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Acid Base Titrations - Worksheet

The document contains a worksheet on acid-base titrations with various problems and calculations related to titration volumes, pH at different stages, and the use of indicators. It includes specific examples involving sulfuric acid, hydrochloric acid, and other acids, along with their corresponding NaOH solutions. Answers to the problems are provided at the end of the document.

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26 views

Acid Base Titrations - Worksheet

The document contains a worksheet on acid-base titrations with various problems and calculations related to titration volumes, pH at different stages, and the use of indicators. It includes specific examples involving sulfuric acid, hydrochloric acid, and other acids, along with their corresponding NaOH solutions. Answers to the problems are provided at the end of the document.

Uploaded by

nicoleenchant565
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Acid Base Titrations

Worksheet

Organic Chemistry Tutor


1. 28.9 mL of H2SO4 was completely titrated with 3. 50 mL of a 1 M HCl solution is titrated with a
38.4 mL of a 0.250 M NaOH solution. What is the 0.50 M NaOH solution. (a) Calculate the volume of
concentration of H2SO4? the NaOH solution needed to reach the
equivalence point. (b) What is the pH of the HCl
solution before any NaOH is added? (c) What is the
pH of the solution after 30 mL of NaOH has been
added? (d) What is the pH at the equivalence
point? (e) What is the pH of the solution after 125
mL of NaOH has been added?

2. 23.6 mL of a 0.460 M monoprotic acid solution


was titrated with a 0.190 M NaOH solution. What
is the volume of NaOH that should be added to the
solution to reach the equivalence point?
4. 100 mL of a 0.50 M HOCl solution is titrated with 5. 50 mL of a 1.0 M NaC2H3O2 solution is titrated
a 0.250 M NaOH solution. (a) Calculate the volume with a 0.50 M HCl solution. (a) Calculate the
of NaOH needed to reach the equivalence point. volume of HCl needed to reach the equivalence
Calculate the pH when the volume of NaOH added point. Calculate the pH when the volume of HCl
to the solution is (b) 0 mL (c) 50 mL (d) 100 mL added to the solution is (b) 0 mL (c) 40 mL (d) 100
(e) 200 mL (f) 225 mL (The Ka for HOCk is 3.5 x 10-8) mL (e) 110 mL (The Ka for HC2H3O2 is 1.8 x 10-5)
6. Bromthymol blue changes from yellow to blue as 7. Which indicator should be used for the titrations
the pH of the solution increases. The Ka value for shown below?
this indicator is 1 x 10-7. What is the color of a
solution with this indicator if the pH is (a) 4.0 (b) Indicator Ka Hin to In-
7.0 (c) 9.0? (d) At what pH will the first color Methyl Orange 3.4 x 10-4 Red to Yellow
change be visible for a weak acid – strong base Methyl Red 7.9 x 10-6 Red to Yellow
titration using this indicator? (e) What about a Bromthymol Blue 1.0 x 10-7 Yellow to Blue
weak base – strong acid titration? Phenolphthalein 5.0 x 10-10 Clear to Pink
8. Which of the following statements is false? 10. Use the titration curve shown below to answer
the following questions. (a) What is the Ka of the
weak acid? At which of the point(s) shown on the
A. The pH is equal to the pKa at one half of the graph is (b) [HA] = [A-]? (c) [HA] < [A-]? (d) [HA] >
volume needed to reach the equivalence point for [A-]? (e) What is the pH of the solution at the
a weak acid – strong base titration. equivalence point?

B. The pH at the equivalence point is less than 7


when a solution of HF is titrated with NaOH.

C. The pH at the equivalence point is equal to 7 for


a strong acid – strong base titration.

D. The pH of the solution is always decreasing for a


weak base – strong acid titration.

E. [A-] = [HA] at one half of the volume needed to


reach the equivalence point for a weak base –
strong acid titration.

9. Which titration will have an equivalence point 11. A 10 mL buffer solution has a pH of 5. A
with the highest pH? separate 10 mL solution of HCl has a pH of 1.
(a) What will be the pH of the solution if 90 mL of
water is added to the 10 mL buffer solution?
A. 0.50 M HCl and 0.50 M KOH (b) What will be the pH of the solution if 90 mL of
B. 0.10 M NH4Cl and 0.10 M KOH water is added to the 10 mL HCl solution?
C. 1.0 M NH3 and 1.0 M HCl
D. 0.50 M NH4Cl and 0.50 M KOH
E. 2.0 M NH3 and 1.0 M HCl
12. A 100 mL solution consists of 0.1 M HNO3 and 13. The pH curve below shows the titration of two
0.1 M HNO2. Which of the following species will different weak acids HA and HB undergoing a
increase in concentration if 25 mL of a 0.1 M KOH titration by a strong base. Which of the following
solution is added to the mixture containing HNO3 statement(s) is true?
and HNO2?
I. HA is a stronger acid compared to HB.
II. HB has a higher Ka value than HA.
A. H3O+ III. HA has a higher pKa value than HB.
B. NO3-
C. NO2-
D. HNO2
E. HNO3

A. I Only
B. II Only
C. II & III
D. I & III
E. I, II, & III
14. Which of the following statement(s) is true? 15. Which of the following acids correspond to the
pH curve shown below when titrated with KOH?
I. The pH is equal to the pKa of the weak acid at
one-half the volume of the equivalence point of a
weak acid – strong base titration.

II. [HA] = [A-] at ½ the volume of the equivalence


point of a weak base – strong acid titration.

III. The pH is equal to the pKa of the weak acid at


twice the volume of the equivalence point of a
strong acid – weak base titration.

A. I Only
B. I & II
C. II Only
D. III Only
E. I, II, & III A. HCl
B. H2SO3
C. H3PO4
D. HBr
E. NH4Cl
Answers:
1. 0.166 M 12. C
2. 57.1 mL 13. A
14. E
3a. 100 mL 15. B
3b. pH = 0
3c. 0.359
3d. 7
3e. 12.85

4a. 200 mL
4b. 3.88
4c. 6.98
4d. 7.46
4e. 10.3
4f. 12.3

5a. 100 mL
5b. 9.37
5c. 4.92
5d. 2.61
5e. 1.51

6a. Yellow
6b. Greenish
6c. Blue
6d. pH = 6
6e. pH = 8

7a. Bromthymol Blue


7b. Phenolphthalein

8. B
9. D

10a. Ka = 1 x 10-5
10b. B
10c. C, D, and E
10d. A
10e. pH = 9

11a. pH = 5. Diluting a buffer solution will have no effect on the pH.


11b. pH = 2.

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