0% found this document useful (0 votes)
29 views7 pages

Shiny Side

The Safety Data Sheet for SHINY SIDE, an aluminium cleaner, indicates that it contains sodium hydroxide, which is classified as causing severe skin burns and eye damage. The document outlines safety precautions, first aid measures, and handling instructions due to the hazardous nature of the product. It also provides information on the product's physical properties, ecological effects, and emergency contact details.

Uploaded by

Utkarsh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
29 views7 pages

Shiny Side

The Safety Data Sheet for SHINY SIDE, an aluminium cleaner, indicates that it contains sodium hydroxide, which is classified as causing severe skin burns and eye damage. The document outlines safety precautions, first aid measures, and handling instructions due to the hazardous nature of the product. It also provides information on the product's physical properties, ecological effects, and emergency contact details.

Uploaded by

Utkarsh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 7

SAFETY DATA SHEET

According to EC Regulation 1907/2006/EC - revision 2020/878


Revision No. 4.8
Print Date 04/02/2024 Creation Date 02/02/2015 Revision date 29/12/2023

SECTION 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

1.1. Product identifier


Product Name: SHINY SIDE
Product Code: 0347G X1 (CLP)
UFI: F503-Y0E3-Q00T-HNDC

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use
Aluminium Cleaner.

1.3. Details of the supplier of the safety data sheet


NCH UK & Ireland,
Arrowmere House, Bilston,
WV14 0QL
Tel (UK): 01902 510200, Tel (Ireland): 042 939 5502
E-mail address [email protected]
Website address www.ncheurope.com

1.4. Emergency telephone number


UK - 01902 510200 (available during Office Hours)
In Republic of Ireland (available from 8am to 10pm daily): 01 809 2166

SECTION 2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP/GHS) and its adaptations


Skin corrosion: Category 1A
Serious damage to eyes: Category 1
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP/GHS)


Contains SODIUM HYDROXIDE.
Hazard pictograms

Signal word Danger


Hazard statements
H314 - Causes severe skin burns and eye damage
Precautionary statements
P301+ P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P310 - Immediately call a POISON CENTER or doctor
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing
P260 - Do not breathe vapors.
P280 - Wear protective gloves/protective clothing/eye protection.
For industrial and institutional use only.
Keep out of reach of children

2.3. Other hazards


No additional hazards identified.
The components in this formulation do not meet the criteria for classification as PBT or vPvB. As defined under the regulation EC 1907/2006.

SECTION 3. COMPOSITION / INFORMATION OF INGREDIENTS


3.2 Mixture
Chemical name CAS No EC No (EU Index EU - REACH reg Weight-% Classification Notes
No) number according to
Regulation (EC)

Page 1 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

No. 1272/2008
[CLP]
SODIUM HYDROXIDE 1310-73-2 215-185-5 01-2119457892- 10 - < 20 Skin Corr. 1A
27 (H314)
Met Corr.1 (H290)
ALKYLPOLYGLYCOSIDE C8-10 68515-73-1 500-220-1 01-2119488530- 1 - < 3 Eye Dam. 1
36 (H318)
For any H statements mentioned in this section, see the full text in section 16.

Chemical name EU - CLP (1272/2008) - Specific


Concentration Limits
SODIUM HYDROXIDE H319 0.5%<=C<2%
H314 C>=5%
H314 2%<=C<5%
H315 0.5%<=C<2%

SECTION 4. FIRST AID MEASURES

4.1. Description of first aid measures


General advice
Do not breathe vapours or spray mist. Do not get in eyes, on skin or on clothing.
Eye Contact
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin Contact
Remove immediately all contaminated clothing. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention
immediately.
Ingestion
Never give anything by mouth to an unconscious person. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention
immediately. Show the Label to the Doctor.
Inhalation
Move to fresh air. If not breathing, give artificial respiration. Get medical attention immediately. If exposed to high concentrations of the vapours /
mists, move to fresh air.

4.2. Most important symptoms and effects, both acute and delayed
Sensitisation
No information available.
Eye contact
Corrosive. Causes burns and may lead to corneal damage and possible blindness.
Skin contact
Corrosive, Causes burns and possible deep ulcerations or scarring.
Ingestion
Ingestion may result in severe burns to the mouth, throat and digestive tract.
Inhalation
Inhalation may result in irritation or burns to the respiratory tract.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
The product causes burns of eyes, skin and mucous membranes. Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media


Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use:. Water spray. Foam. Carbon
dioxide (CO2). Dry chemical.

5.2. Special hazards arising from the substance or mixture


Material can create slippery conditions.

5.3. Advice for firefighters


Firefighters should wear a self-contained breathing apparatus and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures


Avoid contact with skin, eyes, and clothing. Use personal protective equipment. Refer to protective measures listed in sections 7 and 8. Prevent
further leakage or spillage if safe to do so. Material can create slippery conditions.

6.2. Environmental precautions


Avoid release of neat product into surface water and sanitary sewage system.

6.3. Methods and material for containment and cleaning up


Methods for Containment
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container

Page 2 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

for disposal according to local / national regulations (see section 13).


Methods for Cleaning up
Clean preferably with a detergent, do not use solvents. Neutralize with an acid.

6.4. Reference to other sections


Refer to sections 7, 8 and 13.

SECTION 7. HANDLING AND STORAGE

7.1. Precautions for safe handling


Avoid contact with skin, eyes and clothing. Avoid breathing vapours or mists. Do not eat, drink or smoke when using this product. Training : Due to
the hazardous nature of this product, training in its use is recommended. Ensure adequate ventilation.

7.2. Conditions for safe storage, including any incompatibilities


Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.

7.3. Specific end use(s)


No information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure Limits
If vapours, fumes or mists are generated, their concentration in the workplace area should be kept to the lowest reasonable level. For substances.
Chemical name European Union The United Kingdom France Germany Austria
SODIUM HYDROXIDE STEL: 2 mg/m3 VME: 2 mg/m3 STEL: 4 mg/m3
TWA: 2 mg/m3

Chemical name Spain Portugal Italy The Netherlands Switzerland


SODIUM HYDROXIDE STEL: 2 mg/m3 Ceiling: 2 mg/m3 MAK: 2 mg/m3
KZG: 2 mg/m3

Chemical name Denmark Finland Norway Sweden Czech


SODIUM HYDROXIDE Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 Takverdi: 2 mg/m3 NGV: 1 mg/m3 PEL: 1mg/m3
KGV: 2 mg/m3 NPK-P: 2mg/m3

Chemical name Poland Ireland


SODIUM HYDROXIDE NDSCh: 1 mg/m3 STEL: 2 mg/m3
NDS: 0.5 mg/m3

DNEL (Derived No-Effect Level)

Chemical name EU - REACH (1907/2006) EU - REACH (1907/2006) EU - REACH (1907/2006) - DNEL EU - REACH (1907/2006)
- DNEL - DNEL - DNEL
SODIUM HYDROXIDE workers inhalation long term exposure - local effects 1 mg/m3
general population inhalation long term exposure - local effects 1 mg/m3
ALKYLPOLYGLYCOSIDE C8-10 general population oral long term exposure - systemic effects 35.7 mg/kg bw/day
general population inhalation long term exposure - systemic effects 124 mg/m3
workers inhalation long term exposure - systemic effects
420 mg/m3
general population dermal long term exposure - systemic effects
357000 mg/kg bw/day
workers dermal long term exposure - systemic effects
595000 mg/kg bw/day

PNEC (Predicted No-Effect Concentration)

Chemical name EU - REACH (1907/2006) - PNEC EU - REACH (1907/2006) - PNEC


ALKYLPOLYGLYCOSIDE C8-10 freshwater 0.176 mg/L
marine water 0.0176 mg/L
freshwater (intermittent releases) 0.27 mg/L
food chain 111.11 mg/kg food
sediment (freshwater) 1.516 mg/kg sediment dw
sediment (marine water) 0.152 mg/kg sediment dw
sewage treatment 560 mg/L
soil 0.654 mg/kg soil dw

8.2. Exposure controls


Control parameters
Provide an eyewash station. Provide washing facilities.
Engineering Measures
Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Use personal protection equipment as per Regulation (EU) 2016/425.
Respiratory Protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. In case of mist, spray or aerosol
exposure wear suitable personal respiratory protection and protective suit. Conforming to EN 143 - P2 / P3 Particle filters.

Page 3 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

Hand Protection
Wear suitable protective gloves conforming to EN 374. Type of gloves suggested :. Short term use eg occasional contact or splash protection
;. Nitrile rubber (0.4 mm). Long term use eg continuous wear or immersion ;. Butyl rubber (0.7 mm). Fluorinated rubber. Breakthrough time of the
glove material (protective index 6, breakthrough time: >480 min). For break through times, refer to glove manufacturer's recommendations.
Skin Protection
Body protection must be chosen based on activity and possible exposure, e.g. footwear (solid shoes, rubber boots), rubber apron, long-sleeved
work clothing, impervious suit.
Eye Protection
Tightly fitting safety goggles. Approved to EN 166. For large volumes, faceshields should be used.
General Hygiene Considerations
Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice. Wash hands before
breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties


Information below relates to typical values and does not constitute a specification.

Appearance Red
Odour Slight
Physical state Liquid
pH 13
Flash Point Not relevant
Specific gravity 1.18
Viscosity No data available
Solubility Soluble in water
Autoignition Temperature No information available
Boiling Point/Range 100 °C
Melting Point/Range -5 °C
Flammability Limits in Air % No information available
Evaporation Rate No information available
Vapour pressure No information available
Relative vapour density No information available
Explosive properties No information available
Oxidising Properties No information available
VOC content 0%

9.2. Other information


No other information available

SECTION 10. STABILITY AND REACTIVITY

10.1. Reactivity
Not considered as highly reactive. See further information below.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
The mixture itself will not dangerously react or polymerise to create hazardous conditions in normal use.
10.4. Conditions to avoid
No conditions to be specially mentioned.
10.5. Incompatible materials
Strong acids. Oxidising agents. Reducing agents.
10.6. Hazardous decomposition products
None under normal storage conditions and use.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008


Product Information
The product itself has not been tested.

Chemical name Oral LD50 Dermal LD50 Inhalation LC50


SODIUM HYDROXIDE = 325 mg/kg ( Rat ) = 1350 mg/kg ( Rabbit )
ALKYLPOLYGLYCOSIDE C8-10 > 2000 mg/kg ( Rabbit )

Sensitisation
No information available.
Skin contact
Corrosive, Causes burns and possible deep ulcerations or scarring.
Inhalation
Inhalation may result in irritation or burns to the respiratory tract.
Ingestion
Ingestion may result in severe burns to the mouth, throat and digestive tract.
Eye contact
Corrosive. Causes burns and may lead to corneal damage and possible blindness.

Page 4 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

Chronic Toxicity
Inhaled corrosive substances can lead to a toxic edema of the lungs.
Carcinogenicity
There are no known carcinogenic substances in this product.
Mutagenic Effects
There are no known mutagenic substances in this product.
Reproductive Effects
There are no known substances in this product with effects on reproduction.
STOT - single exposure
Based on available data, the classification criteria are not met
STOT - repeated exposure
Based on available data, the classification criteria are not met
Aspiration hazard
Based on available data, the classification criteria are not met

11.2 Information on Other Hazards


The product does not contain substances that have been identified as an endocrine disruptor

SECTION 12. ECOLOGICAL INFORMATION

12.1. Toxicity
Product Information
The product itself has not been tested.
Ecotoxicity effects
pH values above 10.5 may be fatal to fish and other aquatic organisms.
Chemical name Toxicity to Fish Crustacea Toxicity to Algae
SODIUM HYDROXIDE LC50 = 45.4 mg/L Oncorhynchus mykiss
96 h
ALKYLPOLYGLYCOSIDE C8-10 LC50 = 170 mg/L Danio rerio 96 h

12.2. Persistence and degradability


The surfactant(s) contained in this preparation complies (comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on
detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to
them, at their direct request or at the request of a detergent manufacturer.
12.3. Bioaccumulative potential
No information available.
12.4. Mobility in soil
Soluble in water.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB. As defined under the regulation EC 1907/2006.
12.6 Endocrine disrupting properties
The product does not contain substances that have been identified as an endocrine disruptor
12.7 Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods


Waste from Residues / Unused Products
Dispose of in accordance with local regulations.
Contaminated Packaging
Empty containers should be taken for local recycling, recovery or waste disposal. Empty remaining contents. Prevent product from entering
drains. Recycle according to official regulations.
EWC waste disposal No
The following EWC/ AVV waste codes may be applicable:
06 02 04* Sodium and Potassium hydroxide
07 06 01* aqueous washing liquids and mother liquors
Other Information
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific

SECTION 14. TRANSPORT INFORMATION

14.1, 14.2, 14.3, 14.4.


UN number or ID number UN1824
Proper Shipping Name Sodium hydroxide solution
Transport hazard class(es) 8
Packing group II
EmS-No F-A, S-B
ADR / RID
UN number or ID number UN1824
Transport hazard class(es) 8
Packing group II
Classification code C5
Limited Quantity 1L

Page 5 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

Transport Cat. (Tunnel Restriction 2 (E)


Code)
IATA/ICAO
UN number or ID number UN1824
Proper Shipping Name Sodium hydroxide solution
Transport hazard class(es) 8
Packing group II
ERG Code 8L
Shipping Description UN1824, Sodium hydroxide solution, 8, PG II

14.5. Environmental hazards


The mixture is not environmentally hazardous for transport
14.6. Special precautions for user
No special precautions.
14.7 Maritime transport in bulk according to IMO instruments
Packaged product, not typically transported in IBC's
Additional information
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport.

SECTION 15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
This mixture was classified in compliance with EC Regulation 1272/2008 (CLP) and its adaptations.
This is a detergent product and complies with the Detergent Regulation (EC) No.648/2004.
Other regulatory information
UK - The Control of Poisons and Explosives Precursors Regulations 2023. This product contains a Poisonous substance that is on the Reportable
substance list in the UK. Acquisition, introduction, possession or use of this product by the general public is restricted. All suspicious transactions,
and significant disappearances and thefts should be reported. Please see details https://www.gov.uk/government/publications/supplying-explosives-
precursors/supplying-explosives-precursors-and-poison.
Labelling for contents (REGULATION (EC) No 648/2004 - 907/2006):
< 5% non-ionic surfactants,

15.2. Chemical safety assessment


No chemical safety assessment has been carried out for this mixture by the supplier

SECTION 16. OTHER INFORMATION

Text of H statements mentioned in Section 3


H314 - Causes severe skin burns and eye damage. H318 - Causes serious eye damage. H290 - May be corrosive to metals.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
Calculation method. H314 - Causes severe skin burns and eye damage.
Prepared By Austen Pimm
Creation Date 02/02/2015
Revision date 29/12/2023
Revision summary
CLP update. SDS sections updated 2 16 15 8

Abbreviations
REACH: Registration Evaluation Authorisation Restriction of Chemicals
EU: European Union
EC: European community
EEC: European Economic Community
UN: United Nations
CAS: Chemical Abstracts Service
PBT: Persistent Bioaccumulative Toxic
vPvB: very Persistent very Bioaccumulative
LC50: Lethal concentration, 50 percent
LD50 : Lethal dose, 50 percent
EC50: Effective concentration, 50 percent
LogPow: LogP octanol/water
VwVwS: Verwaltungsvorschrift wassergefährdende Stoffe (Administrative order relating to substances hazardous to water - Germany)
WGK: Wassergefahrdungsklasse (Water Hazard Class - Germany).
AVV: Abfallverzeichnis-Verordnung (Waste Code - Germany)
ADR: Accord européen relatif au transport international des marchandises Dangereuses par Route (European agreement governing the international carriage of
dangerous goods by road)
IMDG: International Maritime Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
RID: Reglement international concernant le transport des merchandises dangereuses par chemin der fer (Regulations concerning the International carriage of
Dangerous goods by rail)
EmS: Emergency Response Procedures for Ships Carrying Dangerous Goods
ERG: Emergency Response Guidebook
IUCLID / RTECS International Uniform Chemical Information Database / Registry of Toxic Effects of Chemical Substances
GHS: Globally Harmonised System of classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
VOC: Volatile Organic Chemical
w/w: weight for weight
DMSO: Dimethyl sulphoxide
OECD: Organization for Economic Cooperation and Development

Page 6 / 7
11000593 - SHINY SIDE Print Date 02/04/2024

STEL: Short Term Exposure Limit


TWA: Time Weighted Average
Further Information
Component test results displayed in sections 11 and 12 are typically supplied by Chemadvisor and assembled from publicly available literature
sources e.g. IUCLID / RTECS
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations

Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information
given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a
warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet

Page 7 / 7

You might also like