PART-2 : CHEMISTRY

SECTION-I : (Maximum Marks: 80) 3. Assertion : Although the shapes of 2s and 2p orbitals
This section contains 20 questions. Each question has 4 are different, an electron has the same energy when it
options for correct answer. Multiple-Choice Questions is in the 2s orbital as when it is present in 2p orbital for
(MCQs) Only one option is correct. For each question, all single electron species.
marks will be awarded as follows: Reason : The energy of an electron in a hydrogen atom
Full Marks : +4 If correct answer is selected. is determined solely by the principal quantum number.
Zero Marks : 0 If none of the option is selected. (A) Assertion is false but Reason is true.
Negative Marks : –1 If wrong option is selected.
(B) Assertion is true but Reason is false.
1. What will be the pH of 1% (w/w) aqueous solution
(C) Both Assertion and Reason are true and
of salt NaA ?
Reason is the correct explanation of Assertion.
[Given: Ka(HA) = 10 – 6 ,
density of solution = 1.2 gm/ml, (D) Both Assertion and Reason are true and Reason
Molecular mass of HA = 98, is NOT the correct explanation of Assertion.
Atomic mass of Na = 23]. 4. Which of the following set of elements have most
(A) 4.5 (B) 9 negative electron gain enthalpy in their respective
groups.
(C) 10.5 (D) 9.5
(A) (S , Na , F)
2. Consider following solutions in given solvents :
I : 0.3 M aqueous glucose solution (B) (S , Cl , Ne)
II : 0.2 M aqueous sodium chloride solution (C) (S , Sb , Cl)
III : 0.3 M aqueous ammonium phosphate solution
(D) (F , P , Se)
IV : 0.4 M benzoic acid in benzene (dimerises upto 50%)
Select incorrect statement from given options for the 5. E° (SRP) of different half cells are given
2+ /Cu = 0.34 volt ; EZn2+ /Zn = – 0.76 volt
o
ECu o
above given solutions :
o o
(A) I and IV are isotonic solutions. EAg + /Ag = 0.8 volt ; EMg 2+ /Mg = – 2.37 volt

In which cell among the following Δ G° per mole

(B) III is hypertonic as compared with each of I, II
of electron is most negative : -
and IV.
(A) Zn (s) | Zn2+ (1 M) || Mg2+ (1 M) | Mg (s)
(C) IV is hypotonic as compared with each of I, II
and III. (B) Zn (s) | Zn2+ (1 M) || Ag+ (1 M) | Ag (s)
(D) II is hypotonic as compared with III but (C) Cu (s) | Cu2+ (1 M) || Ag+ (1 M) | Ag (s)
hypertonic as compared with I and IV. (D) Ag (s) | Ag+ (1 M) || Mg2+ (1 M) | Mg (s)
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6. The conductivity of saturated solution of 9. For the hypothetical reaction involving three ideal
–5 –1 –1
Ba3(PO4)2 is 1.2 × 10 Ω cm . The limiting gases as given below :
equivalent conductivities of BaCl2, K3PO4 and KCl
A2(g) + B2(g) ⇌
­ 2AB(g)
are 160, 140 and 100 Ω – 1 cm2 eq – 1, respectively.
The solubility product of Ba3(PO4)2 is : Δ rG° and Δ rS° are 20 kJ/mol and – 20 JK – 1 mol – 1

(A) 1 × 10 – 5 respectively at 200 K. For the given reaction

(B) 1.08 × 10 – 23 Δ r CP is 20 JK – 1 mol – 1 then calculate Δ rH° for the
(C) 1.08 × 10 – 25 given reaction at 400 K :
(D) 1.08 × 10 – 27 (A) 20 kJ/mol
7. In a nitration experiment, 10.0g of benzene gave (B) 7.98 kJ/mol
13.2 g of nitrobenzene. The percentage yield for
(C) 28 kJ/mol
nitration of benzene is :
(D) 18 kJ/mol
(A) 83.7%
10. Which of the following statement is incorrect?
(B) 62.5%
(A) Only oxidizing acids (nitric and hot
(C) 98.2%
(D) 26.6% concentrated sulphuric) react with Cu

8. For the following spontaneous process (B) The high energy to transform Cu(s) to Cu2+(g)
H2O( ℓ ) → H2O(s) at 1 atm and 268 K, which of the
is balanced by its hydration enthalpy
following option is true ?
[Given : Δ Ssys = Entropy change of system and (C) Both, the observed as well as calculated
Δ Ssurr = Entropy change of surrounding during the o
EM values for Cu are highest as compared
2+ /M

process]
to other 3d-series elements.
(A) Δ Ssurr > 0
(B) Δ Ssys > 0 (D) Among all 3d series elements, only Zn has
(C) Δ Ssurr < 0 more 3rd IE value than 3rd IE of Cu
(D) Δ Ssys = – Δ Ssurr

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11. Which of the following actinoid elements contains
no electron in "6d" subshell.
(A) Americium (Am = 95) 13.
(B) Curium (Cm = 96)
(C) Lawrencium (Lr = 103)
(D) Protactinium (Pa = 91) X, Y and Z will be :
12. Treatment of D-glucose with aqueous NaOH (A) CH2 = CH2 , CH3 – CH3, CH3CH2 – I
results in a mixture of monosaccharides, which (B) CH3 – CH2 – I, CH3 – CH3 , CH2 = CH2
are (C) CH3 – CH2 – I, , CH2 = CH2

(D) CH3 – CH2 – I, CH2 = CH2,

(A) , and
14. Which of the following complex show stereo
isomerism.
(I) [Ni(en)3]Cl2
(II) [CoCl2(en)2]Cl
(B) , and (III) [NiCl2(Ph3P)2]
(IV) [Co(H2O)3F3]
(A) II & IV only
(B) I, II, III, & IV
(C) , and (C) I, II & III only
(D) I, II & IV only
15. Considering 2s-2p mixing to be non-operative, which
of the following specie(s) can undergo a transition
from HOMO (gerade) to LUMO (ungerade).
, and
(D) (A) N2 (B) C2
(C) Li2Θ (D) B2
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16. The compound A in the following reaction is :
18. Sn/HCl NaNO2 /HCl H2 O / Δ
−−−−−→ (P) −−−−−
o
−−−→ (Q) −−−−−→ (R)
(i) CH3 MgBr/H2 O ( i ) O3 0 C
A −−−−−−−−−−−−−→ B −−−−−−−−→ C + D
(ii) Conc. H2 SO4 / Δ (ii) Zn/H2 O

Compound (S) is :

Ba(OH )2
(A) (B)
D −−−−−−→

(A)
(C) (D)

(B) 19. List-I (Compound) List-II (Test)

(C) (P) (1) +ve Iodoform test

(D) (Q) (2) +ve Isocynide test

17. Which set of reagent (in the correct order) would
(3) +ve Liebermann
accomplish the following transformation ? (R)
nitroso test
I II
−−
→ −−→
(S) (4) +ve Tollen's test
(A) BH3 – THF; H2O2/NaOH H2SO4
(B) KOH/THF; CH3I H2/Pd/C (A) P→1, Q→3, R→2, S→4
(C) H2/Lindlar catalyst NaNH2/THF; CH3I (B) P→4, Q→2, R→3, S→1
(D) NaNH2/NH3( ℓ ); CH3I H2/Lindlar catalyst (C) P→1, Q→2, R→3, S→4
(D) P→4, Q→3, R→2, S→1
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20. Which of the following reaction yields a coloured 2. B2 H6(g) + 6Cl2(g) → 2BCl3 + 6HCl(g) ;
gas. Δ r H = −1326kJ ...(i)
o
1500 C BCl3(g) + 3H2 O( ℓ ) → H3 BO3(g) + 3HCl(g) ;
(A) C + P 2 O5 −−−−→
(coke)
Δ r H = −112.5 kJ ...(ii)
CuCl2
(B) 4HCl + O2 −−−−→ B2 H6(g) + 6H2 O(l) → 2H3 BO3(s) + 6H2(g) ;
723 K
Δ H = −493.4 kj ...(iii)
(C)
1 1
H2(g) + Cl2(g) → HCl(g) ; Δ H = −92.3 kJ ...(iv)
2 2
(D) H2O + HCN → Using the above given thermochemical data at 300 K,
SECTION-II : (Maximum Marks: 20) calculate molar enthalpy of sublimation of H3BO3 at
This section contains 10 questions Candidates have to 300 K (in kJ/mole).
attempt any 5 questions out of 10. If more than 5 3. When the following skeleton equation is
questions are attempted, then only first 5 attempted balanced with smallest whole number
questions will be evaluated.
stoichiometric co-efficients of species involved,
The answer to each question is a Numerical Value.
what is the sum of stoichiometric co-efficients of
For each question, enter the correct integer value (In case
hydroxide ions and iodide ions,
of non-integer value, the answer should be rounded off to basic
I − (aq) + MnO−4 (aq) −−−−−→ IO− (aq) + MnO2 (s)
the nearest Integer). medium

Answer to each question will be evaluated according to 4. Wavelength of electron waves in two Bohr orbits is
the following marking scheme: in ratio 3 : 5. The ratio of kinetic energy of electron
Full Marks : +4 If correct answer is entered. in these same orbits is 25 : x, hence x is ......... .
Zero Marks : 0 If the question is unanswered. 5. Number of dibasic oxo-acids that contain bond
Negative Marks : –1 If wrong answer is entered. between two identical atoms ("X"-"X")
1. H2S2O8 , H4P2O5 , H5P3O10 , H2S4O6 , H4P2O8 ,
Consider the reaction given below which is use for
H2N2O2
the detection of phosphates in inorganic salt by
using a Molybdenum compound "A". 6. In the hofmann bromoamide degradation &
bromoform reaction, the minimum number of moles
Na2HPO4 + "A" + HNO3 →
of Br2 & NaOH required for per mole of amine &
B + "C" + "D" + "E"
(Canary yellow ppt.) per mole of bromoform produced is (P, Q) & (P', Q')
Find the number of oxygen atoms in (B) Canary P P′
respectively. Then the value of ( + ) is :

yellow ppt. Q Q′

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7. How many reaction correctly matched with their
8.
major product :
Θ
OH
Mono - brominated product(s)
(i) −−→
Find number of fraction obtained after fractional
distillation of mono-brominated products
9. Identify total number of compounds which are
soluble in aq-NaOH and aq-NaHCO3 both :

(ii) , , ,

, , HCl,
(iii)

, ,
(iv) CH3 – CHO CH3 – CH=CH – CHO

(v)
10. Number of 'd'-block halides that do not exist or are
highly unstable
(vi) FeI3 , MnCl3 , TiF2 , VI4 , NiCl2 , CrBr3 , MnI4

(vii)

(viii) Cl3C – CHO Cl3C – CH2OH +

Cl3C – COONa

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