tuaelaliona!

aud (atee
ald.ibalnaleven apulia)
ut
luten
tianiliow
alownie'sug eleeuon
AToICIPECTKA
heel
ani
es
Lepeu
atouy the whe eaulls
halllmotseue
(AJ
de. letuneew
lo -6,-b,) {4i
anrleeue day nidt s absonseda adatte
deleied Aadialiny
Aitot la
Lweoil
doalu
ICO --2. daelo Mo A
 e SPECTROsco
nlendton

comyod.
the .MR. absobad enilid

Casmie Kadionn

chane
utbdal
aveled
lhalet sble lsutthon Sputt
VISIBLE
X. Neau.

( uwgn
k bmas
| e2(inw donse bondi )

bondi apule
Cau not

be deteelad

husgha mpaud haning ltplponda some auhout q

 obseptum dapeuds uperpon the nowe lenghad steehit
the
enengy &ilital
eegybitas ?k)apeetanptootobel, auot igktoq a
- A
to
pass thengh
e ano amnut 'neidet
a hanullool glhl
Light absonption
(*pelhun') Aobtawna d haif tl. A big absotbaee.
M wwane leus spaikum
a
Emyt
Ema
welongh a an absopton
maimn ae warelgh
Ama
lanbeito
tue combined Bee'-
kaw:
t stala thar hhen a.
Kadiation

eomeouthation and 'path euekton(c) path

degth
Akobauee; Ae Lo
e

l t ’Tanioitted (dupene
abs. eicut
Absopuyco the natue
hupotionaity éonstaut ean be
2ue
|
Io
Incideut
beau

wavelupt is ae
cidea sonstinty eM)ito a speete
to
inlens tes ot Tramsnuitleo big
Transmtt auce ( ) Ratio T A o , IxDThs,
To
 (oneyy

no

hantlan)
E,(loNO) to

E, (HoMe)
Shis abzonptim
eetalion
ELET RONe TRANSITIDNS

C=c-C=c
 ’vI60nm
yh henee alleued
-l0nm (70 ’
Alkanes’or
e not do
and
s
nm. -30D 2 9n’t
abuets
au heutee enwgy70 ast quies
abiele
al
tede I70-(90
s ym
hand
al alhenes
alkanes,
n* 3)
nmate at wetyl
7yaleolst
anngs
e and halides kelbnes aldehypss, thes
rhola &otnalid one Aaning
2)n*
alion Lunponla
CoNJUGATED SysTENS! outital
Couyagalol dienes, the Tulal
me
epaalt alhe Ceuue to gine

and n, cud
hanlo tlran T * an

n’thanili at

wtule
the
engy kpeualun
yngated yelang, coliis nduud
sabitd
heleeu the Aounol lali aud

Ama

’
= honds, so the
Aonaloe has 12 eonjugalid nakes lhe

uoleeue colswed.
SHIET
ABSORPTLON AND (NTENSITY
meile iA
n a
te au
suslinal eninoeut

)BATHOHRDMC SHIfT!- She sit a abupliän

 madwum

(inlasae
Ao luen)inpaili 4

anal'ne |aciy) Anium n

-28 om a03 m.

te ewonal e with
canjuçalan

blueud)
imeneass
 byide
Puetate
4) HYPocRROMIC. SHIET prenrl

Caued by the
e moeeula.
CHa Ema ||600 bentoala

Emax 19,000

Balhooic

Cma

and
anly abeoptu
 ohang
Chuom
etylene, aa
a lylaney ete

-csN, -N
AUxO CHROMES!.
Aunoetioies are Aatuaid
Auxoceeo
attahd to a
as we

Aelualy. the aXocenes are the

ane

-ÖR,-ÖH,-NH,-d: ee'
au ausoehuone
d e o tue
jw bene
wlide be
yellos coleu.
 dietngusha
bye
omes thans )he beomatuca)
Dsome
- eteetisn
of
otensilis opieal
dhleetal.tuu coyal
io qo
d, cnln an demination
cpuen
o the In
mt te
Conjuçalon
a !- Weleminatiou
op 2-
eenpd. dne
y knon
e
itlh apelnn alsupton ionpamig eane
e fieato
o ldeti !-ayis
CATIONS? PPL A
hanspanda Apungle,
dealnl
Dto
Cell
polan) (non heoane
most (dhaap prlan) wetu ( &onents
’
3s0mrn bele
7S03SDn
nlensy than
(monochiomato) souleea
a
olololo
(weenentaltou
totteaeo
‘4nknnn
4)- Cheumieal Kunheti- chape ob
Aeaclaul hweluet comen
with e moaan.
(Atostoaee d eonen)
S) MBeeulan wt deuint Msleeulan wlen be
deleñe &unee lhe conen uaaly
6) o wsed tautomerie egwbri
C a n e done as

veny nense an auda

diadelion
 A Numeiealk speet)
& el wheu cis
A 4e Abseuakos in
A = EMM
CCmeeutaatis
1-)
xM ma/L
A l- pathlengtl (eu)
Compound
Aeaule od hanig tenen to
absebee. vale.
EMMoten absopir y
at n 510 oi20 mot /L)
cell. calulale nm M Molan naas
absoatig
Mea albiensalg mud a Mot
a t
the co pna
A
O20

Lnol! -1

(Molau Abcnpui4 )
unaatuate cl kete. d elatine mo. maso LO has
An
with a 1-D n
stluteon this helone heued abs. A 2r0
cell. Caleulali he coun dhe kelone à-(his ution,

(o,000 l0,00

A a tL)* 2 2
-2.
= 2:2x|o
A (0OO
arl
3. A soltn
abs vale he meaned wsing 1-0
1.) eicelu Caleulali
io absetotasliy and Hola abteptiilg alcs; gien maf
maotot
the 200
A
Em arM s 22 x 200
l sL 00l, 2
4o0 As
 a t allzos
Caleulale the me Lelan abssoplilfEn)
e
fo
t
Containng
wheu the 1-0 a mmof dii (t!ox
e Len cell
wey 5
ot /L)
brd
w db

the vae abcobanee 1 doube

=1500 Lmot'cu
A= |:SxIo
A x2 ma/L
l·oxto3
A 3 Ans
ae
A = 1500 x (x0x16)xt fpaased drongh a
soution, the
absbnee
5. wen uv io So,aleulali
Raoiaul boue u Aedueed, to
Sofn Io 50 x o = 0:5 Lo
Io 8olo As.
A dog1o;05 Io 2.

= 80
CaleulalT dhe abs obaee ,1
Sof4
So". A =
 he atuo liae lA)dnd le) the nspeelune
tV-dali
isome shes teals al 228
txplaig

(A)
(8)
eu the balis
uv- vsibe spetlhcscf
 Euehon's.
Seluel
Ju mest
4feol on uv-rs
Suitasle soeut
Wheh clses not absorlo in the key
me Huaut,
ns atualid butanone Cn-n-)
caloye cautnae
an faui tion
ranulion $tef nceases
selnanls (0, cleotls cte)
brlas
de to

-T due tonbordt
AE

none- pran 15rtent)

Mote pelan solveut
neeases wae
poleu

than ton dereases i e s e t e 7

buett deeares than T
ntbitalllgt onoe salbiized
prlarsolwas, Tbola inliacton. eRed slhl
nbialsde to dibete oifea
to
- Atsenttim m
b

AE
 Touble bond causes batioehaoneie s t

i)
kyslein Quladi wiel
doukle benols

j) Hetesannulan
dieves
e

doube bondsi- Aousle bonds freee

xoeyelie doile bond :- Qede bond in aieh a doby

double bond
endooyali
cdelble bnd
deulle bnd
doyal Exocyeli' doble bond to hing AA.
Wedo 4
Juay in dieues' iwee lalmoih'ed byt
knan e
oodwanl les firednale
at a
Ace. tot e hute tue abkoption ales place
Panetvalue conluilithon made by vatny
son :
subelituens, exoeyelui double bond, eudooyelie deule
 ane tahe
{ aa qenaslsyslin
eleot t te paet alue in pdee to
the uay

Panei va lues! As

() Cyelie cmyugaled o5nm

CAubilil uoil
Rosidue
(l Homcaynalan dble bord 5hm
)

(i)Ayilie diene () Doebo bend eylouotod 30n

(Y) HHeleoaynala
Auxoch o e

+30 n
() - sR
a,4-hexndilue!
Dnm

baoic wui substtuet

[uhstte butadie
base valee a m
Too allts = x5 =lonw
534
lfun Homelan dieue
Ama kesidue
3-ning
) Amay ta I, s- þendadieue Caluat:a3n
=75n

k butadieue
()
5
1-alkyl
Caleulat key2dnm e
Obsene

= 235Mm
ceened
 Ec-l
-£A303 K.
where
2303
Ecl =
T: 2-303
base Taley
kog
uteusil heide lo
nteiiy
4trantmiteet
to
sTransmlauee
Lo
) =A dL
called
ad
wheu
and
at
de
-dI
laubets Beer-
Hathenatealy
las to
rasmited I- heau
Ineideut
Monehmate
le
of
Enenget
be
6eau th wì
kelutie nen=
absebeug
Kadiateo-hal (dI)
(ol) me Hue ale meium aeau whn a
la: lambeiti Been-