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Version 1

CERTIFIED REFERENCE MATERIAL

Standard Solution 100 mg/l Al, Ag, As, B, Ba, Be, Bi, Ca, Cd, Cs, Co, Cr, Cu, Fe, In, K, Li, Mg, Mn, Mo,
Na, Ni, Nb, Pb, Rb, Sb, Se, Sr, Ti, Tl, V, U, Zn in HNO3 5%

Lot N: 827775 Ref N: M8A96.K1.5N.L1 Certification Date: 08.06.2022

Barcode: 97639886

Component Certified Value Metrological traceability

and uncertainty [mg/l]
Ag 99.76 ± 0.24 (y) NIST SRM No 3151 Lot 160729
Al 99.44 ± 0.34 (y) NIST SRM No 3101a Lot 140903
As 98.39 ± 0.69 (y) NIST SRM No 3103a Lot 100818
B 99.86 ± 0.34 (y) NIST SRM No 3107 Lot 110830
Ba 99.83 ± 0.32 (y) NIST SRM No 3104a Lot 140909
Be 100.26 ± 0.29 (y) NIST SRM No 3105a Lot 090514
Bi 100.01 ± 0.33 (y) NIST SRM No 3106 Lot 180815
Ca 100.14 ± 0.22 (y) NIST SRM No 3109a Lot 130213
Cd 99.64 ± 0.34 (y) NIST SRM No 3108 Lot 130116
Cs 100.00 ± 0.46 (g) NIST SRM No 3111a Lot 130228
Co 99.76 ± 0.31 (y) NIST SRM No 3113 Lot 190630
Cr 99.92 ± 0.28 (y) NIST SRM No 3112a Lot 170630
Cu 99.55 ± 0.26 (y) NIST SRM No 3114 Lot 121207
Fe 100.38 ± 0.29 (y) NIST SRM No 3126a Lot 140812
In 99.48 ± 0.38 (y) NIST SRM No 3124 Lot 110516
K 100.28 ± 0.30 (y) NIST SRM No 3141a Lot 140813
Li 100.58 ± 0.30 (y) NIST SRM No 3129a Lot 100714
Mg 100.17 ± 0.23 (y) NIST SRM No 3131a Lot 140110
Mn 99.98 ± 0.24 (y) NIST SRM No 3132 Lot 050429
Mo 100.04 ± 0.32 (y) NIST SRM No 3134 Lot 130418
Na 99.83 ± 0.24 (y) NIST SRM No 3152a Lot 120715
Ni 100.05 ± 0.34 (y) NIST SRM No 3136 Lot 120619
Nb 100.47 ± 0.37 (y) NIST SRM No 3137 Lot 120629
Pb 99.12 ± 0.57 (y) NIST SRM No 3128 Lot 101026
Rb 100.07 ± 0.41 (y) NIST SRM No 3145a Lot 150622
Sb 100.93 ± 0.44 (y) NIST SRM No 3102a Lot 140911
Se 99.83 ± 0.58 (y) NIST SRM No 3149 Lot 100901
Sr 100.78 ± 0.68 (y) CPA CRM No SRNO3 Lot 85028081
Ti 100.60 ± 0.25 (y) NIST SRM No 3162a Lot 130925
Tl 99.52 ± 0.47 (y) NIST SRM No 3158 Lot 151215
V 99.91 ± 0.28 (y) NIST SRM No 3165 Lot 160906
U 99.71 ± 0.34 (y) NIST SRM No 3164 Lot 080521
Zn 100.45 ± 0.29 (y) NIST SRM No 3168a Lot 120629

Notes:
(g) WQP 5.15.1.6 The certified value was obtained by gravimetrical dilution of a concentrate calibrated by instrumental
and/or classical analysis
(y) WQP 5.15.1.24 The certified value was obtained by a weighted mean of the results of two independent calibration
methods among: Classical Volumetric,Primary Gravimetric, Instrumental (ICP/OES, ICP/MS or IC)

Density* 1.036 g/cm3 at 20°C

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Starting Material, Purity* Batch

AgNO3 99.996% 82093600
Al(NO3)3 99.999% 82104511
As 99.999% 82112974
H3BO3 99.998% 82104337
Ba(NO3)2 99.999% 82104207
Be4O(C2H3O2)6 99.996% 82105228
Bi 99.999% 82076030
CaCO3 99.993% 82104870
Cd 99.999% 82088095
CsNO3 99.999% 82100513
Co(NO3)2 99.995% 82107840
Cr(NO3)3 99.99% 82107147
Cu(NO3)2 99.999% 82104900
Fe 99.99% 82113230
In 99.995% 82113766
KNO3 99.998% 82104535
Li2CO3 99.998% 82107925
Mg(NO3)2 99.9986% 82107741
Mn(NO3)2 99.998% 82104955
(NH4)6Mo7O24 99.998% 82089740
NaNO3 99.997% 82104733
Ni(NO3)2 99.998 82104597
Nb 99.94% 82093327
Pb(NO3)2 99.996% 82115715
RbNO3 99.99% 82093365
Sb 99.99% 82105365
Se 99.992% 82100810
Sr(NO3)2 99.994% 82099473
(NH4)2TiF6 99.99% 82109219
TlNO3 99.993% 82104436
NH4VO3 99.99% 82107987
UO2(OOCCH3)2 99.96% 82093075
Zn 99.997% 82110352
* These values are not certified

Storage Conditions: Store under normal laboratory conditions, at temperatures between 15° to 25°C

Shelf-life: 08.07.2024 Date of opening: ……………..

(Recommended period of use should not exceed 12 month(s) from date of opening )

Concept of Certification and traceability statement:

This certified reference material (CRM) is produced using a high purity starting material, acid from sub-boiling and 18 MOhm deionised water and filtered
through a 0.2 micron filter.
The reported expanded uncertainty of measurement is stated as the standard uncertainty of measurement multiplied by the coverage factor k = 2, which for a
normal distribution corresponds to a coverage probability of approximately 95%. The standard uncertainty of measurement has been determined in
accordance with EA 4/02
Property of the result of a measurement whereby it can be related to stated references, usually national or international standards, through an unbroken chain
of comparisons all having stated uncertainties (ISO VIM)
The metrological traceability is assured using certified reference material traceable to SI of NIST (SRM) or BAM (CRM). All contributions in relation to the
certification of standard solutions are considered when evaluating the uncertainty.
The measurement results are traceable to SI.
All analytical balances used for the preparation of the solution are calibrated yearly under an in-house procedure with analytical weights, traceable to DKD,
and are checked daily.
Class A laboratory glassware is used.
The results from temperature measurement are traceable to SI. The thermometers used for solution's calibration are calibrated from an ISO 17025 accredited
laboratory. The ambient conditions are controlled with a hygrometer calibrated from an ISO 17025 accredited laboratory.

Intended use: For Laboratory Use Only

Calibration of ICP/OES, AAS Validation of analytical methods
Preparation of “working reference samples” Detection limit and linearity studies
This statement is not intended to restrict the use for other purposes.

Instructions for the correct use of this reference material:

This certified reference material can be used directly or can be diluted in an appropriate high purity matrix. Only a clean class A glassware should be used.
Do not pipet from container. Obtained concentration (in mg/l) after dilution is a result from the multiplication of certified value of CRM concentration and the
CRM's volume used for dilution and divided into the flask's volume used for dilution.

Stability and storage:

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This CRM is with a guaranteed stability until ±0.5% of the certified concentration within its shelf life. Stability is guaranteed, provided that the solution is kept
in its original packaging, tightly closed stored, as written in the section: Storage Conditions. If storage of a partially used bottle is necessary, the cap should
be tightly sealed and the bottle should be stored in refrigerator to minimize transpiration rate. The laboratory performs stability tests according to MQP 5.14.1
therefore solutions with one and the same bar-code number might have different expiration dates.

Hazardous situation:
The normal laboratory safety precautions should be observed when working with this CRM. Further details for the handling of this CRM are available as
safety data sheet.

Level of homogeneity:
This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.
To ensure sufficient homogeneity of the sample prior to use thoroughly mix by inversion.

Names of certifying officers:

Laboratory: Tihomir Stoyanov

Manager: Krassimira Taralova

This document QF 5.17.1/1 version 1 is designed and the certified value(s) and uncertainty(ies) are determined in accordance with ISO Guide 31, ISO Guide
35,and Eurachem / CITAC Guides

This certificate relates solely to the lot number given above.

All processes (including generating of this certificate) are completely controlled by the specialized Computer-Aided-Manufacturing (CAM) software.

This Certified Reference Material was produced under a quality management system that is:
- Registered to ISO 9001 Quality Management System (Lloyd's Register Quality Assurance Ltd Cert No 0039638)
- Accredited according to ISO/IEC 17025
- Accredited according to ISO 17034