ALDEHYDES KETONES & CARBO.
ACID CLASS XII MCQ Hasin Ahmed Dekho seekho jano 9425761832
Q.N. Question Answer
1.
Addition of water to alkynes occurs in acidic medium and the presence of Hg2+ ions as a catalyst. Which
of the following products will be formed on addition of water to but-1-one under these conditions.
2. 2. Which of the following compounds is most reactive towards nucleophilic addition reactions?
3. The correct order of increasing acidic strength is _____________.
i) Phenol < Ethanol < Chloroacetic acid < Acetic acid (ii) Ethanol < Phenol < Chloroacetic acid < Acetic acid
(iii) Ethanol < Phenol < Acetic acid < Chloroacetic acid (iv) Chloroacetic acid < Acetic acid < Phenol < Ethanol
4.
Compound can be prepared by the reaction of _____________.
(i) Phenol & benzoic acid in presence of NaOH (ii) Phenol & benzoyl chloride in presence of pyridine
(iii) Phenol & benzoyl chloride in presence of ZnCl2 (iv) Phenol & benzaldehyde in presence of pd
5. The reagent which does not react with both, acetone and benzaldehyde.
(i) Sodium hydrogen sulphite (ii) Phenyl hydrazine (iii) Fehling’s solution (iv) Grignard reagent
6.
Cannizaro’s reaction is not given by _____________
7.
Which product is formed when the compound is treated with concentrated
aqueous KOH solution?
8.
Structure of ‘A’ and type of isomerism in the above reaction are respectively.
(i) Prop–1–en–2–ol, metamerism (ii) Prop-1-en-1-ol, tautomerism
(iii) Prop-2-en-2-ol, geometrical isomerism (iv) Prop-1-en-2-ol, tautomerism
9.
(i) identical (ii) positional isomers (iii) functional isomers (iv) optical isomers
10. Which is the most suitable reagent for the following conversion?
(i) Tollen’s reagent (ii) Benzoyl peroxide (iii) I2 and NaOH solution (iv) Sn and NaOH solution
11. Which of the following compounds will give butanone on oxidation with alkaline KMnO4 solution?
(i) Butan-1-ol (ii) Butan-2-ol (iii) Both of these (iv) None of these
12. In Clemmensen Reduction carbonyl compound is treated with _____________.
(i) Zn amalgam + HCl (ii) Na amalgam + HCl (iii) Zn amalgam + nitric acid (iv) Na amalgam + HNO3
13. Which of the following compounds do not undergo aldol condensation?
14.
Treatment of compound with NaOH solution yields
(i) Phenol (ii) Sodium phenoxide (iii) Sodium benzoate (iv) Benzophenone
15. Which of the following conversions can be carried out by Clemmensen Reduction?
(i) Benzaldehyde into benzyl alcohol (ii) Cyclohexanone into cyclohexane
(iii) Benzoyl chloride into benzaldehyde (iv) Benzophenone into diphenylmethane
16. Through which of the number of the following reactions of carbon atoms can be increased in the chain?
(i) Grignard reaction (ii) Cannizaro’s reaction (iii) Aldol condensation (iv) HVZ reaction
17. Benzophenone can be obtained by ____________.
(i) Benzoyl chloride + Benzene + AlCl3 (ii) Benzoyl chloride + Diphenyl cadmium
(iii) Benzoyl chloride + Phenyl magnesium chloride (iv) Benzene + Carbon monoxide + ZnCl2
ANSWERS – MCQ 1 2 3 4 5 6 7 8 9 10
HALOALKANE & HALOARENES II I III II III IV II IV II III
11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
II I II, IV II,III II,IV I,III I,II
BY- HASIN AHMED Dekho seekho jano PGT CHEM KV BAIRAGARH 9425761832
