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CHM1046L Exp 1 Part IV Data Sheet

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49 views

CHM1046L Exp 1 Part IV Data Sheet

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Maryam
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© © All Rights Reserved
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DATA SHEET

Name Saif Ahmed Date 30/10/22

Lab Partner ______________ Instructor Dr. Sylvia Riviello

E X P E R I M E N T 1 : P a r t IV: Qualitative Analysis of Sulfide


Group Cations
Rerecord data for this experiment, for each step you must record which reagent is added, then
you record your observation, write chemical reaction for each step and indicate the phase for
reactant and product. Which ones are soluble and which ones are precipitate.

Part added reagent observation chemical reaction soluble precipitate

A-2 6 M NaOH and Precipitates 1. Fe3+ (aq) + 3OH− (aq) → √ √


placed in hot water formed Fe(OH)3 (s) Al3+ and Fe3+ and
bath Cr3+ ion Mn2+ form
2. Mn2+ (aq) + 3OH− (aq) dissolves precipitates
→ Mn(OH)2 (s) in the while
solution.
3. Al3+ (aq) + 4OH− (aq) →
Al(OH)4− (aq)

4. Cr3+(aq) + 4OH− (aq) →


Cr(OH)4 − (aq)
A-3 No reagent is added. Precipitates √ √
Centrifugation was separated
performed from clear
solution
A-4 6 M HNO3 Precipitates Fe(OH)3 (s) + 3HNO3 (aq) → √
dissolves Fe(NO3)3 (aq) + 3H2O (l)
Mn(OH)2 (s) + 2HNO3 (aq) →
Mn(NO3)2 (aq) + 3H2O (l)

B Bacl2 Pale yellow Ba2+ (aq) + CrO42- (aq) → √


precipitates BaCrO4 (s)

C-1 Placed in hot water precipitates 1. Fe3+(s) → Fe3+(aq) √


dissolves
2. Mn2+ (s) → Mn2+ (aq)
C-2 sodium bismuthate Purple color 2 Mn(NO3)2 (aq) + 5NaBiO3 √
solution (aq) + 14HNO3 (aq) →
2NaMnO4 (aq) + 5Bi(NO3)3
(aq) + 7H2O (l) + 3NaNO3 (aq)
C-3 centrifuged Precipitates √ √
separated
from clear
solution
C-4 0.2 M KSCN Dark red Fe(NO3)3 (aq) + KSCN (aq) → √
color [FeSCN]2+(aq) + K+ (aq) +
solution 3NO3- (aq)

Note:

In A-2, A-3 and C-3 I selected both soluble and precipitates, because some of the sample
dissolves and some in present as precipitates.
Write a rationale explaining how you determined which cations are absent and which are present.
Rational must explain stepwise how the observations prove the presence.

In order to check the presence of iron, chromium and manganese in the sample, following
steps will be followed.
 20 drops of mixture or unknown sample will be taken in a test tube.
 10 drops of NaOH will be added and mix well.
 Test tube will be placed in a water bath and centrifuged for 1 minute.
 Supernatant will be taken in a separate test tube.
 If there will be chromium in the sample it will be present in the supernatant, in order to
confirm its presence 2 drops of hydrogen peroxide and barium chloride will be
added into it. The appearance of yellow precipitates will confirm the presence of
chromium.
 The precipitates initially obtained after addition of NaOH will be tested further to
check the presence of iron and manganese in the sample. First of all precipitates will be
dissolved by adding nitric acid and then obtained solution will be divided into two
parts.
 In first half we will add sodium bismuthate and the appearance of purple color will
confirm the presence of manganese in the sample.
 In the second half solution we will add potassium thiocyanate and the appearance of
blood red color will confirm the presence of iron in the sample.

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