Atomic Structure – Part 2-Easy

1. A 3 p orbital has (c) 1s , 2 s, 3s (d)

2 px , 2 py , 2 pz
(a) Two spherical nodes
(b) Two non-spherical nodes
7. The set of quantum numbers n=3, l=0, m=0, s=−1/2
(c) One spherical and one non-spherical nodes belongs to the element
(d) One spherical and two non-spherical nodes (a) Mg (b) Na
(c) Ne (d) F
2. All electrons on the 4 p sub-shell must be characterized
by the quantum number(s)
8. An electron has principal quantum number 3. The
1
n=4 , m=0 , s=± number of its (i) sub-shells and (ii) orbitals would be
(a) 2 (b) l=1 respectively
1 1 (a) 3 and 5 (b) 3 and 7
l=0 , s=± s=±
(c) 2 (d) 2 (c) 3 and 9 (d) 2 and 5

3. The electronic configuration of the element of atomic 2+

9. What is the electronic configuration of Cu (Z=29 ) of
number 27 is
2 2 6 2 6
least position
(a) 1s , 2s 2 p , 3s 3 p , 4 s (↑↓) 4 p (↑↓)(↑↓)(↑↓) 5s (↑) 1 8 2 10 1
(a) [ Ar ] 4 s 3 d (b) [ Ar ] 4 s 3d 4 p
2 2 6 2 6
(b) 1s , 2s 2 p , 3s 3 p 3d (↑↓)(↑↓)(↑↓), 4 s (↑↓) 4 p (↑) 1 10 9
(c) [ Ar ] 4 s 3 d (d) [ Ar ] 3d
2 2 6 2 6
(c) 1s , 2s 2 p , 3s 3 p , 3d (↑↓)(↑↓)(↑↓)(↑↓), 4s (↑)
2 2 6 2 6
(d) 1s , 2s 2 p , 3s 3 p , 3d (↑↓)(↑↓)(↑)(↑)(↑) 4 s (↑↓) 10. The correct electronic configuration of Ti(Z =22) atom
is
2 2 6 2 6 2 2
n (a) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
4. When the value of the principal quantum number is 3,
2 2 6 2 6 4
the permitted values of the azimuthal quantum numbers (b) 1 s 2 s 2 p 3 s 3 p 3 d
l and the magnetic quantum numbers m , are 2 2 6 2 6 4
(c) 1 s 2 s 2 p 3 s 3 p 3 d
l m
2 2 6 2 6 1 3
0 0 (d) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
1 +1, 0, −1
(a) 2 +2,+1, 0 , −1,−2 11. Which of the following configuration is correct for iron
2 2 6 2 6 5
1 1 (a) 1 s 2 s 2 p 3 s 3 p 3 d
2 +2, 1, −1 2 2 6 2 6 2 5
(b) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
(b) 3 +3,+2, 1, −2,−3
2 2 6 2 6 2 7
0 0 (c) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
2 2 6 2 6 2 6
1 1, 2, 3 (d) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
(c) 2 +3, +2, 1, −2,−3
1 0, 1 12. Which of the following set of quantum numbers belong
2 0, 1, 2 to highest energy
(d) 3 0, 1, 2, 3 n=4 , l=0 , m=0 , s =+
1
(a) 2

5. The number of possible spatial orientations of an 1

n=3 , l=0 , m=0 , s =+
electron in an atom is given by its (b) 2
(a) Spin quantum number 1
n=3 , l=1 , m=1 , s =+
(b) Spin angular momentum (c) 2
(c) Magnetic quantum number 1
n=3 , l=2 , m=1 , s =+
(d) Orbital angular momentum (d) 2

6. Which of the following sets of orbitals may degenerate 13. Which quantum number will determine the shape of the
2 s , 2 px , 2 p y 3 s , 3 p x , 3 d xy subshell
(a) (b)

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 Atomic Structure – Part 2-Easy

(a) Principal quantum number

21
(b) Azimuthal quantum number 19. Electronic configuration of Sc is
(c) Magnetic quantum number 2 2 6 2 6 2 1
(a) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
(d) Spin quantum number 2 2 6 2 6 1 2
(b) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
2 2 6 2 6 0 3
14. For the n=2 energy level, how many orbitals of all (c) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
kinds are possible 2 2 6 2 2 2 2
(d) 1 s 2 s 2 p 3 s 3 p 4 s 3 d
(a) 2 (b) 3
(c) 4 (d) 5
20. If n+l =6 , then total possible number of subshells
would be
15. Which one is in the ground state
(a) 3 (b) 4
(c) 2 (d) 5

(a)   
21. An electron having the quantum numbers
 1
s=−
n=4 , l=3, m=0 , 2 would be in the orbital
(b)    (a) 3 s (b) 3 p

(c) 4 d (d) 4 f

(c)    2 2 6 1
22. 1 s 2 s 2 p 3 s shows configuration of
 3+
(a) Al in ground state (b) Ne in excited state
 +
(d)    (c) Mg in excited state (d) None of these

23. Which of the following sets of quantum numbers is not
allowed
16. When the principal quantum number (n=3) , the 1
n=1 , l=0 , m=0 , s =+
possible values of azimuthal quantum number (l ) is (a) 2
(a) 0, 1, 2, 3 (b) 0, 1, 2
1
(c) – 2, – 1, 0, 1, 2 (d) 1, 2, 3 n=1 , l=1, m=0 , s=−
(b) 2
1
17. Which statement is not correct for n=5 , m=3 n=2 , l=1 , m=1, s =+
(c) 2
1
l=0 , 1 , 3 ; s =+ 1
(a) l=4 (b) 2 n=2 , l=1 , m=0 , s=−
(d) 2
(c) l=3 (d) All are correct

15 24. For which of the following sets of four quantum

18. Five valence electrons of p are labelled as numbers, an electron will have the highest energy
AB X Y Z nlm s

3s 3p (a) 3 2 1 +1/2
1 (b) 4 2 1 +1/2
+
If the spin quantum of B and is 2 , the group of
Z (c) 4 1 0 –1/2
electrons with three of the quantum number same are (d) 5 0 0 –1/2

(a) AB , XYZ , BY (b) AB 25. The electronic configuration of gadolinium (atomic no.
64) is
(c) XYZ , AZ (d) AB , XYZ 8 9 2 7 1 2
(a) [ Xe ]4 s 5 d 6 s (b) [ Xe]4 s 5d 6s
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 Atomic Structure – Part 2-Easy

3 5 2 6 2 2 (c) 32 (d) 54
(c) [ Xe ]4 s 5 d 6 s (d) [ Xe ]4 f 5 d 6 s

−
34. Which of the following electronic configurations is not
26. An e has magnetic quantum number as −3 , what is its possible
principal quantum number 2 2 2 2 6
(a) 1 s 2 s (b) 1 s 2 s 2 p
(a) 1 (b) 2
10 2 2 2 2 2 1
(c) 3 (d) 4 (c) 3 d 4 s 4 p (d) 1s 2s 2 p 3s

27. The number of quantum numbers required to describe 35. The electronic configuration of an element is
an electron in an atom completely is 1s 2s 2 p 3s 3 p 6 3d 5 4 s 1 . This represents its
2 2 6 2

(a) 1 (b) 2 (a) Excited state (b) Ground state

(c) 3 (d) 4 (c) Cationic form (d) Anionic form

36. Which of the following set of quantum numbers is

1 s 2 2 s 2 2 p1 2 p 1y 2 p 1z
x
28. The electronic configuration possible
(a) Oxygen (b) Nitrogen 1
s =+
(c) Hydrogen (d) Fluorine (a) n=3; l=2; m=2 and 2
1
s=−
(b) n=3; l=4; m=0 and 2
29. Which one of the following set of quantum numbers is
1
not possible for 4 p electron s =+
(c) n=4; l=0; m=2 and 2
1
n=4 , l=1 , m=−1 , s =+ 1
(a) 2 s =+
(d) n=4; l=4; m=3 and 2
1
n=4 , l=1 , m=0 , s =+
(b) 2
1
37. Which of the following set of quantum number is not
n=4 , l=1 , m=2 , s =+ valid
(c) 2
(a) n=1 , l=2 (b) 3=2 , m=1
1
n=4 , l=1 , m=−1 , s =+
(d) 2 (c) m=3 , l=0 (d) 3=4 , l=2

30. Which of the following orbital is not possible 38. Which one pair of atoms or ions will have same
(a) 3 f (b) 4 f configuration
+ + −
(c) 5 f (d) 6 f (a) F and Ne (b) Li and He
−
(c) Cl and Ar (d) Na and K
31. Which set of quantum numbers for an electron of an
atom is not possible 39. Which of the following sets of quantum number is not
(a) n=1, l=0, m=0, s=+1/2 possible
1
(b) n=1, l=1, m=1, s=+1/2 n=3 ; l=+ 2 ; m=0 ; s =+
2
(a)
(c) n=1,l=0, m=0, s=−1/2 1
n=3 ; l=0 ; m=0; s=−
2
(d) n=2, l=1, m=−1, s=+1/2 (b)
1
n=3 ; l=0 ; m=−1; s =+
(c) 2
32. Electronic configuration of ferric ion is
5 7 1
(a) [ Ar ] 3d (b) [ Ar ] 3d n=3 ; l=1 ; m=0 ; s=−
(d) 2
3 8
(c) [ Ar ] 3d (d) [ Ar ] 3d
40. Which of the following set of quantum numbers is
33. What is the maximum number of electrons which can be correct for the 19th electron of chromium
accommodated in an atom in which the highest principal n l m s
quantum number value is 4 (a) 3 0 0 1/2
(a) 10 (b) 18
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 Atomic Structure – Part 2-Easy

(b) 3 2 –2 1/2 47. The total magnetic quantum numbers for d-orbital is
(c) 4 0 0 1/2 given by
(d) 4 1 –1 1/2 (a) 2 (b) 0,  1,  2
(c) 0, 1, 2 (d) 5
41. When the value of azimuthal quantum number is 3,
magnetic quantum number can have values 2 5
48. The outer electronic structure 3 s 3 p is possessed by
(a) + 1, 0, – 1
(a) Cl (b) O
(b) + 2, + 1, 0, – 1, – 2
(c) Ar (d) Br
(c) – 3, – 2, – 1, – 0, + 1, + 2, + 3
(d) + 1, – 1
49. Which of the following set of quantum number is not
possible
42. The quantum numbers n=2 , l=1 represent n l m1 m2
(a) 1s orbital (b) 2s orbital (a) 3 2 1 + 1/2
(c) 2p orbital (d) 3d orbital
(b) 3 2 1 – 1/2
(c) 3 2 1 0
43. The magnetic quantum number of valence electron of
sodium (Na) is (d) 5 2 –1 + 1/2
(a) 3 (b) 2
(c) 1 (d) 0 2 2 5 1
50. The configuration 1s , 2s 2 p , 3s shows
O−
44. Azimuthal quantum number defines (a) Excited state of 2
(a) e/m ratio of electron (b) Excited state of neon
(b) Spin of electron (c) Excited state of fluorine
(c) Angular momentum of electron (d) Ground state of fluorine atom
(d) Magnetic momentum of electron
51. The quantum number ‘m’ of a free gaseous atom is
45. Quantum numbers of an atom can be defined on the associated with
basis of (a) The effective volume of the orbital
(a) Hund’s rule (b) The shape of the orbital
(b) Aufbau’s principle (c) The spatial orientation of the orbital
(c) Pauli’s exclusion principle (d) The energy of the orbital in the absence of a
(d) Heisenberg’s uncertainty principle magnetic field

46. Which of the following has maximum energy 52. Correct statement is
1 4 2 10 2
3s 3p 3d
(a) K=4 s , Cr=3d 4 s , Cu=3 d 4 s
2 4 2 10 2
(a) (b) K=4 s , Cr=3 d 4 s , Cu=3 d 4 s
3s 3p 3d 2 5 1 10 2
(c) K=4 s , Cr=3d 4s , Cu=3d 4s
1 5 1 10 1
(b) (d) K=4 s , Cr=3d 4 s , Cu=3d 4 s
3s 3p 3d

53. Number of orbitats in h sub-shell is

(c) 3p (a) 11 (b) 15
3s 3d
(c) 17 (d) 19

(d)
54. Electronic configuration
1s 2 , 2s 2 2 p6 , 3s 2 3 p 6 3d 5 , 4 s 1 represents
(a) Ground state (b) Excited state
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 Atomic Structure – Part 2-Easy

(c) Anionic state (d) All of these 61. Which of the following electronic configuration is not
possible according to Hund’s rule
2 2 2 1
55. Which of the following sets is possible for quantum (a) 1 s 2 s (b) 1 s 2 s
numbers 1 s 2 2 s 2 2 p1x 2 p 1y 2 p 1x 1 s 2 2 s 2 2 p2x
(c) (d)
(a) n=4 , l=3, m=−2, s=0
1 s 2 2 s 2 2 p2x 2 p 1y 2 p 1z
1 (e)
n=4 , l=4 , m=+ 2 , s=−
(b) 2
1 62. The ground state term symbol for an electronic state is
n=4 , l=4 , m=−2 , s =+
(c) 2 governed by
1
(a) Heisenberg’s principle
n=4 , l=3 , m=−2 , s =+
2 (b) Hund’s rule
(d)
(c) Aufbau principle
(d) Pauli exclusion principle
56. For principle quantum number n=4 the total number of
orbitals having l=3
(a) 3 (b) 7 63. The electronic configuration of element with atomic
number 24 is
(c) 5 (d) 9 2 2 6 2 6 4 2
(a) 1s ,2s 2 p ,3 s 3 p 3d , 4s
2 2 6 2 6 10
57. The number of 2 p electrons having spin quantum (b) 1s ,2s 2 p ,3 s 3 p 3d
2 2 6 2 6 6
number s=−1/ 2 are (c) 1 s , 2s 2 p ,3 s 3 p 3 d
(a) 6 (b) 0 2 2 6 2 6 5 1
(d) 1 s , 2s 2 p ,3 s 3 p 3 d 4 s
(c) 2 (d) 3

64. The maximum number of electrons in p -orbital with

58. Which of the following sets of quantum numbers is
n=5 , m=1 is
correct for an electron in 4 f orbital
(a) 6 (b) 2
1
n=4 , l=3 , m=+ 1 , s =+ (c) 14 (d) 10
(a) 2
1
n=4 , l=4 , m=−4 , s=−
2 65. Number of two electron can have the same values of
(b)
…… quantum numbers
1
n=4 , l=3 , m=+ 4 , s=+ (a) One (b) Two
(c) 2
(c) Three (d) Four
1
n=3 , l=2 , m=−2 , s=+
(d) 2
66. The number of orbitals present in the shell with n=4 is
(a) 16 (b) 8
59. Consider the ground state of (Z =24 ) . The numbers of (c) 18 (d) 32
electrons with the azimuthal quantum numbers, l=1
and 2 are, respectively 67. Which of the following electronic configuration is not
(a) 16 and 4 (b) 12 and 5 possible
(c) 12 and 4 (d) 16 and 5 2 2 6
(b) 1 s , 2 s 2 p
2 2
(a) 1 s 2 s
102 2 2 2 21
60. The four quantum numbers of the valence electron of (c) [ Ar ] 3d ,4 s 4 p (d) 1 s , 2s 2 p ,3 s
potassium are
1 1 p
2 2 68. x orbital can accommodate
(a) 4, 1, 0 and (b) 4, 0, 1 and
(a) 4 electrons
1 1
+ (b) 6 electrons
(c) 4, 0, 0 and 2 (d) 4, 1, 1 and 2
(c) 2 electrons with parallel spins
(d) 2 electrons with opposite spins
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 Atomic Structure – Part 2-Easy

78. Total number of unpaired electrons in an atom of atomic

69. The maximum number of electrons that can be number 29 is
(a) 1 (b) 3
accommodated in ' f ' sub shell is
(a) 2 (b) 8 (c) 4 (d) 2
(c) 32 (d) 14
2 2 4
79. The number of unpaired electrons in 1s , 2s 2 p is
70. The number of electrons which can be accommodated in (a) 4 (b) 2
an orbital is (c) 0 (d) 1
(a) One (b) Two
(c) Three (d) Four 80. The maximum number of electrons that can be
accommodated in a 3 d subshell is
71. The number of electrons in the atom which has 20 (a) 2 (b) 10
protons in the nucleus
(c) 6 (d) 14
(a) 20 (b) 10
(c) 30 (d) 40
81. The maximum number of electrons which each sub-
shell can occupy is
72. The maximum number of electrons accommodated in (a) 2 n
2
(b) 2 n
5 f orbitals are [MP PET 1996]
(a) 5 (b) 10 (c) 2(2 l+1) (d) (2 l+1 )
(c) 14 (d) 18
73. The maximum number of electrons in an atom with 82. Number of unpaired electrons in the ground state of
l=2 and n=3 is beryllium atom is
(a) 2 (b) 6 (a) 2 (b) 1
(c) 12 (d) 10 (c) 0 (d) All the above

2+
2 2 5 1 83. How many unpaired electrons are present in Ni cation
74. The configuration 1 s 2 s 2 p 3 s shows (atomic number = 28)
(a) Ground state of fluorine atom (a) 0 (b) 2
(b) Excited state of fluorine atom (c) 4 (d) 6
(c) Excited state of neon atom
O−2 O2
(d) Excited state of ion 84. The number of unpaired electrons in an molecule is
(a) 0 (b) 1
75. For sodium atom the number of electrons with m=0 (c) 2 (d) 3
will be
(a) 2 (b) 7 3+
85. The number of unpaired electrons in a chromic ion Cr
(c) 9 (d) 8 (atomic number = 24) is
(a) 6 (b) 4
76. The number of electrons that can be accommodated in (c) 3 (d) 1
dz 2 orbital is
(a) 10 (b) 1 10 0
86. 3 d 4 s electronic configuration exhibits by
(c) 4 (d) 2 ++ ++
(a) Zn (b) Cu
++
(d) Hg
++
2 2 3 (c) Cd
77. Number of unpaired electrons in 1 s 2 s 2 p is
(a) 2 (b) 0
87. Which of the following metal ions will have maximum
(c) 3 (d) 1 number of unpaired electrons
+2 +2
(a) Fe (b) CO

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 Atomic Structure – Part 2-Easy

in Mg (At. No.= 12)

+2 +2
(c) Ni (d) Mn (b) s -electrons

(c) d -electrons in Fe
88. Which of the metal ion will have highest number of −
(d) p -electrons in Cl (At. No. of Cl = 17)
unpaired electrons
+ 2+
(a) Cu (b) Fe 4
3+ 2+ 97. A transition metal X has a configuration [ Ar ]3d in its
(c) Fe (d) Co +3 oxidation state. Its atomic number is
(a) 25 (b) 26
89. The maximum number of unpaired electron can be (c) 22 (d) 19
present in d orbitals are
(a) 1 (b) 3
(c) 5 (d) 7 98. The total number of electrons present in all the p -
orbitals of bromine are
(a) Five (b) Eighteen
90. The molecule having one unpaired electron is
(c) Seventeen (d) Thirty five
(a) NO (b) CO
− O
(c) CN (d) 2 99. Which of the following has the maximum number of
unpaired electrons
2+
91. A filled or half-filled set of p or d -orbitals is (a) Mg (b) Ti
3+

spherically symmetric. Point out the species which has 3+ 2+

spherical symmetry (c) V (d) Fe
(a) Na (b) C
(c) Cl
−
(d) Fe 100. Which of the following has more unpaired d -
electrons
+ 2+
(a) Zn (b) Fe
92. The atom of the element having atomic number 14
3+ +
should have (c) N (d) Cu
(a) One unpaired electron
(b) Two unpaired electrons 101. Maximum electrons in a d -orbital are
(c) Three unpaired electrons (a) 2 (b) 10
(d) Four unpaired electrons (c) 6 (d) 14

93. An atom has 2 electrons in K shell, 8 electrons in L Fe 3+ (Z=26 )

102. The number of unpaired electrons in
shell and 6 electrons in M shell. The number of s - are
electrons present in that element is (a) 5 (b) 6
(a) 6 (b) 5
(c) 3 (d) 4
(c) 7 (d) 10

103. How many unpaired electrons are present in cobalt

94. The number of unpaired electrons in carbon atom in [Co] metal
excited state is (a) 2 (b) 3
(a) One (b) Two
(c) 4 (d) 7
(c) Three (d) Four

104. The number of unpaired electrons in nitrogen is

95. Maximum number of electrons present in ' N ' shell is (a) 1 (b) 3
(a) 18 (b) 32 (c) 2 (d) None of these
(c) 2 (d) 8
105. Which of the following has the least energy
+2
96. The number of d electrons in Fe (atomic number of (a) 2 p (b) 3 p
Fe=26 ) is not equal to that of the
(c) 2 s (d) 4 d
(a) p -electrons in Ne (At. No.= 10)
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 Atomic Structure – Part 2-Easy

106. Pauli's exclusion principle states that 111. Which of the following principles/rules limits the
(a) Nucleus of an atom contains no negative charge maximum number of electrons in an orbital to two
(b) Electrons move in circular orbits around the (a) Aufbau principle
nucleus (b) Pauli's exclusion principle
(c) Electrons occupy orbitals of lowest energy (c) Hund's rule of maximum multiplicity
(d) All the four quantum numbers of two electrons in (d) Heisenberg's uncertainty principle
an atom cannot be equal
112. The electrons would go to lower energy levels
107. For the energy levels in an atom, which one of the first and then to higher energy levels according to which
following statements is correct of the following
(a) There are seven principal electron energy levels (a) Aufbau principle
(b) The second principal energy level can have four sub- (b) Pauli's exclusion principle
energy levels and contains a maximum of eight (c) Hund's rule of maximum multiplicity
electrons (d) Heisenberg's uncertainty principle
(c) The M energy level can have maximum of 32
electrons 113. Energy of atomic orbitals in a particular shell is in
the order
(d) The 4 s sub-energy level is at a higher energy than
(a) s< p< d< f (b) s> p> d> f
the 3 d sub-energy level
(c) p<d < f < s (d) f >d > s> p

108. The statements

(i) In filling a group of orbitals of equal energy, it is 114. Aufbau principle is not satisfied by
energetically preferable to assign electrons to (a) Cr andCl (b) Cu and Ag
empty orbitals rather than pair them into a (c) Cr and Mg (d) Cu and Na
particular orbital.
(ii) When two electrons are placed in two different 115. Which of the following explains the sequence of
orbitals, energy is lower if the spins are parallel. filling the electrons in different shells
are valid for (a) Hund's rule (b) Octet rule
(a) Aufbau principle (c) Aufbau principle (d) All of these
(b) Hund's rule
(c) Pauli's exclusion principle 116. Aufbau principle is obeyed in which of the
following electronic configurations
(d) Uncertainty principle 2 2 6 2 3 2
(a) 1 s 2 s 2 p (b) 1 s 3 p 3 s
2 2 6
(c) 1 s 3 s 3 p
2 2 2
109. According to Aufbau's principle, which of the (d) 1 s 2 s 3 s
three 4 d , 5 p and 5 s will be filled with electrons first
(a) 4 d 117. Following Hund’s rule which element contains six
unpaired electron
(b) 5 p
(a) Fe (b) Co
(c) 5 s (c) Ni (d) Cr
(d) 4 d and5 s will be filled simultaneously

118. Electron enters the sub-shell for which (n+l ) value

2 py is minimum. This is enunciated as
110. The energy of an electron of orbital is
2 px (a) Hund’s rule
(a) Greater than that of orbital
(b) Aufbau principle
2 px
(b) Less than that of orbital (c) Heisenberg uncertainty principle
(c) Equal to that of 2 s orbital (d) Pauli’s exclusion principle
2p
(d) Same as that of z orbital

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 Atomic Structure – Part 2-Easy

119. The atomic orbitals are progressively filled in

order of increasing energy. This principle is called as 129. Electronic configuration of deuterium atom is
(a) Hund’s rule (b) Aufbau principle 1 2
(a) 1 s (b) 2 s
(c) Exclusion principle (d) de-Broglie rule 1 2
(c) 2 s (d) 1 s

120. The correct order of increasing energy of atomic

orbitals is 130. Which of the following atoms and ions are isoelectronic
i.e. have the same number of electrons with the neon
(a) 5 p<4 f <6 s< 5 d (b) 5 p<6 s< 4 f < 5 d atom
(c) 4 f <5 p<5 d <6 s (d) 5 p<5 d <4 f <6 s
−
(a) F (b) Oxygen atom
(c) Mg
−
(d) N
121. The orbital with maximum energy is
(a) 3d (b) 5p
131. Atoms consists of protons, neutrons and electrons.
(c) 4s (d) 6d If the mass of neutrons and electrons were made half
and two times respectively to their actual masses, then
12
122. p-orbitals of an atom in presence of magnetic field the atomic mass of 6 C
are (a) Will remain approximately the same
(a) Two fold degenerate (b) Non degenerate
(b) Will become approximately two times
(c) Three fold degenerate (d) None of these
(c) Will remain approximately half
(d) Will be reduced by 25%
123. Orbital angular momentum for a d-electron is
6h √6 h
(a) 2 π (b) 2 π 132. The increasing order (lowest first) for the values of e / m
(charge/mass) for
12 h √12 h
(a) e , p, n, α (b) n, p, e, α
(c) 2 π (d) 2 π
(c) n, p, α ,e (d) n, α , p, e
124. Number of nodal centres for 2s orbital
(a) 1 (b) 0 133. The electronic configuration of a dipositive metal
2+
(c) 4 (d) 3 M is 2, 8, 14 and its atomic weight is 56 a.m.u. The
number of neutrons in its nuclei would be
125. The orbital angular momentum of an electron in 2 s - (a) 30 (b) 32
orbital is (c) 34 (d) 42
1 h h
(a) 2 2 π (b) 2 π
134. The ratio of the energy of a photon of 2000 Å
h
√ 2 wavelength radiation to that of 4000 Å radiation is
(c) 2π (d) Zero
(a) 1/4 (b) 4
(c) 1/2 (d) 2
126. The maximum number of electrons present in an orbit
l=3 , is
(a) 6 (b) 8 135. Discovery of the nucleus of an atom was due to
(c) 10 (d) 14 the experiment carried out by
(a) Bohr (b) Mosley
4+ (c) Rutherford (d) Thomson
127. Number of unpaired electrons in Mn is
(a) 3 (b) 5
(c) 6 (d) 4 136. In a Bohr's model of atom when an electron jumps
from n=1 to n=3 , how much energy will be emitted or
absorbed
128. Which of the following sequence is correct as per −11 −10
Aufbau principle (a) 2 .15×10 erg (b) 0 .1911×10 erg
(a) 3 s <3 d < 4 s <4 p (b) 1 s <2 p< 4 s< 3 d −12 −10
(c) 2 .389×10 erg (d) 0 . 239×10 erg
(c) 2 s <5 s <4 p< 5 d (d) 2 s <2 p< 3 d <3 p
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

hydrogen atom from the ground state to the first excited

137. The nucleus of an atom can be assumed to be state is (Avogadro’s constant = 6.022 × 1023)
−20 −23
spherical. The radius of the nucleus of mass number A (a) 1 .69×10 J (b) 1 .69×10 J
−13 1/3
is given by 1 .25×10 × A cm Radius of atom is one 23
(c) 1 .69×10 J
25
(d) 1 .69×10 J
Å . If the mass number is 64, then the fraction of the
atomic volume that is occupied by the nucleus is
−3 −5 145. The energy required to dislodge electron from excited
(a) 1 .0×10 (b) 5 . 0×10 IE =13 . 6 eV
−2 −13 isolated H-atom, 1 is
(c) 2 .5×10 (d) 1 .25×10
(a) = 13.6 eV (b) ¿ 13.6 eV

138. The energy of an electron in the first Bohr orbit of (c) ¿ 13 .6 and¿3.4 eV (d) ¿ 3.4 eV
H atom is −13 . 6 eV . The possible energy value(s) of the
excited state(s) for electrons in Bohr orbits to hydrogen
p
is(are) 146. The number of nodal planes in a x is
(a) −3 . 4 eV (b) −4 .2 eV (a) One (b) Two
(c) −6 . 8 eV (d) +6 . 8 eV (c) Three (d) Zero

+ 147. The third line in Balmer series corresponds to an

139. The energy of the electron in the first orbit of He
−20 electronic transition between which Bohr’s orbits in
is −871 . 6×10 J . The energy of the electron in the first hydrogen
orbit of hydrogen would be (a) 5  3 (b) 5  2
−20
(a) −871 . 6×10 J
−20
(b) −435. 8×10 J (c) 4  3 (d) 4  2
−20
(c) −217 . 9×10
−20
J (d) −108 . 9×10 J
148. Which of the following has maximum number of
unpaired electron (atomic number of Fe 26)
140. The total number of valence electrons in 4 .2 gm of (a) Fe (b)Fe (II)
N−
3 ion is ( N A is the Avogadro's number)
(c) Fe (III) (d) Fe (IV)
1 .6 N A 3 .2 N A
(a) (b)
2 .1 N A 4 .2 N A 149. The frequency of one of the lines in Paschen series
(c) (d) 11
of hydrogen atom is 2 .340×10 Hz . The quantum
n
141. The Bohr orbit radius for the hydrogen atom number 2 which produces this transition is
(n=1) is approximately 0 . 530 Å . The radius for the first (a) 6 (b) 5
excited state (n=2) orbit is (c) 4 (d) 3
(a) 0 . 13 Å (b) 1 .06 Å
150. Which of the following electron transition in a
(c) 4 .77 Å (d) 2 .12 Å hydrogen atom will require the largest amount of energy
(a) From n=1 to n=2 (b) From n=2 to n=3
14 −1
142. The frequency of a wave of light is 12×10 s . (c) From n=∞ to n=1 (d) From n=3 to n=5
The wave number associated with this light is
−7 −8 −1
(a) 5×10 m (b) 4×10 cm
151. In Bohr series of lines of hydrogen spectrum, the
−7 −1 4 −1
(c) 2×10 m (d) 4×10 cm third line from the red end corresponds to which one of
the following inter-orbit jumps of the electron for Bohr
orbits in an atom of hydrogen
143. The series limit for Balmer series of H-spectra is
(a) 3  2 (b) 5  2
(a) 3800 (b) 4200
(c) 4  1 (d) 2  5
(c) 3646 (d) 4000
−34
144. The ionization energy of hydrogen atom is 152. The value of Planck’s constant is 6 . 63×10 Js . The
8 −1
−13.6 eV . The energy required to excite the electron in a velocity of light is 3.0×10 ms . Which value is closest to
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

the wavelength in nanometres of a quantum of light with

15 −1
frequency of 8×10 s 159. If electron, hydrogen, helium and neon nuclei are
−25
(a) 3×10
7
(b) 2×10 all moving with the velocity of light, then the
−18 1 wavelengths associated with these particles are in the
(c) 5×10 (d) 4×10 order
(a) Electron > hydrogen > helium > neon
153. As electron moves away from the nucleus, its (b) Electron > helium > hydrogen > neon
potential energy (c) Electron < hydrogen < helium < neon
(a) Increases (b) Decreases
(d) Neon < hydrogen < helium < electron
(c) Remains constant (d) None of these

160. From the given sets of quantum numbers the one

154. The correct set of quantum numbers for the unpaired that is inconsistent with the theory is
electron of chlorine atom is
n l m (a) n=3; l=2; m=−3; s=+1/2
(a) 2 1 0 (b) n=4; l=3; m=3; s=+1/2
(b) 2 1 1
(c) n=2; l=1; m=0l s=−1/2
(c) 3 1 1
(d) 3 0 0 (d) n=4; l=3; m=2; s=+1/2

155. The orbital diagram in which the Aufbau's principle is 161. The uncertainty in the position of an electron
−28
violated is ( mass = 9 . 1×10 g) moving with a velocity of
2s 2px 2py 2pz 3.0×10 4 cm s−1 accurate upto 0.001% will be
(a)     h
(b)     (Use π in
4 the uncertainty expression, where
−27
(c)      h=6 .626×10 erg−s )

(d)      (a) 1 .92 cm (b) 7 . 68 cm

(c) 5 .76 cm (d) 3 . 84 cm

156. The mass of neutron is nearly 162. The orbital angular momentum of an electron in s
−23 −24
(a) 10 kg (b) 10 kg orbital is
−26 −27 1 h
+ .
(c) 10 kg (d) 10 kg
(a) 2 2 π (b) Zero
h h
157. Which electronic level would allow the hydrogen √ 2.
(c) π
2 (d) 2π
atom to absorb a photon but not to emit a photon
(a) 3 s (b) 2 p 163. Values of the four quantum numbers for the last
(c) 2 s (d) 1 s electron in the atom are n=4 , l=1, m=+1 and s=−1/ 2 .
Atomic number of the atom will be
158. Which of the following is not correct for electron (a) 22 (b) 32
distribution in the ground state (c) 33 (d) 36
4s 3d

(a) Co( Ar ) ↑↓ ↑↓ ↑↓ ↑ ↑ ↑ 164. The atomic weight of an element is 39. The

↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑ number of neutrons in its nucleus is one more than the
(b) Ni( Ar )
number of protons. The number of protons, neutrons
(c) Cu( Ar ) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑
and electrons respectively in its atom would be
(d) Zn( Ar ) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ (a) 19, 20, 19 (b) 19, 19, 20

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 Atomic Structure – Part 2-Easy

(c) 20, 19, 19 (d) 20, 19, 20 169. Which of the following pair of orbitals posses two
nodal planes
165. The electrons identified by quantum numbers n p xy , d d xy , d zx
(a) x2− y2 (b)
and l (i) n=4 , l=1 (ii) n=4 , l=0 (iii) n=3 , l=2 (iv) d 2 , d x 2− y 2
p xy , d zx z
n=3 , l=1 can be placed in order of increasing energy (c) (d)
from the lowest to highest, as
(a) (iv) < (ii) < (iii) <(i) 170. The number of atoms in 0.004 g of magnesium are
20 20
(b) (ii) < (iv) < (i) < (iii) (a) 4×10 (b) 8×10
(c) (i) < (iii) < (ii) < (iv) 20 20
(c) 10 (d) 6 . 02×10
(d) (iii) < (i) < (iv) < (ii)

171. Which of the following have the same number of

166. Ground state electronic configuration of nitrogen unpaired electrons in ‘d’ orbitals
atom can be represented by
(a) Cr (b) Mn
(a) ↑↓ ↑↓ ↑ ↑ ↑ (c) Fe 3+
(d) Co3+

(b) ↑↓ ↑↓ ↑ ↓ ↑ 172. The quantum numbers + 1/2 and – 1/2 for the
electron spin represent
(a) Rotation of the electron in clockwise and
(c) ↑↓ ↑↓ ↑ ↓ ↓ anticlockwise direction respectively
(b) Rotation of the electron in anticlockwise and
clockwise direction respectively
(d) ↑↓ ↑↓ ↓ ↓ ↓ (c) Magnetic moment of the electron pointing up and
down respectively
(d) Two quantum mechanical spin states which have
167. Which of the following statements (s) is (are) no classical analogue
correct
5 1 173. The de-Broglie wavelength of a tennis ball of mass
(a) The electronic configuration of Cr is [ Ar ] 3d 4 s
60 g moving with a velocity of 10 metres per second is
(Atomic no. of Cr=24 ) approximately
(b) The magnetic quantum number may have a 10−33 metres −31
negative value (a) (b) 10 metres
−16 −25
(c) In silver atom, 23 electrons have a spin of one type (c) 10 metres (d) 10 metres
and 24 of the opposite type (Atomic no. of
Ag=47 )
174. Which of the following are isoelectronic and
HN 3 −3 NO− , CO 2− −
3 , ClO3 , SO 3
(d) The oxidation state of nitrogen in is isostructural 3
NO−3 , CO 2−
3 SO3 , NO−3
(a) (b)
168. The position of both an electron and a helium
ClO−3 , CO 2−
3 CO 2−
3 , SO 3
atom is known within 1 .0 nm and the momentum of the (c) (d)
−26 −1
electron is known within 50×10 kg ms . The 175. For emission line of atomic hydrogen from
minimum uncertainty in the measurement of the ni =8 to n f =n, the plot of wave number ( v )
momentum of the helium atom is

(a) 50 kg ms
−1
(b) 60 kg ms
−1 against
( n1 )2 will be (The Rydberg constant, R H is

−26 −1 −26 −1 in wave number unit)

(c) 80×10 kg ms (d) 50×10 kg ms
(a) Linear with intercept −R H
(b) Non linear

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 Atomic Structure – Part 2-Easy

(c) Linear with slope R H

(d) Linear with slope – R H
(c)
176. Which of the following combination of
statements is true regarding the interpretation of
the atomic orbitals ?

(1) An electron in an orbital of high

angular momentum stays away from the
nucleus than an electron in the orbital of (d)
lower angular momentum.
(2) For a given value of the principal
quantum number, the size of the orbit is
inversely proportional to the azimuthal 178. The ground state of energy of hydrogen atom
quantum number. is −13.6eV. The energy of second excited state
(3) According to wave mechanics, the of H e
+ ¿¿
ion in eV is :
ground state angular momentum is h
h (a) −54.4 (b) −3.4
equal to . (c)−6.04 (d) −27.2
2π
(4) The plot of ψ vs for various azimuthal
quantum numbers, show peak shifting 179. Heat treatment of muscular pain involves
radiation of wavelength of about 900 nm. Which
towards a higher value.
spectral line of H-atom is suitable for this
(a) (1), (4) (b) (1), (2) purpose ?
(c) (1), (3) (d) (2), (3)

177. Which of the graphs shown below does not [ R H =1 ×105 c m−1 . h=6.6 ×10−34 Js , c=3 ×10 8 m s−1 ]
represent the relationship between incident light
(a) Paschen, ∞ →3
and the electron ejected from metal surface ?
(b) Paschen, 5 →3
(c) Balmer, ∞ →2
(d) Lyman, ∞ →1
(a)
180. The de Broglie wavelength ( λ ) associated with
a photoelectron varies with the frequency ( v ) of
the incident radiation as ¿ is threshold
frequency] :

1 1
λ∝
(b) (a) λ ∝ (b) 1
( v−v 0) ( v−v 0 ) 4

1 1
λ∝ λ∝
(c) 3 (d) 1
( v−v 0 ) 2
( v−v 0 ) 2

181. What is the work function of the metal if the

light of wavelength 4000 Å generates
photoelectrons of velocity 6 ×10 5 m s−1 from it?

(Mass of electron ¿ 9 ×10−31 kg

Velocity of light ¿ 3 ×108 m s−1
Planck’s constant ¿ 6.626 ×10−34 Js
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

Charge of electron ¿ 1.6 ×10−19 Je V −1) frequencies in c m−1. The ratio of ∆ v Lyman / ∆ v Balmer
(a) 0.9 eV (b) 3.1eV is:
(c) 2.1 eV (d) 4.0 eV (a) 4:1 (b) 9:4

182. If the de Broglie wavelength of the electron in

th
(c) 5:4 (d) 27:5
n Bohr orbit in a hydrogenic atom is equal to
1.5 π a0 (a 0 is Bohr radius), then the value of n/z is 186. Which one of the following about an electron
: occupying the 1s orbital in a hydrogen atom is
(a) 0.40 (b) 1.50 incorrect ? (The Bohr radius is represented by a 0
).
(c) 1.0 (d) 0.75
(a) The probability density of finding the
183. The quantum number of four electrons are electron is maximum at the nucleus.
given below: (b) The electron can be found at a
−1 distance 2 a0 from the nucleus
I. n=4 ,l=2, m l=−2 , ms=
2 (c) The magnitude of potential energy is
double that of its kinetic energy on an
+1
II. n=3 ,l=2 ,ml=1 , ms= average.
2
(d) The total energy of the electron is
+1 maximum when it is at a distance from
III. n=4 ,l=1, m l=0 , m s =
2 the nucleus.
2
−1
187. The graph between |ψ| and r (radial
IV. n=3 ,l=1 ,ml=1 , ms= distance) is shown below. This represents :
2
The correct order of their increasing
energies will be:
(a) IV<III<II<I

(b) I<II<III<IV
(c) IV<II<III<I
(a) 3s orbital (b) 2s orbital
(d) I<III<II<IV
(c) 1s orbital (d) 2p orbital
184. If p is the momentum of the fastest electron
ejected from a metal surface after the irradiation
188. The isoelectronic set of ions is :
of light having wavelength λ , then for 1.5 p
−¿ ¿

and N a+¿ ¿
2−¿,F ¿
momentum of the photoelectron, the wavelength (a) N 3−¿ ,O ¿

of the light should be : +¿ ,Mg

2+ ¿ ¿
¿
(b) N 3−¿ ,Li ¿
and O 2−¿¿
(Assume kinetic energy of ejected
+¿ ¿
+ ¿, N a ¿
(c) F−¿, L i ¿
and M g 2+¿¿
photoelectron to be very high in 2−¿ ¿

and F−¿¿
+ ¿,O ¿
(d) L i+¿ , N a ¿
comparison to work function):
3 1
(a) λ (b) λ
4 2
189. The ratio of the shortest wavelength of two
2 4
(c) λ (d) λ spectral series of hydrogen spectrum is found to
3 9 be about 9. The spectral series are:

185. For any given series of spectral lines of (a) Lyman and Paschen
atomic hydrogen, let ∆ v=v max fl v minbe the (b) Balmer and Brackett
difference in maximum and minimum
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

(c) Brackett and Pfund 193. The number of subshells associated

(d) Paschen and Pfund with n=4 and m=−2 quantum numbers is
(a) 2 (b) 8
190. The group number, number of valence (c) 4 (d) 16
electrons, and valency of an element with atomic
number 15, respectively, are :
194. Consider the hypothetical situation
(a) 16, 5 and 2 where the azimuthal quantum number, I ,
(b) 15, 5 and 3 takes value 0 , 1 ,2 n+1 is the principal
quantum number. Then, the element with
(c) 16, 6 and 3
atomic number
(d) 15, 6 and 2 (a) 9 is the first alkali metal
(b) 6 has a 2 p -valence subshell
191. The electrons are more likely to be found : (c) 8 is the first noble gas
(d) 13 has a half-filled valence subshell

195. The region in the electromagnetic

spectrum where the Balmar series lines
appear is
(a) Microwave (b) Ultraviolet
(c) Visible (d) Infrared

196. The shortest wavelength of H atom in

(a) in the region a and c the Lyman series is λ 1The longest wavelength
(b) in the region a and b in the Balmar series of He
+¿¿
is
(c) only in the region a 5 λ1 36 λ1
(a) (b)
(d) only in the region c 9 5

192. The figure that is not a direct 27 λ1 9 λ1

(c) (d)
manifestation of the quantum nature of 5 5
atoms is

197. In the sixth period, the orbitals that

are filled are
(a) (a) 6 s , 4 f ,5 d , 6 p (b)
6 s , 5 d ,5 f , 6 p (c) 6 s , 6 p ,6 d , 6 f (d)
6 s , 5 f , 6 d ,6 p

(b) 198. The correct statement about

probability density (except at infinite distance
from nucleus) is
(a) It can never be zero for 2 s orbital

(c) (b) It can be zero for 3 p orbital

(c) It can be zero for 1 s orbital

(d) It can be negative for 2 p orbital

(d)
199. The number of oribtals associated with
+1
quantum numbern=5 , m s=
2

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 Atomic Structure – Part 2-Easy

(a) 25 (b) 30 (IV )N a3 [Fe (C 2 O4 )3 ]( Δ0 > P)(a)

(c) 50 (d) 35 (III )>( I )>(IV )>(II)
(b) (III )>(I )>(II )>(IV )
200. Amongst the following which is not a
(c)(I )>(IV )>(III )>(II)
postulate of Dalton's atomic theory
(a) Matter is formed of indivisible atoms (d) (II )≈ (I )>(IV )>(III )
(b) (B) When gases combine or reproduced in
a chemical reaction they do so in a simple
ratio by volume provided all gases are at the
same T ∧P 205. and orbitals are arranged in the order of
(c) During chemical reactions atoms remains decreasing energy. The correct option is
conserved and only pass through
rearrangement (a)
(d) Some atoms have same properties
including atomic mass (b)
(c)

201. For the Balmer series in the spectrum (d) (NEET2019)

of for H -atom v=R H

[ 1 1
2
n 1 n2 ]
− 2 Select the correct
206.Which of the following series of transitions in the spectrum of
options regarding this formula for Balmer
hydrogen atom falls in visible region?
series
(a) Brackett series (b) Lyman series
(a) The integer n1 is equal to ¿ 2 (c) Balmer series (d) Paschen series
(b) lonization energy of H atom can be
calculated from wave number of these lines.
207.Orbital having 3 angular nodes and 3 total nodes is
(c) The lines of longest wavelength corresponds
to n2 =3.
(a) (b) (c) (d) (OdishaNEET2019)
(d) If λ decreases then spectrum lines will
converse.
(a) A , B (b) C , D 208.In hydrogen atom, the de Broglie wavelength of an electron in
the second Bohr orbit is [Given that Bohr radius,
(c) A∧C∧B (d) A , B ,C∧D

202. The radius of the second Bohr orbit, in ]

terms of the Bohr radius, a 0, in L i2 +¿¿ is
3 a0 4 a0 (a) 211.6 pm (b) 211.6 pm
(a) (b)
4 3 (c) 52.9 pm (d) 105.8 pm (OdishaNEET2019)

a0 16 a0 209. Which one is a wrong statement?

(c) (d)
3 9 (a) Total orbital angular momentum of electron in ‐
orbital is equal to zero.
203. The de Broglie wavelength of an electron in (b) An orbital is designated by three quantum numbers
the 4 th Bohr orbit is while an electron in an atom is designated by four
(a) 4 π a0 (b) 2 π a0 quantum numbers.
(c) 8 π a0 (d) 6 π a0
(c) The electronic configuration of atom is

204. The correct order of the spin-only magnetic

moments of the following complexes is
(I ) [Cr ⁡(H 2 O)6 ] Br 2
(II )N a 4 ¿
(III) N a3 [ Fe(C 2 O 4)3 ](Δ 0> P)
(d)

The value of for is zero.(NEET2018)

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

210. Which one is the wrong statement? 215. The number of ‐electrons in is
not equal to the number of electrons in which one
of the following?
(a) The uncertainty principle is
(b)Half-filled and fully filled orbitals have greater (a) ‐electrons in Fe
stability due to greater exchange energy, greater
(b) ‐electrons in Ne
symmetry and more balanced arrangement.
(c) The energy of ‐orbital is less than the energy of (c) ‐electrons in Mg
‐orbital in case of hydrogen like atoms.
(d) ‐electrons in Cl (2015, Cancelled)

(d)de‐Broglie’s wavelength is given by , where

216. The angular momentum of electron in ’ orbital is
mass of the particle, equal to
group velocity of the particle.(NEET2017)
(a)

211. How many electrons can fit in the orbital for which (b)
and ?
(c)
(a) 2
(b) 6 (d) (2015, Cancelled)
(c) 10
217. What is the maximum number of orbitals that can
(d) 14(NEET‐II2016)
be identified with the following quantum numbers?

212. Which of the following pairs of ‐orbitals will

have electron density along the axes? (a) 1
(b) 2
(a) (c) 3
(d) 4(2014)
(b)

(c) 218. Calculate the energy in joule corresponding to light

of wavelength 45 nm. (Planck’s constant,
(d) (NEET‐II2016)
, speed of light,
213. Two electrons occupying the same orbital are (a)
distinguished by (b)
(a) azimuthal quantum number
(c)
(b) spin quantum number
(d) (2014)
(c) principal quantum number
(d) magnetic quantum number.(NEET‐I2016)
219. is isoelectronic with which ofthe following
ions?
214. Which is the correct order of increasing energy of
(a)
the listed orbitals in the atom of titanium? At. no.
(b)
(a) (c)
(b)
(d) (2014)
(c)
(d) (2015) 220. What is the maximum numbers of electrons that
can be associated with the following set of quantum
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

numbers?
and
(a) 4
(b) 2 (a)
(c) 10
(d) 6(NEET2013) (b)

(c)
221. Based on equation ,
certain conclusions are written. Which ofthem is
not correct? (d) (KarnatakaNEET2013)
(a) Equation can be used to calculate the change in
energy when the electron changes orbit. 225. Maximum number of electrons in a subshell with
(b) For , the electron has a more negative energy and is
than it does for which means that the electron is (a) 14
more loosely bound in the smallest allowed orbit. (b) 16
(c) The negative sign in equation simply means that the (c) 10
energy of electron bound to the nucleus is lower than it (d) 12(2012)
would be if the electrons were at the infinite distance
226. The correct set of four quantum numbers for the
from the nucleus.
(d) Larger the value of , the larger is the orbit radius. valence electron of rubidium atom is
(NEET2013) (a) 5, 1,
(b) 6,
222. The value of Planck’s constant is 6. (c) 5,
The speed of light is nm . Which value
(d) 5, 1, (2012)
is closest to the wavelength in nanometer of a
quantum of light with frequency of ?
(a) 50 227. The orbital angular momentum of a ‐electron is
given as
(b) 75
(c) 10
(d) 25(NEET2013) (a)

223. The outer electronic configuration of Gd (At. No. (b)

64) is

(a) (c)

(b)
(d) (Mains2012)
(c)
228. The
total number of atomic orbitals in fourth
(d) (KarnatakaNEET2013) energy level of an atom is
(a) 8
224. According to law of photochemical equivalence the (b) 16
energy absorbed (in ergs/mole) is given as (c) 32
ergs, cm (d) 4(2011)

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 Atomic Structure – Part 2-Easy

234. Which of the following is not permissible

229. The energies and of two radiations are 25 arrangement of electrons in an atom?
and 50 respectively. The relation (a)
between their wavelengths i.e., and will be (b)
(c)
(a)
(d) (2009)
(b)
235. If uncertainty in position and momentum are equal,
(c) then uncertainty in velocity is

(d) (2011)
(a)

230. If , the correct sequence for filling of

electrons will be (b)
(a)
(c)
(b)

(c)
(d) (2008)
(d) (2011)
236. The measurement of the electron position is
associated with an uncertainty in momentum,
231. According to the Bohr theory, which of the
following transitions in the hydrogen atom will which is equal to cm . The
give rise to the least energetic photon? uncertainty in electron velocity is (mass of an
(a) to
electron is )
(b) to
(a) cm
(c) to
(b) cm
(d) to (Mains2011)
(c) cm
(d) cm (2008)
232. A 0.66 kg ball is moving with a speed of 100
The associated wavelength will be
237. Consider the following sets of quantum numbers:

(a) (i) 3
(b) (ii) 2 2
(c) (iii) 4
(d) (Mains2010) (iv) 1
(v) 3 2
233. Maximum number of electrons in a subshell of
an atom is determined by the following Which of the following sets of quantum number is not
(a) possible?
(a) (i), (ii), (iii) and (iv)
(b)
(b) (ii), (iv) and (v)
(c) (c) (i) and (iii)
(d) (2009) (d) (ii), (iii) and (iv). (2007)

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 Atomic Structure – Part 2-Easy

238. The orientation of an atomic orbital is governed by (a) (b)

(a) principal quantum number
(c) (d) (2002)
(b) azimuthal quantum number
(c) spin quantum number
(d) magnetic quantum number. (2006) 244. Main axis of a diatomic molecule is ,

molecular orbital and overlap to form which

239. Given: The mass of electron is
of the following orbitals.
Planck constant is 6. , the uncertainty
involved in the measurement of velocity within a
(a) molecular orbital
distance of 0.1 Å is
(a) (b) molecular orbital
(c) 6 molecular orbitals
(b)
(d) No bond will form. (2001)
(c)
(d) (2006) 245. The following quantum numbers are possible
for how many orbitals: ?
240. The energy of second Bohr orbit of the hydrogen (a) 1 (b) 2
atom is ; hence the energy of fourth (c) 3 (d) 4(2001)
Bohr orbit would be
(a) 246. For given energy, Joules
(b) corresponding wavelength is
(c)
(d) (2005) (a) 65.6 nm (b) 6.56 nm
(c) 3.4 nm (d) 656 nm (2000)
241. The frequency of radiation emitted when the
electron falls from to in a hydrogen 247. Isoelectronic species are
atom will be (Given ionization energy of
(a) CO, CN,
and )
(a) 1. (b) CO, CN, NO,
(b) 1.
(c) , NO,
(c) 3.
(d) 2. (2004) (d) CO, CN, NO, (2000)

248. The uncertainty in momentum of an electron is

242. The value of Planck’s constant is
kg . The uncertainty in its position
The velocity oflight is . Which value
is closest to the wavelength in nanometers of a will be
quantum of light with frequency of ? (a)
(a)
(b) 1.
(b)
(c) 1.
(c)
(d) 5. (1999)
(d) (2003)
249. Who modified Bohr’s theory by introducing
243. In hydrogen atom, energy of first excited state is elliptical orbits for electron path?
. Then find out K.E. of same orbit of (a) Rutherford
hydrogen atom
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

(b) Thomson
(c) Hund 256. Uncertainty in position of an electron (mass
(d) Sommerfield(1999)
moving with a velocity of
accurate upto 0.001% will be (Use
250. The de Broglie wavelength of a particle with mass
1 and velocity 100 is in uncertainty expression where
(a) 6. erg second)
(a) 5.76 cm (b) 7.68 cm
(b) 6.
(c) 1.93 cm (d) 3.84 cm (1995)
(c) 6.
(d) 6. (1999) 257. The radius of hydrogen atom in the ground state is

251. The Bohr orbit radius for the hydrogen atom 0.53 Å. The radius ion (atomic number )
in a similar state is
is approximately 0.530 Å. The radius for (a) 0.53 Å (b) 1.06 Å
(c) 0.17 Å (d) 0.265 Å (1995)
the first excited state orbit is (in Å)
(a) 4.77 (b) 1.06
258. For which of the following sets of four quantum
(c) 0.13 (d) 2.12(1998) numbers, an electron will have the highest energy?

252. The position of both, an electron and a helium atom (a) 3 2

are known within 1.0 nm. Further the momentum
(b) 4
of the electron is known within kg .
The minimum uncertainty in the measurement of (c) 4 1
the momentum of the helium atom is (d) 5 (1994)
(a) 8. kg
(b) 80 kg 259. Which one of the following is not isoelectronic
(c) 50 kg with ?
(d) 5. kg (1998) (a) (b)
(c) (d) (1994)
253. The ion that is isoelectronic with CO is
260. Electronic configuration of calcium atom can be
(a) (b) written as
(c) (d) (1997) (a) [Ne]
(b) [Ar]
254. What will be the longest wavelength line in Balmer
series of spectrum? (c) [Ne]
(a) 546 nm (b) 656 nm
(d) [Kr] (1992)
(c) 566 nm (d) 556 nm (1996)

261. The energy of an electron in the Bohr orbit of

255. Ina Bohr’s model of an atom, when an electron
hydrogen atom is
jumps from to , how much energy will
be emitted or absorbed?
(a)
(a) 2. ergs
(b) 0. ergs
(b)
(c) 2. ergs
(d) 0. ergs (1996) (c)
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 Atomic Structure – Part 2-Easy

(b) The electron in the orbit nearest the nucleus has the
(d) (1992) lowest energy.
(c) Electrons revolve in different orbits around the
262. In a given atom no two electrons can have the same nucleus.
values for all the four quantum numbers. This is (d) The position and velocity of the electrons in the
called
orbit cannot be determined simultaneously. (1989)
(a) Hund’s Rule
(b) Aufbau principle
269. Number of unpaired electrons in
(c) Uncertainty principle
(a) 2 (b)
(d) Pauli’s Exclusion principle. (1991)
(c) 1 (d) 3 (1989)
263. For
azimuthal quantum number , the maximum
270. Themaximum number of electrons in a subshell is
number of electrons will be
given by the expression
(a) 2 (b) 6
(a) (b)
(c) (d) 14(1991)
(c) (d) (1989)
264. Theorder of filling of electrons in the orbitals of an
atom will be 271. The spectrum of He is expected to be similar to that
(a) (a) (b)
(b) (c) Na (d) (1988)
(c)
272. The number of spherical nodes in orbitals are/is
(d) 3 (1991)
(a) one (b) three
(c) none (d) two (1988)
265. The electronic configuration of Cu (atomic number
29) is
273. If is the radius of the first orbit, the radius of
(a)
orbit of ‐atom is given by
(b) (a) (b)
(c)
(c) (d) (1988)
(d) (1991)
274. Given below are two statements :
Statement-I: Two photons having equal linear
266. The total number of electrons that can be momenta have equal wavelengths.
accommodated in all the orbitals having principal Statement-II: If the wavelength of photon is
quantum number 2 and azimuthal quantum number decreased, then the momentum and energy
1 are of a photon will alsodecrease.
In the light of the above statements, choose
(a) 2 (b) 4
the correct answer from the options given
(c) 6 (d) 8 (1990) below.
(a) Statement-I is false but Statement-II
267. An ion has 18 electrons in the outermost shell, it is is true
(a) (b) (b) Both Statement-I and Statement-II are
true
(c) (d) (1990)
(c) Both Statement-I and Statement-II are
false
268. Which of the following statements do not form (d) Statement-I is true but Statement-II is
a part of Bohr’s model of hydrogen atom?
false
(a) Energy of the electrons in the orbits are quantized.

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 Atomic Structure – Part 2-Easy

275. According to Bohr's atomic theory : magnetic momenPresume all the three, high spin
Z
2 system. (Atomic numbers Ce=58 ,Gd=64 and
(A) Kinetic energy of electron is∝
n
2 Eu=63 )
(B) The product of velocity (v) of electron and [
(a) ( NH 4 )2 Ce ( NO 3 )6 ] (b) Gd ( NO 3 )3 and
principal quantum number (n). 'vn' ∝ Z 2.
(c) Eu ( NO3 )3
(C) Frequency of revolution of electron in an
3 Answer is:
Z (a) (b)<(a)<(c) (b) (c )<(a)<(b)
orbit is ∝ 3 .
n (c) (a)<(b)<(c) (d) (a)<(c )<(b)
(D) Coulombic force of attraction on the
3
Z
electron is ∝4
. Choose the most appropriate 279. What is the spin-only magnetic moment value
n (BM ) of a divalent metal ion with atomic number
answer from theoptions given below:
25 , in it'saqueous solution?
(a) (C) only
(a) 5.92 (b) 5
(b) (A) and (D) only (c) Zero (d) 5.26
(c) (A) only
(d) (A), (C) and (D) only 280. A certain orbital has no angular nodes and
two radial nodes. The orbital is:
276. The plots of radial distribution functions for (a) 2 s (b) 3 s
various orbitals of hydrogen atom against 'r' are (c) 3 p (d) 2 p
given below:
281. Given below are two statements:
Statement I : Bohr's theory accounts for
+¿¿
thestability and line spectrum of Li ion.
(A) Statement II : Buhr's theory was unable
toexplain the splitting of spectral
lines in the presence of amagnetic field. In
the light of the above statements, choose the
most appropriate answer from the options
given below:
(B) (a) Both statement I and statement II are
true.
(b) Statement I is false but statement II is
true.
(c) Both statement I and statement II are
false.
(C) (d) Statement I is true but statement II is
false.

282. Given below are two statements.

Statement I: According to Bohr's model of
(D) an atom, qualitatively the magnitude of
velocity of electronincreases with decrease
in positive charges on the nucleus as there
is no strong hold on the electron by
The correct plot for 3 s orbital is: thenucleus.
(a) D (b) B Statement II: According to Bohr's model of
(c) A (d) C an atom, qualitatively the magnitude of
velocity of electronincreases with decrease
277. The orbital having two radial as well as two in principal quantum number.
angular nodes is In the light of the above statements,
choose the answer from the options given
(a) 5d (b) 4f below:
(c) 3p (d) 4d (a) Both Statement I and Statement II are
false
(b) Both Statement I and Statement II are
278. Arrange the following metal complex/
true
compounds in the increasing order of spin only
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Atomic Structure – Part 2-Easy

(c)Statement I is false but Statement II is

true 289. The minimum energy that must be possessed
(d)Statement I is true but Statement II is by photons in order to produce the photoelectric
false effect with platinum metal is:
[Given: The threshold frequency of platinum is
283. Outermost electronic configuration of a group 1.3 x1015s-1and h = 6.6x10-34Js.]
(a) 3.21 x 1044 J (b) 6.24 x 10-16 J
13 element, E, is . The electronic -19
(c) 8.58 x 10 J (d) 9.76 x 10-20 J
configuration of an element of p-block period-five
placed diagonally to element, E is : 290. If the radius of the 3 rd Bohr's orbit of hydrogen
atom is r3 and the radius of 4th Bohr's orbit is r4.
(a) (b)
Then :
(c) (d)
(a) (b)
284. Which one of the following species doesn't
have a magnetic moment of 1.73BM, (spin only
value) ? (c) (d)

(a) (b)CuI
291. The number of radialand angular nodes in 4d
orbital are. respectively
(c) (d)
(a)1 and 2 (b) 3 and 2
(d) 1 and 0 (d) 2 and 1
285. The spin only magnetic moments (in BM) for
free and ions respectively are (At.No. 292. Consider the following statements :
Sc: 21, Ti: 22, V:23) (a) The principal quantum number 'n' is a
(a)3.87, 1.73, 0 (b)1.73, 3.87, 0 positive integer with values of 'n' = 1, 2, 3, ....
(c)1.73, 0, 3.87 (d)0,3.87,1.73 (b) The azimuthal quantum number ' ' for a
given 'n' (principal quantum number) can have
286. Consider the following pairs of electrons values as ‘ ’ = 0, 1,2, ....n
(c) Magnetic orbital quantum number for a
(a) (a) n = 3, 1 = 1, ml = 1, ms = + particular (azimuthal quantum number) has

values
(b) n = 3, 1 = 2, mi = 1, ms = +
(d)±1/2 are the two possible orientations of
electron spin.
(b) (a) n = 3, 1 = 2, m1 = - 2, ms = - (E) For = 5, there will be a total of 9 orbital.
Which of the above statements are correct?
(a) (a), (b) and (c) (b)(a),(c),(d)and(E)
(b) n = 3, 1 = 2, m1 = -1, ms =
(c) (a), (c) and (d) (d) (a), (b), (c) and (d)

(c)(a)n = 4,l=2,m1 = 2, ms = + 293. Which of the following statements are correct ?

(a) The electronic configuration of Cr is [Ar] 3d 5
4s1.
(b) n = 3, 1 = 2, m1 = 2, ms = +
(b) The magnetic quantum number may have a
The pairs of electron present in degenerate
negative value.
orbitals is/are:
(c) In the ground state of an atom, the orbitals
(a) Only A (b) Only B
are filled in order of their increasing energies.
(c)Only C (d) (b) and (c)
(d) The total number of nodes are given by n -
2.
287. The energy of one mole of photons of radiation Choose the most appropriateanswer from the
of wavelength 300 nm is options given below:
(Given : h = 6.63 x 10 -34 Js, NA = 6.02 x (a) (a), (c) and (d) only (b) (a) and (b) only
1023mol-1, c = 3x 108ms-1) (c) (a) and (c) only (d) (a), (b) and (c) only
(a) 235 kJ mol-1 (b) 325 kJ mol-1
(c) 399 kJ mol-1 (d) 435 kJ mol-1
294. The electronic configuration of Pt (atomic
number78) is:
288. The pair, in which ions are isoelectronic with (a)[Xe]4f145d96s1 (b) [Kr] 4f14 5d10
A13+ is :- l4
(c)[Xe]4f 5d 10
(d)[Xe]4f145d86s2
(a) Br and Be2+ (b) Cl- and Li+
(c) S2- and K+ (d) O2-and Mg2+

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 Atomic Structure – Part 2-Easy

295. Which of the following is the correct plot for (b)An orbital is the one electron wave function

the probability density as a function of in an atom.

distance V of the electron form the nucleus for 2s (c) The existence of Bohr's orbits is supported
orbital? by hydrogen spectrum.
(d) Atomic orbital is characterised by the
quantum numbers n and only
(a) (b)
300. Given below are the quantum numbers for 4
electrons.
A. n = 3, = 2, m1 = 1, ms = +1/2
B. n = 4, =l,m1 = 0,ms = +l/2
(c) (d) C. n = 4, = 2, m1 = -2, ms = -1/2
D. n = 3, = 1, m1 = -1, m2 = +1/2
The correct order of increasing energy is :
(a)D<B<A<C (b)D<A<B<C
296. Which of the following sets of quantum (c)B<D<A<C (d)B<D<C<A
numbers is not allowed ?
301.The measurement of the electron position is associated with

(a)n = 3,l = 2,mi=0,s = + an uncertainty in momentum of . The

uncertainty in electron velocity is
(b)n = 3,l = 2,m, = -2,s = + (a) (b)

(c) (d)
(c)n = 3,l = 3,m1=-3,s = -
302.Match the following:
(d)n = 3,l = 0,m1=0, s = -

297. Given below are two statements. One is

labelled as Assertion A and the other is labelled
as Reason R.
Assertion A : Energy of 2s orbital of
hydrogen atom is greater than that of 2s (a)(i)‐S, (ii)‐P, (iii)‐R, (iv)‐Q
orbital of lithium.
Reason R : Energies of the orbitals in the (b)(i)‐R, (ii)‐Q, (iii)‐P, (iv)‐S
same subshell decrease with increase in the (c)(i)‐S, (ii)‐ R, (iii)‐ P, (iv)‐Q
atomic number. (d)(i)‐S, (ii)‐ Q, (iii)‐ P, (iv)‐R
In the light of the above statements, choose
the correct answer from the options given
below. 303.For the electrons of oxygen atom, which of the following
(a) Both A and R are true and R is the correct statements is incorrect?
explanation of A. (a)Zeff for an electron in a 2s‐orbital is greater than the
(b) Both A and R are true but R is NOT the Zeff for an electron in a 2p‐orbital.
correct explanation of A. (b)An electron in the 2s‐orbital has lesser energy as an
(c) A is true but R is false. electron in the 2p‐orbital.
(d) A is false but R is true.
(c)Zeff for an electron is ls‐orbital is different from that of
an electron in 2s‐orbital.
298. The correct decreasing order of energy, for the
orbitals having, following set of quantum (d)The two electrons present in the 2s‐orbital have
different quantum number values with same sign.
numbers:
(a)n = 3,l = 0,m=0 (b) n = 4,1 = 0, m = 0
(c)n = 3,l=1,m = 0 (d)n = 3,l = 2,m=l 304.Which of the following series of transitions in the spectrum of
(a)(d)>(b)>(c)>(a) (b) (b) > (d) > (c) > (a) hydrogen atom falls in the visible region)
(c) (c) > (b) > (d) > (a) (d) (b) > (c) > (d) > (a) (a)Lyman series
(b)Balmer series
299. Identify the incorrect statement from the (c)Paschen series
following.
(d)Brackett series
(a) A circular path around the nucleus in which
an electron moves is proposed as Bohr's orbit.
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 Atomic Structure – Part 2-Easy

305.The probability density plots of ls and orbitals are given (a) (b)
in figure:
(c) (d)

‐E. The energy of an electron in the first orbit will be

311.The energy of an electron in the orbit of hydrogen atom is
The density of dots in a region represents the probability
density of finding electrons in the (a) (b)
region. On the basis of above diagram which of the
following statements is/are correct) (c) (d)
(i)ls and 2s orbitals are spherical in shape.
(ii)The probability of finding the electron is minimum
near the nucleus. 312.In a hydrogen spectrum if electron moves from to
(iii)The probability of finding the electron at a given by transition in multi‐steps then find the number of lines in
distance is equal in all directions. spectrum.
(iv)The probability density of electrons for 2s‐orbital (a)10 (b)6
decreases uniformly as distance from the nucleus (c)2 (d)8
increases.
(a)(i) & (ii) only
313.The number of photons which will provide 2 of energy and
(b)(ii) a (iii) only having wavelength 7500 A is approx.
(c)(i) & (iii) only
(d)only (iv) (a) (b)

(c) (d)
306.The aim of Millikan’s oil drop experiment is to determine
(a)mass of electron 314.Assertion: Greater the magnitude of the negative charge on
(b)velocity of electron the particle, greater is the interaction with electric or magnetic
(c)charge of electron field and thus greater the deflection.
(d)elm of an electron Reason: The deflection of electrons from its original path
decreases with the increase in the voltage across the
electrodes.
307.The energy associated with the first orbit of is (a)Both A and R are true and R is the correct explanation
of A.
(a) (b)
(b)Both A and R are true but R is not the correct
(c) (d) explanation of A.
(c)A is true but R is false.
308.The number of electrons and neutrons of an element is 18 and (d)Both A and R are false.
20 respectively. Its mass number is f
(a)18 (b)38 315.Match the following species with their corresponding ground
(c)20 (d)37 state electronic configuration.

309.Few sets of quantum numbers are given below. Which of the

following sets are incorrect?

(I)

(II)

(III)
(a)(i)‐R, (ii) ‐ P, (iii)‐T, (iv)‐Q
(b)(i)‐R, (ii) ‐ P, (iii) ‐ S, (iv) ‐T
(IV)
(a)(II) & (I1I) only
(b)(I) and (IV) only (c)(i)‐P, (ii)‐ R, (iii)‐ S, (iv)‐T
(c)(I), (II) & (III) only (d)(i)‐P, (ii)‐Q, (iii)‐ T, (iv)‐S
(d)All of these
316.Match the following:
310.A ball has a mass of 20 g and a speed of 45 m/s. It speed can
be measured within the accuracy of 0.5%. The uncertainty in
its position will be

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 Atomic Structure – Part 2-Easy

322. The radius of the 2nd orbit of Li2+ is x. The

expected radius of the 3rd orbit of Be3^ is

(a) x (b) x

(c) x (d) x
(a)A‐(iii), B‐(iv),C‐(ii), D‐(i)
(b)A‐(ii), B‐(iv), C‐(i), D‐(iii) 323. The shortest wavelength of hydrogen atom in
(c)A‐ (ii), B‐(i), C‐ (iv), D‐ (iii) Lyman scriesis . The longest wavelength in
Balmer series of He+ is
(d)A‐ (iii), B‐ (ii), C‐(i), D‐ (iv)

317.The specific charge for positive rays is X and that of cathodic (a) (b)
rays is Y then
(a) (c) (d)
(b)
324. Maximum number of electrons that can be
(c) accommodated in shell with n = 4 are:
(d)X can be greater or less than Y. (a)16 (b) 32
(c)50 (d) 72
318.Write the complete symbol of an element with number of
protons 56 and mass number 138.
325. The wave function of 2s is given by
(a) (b)

(c) (d)
At r = r0, radial node is formed. Thus, r 0 in
319.Which of following is responsible to rule out the existence terms of a0
of definite paths or trajectories of electrons. (a)r0 = a0 (b)r0 = 4a0
(a)Zeeman effect
(b)Heisenberg’s uncertainty principle (c) r0 = (d) r0 = 2a0
(c)Hund’s rule of maximum multiplicity
(d)None of these 326. Which transition in the hydrogen spectrum
would have the same wavelength as the Balmer
320. It is observed that type transition from n=4 to n = 2 of He +
characteristic X-ray spectra of elements show spectrum
regularity. When frequency to the power 'n' i.e. (a)n = 2ton= 1 (b) n = 1 to n = 3
vn of X-rays emitted is plotted against atomic (c) n = 1 to n = 2 (d
number 'Z', following graph is obtained.
327. Arrange the following orbitals in decreasing
order of energy?
(A)n=3, l = 0, m = 0 (B) n = 4,1 = 0, m =
0
(C)n = 3, l=1, m=0 (D)n = 3,l = 2,m=1
The correct option for the order is :
(a) B>D>C>A (b) D>B>C>A
The value of 'n' is (c) A>C>B>D (d) D>B>A>C
(a) 1 (b) 2
328. Which one of the following sets of ions
represents a collection of isoelectronic species?
(c) (d)3 (Given : Atomic Number : F :9 , Cl : 17, Na = 11,
Mg = 12, Al = 13, K = 19, Ca = 20, Sc = 21)
321. The number of s-electrons present in an ion (a)Li+,Na+,Mg2+,Ca2+
with 55 protons in its unipositive state is (b) Ba2+ , Sr2+, K+ , Ca2+
(a) 8 (b) 9 (c) N3-, O2-,F-, S2-
(c) 12 (d) 10 (d) K+, Cr-, Ca2+, Sc3-

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 Atomic Structure – Part 2-Easy

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782