Punjab College P.D.

Khan Campus
Sendup Exams 2023 Roll No: ______________
Paper code: 2048 Name:
Class: Inter Part–I Max. Marks: 17
Subject: Chemistry Time Allowed: 20 Mints

Objective
Q1. You have four choices for each objective type question as A, B, C and D. The choice which you think is correct; fill
that circle in front of that question number on given objective answer sheet. Use blue marker or pen to fill the circles.
Cutting or filling two or more circles will result in zero mark in that question.
1) Acetone & chloroform are soluble into each other due to:
(a) Hydrogen Bonding (b) Dipole-Dipole Forces (c) Instantaneous dipole (d) All of these
2) Which is called Pseudo solid?
(a) CaF2 (b) NaCl (c) Glass (d) CaCl2
3) Which liquid has the lowest vapour pressure?
(a) Br2 (b) H2O (c) Ether (d) Ethanol
4) The number of amino acid units for each turn of helix, on average are:
(a) 21 (b) 23 (c) 25 (d) 27
5) Strength of Hydrogen Bond is maximum in:
(a) HF (b) H2O (c) HCl (d) NaCl
6) Liquid Crystal can
(a) Reflect Light (b) Diffract Light (c) Bend Light (d) All of These
7) The wave number of the light emitted by a certain source is 2 x 10 6 m. the wavelength of this light will be
(b) 500nm (b) 500m (c) 5 × 107 m (d) 200nm
8) In Paschan Series Jump of electron is from any orbit to:
(b) 1st Orbit (b) 2nd Orbit (c) 3rd Orbit (d) 4th Orbit
9) n+l value for 6d orbital is:
(a) 08 (b) 09 (c) 10 (d) 11
10) The molecular shape of SO2 is:
(a) Trigonal Planar (b) Bent or V-Shaped (c) Linear (d) Not sepcified
11) Dipole moment of H2O is:
(a) 1.85 D (b) 1.25 D (c) 3.1 D (d) Zero
12) Electron in the sub shell filled according to the formula
(a) 2n (b) 2n2 (c) 2(2l+1) (d) 2l+1
13) Radius of electron is directly related to:
(a) Atomic Number (b) Velocity (c) Number of Orbit (d) Both option (a) & (b)
14) Which of the following has shortest C-C bond length?
(a) Ethyne (b) Ethene (c) Benzene (d) Ethane
15) Which of the following has bond angle 107.5°
(a) NH3 (b) H2O (c) CH4 (d) CCl4
16) The nature of positive rays depends upon:
(a) Nature of Residual gas (b) Nature of Electrodes (c) Nature of Discharge tube (d) None
17) The following, the element with highest ionization energy is:
(a) [Ne],3s2 3p1 (b) [Ne], 3s2 3p2 (c) [Ne], 3s2 3p3 (d) [Ne], 3s2 3p4
 Punjab College P.D. Khan Campus
Send – Up Examination 2023 Roll No: ________
Paper code: 2048 Name:
Class: Inter Part–I Max. Marks:68
Subject: Chemistry Time Allowed: 2:10 Hrs

Subjective
SECTION-I
Q.2.Answer any eight parts from the followings. 2*8=16
i. Evaporation causes cooling. why?
ii. Difference between Isomorphism and polymorphism?
iii. Differentiate between atomic emission and absorption spectrum?
iv. Differentiate between orbital and orbit?
v. Give electronic configuration atomic number 24 and 30?
vi. Why radius of atom cannot determine precisely?
vii. Differentiate between polar and non-polar bond?
viii. Differentiate between B.M.O. & A.B.M.O.?
ix. Explain Hydrogen Bonding in DNA.
Q.3.Answer any eight parts from the followings. 2*8=16
i. Name factors affecting Rate of Evaporation.
ii. H2O is a liquid but H2S and H2Se are gases at room temperature. Justify it.
iii. Define Debye and London dispersion forces.
iv. Ionic solids do not conduct electricity in solid state, why?
v. What is Zeeman and Stark effect?
vi. Difference between frequency and wave number.
vii. Whichever gas is used, nature of cathode rays remain same, why?
viii. Why is it necessary to decrease the pressure in discharge tube to get cathode rays?
ix. Why He2 doesn’t exist?
Q.4.Answer any six parts from the followings. 2*6=12
i. Explain AB3-type with multiple bond according to VSEPR theory.
ii. Calculate wave number for 2nd spectral line in Balmer series.
iii. Difference between slow and fast neutron?
iv. Why second electron affinity is positive?
v. Why cationic radius is smaller than parent atom?
vi. One-unit cell of sodium chloride crystal contain 4 formula units of NaCl, justify.
vii. Bond distance between two atoms is a compromise distance, Justify it.
SECTION-II
Attempt any three questions from the following. 8*3=24
Q.5. (a). What are liquid crystals, give their three uses. (4)
(b). Give assumptions and postulates of VSEPR theory. (4)
Q.6. (a). State Moseley law, what is its importance? (4)
(b). Draw out geometry of O2-2 according to MOT and explain it. (4)
Q.7. (a). Explain different theories about metallic solids. (4)
(b). Write applications of equation derived for radius of electron. (4)
Q.8. (a). Explain structure of diamond. (4)
(b). Define vapour pressure and explain method to determine it. (4)