Note 3 -MEB4033- Forming and Shaping of Plastics and Composite Materials - Sept 2022
Note 3 -MEB4033- Forming and Shaping of Plastics and Composite Materials - Sept 2022
ASSESSMENT
2
Appraise various surface treatments and coatings that can be
performed for technical and aesthetic reasons subsequent to
manufacturing a part.
1 2 3 4 5 6 8 - 12
Forming and shaping Forming and Shaping Forming and Shaping of Manufacturing Operation
Introduction process of metals of Ceramic, Glasses Plastics and Composite Manufacturing industries and
Rolling of metals and Metal Powder Materials products
Fundamental of materials:
Behaviour and manufacturing Forging of metals Injection molding Product / production relationships
properties Shearing Shaping ceramics Extrusion Production concepts and
WEEK 1 Bending and drawing Forming and shaping Processing of metal mathematical models
of glasses matrix composites Cellular Manufacturing
WEEK 2 and 3 Strengthening and WEEK 5 and 6
annealing glasses WEEK 8 - 12
WEEK 4
What is a Polymer?
Poly mer
many repeat unit
repeat repeat repeat
unit unit unit
H H H H H H H H H H H H H H H H H H
C C C C C C C C C C C C C C C C C C
H H H H H H H Cl H Cl H Cl H CH3 H CH3 H CH3 Adapted from Fig. 14.2, Callister & Rethwisch 8e.
Polyethylene (PE) Poly(vinyl chloride) (PVC) Polypropylene (PP)
Polymer Composition
MOLECULAR WEIGHT
• Molecular weight, M: Mass of a mole of chains.
Not all chains in a polymer are of the same length — i.e., there is a distribution of molecular weights
Low M high M
Polyesters Polyurethanes
Rubbers (Natural)
Phenolic
Acrylics
Silicones (Synthetic)
Epoxy resins
Nylons
Polyesters Polyurethanes
Acrylics
Polymer Additives
Improve mechanical properties, processability, durability, etc.
• Fillers
• Added to improve tensile strength & abrasion resistance, toughness & decrease cost
• ex: carbon black, silica gel, wood flour, glass, limestone, talc, etc.
• Plasticizers
Added to reduce the glass transition temperature Tg below room temperature
– Presence of plasticizer transforms brittle polymer to a ductile one
– Commonly added to PVC - otherwise it is brittle
• Stabilizers • Lubricants
• Antioxidants – Added to allow easier processing
• UV protectants – polymer “slides” through dies easier
– ex: sodium stearate
Polymer is heated to a highly plastic state and forced to flow under high pressure into
a mold cavity where it solidifies; molded part is then removed from cavity
• Produces discrete components almost always to net shape
• Typical cycle time 10 to 30 sec, but cycles of one minute or more are not uncommon
• Mold may contain multiple cavities, so multiple moldings are produced each cycle
• Injection molding is the most widely used molding process for thermoplastics
• Some thermosets, elastomers, metals and ceramics are also injection molded
• Modifications in equipment and operating parameters must be made
Injection Molding Cycle: Stage 1 (mold is closed) Injection Molding Cycle: Stage 2 (melt is injected into cavity)
Injection Molding Cycle: Stage 3 (screw is retracted) Injection Molding Cycle: Stage 4 (mold opens and part is ejected)
Dc = Dp + DpS + DpS2
• The control of processing parameters such as extruder-screw rotational speed, barrel-wall temperatures,
die design, and rate of cooling and drawing speeds are important in order to ensure product integrity and
uniform dimensional accuracy.
• Die shape is important, as it can induce high stresses in the product, causing it to develop surface
fractures (as also occur in metals).
• The shape of the die orifice determines the cross-sectional shape of the extrudate
• Common die profiles and corresponding extruded shapes:
• Solid profiles
• Hollow profiles, such as tubes
• Wire and cable coating
• Sheet and film
• Filaments
• Fig 19.3 shows the common extrusion die geometries: (a) coat-
hanger die for extruding sheet; (b) round die for producing rods;
and (c) and (d) nonuniform recovery of the part after it exits the
die.
• The control of processing parameters such as extruder-screw rotational
speed, barrel-wall temperatures, die design, and rate of cooling and
drawing speeds are important in order to ensure product integrity and
uniform dimensional accuracy.
• Die shape is important, as it can induce high stresses in the product,
causing it to develop surface fractures (as also occur in metals).
Vacuum thermoforming: (1) a flat plastic sheet is Vacuum thermoforming: (2) sheet is Vacuum thermoforming: (3) vacuum
softened placed over mold cavity draws sheet into the cavity
Process Capabilities
• Three types of compression molds are available:
1. Flash type: for shallow or flat parts
2. Positive type: for high-density parts
3. Semipositive type: for quality production
COMPOSITES
Spheroidite steel
Matrix ferrite
(a) ductile Continuous Discontinuous Sandwich panels Laminates
Particle (aligned)
cementite
(Fe3C)
brittle
particles: WC
(brittle, hard)
particles:carbon
black (stiff) Aligned Random
Terminology/Classification of Composites
• Composite:
Multiphase material that is artificially made. • Matrix phase:
-- Purposes are to:
• Phase types: - transfer stress to dispersed phase
-- Matrix - is continuous - protect dispersed phase from
-- Dispersed - is discontinuous and surrounded environment
by matrix -- Types: MMC, CMC, PMC
• Dispersed phase:
-- Purpose:
MMC: increase sy, TS, creep resist.
CMC: increase KIc
PMC: increase E, sy, TS, creep resist.
Adapted from Fig. 16.1(a),
Callister & Rethwisch 8e.
-- Types: particle, fiber, structural
Reprinted with permission from
D. Hull and T.W. Clyne, An Introduction to
Composite Materials, 2nd ed., Cambridge
University Press, New York, 1996, Fig. 3.6, p. 47.
Composite Benefits
• CMCs: Increased toughness • PMCs: Increased E/r • MMCs: Increased creep resistance
Force 3 ceramics
particle-reinf 10
E(GPa) 2 PMCs
10
fiber-reinf 10 metal/
1 metal alloys
un-reinf
0.1 polymers
0.01
Bend displacement 0.1 0.3 1 3 10 30
Density, r [mg/m3]
Adapted from T.G. Nieh, "Creep rupture of a silicon-
carbide reinforced aluminum composite", Metall.
Trans. A Vol. 15(1), pp. 139-146, 1984. Used with
permission.
Fibre reinforced
(a) fracture
surface
❑ Elastic behavior of a continuous and oriented fibrous composite that is loaded in the direction of fibre alignment.
❑ It is assumed that the fibre-matrix interfacial bond is very good, such that the deformation of both matrix and fibre is the same
(an isostrain situation)
Ecl = EmVm + E f V f
or
Ecl = Em (1 − V f ) + E f V f
face sheet
adhesive layer
honeycomb
Tape lay up
Hand Lay-Up: The resin and fiber (or pieces cut from prepreg) are placed manually, air is expelled with squeegees and if
necessary, multiple layers are built up.
· Hardening is at room temperature but may be improved by heating.
· Void volume is typically 1%.
· Foam cores may be incorporated (and left in the part) for greater shape complexity. Thus essentially all shapes can
be produced.
· Process is slow (deposition rate around 1 kg/h) and labor-intensive
· Quality is highly dependent on operator skill.
· Extensively used for products such as airframe components, boats, truck bodies, tanks, swimming pools, and
ducts.
SPRAY-UP MOLDING
A spray gun supplying resin in two converging streams into which roving is chopped
· Automation with robots results in highly reproducible production
· Labor costs are lower
Filament Winding
❑ Continuous reinforcing fibers are accurately positioned in a predetermined pattern to form a
hollow (usually cylindrical) shape
❑ Fibers are fed through a resin bath to impregnate with thermosetting resin
❑ Impregnated fibers are continuously wound (typically automatically) onto a mandrel
❑ After appropriate number of layers added, curing is carried out either in an oven or at room
temperature
❑ The mandrel is removed to give the final product
Vacuum-Bag Molding
The vacuum–bag process was developed for making a variety of
components, including relatively large parts with complex shapes.
Applications are large cruising boats, racecar components, etc.
Pressure-Bag Molding
Pultrusion
Continuous fibers pulled through resin tank, then preforming die & oven to cure
▪ Continuous fibers pulled through resin tank to impregnate fibers with thermosetting resin
▪ Impregnated fibers pass through steel die that preforms to the desired shape
▪ Preformed stock passes through a curing die that is
▪ precision machined to impart final shape
▪ heated to initiate curing of the resin matrix
▪ The prepreg is stored at 0C (32 F) or lower because thermoset matrix undergoes curing reactions at room
temperature. Also the time in use at room temperature must be minimized. Life time is about 6 months if properly
handled.
▪ Both thermoplastic and thermosetting resins are utilized: carbon, glass, and aramid fibers are the common
reinforcements.
▪ Actual fabrication begins with the lay-up. Normally a number of plies are laid up to provide the desired thickness.
▪ The lay-up can be by hand or automated.