Material Safety Data Sheet

SERCK AUDCO VALVE (SAV) 733 STICK SEALANT

1. Product and company identification

Product name : SERCK AUDCO VALVE (SAV) 733 STICK SEALANT
Material uses : Sealants / Lubricants
Supplier/Manufacturer : Flowserve Corp
5215 N. O'Connor Blvd., Suite 2300
Irving, Texas 75039
Telephone: 937-707-0064 (24 hours)
Prepared by : IHS
In case of emergency : CHEMTREC® (USA): 800-424-9300
CANUTEC (Canada): 613-996-6666

2. Hazards identification
Physical state : Solid. [semi-solid / grease (stick)]
Color : Tan.
Odor : Fatty. [Slight]
Emergency overview
Signal word : WARNING!
Hazard statements : CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT AND SKIN
IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE,
BASED ON ANIMAL DATA.
Precautions : Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation : Moderately irritating to the respiratory system. Exposure to decomposition products
may cause a health hazard. Serious effects may be delayed following exposure.
Ingestion : No known significant effects or critical hazards.
Skin : Moderately irritating to the skin.
Eyes : Irritating to eyes.
Potential chronic health effects
Chronic effects : Contains material that may cause target organ damage, based on animal data.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Target organs : Contains material which may cause damage to the following organs: kidneys, lungs,
upper respiratory tract, skin, eye, lens or cornea.

Over-exposure signs/symptoms
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
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2. Hazards identification
Ingestion : No specific data.
Skin : Adverse symptoms may include the following:
irritation
redness
Eyes : Adverse symptoms may include the following:
pain or irritation
watering
redness
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure

3. Composition/information on ingredients
Name CAS number %
Polyester resin - 30-60
crystalline silica non-respirable 14808-60-7 10-30
lithium 12-hydroxystearate 7620-77-1 10-30
propylene carbonate 108-32-7 10-30
Castor oil, hydrogenated 8001-78-3 5-10
calcium distearate 1592-23-0 1-5
Copper corrosion inhibitor - 1-5
1,2-Dihydro-2,2,4-trimethylquinoline, oligomers 26780-96-1 0.1-1
12-hydroxystearic acid 106-14-9 0.1-1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

4. First aid measures

Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Antidote information
Product/ingredient name Antidote information
No antidote information known
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

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5. Fire-fighting measures
Flammability of the product : No specific fire or explosion hazard.
Extinguishing media
Suitable : In case of fire, use carbon dioxide. Use foam or all-purpose dry chemical to extinguish.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures

Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment (see Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill : Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.

7. Handling and storage

Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
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8. Exposure controls/personal protection

Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
crystalline silica non-respirable QC 1/2014 - 0.1 - - - - - - - [a]
calcium distearate US ACGIH 4/2014 - 10 - - - - - - - [b]
AB 4/2009 - 10 - - - - - - - [3]
BC 2/2015 - 10 - - - - - - -
ON 1/2013 - 10 - - - - - - - [b]

[3]Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules
is not required.
Form: [a]Respirable dust. [b]Total particulate mass

Consult local authorities for acceptable exposure limits.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, particulate filter respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

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9. Physical and chemical properties

Physical state : Solid. [semi-solid / grease (stick)]
Flash point : Open cup: >160°C (>320°F) [Cleveland.]
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : Tan.
Odor : Fatty. [Slight]
pH : (Neutral.)
Boiling/condensation point : Not applicable.
Melting/freezing point : Not applicable.
Relative density : 1.17 [24°C (75°F)]
Density : Not available.
Vapor pressure : Nil
Vapor density : Not applicable.
Odor threshold : Not available.
Evaporation rate : Nil
Viscosity : Not available.
Solubility : Very slightly soluble in the following materials: hot water.
Insoluble in the following materials: cold water.
LogKow : Not available.
Physical/chemical : Solids (% by weight): 30-52
properties comments Volatile (% by weight): Nil
VOC content: Nil

10. Stability and reactivity

Chemical stability : The product is stable.
Conditions to avoid : Keep away from fire.
Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerization will not occur.

11. Toxicological information

Acute toxicity
Product/ingredient name Result Species Dose Exposure
propylene carbonate LD50 Oral Rat >5000 mg/kg -
calcium distearate LD50 Oral Rat >10 g/kg -
Chronic toxicity
Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
propylene carbonate Eyes - Moderate irritant Rabbit - 60 milligrams -
Skin - Moderate irritant Rabbit - 500 -
milligrams
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11. Toxicological information

Sensitizer
Not available.

Carcinogenicity
Conclusion/Summary : The respirable fraction of crystalline silica is less than 1%.
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
crystalline silica A2 1 - + Known to -
be a human
carcinogen.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.

12. Ecological information

Ecotoxicity : No known significant effects or critical hazards.
Aquatic ecotoxicity
Not available.
Persistence/degradability
Not available.

Partition coefficient: n- : Not available.

octanol/water
Bioconcentration factor : Not available.
Mobility : Not available.
Toxicity of the products of : Not available.
biodegradation
Other adverse effects : No known significant effects or critical hazards.

13. Disposal considerations

Waste disposal : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.

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13. Disposal considerations

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14. Transport information

TDG/IMDG/IATA : Not regulated.

15. Regulatory information

United States inventory : All components are listed or exempted.
(TSCA 8b)
WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
Canadian NPRI : None of the components are listed.
CEPA Toxic substances : None of the components are listed.
Canada inventory : Not determined.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists : Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Chemical Weapons : Not listed
Convention List Schedule
I Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals

16. Other information

Label requirements : CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT AND SKIN
IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE,
BASED ON ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
Health * 2

Flammability 1
Physical hazards 0

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16. Other information

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue : 1/12/2016
Date of previous issue : No previous validation
Version : 1
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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