2 SAMPLE PAPER For Revision

Notes
(Easy Conceptl
Hours] |Maximum Marks: 70
Tine Allowed: 3
General Instructions:
Readthe following instructions carefully.
ia) There are 33 questions in this question paper with internal choice.
A SECTION Aconsists of 16 multiple-choice questions carrying 1 mark each.
(c)SECTION Bconsists of 5 short answer questions carrying 2 marks cach.
i SECTION Cconsists of 7 short answer questions carrying 3 marks each.
le) SECTION D Consists of 2 case-based questions carrying 4 marks each.
A SECTION E consists of 3 long answer questions carrying 5 marks each.
() All questions are compulsory.
A Use of log tables and calculators is not allowed.

SECTION -A
The following questions are multiple-choice questions with one correct answer. Each question carries
1mark. There is no internal choice in this section.
1. The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is
0.0225, the mole fraction of non-volatile solute is
(a) 0.80 (b) 0.725 (c) 0.15 (d) 0.0225
2. Which of the following is most reactive towards S1 reaction?
(a) CH,Cl (6) CH,-CH,CI
(c) CH,CH,CI (d) CH,-CH-CH,
C
3. Match the following:
ColumnI Column II

(p) High third lonisation enthalpy (i) Charge transfer from ligand to metal
(9) Orange colour of K,Cr,0, (ii) CrO,
(r)Acidic oxide (iüi) Mn

(a) p- () q - (ii) r- (ii) (b) p- (iii) q-(i) r- ()

(c) p- (ii) q -)r- (ü) (d) p-(i) q- (üü) r-(@)
4. Which of the following has lowest boiling point?
(b) 2-Bromo butane
(a) 1-Bromo butane
(c) 1-Bromo-2-methyl propane (d) 2-Bromo-2-methyl propane

å, Sample Papers 67
 5. The half life of O is 123 scconds and O is 29 seconds, which of the isotope has
constant? higher
(a) o (6) "o
(c) Botlh will have same rale constant (d) Can't be predicted
6. Acetophenone and Benzophenonc can be distinguished by
(a) Fehling's test (b) Tollen's test (c) lodoform test (d) Schiff'sreagent tes
7. Which of the following is diamagnetic in nature?
(a) Co* in octahedral complexX with strong field ligand
(b) Co* in octahedral complex with weak field ligand
(c) Co in square planar complex
(d) Co'+ in tetrahedral
complex
8. Which of the following is not true
about glucose?
(a) It is an aldohexOse
(b) Itgives 2,4-DNP test
(c) It is present in pyranose form
(d) On heating with HI it gives
9. Which of the following has n-hexane
lowest magnetic moment?
(a) Fe2+ (b) Co2+ (c) C+ (d) Ni'+
(Atomic number of Fe = 26, Co = 27, Cr = 24, Ni =
10. Which of the following is 28)
correct plot between In k and 1/T?
In A
Intercept =In A
Ink Slope = -E,
Slope = -E,
R
(a)
(b) log k 2.303 R

T 1
T
-In A

(c) log k +E,a

(a) log k Slope =
R
Slope
R

11.
T
Which of the following
statement is correct about amines?
(a) Aniline is more basic
than NH,
(b) (C,H),NH is more basic
than (C,H),N in gaseous state.
(c) Aniline is o and
p-directing towards electrophilic
(d) Aniline gives
p-toluidine on reaction with CH,Cl substitution
and AlCI,.
reactions.

68
Together with EAD Chemistry--12
 The IUPAC name of CH,--CH,-His
(a) 1-0xobutanol-3-one (b) 1-0xobutanal
(c) 3-0xo butanal (d) 3-0xo butanone
following questions (Q. No. 13 - 16), a statement of assertion followed by statement of a reason
Inthe
given. Choose the correct answer out of the following choices.
is
Both A and R are true and Ris the correct explanation of A.
(a)
and RRare true but R is not the correct explanation of A.
(b) Both A
R is false.
(c) A is true but
but Ris true.
(d) Ais false
Assertion (A): Linkage isomerism arises in coordination compounds containing ambidentate
ligand.
13.
Reason (R): Ambidentate ligand has two same donor atoms.
14 Assertion (A): LDuring electrolysis of aq. NaCI, Hydrogen is released at cathode.
Reason (R): CI, is liberated at anode.
reduces Tollen's reagent.
16. Assertion (A): Fructose does not contain aldehyde group still
to form glucose and mannoSe.
Reason (R): In presence of a base, fructose undergoes rearrangement
same for complex reaction.
16, Assertion (A): Order and molecularity of reaction are always
applicable to elementary reactions
Reason (R): Order is determined experimentally and molecularity is
only.

SECTICN - B
very
choice in one question. The following questions are
This section contains 5 questions with internal
markS each.
short answer type and carry 2 aqueous
mm Hg. Calculate the vapour pressure of
17. Vapour pressure of water at 293 K is 17.536 dissolved in 500g of water.
180 g/mol) is
solution when 20 g of glucose (Molar mass =
OR
solution after mixing.
mL of chloroform, what will be volume of
On mixing 10 mL of acetone and 50
solution? Explain your observation.
What happens to temperature of
following complex:
18. (a) Write IUPAC name of the
(Co(NH,),CIjd, coordination entities?
rarely observed for tetrahedral
(b) Why are low spin configuration becomes greater than E ?
What happens if external emf applied
19. Define electrochemical cell. (any two)
20. How will you convert:
chlorobenzene
() Benzene to m-nitro
cyclohexene
(ü) Cyclohexene to 3-chloro
(ii) Aniline to chlorobenzene
21. Differentiate between the following:
non-essential amino acids
(a) Essential and
protein
(b) Fibrous and Globular
Sample Papers 69
 SECTION - C

This section contains 7 questions with internal choice in one question. The following questions are
answer type and carry3 marks each. shom
22. (1) Calculate the cellemf for the following cell reaction at 298K for the cell:
Mg(s)| Mg' (0.01 M)|| Sn"(0.1 M)| Sn(s)
Pce = 2.204 V, log 10 = 1]
(i) On thebasis of E values identify which amongst the following is the
strongest oxidising a
C, + 2e ’ 2CI (E = 1.36 V]
MnO, + 14H + 5e ’ Mn* + 4H,0 E = 1.51 V]
Cr,0 + 14H* + 6e 2C-* + 7H,0 [E = +1.33 V]
23. (a) Write any one consequence of lanthanoid contraction.
(b) Name the element of 3d series which
exhibits the largest number of oxidation states. C
reason.

(c) EM2+Mo Value is highly negative as compared to other

elements. Why?
24. An organic compound 'A with molecular
formula C,H,0, was hydrolysed with dil. H,SO, to give
carboxylic acid Band an alcohol 'C.'C, on dehydration gives ethene and Con oxidation give:
back B. Identify A, B,C and write the chemical
equations for the reactions involved.
OR
Identify A and B the following reactions:
(a) CH,CH,0H Cro, (i) dil. NaOH
’ B'
(i) heat
CH,
(b) () KMnO,(KOH/A
A ’B
(üi) Ht
Conc.
(c) + CO + HCI AICI, A Heat, HNO,
B
25. (a) What is meant by conc. H,S0,
mutation in DNA?
(b) What is major function of
DNA?
(c) Give two structural
26. (a) Out of tert. butyl
differences between DNA and RNA.
alcohol and n-butanol, which one undergo acid catalysed
and why? dehydration faster
(6) Carry out the following
(i) Phenol to
conversions:
(iü) Tert. butyl benzoquenone
chloride to tert. butyl ethyl ether
27. Primary alkyl halide A
B is reacted with HBr to(CH,Br) is treated with alcoholic KOH to give
give C which is an isomer of A. compound 'B. Compound
When A is reacted with sodium
gives a compound D(C,H,) which is different from the metal it
is reacted with sodium.
Give compound formed
structural formula of A, B,C and D' and write when n-Butyl bromide
all the reactions
involved. the equations for
28. The resistance of the
the resistance of same conductivity cell filled with 0.1
cell when filled with 0.02 mol Lmol L KCI solution is 100 ohms. If
the conductivity and molar KCI solution is 520 ohms,
0.1 mol L' KCl solution is 1.29conductivity of 0.02 mol L KCI calculate
× 10 S cm. solution. The conductivity of
70
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 SECTION -D
and carries 4
The following questions are case-based questions. Each question has an internal choice
(2+1+1) marks each. Read the passage carefully and answer the questions that follow.
Chemical kinetics deals with rate of chemical reactions, how fast reactants get used up or how
29. different speed. Rate
fast products are formed in the reaction, Different chemical reactions have
especially in gaseous
of reaction depends upon concentration of reactants, temperature, pressure
reactions and presence of catalyst. Chemical reaction takes place as a results of collision betwen
collisions rather
reacting molecules. The rate of reaction does not depend upon total number of -ve
is 4ve, AG will be
it depends upon number of effective collisions. In a redox reaction, if Pmore than the reactants.
and 'K equilibrium constant will be high i.c, Droducts formed will be 10"s.
Constant) are 3 X
(a) k (The rate constant), (Activation Energy) E, and 'A (Arrhenius
104.4 kJ mol and 6.0 × 10 s respectively. What is value of k' when T’?
(h) What represents fraction of molecules possessing E, or more than E,?
OR
effective collisions.
Give twO conditions which must be satisfied by molecules to undergo
(c) What is activation energy?
for strong electrolytes KCI, NaCI, MgSO:
30. Rachit is investigating valuesof van't Hoff factor i different concentrations.
at various concentrations. He recorded the following values of
Values of i van't Hoff factor i for comnplete
dissociation of solute
Salt 0.01 m 0.001 mn
0.1 m
1.97 2.0
NaCI 1.87 1.94
1.98 2.0
KCI 1.85 1.94
1.82 2.0
1.21 1.53
MgSO, 3.0
2.32 2.70 2.84
K,SO,
the questions that follow:
Observe the table carefully and answer
solution and explain.
Vs van't Hoff factor for NaCl
(a) Plot a graph between molality
van't Hoff factor?
(b) Which of the following has highest (iv) K,SO,
(i) NaCi (ü) KCI (ii) MgSO4
is the value of van't Hoff factor (i) if K,Fe(CN)1is 50% ionised?
(c) What (v) 5
(iü) 3 (üi) 4
(i) 2 OR
degree of ionisation?
(c) If value of is 2.84 for K,SO,, what is (iv) 98%
(i) 94% (üi) 96%
() 92%
SECTION E

carry5marks each. All questions have an internal choice.

The following questions are long answer types and
reducing agent?
31. (a) () Why is Fe good 3d series?
lowest in
(ü) Why is density of Sc complexes:
hybridisation and magnetic characters of following
(b) Write the
() [Fe(CN),
() (CoF,j
(ii) [Ni(CO)J = 26, Co = 27, Ni =
28)
(Atomic number of Fe
Sample Papers
 OR
(a) ) Why is Nio basie where as Ci0, is acidic oxide?
(n) Name anactinoid which shows +7oxidation state.
(0) 0) What is the differece between double salt and complex compound?
(0) DiscuNs the shape, hybridisation and magnetic behaviour of (Cu(NH,)J on the
basis.
valence bond theony.
32. (a) ) Aniline is weaker base as compared to0 ethanamine, Why?
() How is aniline purified? Give reason.
(m) Aronatic amines cannot be preparcd by Gabriel phthalimide
(b) Why are amides less basic than amines?
synthesis? Give reason.
(c) Why is aniline insoluble in water?
OR
(a) How will you carry out following conversions:
(i) Nitrobenzene to Acetanilide
(ü) Aniline to Toluene
(iü) Methanamine to Ethanamine.
(b) Write chemical reaction involved in
(i) Gabriel phthalimide synthesis
(ii) Coupling reaction
33. (a) Draw the structure and name the
product formed if the following alcohols are
that an excess of oxidising agent is
used. oxidised. Assume
() CH,CH,CH,CH,0H (ii) 2-butenol
(b) Draw the structure of the (ii) 2-methyl-1-propanol
following derivatives:
(i) 2,4-DNP of benzaldehyde
(ii) Propanone oxime
OR
(a) Predict the products of the
following reaction:
() CH, CH=CH, B,H, ()
(i) 3H,0,/0H ’?
(i) CHOH Br,(aq)’?
(i) CH,CH,OH Cu/S73K
’?
(b) How willyou convert ethanal into following
) Ethanol compounds?
(i) Ethane

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