules move from higher
241. If 3 gm of glucose (mol. wt. 180) is dissolved in
o concentration to lower concentration
60 gm of water at 15 C . Then the osmotic pressure of
(b) Solvent molecules move from lower to higher
this solution will be
concentration
(a) 0.34 atm (b) 0.65 atm
(c) Solute molecules move from higher to lower
(c) 6.57 atm (d) 5.57 atm
concentration
(d) Solute molecules move from lower to higher
242. The concentration in gms per litre of a solution of concentration
cane sugar
( M=342 ) which is isotonic with a solution

containing
6 gms of urea ( M=60 ) per litre is 249.Semipermeable membrane is that which permits the
(a) 3.42 (b) 34.2 passage of

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 (a) Solute molecules only (a) 1000 (b) 1200
(b) Solvent molecules only (c) 1400 (d) 1800
(c) Solute and solvent molecules both
(d) Neither solute nor solvent molecules 257. The osmotic pressure of 0.4% urea solution is
1.66 atm and. that of a solution of suger of 3.42 % is
2.46 atm. When both the solution are mixed then the
250. Two solutions A and B are separated by semi- osmotic pressure of the resultant solution will be
permeable membrane. If liquid flows form A to B then (a) 1.64 atm (b) 2.46 atm
(a) A is less concentrated than B (c) 2.06 atm (d) 0.82 atm
(b) A is more concentrated than B
(c) Both have same concentration
258. Blood is isotonic with
(d) None of these
(a) 0.16 M NaCl (b) Conc. NaCl
(c) 50 % NaCl (d) 30 % NaCl
251. A 5% solution of canesugar (mol. wt. =342) is
isotonic with 1% solution of a substance X . The
259. Which inorganic precipitate acts as
molecular weight of X is semipermeable membrane or The chemical
(a) 34.2 (b) 171.2 composition of semipermeable membrane is
(c) 68.4 (d) 136.8 (a) Calcium sulphate (b) Barium oxalate
(c) Nickel phosphate (d) Copper ferrocyanide

252. Which of the following colligative properties can

provide molar mass of proteins (or polymers or
The osmotic pressure of 1 m solution at 27 C is
o
colloids) with greater precision 260.
(a) Relative lowering of vapour pressure (a) 2.46 atm (b) 24.6 atm
(b) Elevation of boiling point (c) 1.21 atm (d) 12.1 atm
(c) Depression in freezing point
(d) Osmotic pressure 261. Osmotic pressure of a solution can be measured
quickly and accurately by
(a) Berkeley and Hartley's method
253. The average osmotic pressure of human blood is
(b) Morse's method
7.8 bar at 37 o C . What is the concentration of an (c) Pfeffer's method
aqueous NaCl solution that could be used in the blood (d) De Vries method
stream

(a) 0.16 mol/ L (b) 0 .32 mol/ L

262. The solution in which the blood cells retain their
0.60 mol/ L 0.45 mol/L normal form are with regard to the blood
(c) (d) (a) Isotonic (b) Isomotic
(c) Hypertonic (d) Equinormal
254. A solution of sucrose(molar mass = 342 g/mol) is
prepared by dissolving 68.4 g of it per litre of the
solution, what is its osmotic pressure (R = 0.082 lit. 263. The osmotic pressure of a solution is given by the
−1 −1 relation
atm.k mol ) at 273k
RT CT
(a) 6.02 atm (b) 4.92 atm P= P=
(a) C (b) R
(c) 4.04 atm (d) 5.32 atm
RC P
P= =RT
(c) T (d) C
255. Blood has been found to be isotonic with
(a) Normal saline solution
(b) Saturated NaCl solution 264. The osmotic pressure of a solution is directly
proportional to
(c) Saturated KCl solution (a) The molecular concentration of solute
(d) Saturated solution of a 1 : 1 mixture of NaCl and (b) The absolute temperature at a given
KCl concentration
(c) The lowering of vapour pressure
(d) All of the above
256. If 20 g of a solute was dissolved in 500 ml of
water and osmotic pressure of the solution was found

to be 600 mm of Hg at 15o C , then molecular weight of

265. What would happen if a thin slice of sugar beet is
the solute is placed in a concentrated solution of NaCl
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 (a) Sugar beet will lose water from its cells 274. Solutions having the same osmotic pressure
(b) Sugar beet will absorb water from solution under a given set of conditions are known as
(a) Hypertonic (b) Hypotonic
(c) Sugar beet will neither absorb nor lose water
(c) Normal (d) Isotonic
(d) Sugar beet will dissolve in solution

275. At low concentrations, the statement that

266. The osmotic pressure of a dilute solution is given
equimolal solutions under a given set of experimental
by
conditions have equal osmotic pressure is true for
P=P o x
(a) (b) πV =nRT (a) All solutions

ΔP Po −P (b) Solutions of non-electrolytes only

= (c) Solutions of electrolytes only
ΔP=P o N 2 Po Po
(c) (d)
(d) None of these

267. Which statement is wrong regarding osmotic

pressure (P), volume (V) and temperature (T)
1
P∝
(a) V if T is constant
(b) P∝ T if V is constant
(c) P∝ V if T is constant
(d) PV is constant if T is constant

268. Isotonic solutions have

(a) Equal temperature (b) Equal osmotic pressure
(c) Equal volume (d) Equal amount of solute

269. Which of the following associated with isotonic

solutions is not correct
(a) They will have the same osmotic pressure
(b) They have the same weight concentrations
(c) Osmosis does not take place when the two
solutions are separated by a semipermeable
membrane
(d) They will have the same vapour pressure

270. Isotonic solution have the same

(a) Density (b) Molar concentration
(c) Normality (d) None of these

271. A 0.6% solution of urea (molecular weight = 60)

would be isotonic with

(a) 0 . 1 M glucose (b) 0.1M KCl

(c) 0.6% glucose solution (d) 0.6% KCl solution

272. The value of osmotic pressure of a 0.2 M aqueous

solution at 293K is
(a) 8.4 atm (b) 0.48atm
(c) 4.8 atm (d) 4.0 atm

273. Diffusion of solvent through a semi permeable

membrane is called
(a) Diffusion (b) Osmosis
(c) Active absorption (d) Plasmolysis

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782