#Chapter: 10 (10) uty Dud Konjesd srcbrand Ae Mley Sis QE Sonyeonevti iusiriG\sS) CauGong sanjeodler Ce Mlanss Spores eid Geruscrapsnm GUL aye. *arligeer WyRSyPlensvt Ysrafenn aPlousiares Hue uusiru Gs uGAssrp AP SUG UpMIpSw BTL yss AG id. Glonsu sa sSH DG TOU Plowompo perp TPUGSH Uses epovid aici err ssong Glories 2 syd. oblen eipev BIWASILIIed ung yeuTEsL LUsETUOSSUUGAsiy onslev aperss ssl igescir engGwoned fevid Souiny west LT YCmnGomiGansd oud —_ webzeir ‘205 4 | [Gwengsd Gninowsact @ Garinowiscr —)_weisai 37 Gwenged Fouiy Flouiiny webaeit 5.0 GGonnGymienrsd Aoviny wedeeit Slowing 52-68 60 YGynGwrengGaned Bord weiseit Boob 60-76 7.1 ANGsne Aowiny web eeit Flouiny 72-88 82 D| Sceamispasei Boodos © Souiny Gay Gwsidoun 83-100 9.6 # Q1Mlevmiserflest usmHBeT M 01. sustreorMeuriseir: Eg:- HCI, HBr Hi Siblevid sGiblenev Saad HNO3, i 1 L H2s04 HCIO4 02. GlosireorDlevraies cir: Eg: HF i : HNO2 2 . H2s03 4 J j H3P04 lal H2C03 CH3COOH (24D SYLAavid) Re-Orenve veton ‘so # EITmBeHleot ueM see 01, cueoTe Tye: Eg: LiOH, NaOH, KOH, RbOH, CsOH Sr(OH)2, Ba(OH)2 Na2co3 02. Cloctrasmypnuascit. Eg- Mg(OH)2 NH40H NaHCO3 (sodium bicarbonate, a4UéGemLm) _ eso __ Chemical Calculation MrM.VIITHARAN, Bscrape+ Burau, (0 SUSTESTTD LWISSTLUBSE ug sir Nomis seSlonawr ge SM puss aie guid UUNSTLIDS ORGLID. GDS MLD ULARETLIGSH Cig ot Gants eaS\ener LUUSETIGIS Upig usr) 216s Gunes Bester Bleu UnsG sss LLug ctr roongsed Qebwo(gysoner gop art wguires wiser 1D LALICOTLIBISS apig tit. GiochemBleub LUST UG KE use claanee Geib ugeener LUSETBISS upyunsy. *AWUMLUIDE CEmeuwirer BWajFar © USTeormEei ot aera O3 GQ] EE” |E[ omagaate KI eorre o2 er for safe volume 03 wera Bly pipetting [2] measuring | calibration 04) srLig. \ rations 05) Glausrener lm womiMletr gL) ‘alibration 06) saLdYy& Gbhonou c. burette 07) Ysored 01) ( 08) ssrrraiéé) 07 — volumetric flask 02 vedker ‘tant O06 * HereaMlulerred JeTaNs Figs MSS GEOMIS HeoreusTrey 0.05 cm3 1D. Qs! Sera Ue A GHHI NOAM HG Hietluesr & eoreusTey eh Chemical Calculation MrM.VIITHARAN, Bscrape# BU NaOH gg LMETLOSH HCl sir Qerlones oyHlesad ACID-BASE TITRATION A process through which the concentration of either acid or base is determined. NeoH Gp Add few drops of ¥-=10/cm indicator like Phenolphthalein, M=0.5M [ee soend = a Cho: Note down initial volume of base. ca *30.0 cm3 HCl 2 & GOsvauudlonyir o Hao #2 geil Coors be (senye60 lp wpmIs sMeserluGio) & Start adding NaOH. Untill colour changes. & Note down the final volume of base. _> V = 30cm? & Find the volume of NaOH used in... ae m3 mea] Oem? Gs ory Copy, Glascrenar flo omer gsc Cine ensued + gieraShled Qayslay Gipsflfigs NaOH ep OSB) Sipser aubL eunFlenLss GMI Qlesireirerrev (10 em3) + guoraiuioG bg) gisflessaflwines NaOH Cajgg oieusmonN sso MD BSDITEEY aie ail Downs wid Gung HWUVIGEOU Blois) soraNudesr * ppp GINS amndcone elses Asnerote GO ems) * aunt 2 Ssh eure 6 auefl 550 BOOMS HVSST TITRATION CALCULATION Find the concentration of HCL. NaOH + HCl —> NaCl + H2,0 20cm} 0.5M NaOH : HCl 131 == Known Concentration NaOH 20cm3 1000 No.of moles = concen x vol = 0.02 dm? = 0.5M x 0,02 dm? = 0.01 mol od Biemsgy HC! sir SrdElws NaOH Geir sareustensu Unknown Concentration HCI 3 30cm? = 0.03 dm? 1000 No.of moles = 0.01 mol 0.01 mol Cone. = 0.03 dm? |= 0.3333 Chemical Calculation MnM.VIITHARAN, Bserape# lus HC! go UWISoTUG)SH) Na2CO3 Q)sir Clepilencu sinhs6v Acid/ Base Titrations Hydrochloric Acid. -v__ Sodium carbonate Viz 10.00 em3 ——> C=0.1 moldm3 = He Indicator:- Methyl Orange Loehrer — a,c0, 10.0 cm3 * 10.0 cm3 Na2003 gy sald Ss GGonauwener eH Sd +2 ge Coens Broek ony espe) Geen Bio omer HL igsir Guns enoussssd (Sonmecv oGpercit Hones sirevorLuGo) * sores pe uso ola 5H) ASOT STU uTALSM Is GIST Glasmeitansi (10 cm3) + gereAuiesl eis) Syl 5g)oMusres HCI go Cojss1 Siesmeofld,s560 * geen s)ps ‘Banja Soyer Glawwerssi Hp wompid Cungy Hlusudluenus Gps: giares os oi oundlion ss GB Qiasreitaney (20 em) + QYTOU Q\niB) euALyeeserhed Q)e5sbs) Na2CO3 2 1 obr sal HCl Glebr seoraueseu FOMSHOV . . . HOM SEBVSEET Na,CO,(s) +2HCI(aq) —} 2NaCl(aq) + H.0 (I) + CO,(g] v HCI = VF-Vi =20.00 ¢m3-10.00 em? = 10.00 Crm3 "wel = ev =0.1moldm™* 10.00% 10-3 dm3 =1,00x 10-3 mol Na2CO3:HCl=1: 2 & Na2CO3 Glsir epsd = 0.5x 10-3 mol C=nVv c Na2CO3 @)est Gleniley = 0.5x10- 3 mol /10 x 10- 3dm3 = 0.05M Chemical Calculation MrM.VIITHARAN, Bscrape# Na2CO3 29 HCI S460 BWIA id CLursy Mesteu(thLo B)iyevor(h) Lig seth ov sree L Haw. 'bH 14 L Step:Na,CO,(oq) + HCl (aq) > NaHCO: (aq}+ NaCi{oq) + CO, (g)+ H,0 (!) * Closnss6v Cle G,eer STL p6MW Na2CO3 QMS Capsa) Hulse Cursy Step-1 , Step-2 QS Aw Q\ysvorG) Srass rus CHL Hla ips Mester iy Lo@pEcir Hint Clevo E5esiT HUOWITE MMI. SS TOUS| STLIg HOwmiMmsensses BrTEsM NG (GD. Na,cO, + 2HCIM9 co, + H,0 + 2NaCl + Mars poSleir aml igsnw Na2C03 Gine Coss Hulse. Curgy Steps] OG Flul sree Maqpiog, @:coereu Ciesla Bow i eos DMD. AFTag) srLe Amonhosoogé amok NEG. :Na;CO,(aq) + HCl (aq) "3 NaHCO, (ag}+ Naci(ag) 0 volume of add added (m3) | Chemical Calculation MrM.VIITHARAN, Bscrapeut Na2C03(aq)-— i Phenolphthatein 6 4 Methyl orange 2 °o 5 10 15 20 25 30 35 40 45 $0 HCl(aq) -— Volume of 0.1 mol da base added/cm? FA wate | HCI senmeeney Na2C03 sents oTed HUILILUE IG NEsornigsoilesr, longed Glaidw eyereh srLysoner UWETLGS Som. QPWUVITS cress lp LILETLGSHU Lig soy. Syevor() Lig Sore LD HBL Sy BME EOpDMIC! OLipdy Mesrawry seg E\mLOMPM Benge aaron N10. hc Na,CO; + 2HCI Ms’ Co, + H,0 + 2NaCl PN ote:- THHSCUTE STUGETH MID SHlevid lens wire 2 iret CUMS) (YHOoOTasS STHA COZ urrujsmen al Hans Go. © Busty 01. 10m! 0.2moldm? Na2CO3 —ssmysena 0.2moldm? HCI ssngasomd Pundiugiis, 20m! Spomordurr gy safe NaxCOs rath HCI jot ©. NaOH , NaCl asius supaisin 90, Posiopps 4g Pys2pOSainn's gy 100M! sensed Bowing). oubsonss00 25ml w PuaBiiuypiy 0.1 MHC! sensed 40m! Gpomouinn’r a) ssnsasted NaOH oi QaySoy uni? b) NaOH st fiesta ung? oy ©) AG iain Posing Psd » cape gniomnist grnrgisipis uns? 03. 5.3g Subp NarCO3 gh songistun.G 25Ocm? songsd ysscun'r g) DPisonsssO 25cm? Gone ppprs pOPeraunss gi HClet 20cm? Cpenauiun'r gi Hop HCI ot QsyGay wry? 04, 5.72g BGajpghu Na2COs.10H20 ged senpénitun 250cM? wonssad gpirniun' a1 Dinonsseed 25cm? Gener ypprs soPonaunés 1M HCI si ssreusrey ung? 08. 99 gayi GOsnaniiggidt 0.1MNa2COs sempre 20m! aerargy Dads sinsiied Doybss 0. Pa Mgrs CrisiuGseipss Tsing sppiuisedd Ppundpsemp sup, Gpomoumer ouiropflet memes anoxic, |. SGarnipalst omy. uusiudAgndsuTI Il, methyl orange'smy. uusiugésnbGur3y oo aiaoron Fausto um gi? Chemical Calculation MrM.VIITHARAN, Bscrape