aS RERE RRR Time Allowed: 3 hours] [Maximum Marks: 70 \ ‘questions ew ot? case-based questions et i) marks each. 1 E consists of 3 long answer questions carrying 5 marks each. are compulsory. ‘Use of log tables and calculators is not allowed. J section-a § The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1, Which of the following solutions will have the highest conductivity at 298 K? (@) 0.01 M HCI solution (6) 0.1 M HCI solution () 0.01 M CH,COOH solution (@) 0.1 M CH,COOH solution dil. NaOH q 2 A+B ——> CH=CH-C— Identify A and B: (a) A= L-phenylethanal , B = acetophenone (6) A = Benzophenone B = formaldehyde (c) A = Benzaldehyde , B = Acetophenone (d) A= Benzophenone , B = Acetophenone 3. The vitamins which can be stored in our body are: (2) Vitamin A, B, D and E (@) Vitamin A, C, D and K (©) Vitamin A, B, C and D (d) Vitamin A, D, E and K 4. What is IUPAC name of the ketone A, which undergoes iodoform reaction to give CH,CH=C(CH,)COONa and yellow precipitate of CHI, ? (a) 3-Methylpent-3-en-2one (b) 3-Methylbut-2-en- one (c) 2, 3-Dimethylethanone (@) 3-Methylpent-4-one . Which of the following is not correct? (@) In haloarenes, the electron pairs on halogen atom are in conjugation with n-electrons of the ring. and non-polar in nature. ‘ed in the slow step being sp? hybridised is pia, 1 is more reactive towards S,1 re; Mar, (b) The carbon-magnesium bond is covalent a (c) During S,1 reaction, the carbocation form« (d@) Out of CH,= CH—Cl and C,H,CH,Cl, C,H,CH,CI 6. Match the properties with the elements of 3d series: (@) lowest enthalpy of atomisation @) Sc (i) shows maximum number of oxidation (q) Mn (iii) transition metal that does not form co! Ne a ) Ti @ @ ©, @ @, Gi 6) © ©, @ ©) Gi) &) oO o CO Dey @ ©) @ O, Gi) &) 7. Which of the following statement is true? (@) molecularity of reaction can be zero or a fraction. (6) molecularity has no meaning for complex reactions. (c) molecularity of a reaction is an experimental quantity (@) reactions with the molecularity three are very rare but are fast. the cus is soluble; (©) water @) bromine water 1 with Lucas Reagent? ction states oured compounds 8. In which of the following solvents, (a) ether (®) acetone 9. Which of the following observation is shown by 2-phenyl ethanol (a) Turbidity will be observed within five minutes (6) No turbidity will be observed (c) Turbidity will be observed immediately (@) Turbidity will be observed at room temperature but will disappear after five minutes, (0. If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction if it follows zero - order kinetics is: (a) 0.00625 mol Ls (6) 0.00625 s* (c) 0.00578 molL's* —(d) 0.00578 s* 11. Anisole undergoes bromination with bromine in ethanoic acid even in the absence of iron (Ill) bromide catalyst (@) Due to the activation of benzene ring by the methoxy group. (6) Due to the de-activation of benzene ring by the methoxy group. (c) Due to the increase in electron density at ortho and para positions (@) Due to the formation of stable carbocation . 12. The trend of which property is represented by the following graph? 19 18 7 16 Radiusinm 15 14 13 12 Sc TV Cr Mn Fe Co Ni cu Zn (a) ionization enthalpy (b) atomic radii (c) enthalpy of atomization (4) ‘melting point For Visually Challenged Learners 12. Which of the following is not considered a transition element? (@ Scandium () SiWver (©) Vanadium (a) Zine13, Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A): Alcohols react both as nucleophiles and electrophiles. Reason (R): The bond between C-O is broken when alcohols react as nucleophiles. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A (6) Both A and R are true but R is not the correct explanation of A. (c) Ais true but R is false, (@) Ais false but R is true. 14, Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A): Strong oxidising agents oxidises toluene and its derivatives to benzoic acids. Reason (R): Itis possible to stop the oxidation of toluene at the aldchyde stage with suitable reagents. Select the most appropriate answer from the options given below: (@) Both A and R are true and R is the correct explanation of A (6) Both A and R are true but R is not the correct explanation of A. (©) Ais true but R is false. (@) Ais false but Ris true. 15. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion : Enzymes are very specific for a particular reaction and for a particular substrate. Reason : Enzymes are biocatalysts, Select the most appropriate answer from the options given below: (@) Both A and R are true and R is the correct explanation of A (©) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false. (d) Ais false but R is true. 16. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes, hydrogen gas is released at the cathode. Reason (R): The electrode potential of Cu?* (Cu is greater than th Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A (6) Both A and R are true but R is not the correct explanation of A. (c) Ais true but R is false. (d) Ais false but R is true. HH, J sections & This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. (a) Radioactive decay follows first - order kinetics. The initial amount of two radioactive elements X and Y is 1 gm each. What will be the ratio of X and Y after two days if their half-lives are 12 hours and 16 hours respectively? (6) The hypothetical reaction P + Q —=> R is half order w.r.t ‘P” and zero order w.r.t ‘Q’. What is the unit of rate constant for this reaction? 18. A5% solution of Na,SO,.10H,O (MW = 322) is isotonic with 2% solution of non- electrolytic, non- volatile substance X. Find out the molecular weight of X. 19, (a) Arrange the isomeric dichlorobenzene in the increasing order of their boiling point and melting () Explain why the electrophilic substitution reactions in haloarenes occur slowly and require more drastic conditions as compared to those in benzene. 20. (a) Out ofp-tolualdehyde and p-nitrobenzaldehyde ,which one is more reactive towards nucleophilic addition reactions, why?+ formed when acetone reacts with 2,4 DNP reagent (b) Write the structure of the produc! en Convert the following: (a) Benzene to m-nittoene (b) Bromobenzene to benzoic act ity of an individual. Which pro 1. (a) DNA fingerprinting is used PY toy, nelps inthe rowed? ron a native protein is subjected to change i change will occur whe oN? (@) What structural chang ee I) section - © ‘This section contains 7 questions with internal choice in one question. The following questions are 5, : he answer type and carry 3 marks ce ; it for the following coordination compoun ci Wi "yxidochromium(ILI) chloride (b) Does jonization isomer for the following compound exist? Justify your answer. ation complexes a Lewis acid or a Lewis base? Explsin HafCo(SCN) eal Is the central metal atom 1 © alf-cells composed of ZnSO, solution ang 23, (a) Can we construct am electrochemical Sine clectrodes? Explain your answers (b) Calculate the %), en below: ‘Ae, MgCl, = 258.6 Sem’mol? ‘and A!, Mge* = 106 Sem’mol (c) The cell constant of 146 cm’, What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm? 24, Write the name of the reaction, structure and IUPAC name of the product formed when (any 2) (a) Phenol reacts with CHI, in the presence of NaOH followed by hydrolysis. (0) CH,CH,CH(CH,)CH(CH,)ONa reacts with CHBr. {@) CHLCH,CN reacts with stannous chloride in the presence of hydrochloric acid followed by hydrolysis. "| 95, You are given four organic compounds “A’, “B", “C” and “p”, The compounds “A”, “B” and °C soaty orange- red precipitate with 2,4 DNP reagent. Compounds “A and “B” reduce Tollen’s reagent while compounds “C” and “D” do not. Both “B” and “C” give a yellow precipitate when heated with iodine in the presence of NaOH. Compound “D” gives brisk effervescence with sodiun eatoee solution. Identity “A’, “B”, “C” and “D” given the number of carbon atoms in three 7 these carbon compounds is three while one has two carbon atoms. Give an explanation for your 26, When sucrose is hydrolysed the of i WV )ptical rotation values a given in the following table: Valaes ate mentined e in coordin: I cell with two hi yolarimeter and are | 1 a (Aso for the two sede tation ales vat if : () hat te specie ae hen to sucrose asd on the above observation. Ds of te me formed during the hydrolysis of sucrose is a glucose, that re oe compound A. Identify compound A. ; tose : 2) An oanic compound A with the molecular formula +)C HBr undergoes hydrotysis 0 for A and write the mechanism of the reaction. The rate constants of a reacti reaction at 2 is value of E, (Given 2.303R = 19.15 Tae 10 fe dete eT acts wil? ateJ section-o § question has an internal choice and carries 4 ‘The following questions are case-based questions. Each ee (1+142) marks each. Read the passage carefully and answer the questions that 29. Crystal field splitting by various ligands Metal complexes show different colours due to d-d trans wavelength to promote the electron from f,, to ¢, level. The colour of th transmitted light, which is complementary of the colour absorbed. The wave number of light absorbed by different complexes of Cr ion are given below: ons. The con.plex absorbs light of specific 1¢ complex is due to the [Cra [crB,}* 17830 213 [oro 21680 259 [cD 26280 314 Answer the following questions: (@) Out of the ligands “A”, “B”, “C” and “D”, which ligand causes maximum crystal field splitti Why? OR Which of the two, “A” or “D” will be a weak field ligand? Why? (6) Which of the complexes will be violet in colour? [CrA,}> or [CrB,}* and why? (Given: If 560 - 570 nm of light is absorbed, the colour of the complex observed is violet.) (©) If the ligands attached to Cr°* ion in the complexes given in the table above are water, cyanide ion, chloride ion, and ammonia (not in this order) Identify the ligand, write the formula and TUPAC name of the following: @ [oAP Gi) [GrC P* 30. The lead-acid battery represents the oldest rechargeable battery technology. Lead acid batteries can be found in a wide variety of applications including small-scale power storage such as UPS systems, ignition power sources for automobiles, along with large, grid-scale power systems. The spongy lead act as the anode and lead dioxide as the cathode. Aqueous sulphuric acid is used as an electrolyte. The half-reactions during discharging of lead storage cells are: Anode: Pb(s) + SO (aq) —> PbSO, (s) + 2e- Cathode: PbO, (5) + 4H* (aq) + SO%; (aq) + 2 —+ PbSO,(s) + 2H,0 There is no safe way of disposal and these batteries end - up in landfills. Lead and sulphuric acid are extremely hazardous and pollute soil, water as well as air. Irrespective of the environmental challenges it poses, lead-acid batteries have remained an important source of energy. Designing green and sustainable battery systems as alternatives to conventional means remains relevant. Fuel cells are seen as the future source of energy. Hydrogen is considered a green fuel. Problem with fuel cells at present is the storage of hydrogen. Currently, ammonia and methanol are being used as a source of hydrogen for fuel cell. These are obtained industrially, so add to the environmental issues, If the problem of storage of hydrogen is overcome, is it still a “green fuel?” Despite being the most abundant element in the Universe, hydrogen does not exist on its own so needs to be extracted from the water using electrolysis or separated from carbon fossil fuels. Both of these processes require a‘The following questions are I 3. 33. which is currently more than that gained from the fy q ily requires the use of fossil fuels. More research j "drogen Despite the problem of no good means to cee cong ct Hy significant amount of energy addition, this extraction typical \ in this field to solve these problems. ica uniquely abundant and renewable source of ener, perfect for our future 2 AY ; €TO-carhon 8 “Answer the following questions: | (a) How many coulombs have been transferred from anode to cathode in order to cons, : Hiiphurte acid during te dscharging of Tad sr call? Me one during ie tracted by using lead storage cll feach cll delivers about 29 Me | OV of, ‘4 (b) How much worl (1 F = 96500 C) (0) Do you agree with the state! this statement and justify your views. OR cy funding scientific res icl agen 1g scientific research. Which of the followin, : 8 Pte, ment ~ “Hydrogen is a green fuel” Give your comments f 7 ot in, Imagine you are a member of an will you fund and why? (i) safe recycling of lead batteries (ii) extraction of hydrogen 4 section FE ong answer type and carry S marks each. All questions havean interna hic ‘Attempt any five of the following: (a) Which of the following ions wil Sci, Tit, Ti, Cu’, Zn?* which one will you prefer as a sacrificial electrode, y, 1 have a magnetic moment value of 1.73 BM. (b) In order to protect iron from corrosion, aaa? Why? (Given standard electrode potentials of Ni, Fe and Zn are -0.25V, -0.44 V 0.76 V respectively.) 7 um and manganese are 1592 and 1509 Kino! (©) The second ionization enthalpies of chvomi respectively. Explain the Iower value of Mn. (d) Give two similarities in the properties of Se and Zn. (@) What is actinoid contraction? What causes ‘actinoid contraction? in chromate ion and dichromate ion? () What is the oxidation state of chromium i (@) Write the ionic equation for reaction of KT with acidified KMnO,. (a) What i the effect of temperature on the solubility of glucose in water? (b) Ibrahim collected a 10mL each of fresh water and ocean water. He observed that one sample labeled “P” froze at 0°C while the other “Q” at -1.3°C. Ibrahim forgot which of the 0 soe “Q” was ocean water. Help him identify which container contains ‘ocean water, giving rationalization for your answer. (© Caleulate van't Hoff factor for an aqueous solution of K [Fe(CN),] if the degree of dsociasn (a) is 0.852. What will be boiling point of this solution if Hts concentration is 1 mol!” |) (K, = 0.52 K ke/mol) OR (a) What type of deviation from Roult’s Law is expect each other? What change in the net volume of the mixture is expect the deviation. (6) The vapour pressure of ire is 23.80 mm Hg. If non-volatile non-electrol the resu! pressure of the solution. An organic compound with molecular formula C,H,NO, exists in three isomeric forms, - in highest melting point of the three. ‘8 on reduction gives compound ‘B’ with molect! HN. 8 on treatment with NaNO,/FCI at 0-5 °C to form compound ‘C: On treating C with 1 ot | fis sonverted te D with formula C'H, , which on further reaction with CrO,Cl, followed ee forms ‘E’ it wt CH,O . Write the structure of compounds A to E . Write the chemical equations involv rived witb ed when phenol and aniline are : ese! ted? Graphically 1°?! pure water at a certain temperatu 0.1 mole lytic solute is dissolved in 100g water, Calculate tant vapor the isomet™ Jar for |)OR (a) Account for the following: (i) N-ethylbenzene sulph (ii) Reduction of nitrobenzene using Fe and HCl is pre (b) Arrange the following in: (i) decreasing order of pK, values C,H.NH, C,H,NHCH,, C,H,CH,NH,, CH,NH,, NH, (ii) increasing order of solubility in water C,H, Cl, C,H,NH,, C,H,OH (iii) decreasing boiling point CH,COOH, C,H,OH, CH,NH,, CH,OCH, onyl amide is soluble in alkali . ferred over Sn and HCl.