NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom DPP: 1

Q1 The charge to mass ratio of electron was found is not su�cient.

to be (B) A nucleus has a much smaller volume than
−19 −1
(A) 1.6022 × 10 Ckg that of an atom.
−1
12
(B) 1.925 × 10 Ckg (C) The force of repulsion acting on the fast
−1
(C) 1.758 × 1011 Ckg moving α-particles is very small.
−1
(D) 1.869 × 1013 Ckg (D) The neutrons in the nucleus do not have any
e�ect on the α-particles.
Q2 When α-rays strike a thin gold foil then
(A) Most of the α-rays do not pass through the Q7 Discovery of the nucleus of an atom was due to
gold foil the experiment carried out by
(B) Most of the α-rays get deflected back (A) Bohr (B) Mosley
(C) Most of the α-rays get deflected through (C) Rutherford (D) Thomson
small angles
Q8 Rutherford's scattering experiment is related to
(D) Most of the α-rays pass through without any
the size of the
deviation
(A) Nucleus (B) Atom
Q3 Metal of which foil was used in (C) Electron (D) Neutron
Rutherford experiment?
Q9 Which of the following is not a part of
(A) Silver (B) Gold
the observations made by Rutherford in
(C) Platinum (D) Iron
his experiment?
Q4 The charge on the chemical species containing (A) Very few alpha particles deflected at small
7 protons, 8 neutrons and 8 electrons is angles.
(A) -1 (B) +1 (B) A large number of alpha particles bounced
(C) zero (D) -2 back completely.
(C) Only a few alpha particles were scattered at
Q5 Which is true?
large angles
(A) e/m values of cathode rays generated
(D) Most alpha particles passed straight through
by discharge of di�erent gases are di�erent
gold foil.
(B) (e/m) value of anode rays generated by
discharge of di�erent gases is same Q10 The canal rays led to the discovery of which
e
(C) ( m )proton > ( me )electron subatomic particle?
e
(D) ( m )proton > ( me )α− particle (A) Beta rays (B) Protons
(C) Neutrons (D) Electrons
Q6 When a gold sheet is bombarded by a beam of
Q11 Which has highest e/m ratio?
α− particles, only a few of them get deflected
(A) He2+
whereas most go straight, undeflected. This is
(B) H+
because
(C) He+
(A) The force of attraction exerted on the α−
(D) H
particles by the oppositely charged electrons

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Q12 Cathode rays have: depend upon the material of electrodes in

(A) mass only cathode ray tube.
(B) charge only (D) Characteristics of cathode rays depend upon
(C) neither mass nor charge the nature of gas present in the cathode ray
(D) mass and charge both tube.

Q13 Which of the following statement is not Q14 What are the essential conditions for
correct about the characteristics of cathode rays? the production of anode rays?
(A) They start from the cathode and move (A) High voltage and low pressure
towards the anode. (B) High voltage and high pressure
(B) They travel in straight line in the absence of (C) Low voltage and high pressure
an external electrical or magnetic field. (D) Low voltage and low pressure
(C) Characteristics of cathode rays do not

Answer Key
Q1 (C) Q8 (A)

Q2 (D) Q9 (B)

Q3 (B) Q10 (B)

Q4 (A) Q11 (B)

Q5 (D) Q12 (D)

Q6 (B) Q13 (D)

Q7 (C) Q14 (A)

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 NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom DPP: 2

Q1 Calculate the wavelength of a light whose time (D)

−8
period is 4 × 10 s
(A) 10m (B) 14m
(C) 12m (D) 8m

Q2 The number of photons of light of wavelength

7000Ao equivalent to 1 J are
Q5 The velocity of light is 3.0 × 108 ms−1 . Which
(A) 3.52 × 10−18
value is closest to the wavelength in nanometres
(B) 3.52 × 1018
of quantum of light with frequency of
(C) 50,000 15 −1
8 × 10 s
(D) 10,0000
(A) 3 × 107
Q3 A 100 watt bulb emits monochromatic light of (B) 2 × 10−25
wavelength 400 nm. Calculate the number of (C) 5 × 10−18
photons emitted per second by the bulb. (D) 3.7 × 10−8
(A) 2.022 × 1023
Q6 The frequency of a wave of light is
(B) 2.012 × 1020 14 −1
12 × 10 s . The wave number associated
(C) 20.21 × 1021
with this light is
(D) 22.06 × 1020
(A) 5 × 10−7 m−1
Q4 Which graph shows how the energy E of a (B) 4 × 10−8 cm−1
photon of light is related to its wavelengths (λ) ? (C) 2 × 10−7 m−1
(A) (D) 4 × 104 cm−1

Q7 Rank the following types of radiations from

the highest energy to the lowest. Ultraviolet/
visible/X- ray/microwave/infrared
(A) X-ray, ultraviolet, microwave, infrared, isible
(B) (B) ultraviolet, X-ray, visible, infrared, microwave
(C) infrared, microwave, ultraviolet, visible, X ray
(D) X-ray, ultraviolet, visible, infrared, microwave

Q8 The frequency of a green light is 6 × 1014 Hz.

Its wavelength is:
(C)
(A) 500 nm
(B) 5 nm
(C) 50, 000 nm
(D) None of these

Q9 The number of photons emitted in 10 hours by a

60 sodium lamp (λ of photon = 6000A∘ )

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(A) 6.50 × 1024 (II)

23
(B) 6.40 × 10
(C) 8.40 × 1023
(D) 3.40 × 1023

Q10 Light of wavelength λ strikes on a metal

surface with intensity X and metal emits Y (III)
electrons per second of average energy Z . What
will happen to Y and Z if X is doubled?
(A) Z will remain constant and Y will increase
(B) Both Z and Y will remain constant
(C) Z will decrease and Y will increase
(D) Both Z and Y will increase
(IV)
Q11 Which is the correct graphical representation
based on photoelectric e�ect?
(I)

(A) I and II (B) II and III

(C) III and IV (D) II and IV

Answer Key
Q1 (C) Q7 (D)

Q2 (B) Q8 (A)

Q3 (B) Q9 (A)

Q4 (D) Q10 (A)

Q5 (D) Q11 (D)

Q6 (D)

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 NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom
DPP: 3

Q1 Radius of Bohr's orbit of hydrogen atom is (A)

o o
(A) (B)
0. 24 A 0. 48 A
o o
(C) (D)
0. 53 A 1. 06 A

Q2 Bohr theory is not applicable for

(A) He+
(B) Li2+ (B)
(C) Be+
(D) H

Q3 Calculate the ratio of the radius of 1st orbit of

H atom to that of 4th orbit.
(A) 1 : 4 (B) 1 : 16
(C) 1 : 36 (D) 1 : 2 (C)

Q4 Ratio of the radius of first orbit of Li2+ to the third

orbit of He+ ions will be
(A) 1 : 5 (B) 2 : 5
(C) 3 : 8 (D) 2 : 27

Q5 Velocity for 1st orbit of H = x . Velocity for 2nd (D)

orbit of He+ =
(A) x
(B) 2x
(C) 3x
(D) 4x

Q6 Calculate ratio of velocities of 3rd and 4th orbit

Q8 Calculate energy of electron in He+ for 3rd orbit
of Li+2 and He+ respectively. 2
(A) −13.6 × 2 eV/ atom
(A) 2 : 1 9
2
(B) 1 : 2 (B) −2.18 × 10−18 × 2 J/ atom
9
2
(C) 1 : 3 (C) −1312 × 2 kJ/mol
9
(D) 3 : 1 (D) All of these

Q7 Select the incorrect graph for velocity of Q9 Calculate ratio of energy of 2nd orbit of He+ to
electrons in an orbit vs. Z, n1 and n . 3rd orbit of Li+2
(A) 1 : 2 (B) 2 : 3
(C) 3 : 1 (D) 1 : 1

Q10 In hydrogen atom, energy of first excited state is

- 3.4eV. Then find out KE of same orbit of

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hydrogen atom (B) − 49 × eV

(A) +3.4eV (C) +2xeV
(B) +6.8eV 9
(D) − 4 × eV
(C) −13.6eV
(D) +13.6eV Q12 Angular momentum of an electron moving in 5th
orbit is
Q11 In a hydrogen atom, if the energy of electron in (A) 10h
π
the ground state is −xeV. , then that in the 2 nd
(B) 5h
+ π
excited state of He is (C) 2.5h
π
(A) −xeV h
(D) 2π

Answer Key
Q1 (C) Q7 (D)

Q2 (C) Q8 (D)

Q3 (B) Q9 (D)

Q4 (D) Q10 (A)

Q5 (A) Q11 (B)

Q6 (A) Q12 (C)

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 NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom
DPP: 4

Q1 Electrons in a sample of H-atom from an excited the wavelength be minimum.

state returns to ground state in one or more (A) n = 6 to n = 4
steps show emission of 10 lines. How many of (B) n = 4 to n = 2
these belong to visible region? (C) n = 3 to n = 1
(A) 6 (B) 5 (D) n = 2 to n = 1
(C) 4 (D) 3
Q7 The wavelength of third line of the Balmer series
Q2 The number of lines obtained in the Lyman series for a H atom is
21
when an electron jumps from 6th orbit to 2nd (A) 100R
orbit is 100
(B) 21R
(A) 4 (B) 10 (C) 21R
100
(C) 15 (D) Zero (D) 100R
21
Q3 If the shortest wavelength of H-atom in Lyman Q8 When the electron of a hydrogen atom jumps
Series is ' X ' then the longest wavelength in from n = 4 to n = 1 state, the number of
Balmer Series of He+ is spectral lines emitted is
(A) 9X
5 (A) 15 (B) 6
(B) 38X
5 (C) 3 (D) 4
(C) X
4
(D) 5X Q9 The first emission line in the H-atom spectrum in
9
the Balmer series will have wave number:-
Q4 Third line of Balmer series is produced by (A) 5R
36
cm−1
which transition in spectrum of H-atom (B) 3R
4
cm−1
(A) n = 5 to n = 2 7R
(C) 144 cm−1
(B) n = 5 to n = 1 9R
(D) 400 cm−1
(C) n = 4 to n = 2
(D) n = 4 to n = 1 Q10 How many spectral lines are produced in
the spectrum of hydrogen atom from 5 th energy
Q5 The limiting line in Balmer series of hydrogen level?
atom will have a frequency of:- (A) 5 (B) 10
(A) 3.65 × 1014 sec−1 (C) 15 (D) 4
(B) 3.29 × 1015 sec−1
(C) 8.22 × 1014 sec−1 Q11 An electron jumps from 6th energy level to
14 −1 3rd energy level in H-atom, how many lines
(D) −8.22 × 10 sec
belong to visible region?
Q6 In which of the following transition will

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(A) 1 (B) 2 (C) 3 (D) Zero

Answer Key
Q1 (D) Q7 (B)

Q2 (D) Q8 (B)

Q3 (A) Q9 (A)

Q4 (A) Q10 (B)

Q5 (C) Q11 (D)

Q6 (C)

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 NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom
DPP: 5

Q1 Which wave property is directly proportional to

energy of electromagnetic radiation:
(A) velocity
(B) frequency
(C) wave number
(D) all of these (IV)

Q2 The relation between energy of a radiation and

its frequency was given by:
(A) de Broglie (B) Einstein
(C) Planck (D) Bohr

Q3 Which is not characteristic of Planck's (A) I and II (B) II and III

quantum theory of radiation? (C) III and IV (D) II and IV
(A) Radiation is associated with energy.
Q5 A certain metal when irradiated with light
(B) Energy is not absorbed or emitted in whole
(v = 3.2× 1016 Hz) emits photo electrons
number or multiples of quantum.
with twice kinetic energy as did photoelectrons
(C) The magnitude of energy associated with a
when the same metal is irradiated by light
quantum is proportional to the frequency.
(D) Radiation energy is neither emitted nor
(v = 2.0 × 1016 Hz). Calculate v0 of electron?
(A) 1.2 × 1014 Hz
absorbed continuously but in small packets
(B) 8 × 1015 Hz
called quanta.
(C) 1.2 × 1016 Hz
Q4 Which is the correct graphical representation (D) 4 × 1012 Hz
based on photoelectric e�ect?
Q6 In the emission of photoelectrons, the number of
(I)
photoelectrons emitted per unit time depends
upon
(A) energy of the incident radiation
(B) intensity of the incident radiation
(C) frequency of the incident radiation
(II) (D) wavelength of the incident radiation

Q7 What is the work function (w0 ) of the metal

whose threshold frequency (v0 ) is
14 −1
5.2 × 10 s ?
(A) 3.44 × 10−19 J
(III) (B) 34.4 × 10−19 J
(C) 0.344 × 10−18 J
(D) 3.03 × 10−19 J

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Answer Key
Q1 (D) Q5 (B)

Q2 (C) Q6 (B)

Q3 (B) Q7 (A)

Q4 (D)

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 NEET

Yakeen NEET (2025)

Physical Chemistry
Structure of Atom
DPP: 6

Q1 Calculate the momentum of the particle which in velocity is 0.011% ?

−10
has de Broglie wavelength 1 Å (10 m) and (A) 1.92 cm
−34 (B) 7.68 cm
h = 6.6× 10 J − sec .
−22
(A) 6.1 × 10 kg msec−1 (C) 0.175 cm
(B) 6.6 × 10−24 kg msec−1 (D) 3.84 cm
(C) 6.2 × 1023 kg msec−1
Q7 A ball of mass 200 g is moving with a velocity of
(D) 6.4 × 10−24 kg msec−1
10 m s−1 . If the in measurement of velocity is
Q2 If the kinetic energy of an electron is increased 4 0.1% , the uncertainty in its position is:
times, the wavelength of the Broglie (A) 3.3 × 10−31 m
wave associated with it would become: (B) 3.3 × 10−27 m
(A) 4 times (C) 5.3 × 10−25 m
(B) 2 times (D) 2.64 × 10−32 m
(C) 12 times
Q8 The Heisenberg's Uncertainty Principle states
(D) 14 times
that...
Q3 Which of the following has least de-Broglie (A) no two electrons in the same atom can
wavelength, moving with same speed? have the same set of four quantum numbers
−
(A) e (B) two atoms of the same element must have
(B) p the same number of protons
(C) CO2 (C) it is impossible to determine accurately both
(D) SO2 the position and momentum of an electron
simultaneously
Q4 Heisenberg uncertainity principle is not valid for (D) electrons of atoms in their ground states
(A) Moving electron enter energetically equivalent sets of orbitals
(B) Motor car singly before they pair up in any orbital of the
(C) Stationary particles set
(D) B and C both
Q9 If the uncertainty in the position of an electrons
Q5 If uncertainty in position and momentum are is zero, the uncertainty in its momentum be
equal then the uncertainty in velocity is? (A) Zero
−
−
(A) √ h h
(B) 2π
π
−
− h
(B) 1 √ h (C) 4π
2m π
−− (D) Infinity
(C) √ h
2π
−
− Q10 In the Schrodinger's wave equation ψ represents
(D) 1 √ h
m π (A) Orbit
(B) Wave function
Q6 Calculate the uncertainty in the position of
(C) Wave
an electron (mass 9.1 × 10−28 g ) moving with a
(D) Radial probability
velocity of 3 × 104 cmsec−1 , if the uncertainity

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Q11 The correct set of four quantum numbers of a (B) (b) < (d) < (a) < (c)
3d− electron is (C) (c) < (d) < (b) < (a)
(A) n = 3, ℓ = 2, m = 0, s = +1/2 (D) (c) < (d) < (b) < (a)
(B) n = 3, ℓ = 3, m = 0, s = +1/2
Q16 Which of the following is not
(C) n = 3, ℓ = 1, m = 2, s = +1/2
permissible arrangement of electrons in an atom?
(D) n = 3, ℓ = 1, m = 0, s = +1/2
(A) n = 5, ℓ = 3, m = 0, s = + 12
Q12 Consider the following sets of quantum numbers (B) n = 3, ℓ = 2, m = −3, s = − 12
(C) n = 3, ℓ = 2, m = −2, s = − 12
(D) n = 4, ℓ = 0, m = 0, s = + 12

Q17 Maximum number of electrons in a subshell with

l = 3 and n = 4 is
(A) 10 (B) 12
(C) 14 (D) 16

Q18 Which orbital has two angular nodal planes:

Which of the above sets of quantum numbers is
(A) s
not permissible?
(B) p
(A) II, III only
(C) d
(B) Only I
(D) f
(C) III and IV only
(D) II, III and IV Q19 Which configuration does not obey paulis
exclusion principle.
Q13 Orbital angular momentum of electron in
(A)
5 dz 2 orbital
–
(A) √5ℏ
– (B)
(B) √6ℏ
–
(C) √2ℏ
(C)
(D) Zero

Q14 Maximum number of electrons, that can be (D)

present in a d-orbital is
(A) 2 (B) 10
Q20 Which of the following configuration follows
(C) 8 (D) 6
the Hund's rule:-
Q15 The electrons identified by quantum numbers n (A)
and l
(B)
(a) n = 4, l = 1
(b) n = 4, l = 0
(c) n = 3, l = 2 (C)
(d) n = 3, l = 1
can be placed in order of increasing energy as (D)
(A) (d) < (b) < (c) < (a)

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Answer Key
Q1 (B) Q11 (A)

Q2 (C) Q12 (D)

Q3 (D) Q13 (B)

Q4 (D) Q14 (A)

Q5 (B) Q15 (A)

Q6 (C) Q16 (B)

Q7 (D) Q17 (C)

Q8 (C) Q18 (C)

Q9 (D) Q19 (B)

Q10 (B) Q20 (A)

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