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This document outlines the examination structure for the B.Tech I Year II Semester in Chemistry at Jawaharlal Nehru Technological University Hyderabad, scheduled for September/October 2021. It includes a list of topics and questions covering molecular orbital theory, crystal field splitting, ion-exchange processes, water hardness, electrochemical series, corrosion methods, nucleophilic substitution reactions, and electronic transitions in UV-Visible light. Students are required to answer any five questions, with all questions carrying equal marks.

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6 views

ec qpppp

This document outlines the examination structure for the B.Tech I Year II Semester in Chemistry at Jawaharlal Nehru Technological University Hyderabad, scheduled for September/October 2021. It includes a list of topics and questions covering molecular orbital theory, crystal field splitting, ion-exchange processes, water hardness, electrochemical series, corrosion methods, nucleophilic substitution reactions, and electronic transitions in UV-Visible light. Students are required to answer any five questions, with all questions carrying equal marks.

Uploaded by

old55898
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Code No: 152AB

R18
JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD
B.Tech I Year II Semester Examinations, September/October - 2021
CHEMISTRY
JN
(Common to CE, ME, ECE, EIE, MCT, MMT, ECM, AE, MIE, CSBS, CSE(AI&ML),
CSE(IOT))
Time: 3 Hours Max. Marks: 75
Answer any five questions
TU
All questions carry equal marks
---

1.a) Explain the postulates of molecular orbital theory.


H
b) With the help of molecular orbital energy level diagram, calculate bond order and predict
magnetic behavior of N2. [6+9]
U
2.a) Discuss the crystal field splitting of d-orbitals in tetrahedral geometry.
b) Explain the effect of doping on the conductance of the solids. [7+8]
SE
3.a) Give an account on ion-exchange process. How exhausted resins are regenerated?
b) What do you understand by desalination of water? Explain about the reverse osmosis.
[7+8]
D
4.a) Define Hardness of water. How would you determine it by complexometric method?
b) Discuss the disinfection of water by chlorination. [9+6]
SE
5.a) What is Electrochemical series? Write the reduction potential values of metals. What are
the important applications of electrochemical series?
b) What is meant by reference electrode? Construct calomel electrode and write its half cell
reaction. [9+6]
PT
6.a) Differentiate between Galvanizing and tinning. How these procedures can protect the
metals from corrosion.
b) Explain the theory of chemical corrosion. [9+6]
-2
7.a) Discuss the mechanism of Nucleophilic substitutions reactions- SN1 and SN2 reactions.
b) What are Enantiomers? Give examples. [11+4]
02
8.a) What are the various modes of electronic transitions observed, when a molecule is
irradiated with UV-Visible light.
1
b) What is chemical shift value in NMR spectroscopy? Explain shielding and dishielding
effect in NMR spectroscopy. [9+6]

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